3128 results about "Superalloy" patented technology

A component (202) is disclosed that includes a body (206) and an additive manufactured (AM) metal mass (200) that includes a first section (292) and a stress relief section (294). The stress relief section (294) includes a porous region (300) having a porosity in which an open spatial volume accounts for 2% to 50% of the total volume of the stress relief section (294). The stress relief section (294) has a smaller at least one of thermal conductivity, tensile strength, ductility, and fatigue strength than the first section (292). A braze material (310) couples the AM metal specimen block (200) to a specimen block opening (204) in the body (206). The stress relief section (294) creates a low stress zone in the metal specimen block (200), which can be located near or adjacent to a high stress zone. The stress relief section (294) reduces residual stress in the metal sample block (200), which reduces related challenges to couple the metal sample block (200) to the body (206) of the component (202), particularly in the case of the use of superalloy materials.

A component including a body, and an additively manufactured (AM) metal coupon including a first section and a stress-relief section, is disclosed. The stress-relief section includes a porous region having a porosity between 2% to 50% open space volume to total volume of the stress-relief section. The stress-relief section has at least one of thermal conductivity, tensile strength, ductility, or fatigue strength less than first section. A braze material couples the AM metal coupon to a coupon opening in the body. The stress-relief section creates a low-stress zone in the metal coupon that can be located near or adjacent to a high-stress zone. The stress-relief section reduces residual stress in the metal coupon, which reduces the related challenges of coupling the metal coupon to the body of the component, especially where superalloy materials are used.

The invention relates to a preparation method of a carbide ceramic reinforced high-temperature alloy, and belongs to the technical field of additive manufacturing. The preparation method comprises the following steps: taking a high-temperature alloy as a matrix, and then adding carbide ceramic to prepare the composite material; the method comprises the following steps: mixing carbide ceramic powder with high-temperature alloy powder; the carbide ceramic is TiC, HfC or NbC; the high-temperature alloy is a CoNiCrW series high-entropy alloy or a NiCrWMo series medium-entropy alloy; the particle size of the carbide ceramic powder is 40-80 microns; the particle size of the high-temperature alloy powder is 40-90 microns; the composite material is prepared through an additive manufacturing process. The W element in the high-temperature alloy powder diffuses towards the surface of the carbide ceramic to form a thin interface layer, so that the interface bonding force between a matrix and the carbide ceramic phase can be ensured, the compatibility between the high-temperature alloy matrix and the carbide ceramic is improved, the interface cracking risk is effectively reduced, and the metallurgical quality of a composite material is greatly improved.

The invention relates to the technical field of intelligent control, and discloses a self-adaptive temperature curve control system for high-temperature alloy vacuum casting, which comprises a sensing module, a control module and a control module, and is characterized in that the sensing module acquires multi-point temperature information and preprocesses the information to obtain temperature distribution in a furnace; the acquisition module obtains vacuum environment parameters. The simulation module establishes a three-dimensional dynamic coupling model based on heat conduction, radiation, convection and phase change heat effect, and obtains a real-time temperature evolution prediction result. The generation module obtains a target temperature curve of the corresponding stage. The prediction control module collects a real-time temperature evolution prediction result and a target temperature curve, deviation calculation and trend analysis are carried out, and a heating power and cooling flow control instruction is generated. And collecting product feedback errors and carrying out self-learning correction on prediction model parameters to obtain an optimized control output result. The control and optimization of the high-temperature alloy vacuum casting temperature field are realized, and the structure uniformity of castings and the quality stability of finished products are improved.

