1704 results about "Syngas" patented technology

The invention discloses a production method and a production device of an energy-saving sustainable aviation fuel, and the production method comprises the following steps: S1, adsorbing carbon dioxide in air by using an adsorbent, desorbing through high-temperature carrier gas, and cooling and compressing the desorbed carbon dioxide; s2, carbon dioxide and deionized water are preheated and then electrolyzed, and synthesis gas and oxygen are generated; s3, after the synthesis gas is compressed, performing Fischer-Tropsch reaction to generate a mixture of Fischer-Tropsch oil wax, light hydrocarbon and water, cooling and separating, and returning the Fischer-Tropsch reaction heat to preheat the synthesis gas; s4, pressurizing the Fischer-Tropsch oil wax, mixing the Fischer-Tropsch oil wax with hydrogen, carrying out hydrofining reaction to generate a gas-liquid isomerous oil-gas mixture, cooling and separating, and recycling heat energy of a product to And S5, after gas-liquid separation, preheating a liquid phase, carrying out rectification operation, separating and cooling to obtain a sustainable aviation fuel product. By recovering the heat in each link, the heat is efficiently utilized, and the energy-saving performance of production is improved.

Systems and methods of the present disclosure includes a mixer configured to mix air and hydrocarbons and a burner configured to receive the mixed air and hydrocarbons and to generate syngas. The system also includes a cooling system configured to receive the syngas and to cool the syngas to form cooled syngas. The system further includes a collector configured to collect carbon from the cooled syngas as soot. Moreover, the system includes a flare stack configured to receive the cooled syngas and to burn off at least part of the cooled syngas.

The invention discloses a method for preparing fuel from waste polyolefin through noble-metal-free low-temperature aromatization, which comprises the following steps: in the atmosphere of synthesis gas, carrying out catalytic cracking on polyolefin serving as a raw material by adopting a binary mixed catalytic system to obtain aromatic hydrocarbon; the binary mixed catalytic system comprises Zr-ZnO and a molecular sieve; the catalytic cracking temperature is less than or equal to 300 DEG C. According to the low-temperature aromatization method disclosed by the invention, methanol is generated in situ through the synthesis gas, and the methanol and olefin generated by polyolefin cracking are subjected to Prins reaction, so that the aromatization reaction can be realized at the pyrolysis temperature far lower than that in the prior art, precious metals are not needed, the additional value and the application range of a plastic recovery product are greatly enhanced, and the method is suitable for industrial production. And the cost of the recovery process is reduced.