The invention discloses a water jet assisted laser-electrochemical combined machining method which comprises the following steps: pre-treating a nickel-based superalloy to be machined, and fixing the nickel-based superalloy on a machining table; a machining area is positioned, parameters of water jet assisted laser and electrochemical machining are set, so that during laser machining, water jet cools the machining area and removes slag, and an electrolyte does not affect a non-machining area; meanwhile, water jet assisted laser and electrochemistry are started to machine the nickel-based superalloy, and the machining state is monitored in real time; and after composite machining is completed, the nickel-based high-temperature alloy is cooled. By accurately setting laser, water jet and electrochemical machining parameters, the efficient synergistic effect of the laser, water jet and electrochemical machining parameters in a machining area is ensured, the machining precision and the surface quality are effectively improved, the defects of heat affected zones, microcracks, recast layers and the like are remarkably reduced, and the machining quality is improved. And meanwhile, corrosion to a non-machining area is reduced through the mode of spraying the electrolyte in a pulse mode.

The invention belongs to the technical field of powder metallurgy, and relates to a preparation method and application of a high-performance isotropic GH4698 drum piece, prepared GH4698 high-temperature alloy powder with the particle size of 53-250 microns is loaded into a prefabricated sheath under the condition that the vacuum degree is smaller than or equal to 1 * 10 <-3 > Pa, after treatment is conducted 2-3 times through a multi-cycle hot isostatic pressing process system, furnace cooling is conducted, and the high-performance isotropic GH4698 drum piece is obtained. And machining is adopted to remove the sheath to obtain a GH4698 drum piece blank in a powder metallurgy state, and a solid solution and aging heat treatment process is adopted for the drum piece blank, so that the high-performance isotropic GH4698 drum piece can be obtained. According to the preparation method, the yield of the GH4698 drum part can be effectively increased, the GH4698 drum part with high performance and isotropic performance can be obtained by effectively improving the grain size and distribution of the part, the carbide distribution and the internal stress state of the part, the utilization rate of an alloy material is promoted to be increased, the stability of the production process is improved, and in addition, the yield of the GH4698 drum part is improved. All mechanical properties of the prepared GH4698 drum piece meet the performance requirements of a drum shaft for a novel aero-engine.

The invention belongs to the field of high-temperature alloy manufacturing, and particularly discloses a low-segregation nickel-based high-temperature alloy, a preparation method of the low-segregation nickel-based high-temperature alloy and a segregation defect control method. The segregation defect control method comprises the steps that the melting speed of the nickel-based superalloy in the steady-state melting stage of vacuum consumable smelting is determined on the basis of the content of segregation-prone elements in the nickel-based superalloy; based on the determined melting speed of the steady-state melting stage, the filling ratio adopted for vacuum consumable smelting of the nickel-based superalloy is determined; and carrying out vacuum consumable smelting on the nickel-based superalloy according to the determined filling ratio and the determined melting speed in the steady-state smelting stage. According to the segregation defect control method, black spots, white spots and surface quality of the cast ingot in the nickel-based superalloy vacuum consumable smelting process can be effectively controlled.

The invention relates to a heat treatment method for additive manufacturing of a nickel-based superalloy, and relates to the technical field of additive manufacturing. The heat treatment method comprises the following steps that the additive manufacturing nickel-based superalloy is placed at the first temperature, and first-step stress relief annealing treatment is carried out; and then the temperature is increased to a second temperature for second-step stress relief annealing treatment, and after cooling, the additive manufacturing nickel-based high-temperature alloy subjected to stress relief annealing treatment is obtained. The first temperature is 850-890 DEG C, and the second temperature is 900-950 DEG C; carrying out solution treatment on the additive manufacturing nickel-based superalloy subjected to the stress relief annealing treatment to obtain the additive manufacturing nickel-based superalloy subjected to the solution treatment; and aging treatment is conducted on the additive manufacturing nickel-based superalloy obtained after solution treatment, and the additive manufacturing nickel-based superalloy obtained after heat treatment is obtained. The method is mainly used for improving the volume fraction of the gamma'phase of the additive manufacturing nickel-based superalloy, obtaining the gamma 'phase with high cubic degree and proper size, and eliminating cracking and recrystallization caused by residual stress.

The invention relates to the technical field of machine tool control, in particular to an electrolysis arc milling composite numerical control machine tool control method and system for case machining. The method comprises the steps that firstly, an electrolyte supply system, an electric arc generation system, a high-pressure water jet system and an ultrasonic vibration system are started in sequence, operation data are obtained, and rough machining parameters are calculated; in the rough machining process, the machining gap, the discharging state and the temperature are monitored in real time and compared with standard parameters, and correction values are calculated; after rough machining is completed and the electrolytic arc milling device is detached, the feeding speed and the spindle rotating speed are adjusted according to the correction value, and finish machining parameters are obtained; by electrolyzing electric arc corrosion materials and combining the synergistic effect of high-pressure water jet and ultrasonic vibration, efficient removal and accurate control of super-difficult-to-machine materials such as titanium alloy and high-temperature-resistant alloy in the machining process are achieved, and the machining efficiency and quality are improved.

The embodiment of the invention provides a nickel-based superalloy yield strength prediction model, a modeling method, a device and a system. The modeling method comprises the following steps: step 1, simplifying a gamma'precipitation strengthening model formula, and establishing a probability-related simplified gamma 'precipitation strengthening model; 2, according to the grain boundary strengthening contribution, the solid solution strengthening contribution and the simplified gamma'precipitation strengthening model, a yield strength model used in component design of the nickel-based high-temperature alloy is established; 3, temperature variables and parameters are introduced, and a novel yield strength model suitable for the full temperature range is established according to the yield strength model; 4, obtaining the coefficient of the novel yield strength model according to the yield strength data in the nickel-based superalloy component design; and 5, obtaining a yield strength model formula of the nickel-based superalloy according to the coefficient and the novel yield strength model. The method is suitable for predicting the yield strength of the nickel-based superalloy in a full temperature range.

The invention relates to a crack repairing method for an additive manufacturing nickel-based high-temperature alloy part, and relates to the technical field of high-temperature alloys. According to the main technical scheme, filler powder and solder powder are adopted for conducting crack repairing on the additive manufacturing nickel-based high-temperature alloy part; wherein the solder powder comprises the following chemical components in percentage by weight: 11.0 to 17.0 weight percent of Cr, 5.0 to 9.0 weight percent of W, 1 to 4 weight percent of B, less than or equal to 0.06 weight percent of C, less than or equal to 0.1 weight percent of Co and the balance of Ni; wherein the filler comprises the following chemical components in percentage by weight: 6 to 10 weight percent of Cr, 6 to 10 weight percent of Co, 6 to 10 weight percent of W, 0.5 to 3 weight percent of Mo, 3 to 6 weight percent of Al, 0.5 to 2 weight percent of Ti, 3 to 6 weight percent of Ta, less than or equal to 0.2 weight percent of C, less than or equal to 0.1 weight percent of B, less than or equal to 2 weight percent of Hf and the balance of Ni; the additive manufacturing nickel-based superalloy comprises the following chemical components in percentage by weight: 6 to 10 percent of Cr, 6 to 10 percent of Co, 6 to 10 percent of W, 0.5 to 3 percent of Mo, 3 to 6 percent of Al, 0.5 to 2 percent of Ti, 3 to 6 percent of Ta, less than or equal to 0.2 percent of C, less than or equal to 0.1 percent of B, less than or equal to 2 percent of Hf and the balance of Ni. The method is mainly used for solving the problem of repairing and remanufacturing the cracks of the additive manufacturing nickel-based superalloy part, and has important application value.

The invention relates to the technical field of intelligent detection, and discloses a high-temperature alloy casting size on-line detection system based on machine vision, and the system comprises an imaging fusion module which collects image data of a high-temperature alloy casting, carries out the pixel-level registration of infrared image data and visible light image data, and generates a multispectral fusion image. The feature extraction module performs temperature distribution analysis and brightness feature extraction based on the multispectral fusion image, generates an edge confidence map and extracts a feature point set. And the calculation module performs weighted fitting on the feature points according to the feature point set to obtain thermal state size parameters. And the thermal compensation module performs thermal compensation and geometric correction on the thermal-state size parameters to obtain cold-state size parameters. And the judgment module carries out comparison to judge whether the casting is a qualified casting. According to the invention, stable imaging and accurate registration in high-temperature radiation and strong reflection environments are realized, and the detection efficiency and the size control level of the high-temperature alloy casting are improved.

The invention discloses a preparation method of a ceramic particle reinforced high-temperature alloy wear-resistant coating of a boiler water-cooled tube. The preparation method comprises the following steps: carrying out roughening treatment on a matrix; the prepared NiCr powder and ZrB2 powder are subjected to high-energy ball milling and mixing, drying is conducted after treatment, and dried NiCr-based composite powder is obtained; niCr-based composite powder is sprayed through atmospheric plasma, and a composite coating with the thickness ranging from 200 micrometers to 300 micrometers is deposited on the roughened surface of the base body; the composite coating is subjected to remelting treatment, and a remelting coating is formed on the surface of the base body; wherein the matrix is 304 stainless steel, and the composition proportions of the NiCr powder and the ZrB2 powder are as follows: 80-99 wt% of NiCr and 1-20 wt% of ZrB2 respectively; by means of the method, the wear resistance of the coating is remarkably improved, and controllable deposition of the high-performance ceramic particle reinforced high-temperature alloy wear-resistant coating is achieved.

The invention relates to the technical field of high-temperature alloy powder metallurgy, in particular to a preparation method of a high-strength cellular distribution gamma'phase high-temperature alloy, which comprises the following steps: preparing high-temperature alloy powder; the prepared high-temperature alloy powder is loaded into a first sheath, and the first sheath is vacuumized and sealed; carrying out preheating treatment on the first sheath; the high-temperature alloy powder in the first package sleeve is dispersed; opening the first sheath, and transferring the high-temperature alloy powder from the first sheath into a second sheath through a charging bucket under a vacuum condition; performing hot isostatic pressing treatment on the second sheath filled with the powder to obtain a first workpiece; cooling the first workpiece to obtain a second workpiece; removing a second sheath outside the second workpiece to obtain a blank, and performing heat treatment on the blank to obtain a target alloy; the powder metallurgy technology is utilized, the preparation technology is adjusted, a specially-distributed gamma'phase is formed in the alloy, and therefore the tensile strength and the endurance strength of the alloy are improved.

The invention relates to the technical field of alloys, in particular to a nickel-based high-temperature alloy and a preparation method thereof. The invention provides a nickel-based high-temperature alloy which comprises the following components in percentage by mass: 0.04% to 0.06% of C, 15.0% to 15.04% of Co, 10.08% to 10.13% of Cr, 5.74% to 5.81% of W, 3.30% to 3.34% of Mo, 3.73% to 3.78% of Al, 3.68% to 3.73% of Ti, 1.77% to 1.81% of Nb, 0.20% to 0.40% of Hf, 0.010% to 0.014% of B, 0.008% to 0.01% of Zr, 0.002% to 0.006% of Mg and the balance of Ni. Compared with an FGH4097 alloy, the nickel-based high-temperature alloy disclosed by the invention has more excellent comprehensive performance by adjusting components.

The invention provides a novel model and a novel method for component design of a high-flux nickel-based superalloy for additive manufacturing based on multi-objective optimization and a novel alloy, and relates to the technical field of component design of nickel-based superalloy and additive manufacturing. The invention aims to design a novel K438 alloy with excellent mechanical properties at 850 DEG C by taking the K438 alloy as an example, and the novel K438 alloy has lower crack sensitivity. The method is mainly characterized in that the influence of solidification cracks, liquefaction cracks and solid cracks is comprehensively considered, and a comprehensive crack sensitivity (CCS) model is established; the CCS values and the yield strength of 850 DEG C of tens of thousands of alloys are obtained through high-flux thermodynamics calculation by combining a CCS model and a high-temperature yield strength model, and the Pareto alloy is automatically optimized by utilizing a self-written Python script. According to the method, a data basis can be provided for design and production of the nickel-based high-temperature alloy for additive manufacturing, and a new theoretical basis and method are provided for development of the high-strength printable nickel-based high-temperature alloy.

The present application belongs to the technical field of superalloys. Disclosed is a preparation method for a nickel-based superalloy. The present application solves the problem of a nickel-based superalloy in the prior art making it difficult to satisfy the comprehensive requirements of a component for both a long alloy endurance life and a low crack propagation rate. The preparation method comprises: step 1: performing smelting, so as to obtain a cast ingot; step 2: subjecting the cast ingot to a homogenizing heat treatment, wherein the homogenizing heat treatment comprises two sections of heat preservation; and after the second-section heat preservation, performing furnace cooling to 1000+ / -10°C or below, and then performing discharging and air cooling; step 3: preparing a bar blank and a forging piece by means of forging; step 4: performing a solution treatment; and step 5: performing a stabilization and aging treatment, so as to obtain a nickel-based superalloy. The nickel-based superalloy prepared by means of the method of the present application has a high strength, good low-cycle fatigue performance, a low crack propagation rate and excellent comprehensive performance.

The invention belongs to the technical field of hydrometallurgy, and particularly relates to a method for separating metal molybdenum and rhenium from a nickel-based superalloy electrochemical dissolving solution, which comprises the following steps: providing the nickel-based superalloy electrochemical dissolving solution, and adjusting the pH value to 0-1.5; the modified MTS9570 resin is used for adsorbing the nickel-based superalloy electrochemical dissolving solution to obtain a molybdenum-absorbed solution, then a sulfuric acid solution is used for leaching, then an ammonia water solution is used for desorption, and a molybdenum desorption solution is obtained; adjusting the pH value of the molybdenum-absorbed solution to 0.5-1.5, adsorbing with modified MTA1721 resin, leaching with a sulfuric acid solution, desorbing with an ammonium sulfate and ammonia water mixed solution, and desorbing with an ammonia water solution to obtain a second-stage rhenium desorption solution; and the molybdenum desorption solution and the second-stage rhenium desorption solution are subjected to evaporation concentration, crystallization, recrystallization and high-temperature hydrogen reduction respectively, and metal molybdenum and rhenium are obtained. According to the method for separating rhenium and molybdenum from the nickel-based high-temperature alloy electrochemical dissolving solution, the rhenium and molybdenum recovery rate and rhenium purity are improved, and the process is simple, convenient and practical.

The invention discloses a method and device for predicting the fatigue life of a high-temperature alloy vacuum electron beam welding structure, and belongs to the technical field of aero-engines. The method comprises the following steps: acquiring fatigue experiment data of a target high-temperature alloy standard sample; extracting the maximum area of an initial defect, a defect shape factor and crack source position information; obtaining a stress intensity factor range considering defect morphological characteristics and a fatigue crack propagation threshold value of a material structure containing initial defects, and correcting a damage tolerance theoretical formula to obtain simulation data; fatigue test data and simulation data are fused to form an initial data set, a fatigue limit is calculated and expanded to the data set, the expanded data set serves as input, training is conducted through a support vector regression method, hyper-parameters are determined through Bayesian optimization, and a fatigue life prediction result of the high-temperature alloy vacuum electron beam welding structure is output. The method provided by the invention can well consider the influence of different morphology defects on the fatigue performance of the welded joint.

The invention relates to a data-driven deformation nickel-based superalloy multi-objective performance reverse design optimization method, which belongs to the technical field of metal material design and development, and comprises the following steps: calculating a stable high-strength deformation nickel-based superalloy system based on a first principle, and on this basis, calculating a deformation nickel-based superalloy system; constructing a deformed nickel-based superalloy component design space based on the knowledge of the nickel-based superalloy field; based on a deformed nickel-based superalloy component design space, the deformed nickel-based superalloy component design space is reduced by adopting an empirical formula in combination with thermodynamic high-throughput calculation to obtain the reduced deformed nickel-based superalloy component design space, and based on the reduced deformed nickel-based superalloy component design space, based on machine learning and a genetic algorithm, the deformation nickel-based superalloy component design space is obtained. And a deformed nickel-based high-temperature alloy reverse design model is established, and the deformed nickel-based high-temperature alloy with the target performance is screened. Compared with the prior art, the oriented development method for the high-strength and high-toughness nickel-based high-temperature alloy is achieved by fusing cross-scale calculation, domain knowledge constraint and machine learning reverse design.

The invention discloses a precise etching method for a nickel-based high-temperature alloy core plate micro-channel, and belongs to the field of metal chemical etching. According to the method, the mask pattern is optimized, the formulas of the etching liquid and the anti-lateral etching liquid are accurately designed, key parameters such as the etching temperature, the etching time and the spraying pressure are strictly controlled, the anti-lateral etching liquid is designed to form the protective film layer on the side wall of the groove, the lateral etching phenomenon is inhibited by combining the process of alternately spraying the etching liquid and the anti-lateral etching liquid, the etching efficiency and stability are improved, and the etching quality is improved. And meanwhile, the surface quality is optimized, high-precision etching processing of the nickel-based high-temperature alloy core plate micro-channel is realized, and the lateral erosion phenomenon caused by isotropy of wet etching is inhibited.

The invention discloses a modularized multipurpose gas flow heat exchange experiment section. The experiment section comprises a cooling ring cavity assembly, an experiment section heat exchange inner pipe, an inlet and outlet gas guide pipe, a heat insulation layer, a wall surface temperature thermocouple, a thermocouple fixing curved surface, an outer ring cavity fixing lantern ring, a fixing bolt and a flexible sealing material. An experiment section heat exchange inner pipe is a high-temperature-resistant alloy long pipe, working medium gas and a cooling medium are arranged inside and outside the pipe respectively, and a nanometer heat insulation layer and a gas circulation guide pipe are arranged in the two ends of the inner pipe so as to reduce unnecessary gas heat exchange; the wall surface temperature measuring thermocouple is fixed on the pipe wall in a silver brazing manner to realize accurate measurement of the wall surface temperature; in addition, the cooling ring cavity assembly is composed of an upper piece and a lower piece which are connected in a flange mode and filled with flexible materials for sealing. The experimental section can be used for carrying out flow heat exchange research on heating or cooling working conditions according to requirements in the use process, and meanwhile, each component is modularly mounted to realize flexible replacement and change, so that the reliability and the expandability are greatly improved.

The invention provides a high-temperature alloy for manufacturing a nickel-copper alloy hot extrusion die, which is characterized by comprising the following components in percentage by weight: 0.02 to 0.08 percent of C, less than or equal to 0.15 percent of Si, less than or equal to 0.15 percent of Mn, less than or equal to 0.01 percent of P, less than or equal to 0.01 percent of S, 14.0 to 17.0 percent of Cr, 7.5 to 9.5 percent of Mo, 2.2 to 2.6 percent of Nb, 1.0 to 1.6 percent of Al, 2.2 to 2.8 percent of Ti, 0.005 to 0.015 percent of B, 0.01 to 0.05 percent of Zr, 21.0 to 24.0 percent of Fe and the balance of Ni. The preparation method of the alloy comprises the following processes: firstly, alloy raw materials are subjected to vacuum induction melting and then cast into ingots, then electroslag ingots are obtained through electroslag remelting, then the electroslag ingots are subjected to multi-heating-number forging, and then heat treatment is carried out. The highest use temperature of the alloy reaches 1000 DEG C, and the oxidation rate at 1000 DEG C is as low as 0.08 g / m < 2 >. H; at the temperature of 650 DEG C, the tensile strength reaches 1000 MPa, the yield strength reaches 850 MPa, the fatigue strength is higher than 400 MPa, and the lasting time of the load of 700 MPa reaches 80 h; the service life of a nickel-copper alloy hot extrusion die made of the alloy can reach 25000 times.

The invention discloses a nickel-based superalloy microstructure image diffusion generation method, system and equipment, a medium and a product, and relates to the field of superalloy microstructure reconstruction. The method comprises the following steps: gradually diffusing an original training image into a Gaussian noise-like image by adopting a forward diffusion process of a denoising diffusion generation network, and gradually denoising in a reverse diffusion process to obtain a nickel-based high-temperature alloy microstructure-like image; adopting a geometric structure feature loss penalty mechanism to obtain a trained denoising diffusion generation network based on the geometric feature difference value; and adopting a back diffusion process of the trained de-noising diffusion generation network to obtain a virtual microstructure image, and screening to obtain a final microstructure image. According to the method, the problems that data samples are scarce, and acquisition of the alloy internal microstructure is tedious, time-consuming, high in cost and the like are solved, similar microstructure images are visually represented, and intelligent generation of the virtual microstructure is achieved.

The invention provides an ultrasonic nonlinear static parameter monitoring method for creep damage of a high-temperature alloy component, and particularly relates to the technical field of material monitoring. The method comprises the following steps: S1, arranging an ultrasonic probe; s2, determining the emission frequency of the excitation end; s3, respectively calculating an incident angle and an emergent angle of the signal; s4, exciting fundamental frequency ultrasonic waves; s5, receiving the signal and uploading the collected signal to a cloud processing system; s6, carrying out fast Fourier transform and calculating a nonlinear parameter of a static component; s7, establishing a linear relation with creep time, and constructing a creep damage linear quantitative model; s8, calculating a static component nonlinear parameter of the healthy sample; and S9, completing quantitative analysis of the damage by using nonlinear parameters. The method solves the problems that a traditional nonlinear ultrasonic method depends on second harmonic nonlinear parameters, phase velocity matching conditions in the middle and later periods are seriously damaged, response shows a nonlinear trend, unique creep time cannot be determined according to the parameters, and then the unique damage state cannot be determined.

The invention discloses a nickel-magnesium intermediate alloy for a high-temperature alloy and a preparation method thereof.The nickel-magnesium intermediate alloy is composed of, by mass, 4%-50% of Mg and the balance Ni and inevitable impurities, and the method comprises the steps that firstly, electrolytic nickel and magnesium ingot raw materials are selected, cut and polished, and ingredients are calculated, weighed and subpackaged; 2, the raw materials are put into a crucible of an induction melting furnace to be smelted, and alloy melt is obtained; and thirdly, a steam suction filtration system is started, the alloy melt is poured into a cast iron ingot mold, and the nickel-magnesium intermediate alloy ingot is obtained after cooling. A proper amount of inert gas is introduced in the vacuum induction smelting process, smelting and pouring in a micro-negative pressure state are guaranteed, impurity introduction in the smelting and pouring processes is reduced by controlling smelting process parameters, meanwhile, gasification loss of the magnesium element is reduced, and the high-strength magnesium alloy with uniform components and high strength is obtained. The nickel-magnesium intermediate alloy is high in cleanliness and low in content of harmful gas elements and inclusions, and is suitable for the field of downstream high-temperature alloys.

The invention discloses a high-strength high-temperature alloy and a preparation method thereof. The high-strength high-temperature alloy comprises a high-temperature alloy matrix and rare earth oxides dispersed and distributed in the high-temperature alloy matrix. The high-temperature alloy matrix is GH4169, and the high-temperature alloy matrix is made of The rare earth oxide is one or two of La2O3 and Ce2O3, the particle size of the rare earth oxide is 50-500nm, and the total adding amount of the rare earth oxide is 0.02-0.03% of the mass of the alloy; the preparation method of the high-strength high-temperature alloy comprises the following steps: (1) preparing rare earth oxide particles; (2) charging and smelting rare earth oxide particles and alloy raw materials in a vacuum induction furnace, and casting into ingots after the components are qualified; (3) electroslag remelting: adding analytically pure rare earth oxide into a slag system; and (4) the electroslag ingot is subjected to homogenization, forging and solid solution aging treatment, and then the alloy is obtained. According to the method, the strength and plasticity of the high-temperature alloy are improved.

The invention relates to the technical field of rolling of high-temperature alloy ring forgings, particularly discloses a preparation method of an ultra-large-specification ring piece capable of resisting the temperature of 800 DEG C, and solves the problems that due to the fact that the size of the ring forgings is increased through alloy, cracking is prone to occurring, and the structure property control difficulty is large. The preparation method comprises the following steps that an alloy bar is cut and blanked according to the feeding weight of the ring forge piece, upsetting and punching are conducted on the bar after heat preservation treatment is conducted on the bar at the temperature of 1000-1150 DEG C, trestle chambering is conducted on a cake blank after heat preservation treatment is conducted on the cake blank at the temperature of 1000-1150 DEG C, rolling is conducted after heat preservation treatment is conducted on the cake blank at the temperature of 1000-1150 DEG C, and an alloy forge piece blank is obtained; and then standard heat treatment is conducted, and finally the GH4586 alloy ring forge piece with the diameter ranging from 400 mm to 1600 mm is obtained. According to the preparation process, the cracking tendency of the ring forge piece is greatly reduced, a uniform structure is obtained, and the comprehensive performance of the GH4586 large-size ring forge piece is guaranteed.

The invention relates to the technical field of additive manufacturing, and discloses an additive manufacturing hot-crack-free precipitation strengthening high-temperature alloy and a preparation method thereof.The method comprises the steps that a laying layer is divided into a plurality of parallel scanning strips according to the preset translation direction and the scanning strip interval, strip type scanning is conducted in a laser autorotation and translation motion coupling mode, and the high-temperature alloy is obtained; molten pool disturbance is remarkably enhanced, periodic shear fracture of the tip of dendritic crystal is achieved, epitaxial growth of columnar crystal is broken, grain equiaxalization is achieved, and anisotropy is weakened; in addition, laser scanning is a high-speed scanning strategy with the translation speed larger than or equal to 1500 mm / s, a shallow molten pool is formed through regulation and control of the high scanning speed, surface tension in the shallow molten pool is utilized, convection in the molten pool is enhanced, dendritic crystals are refined, columnar crystals in the high-temperature alloy are further reduced, and anisotropy of mechanical properties is remarkably eliminated; and the transverse strength and creep resistance at high temperature are improved. The isometric crystals can effectively prevent cracks from expanding in the orientation direction of the columnar crystals, and the fatigue life and the damage tolerance are remarkably prolonged.

The invention provides nickel-based superalloy powder and a preparation method and application thereof, nickel-based superalloy and a preparation method and application thereof, and relates to the technical field of alloys. The preparation method comprises the following steps: smelting a nickel-based high-temperature alloy raw material to obtain alloy liquid; and the alloy liquid is atomized and crushed, and the nickel-based high-temperature alloy powder is obtained. Compared with traditional nickel-based superalloy preparation, aluminum nitride and titanium nitride raw materials are added in the nickel-based superalloy powder preparation process, aluminum nitride and titanium nitride are separated out in the alloy powder preparation process to form a strengthening phase, and the tensile strength and the elongation at break of the nickel-based superalloy can be improved; and particularly, as a main raw material for additive manufacturing of high-performance metal components, the material has a very good application prospect.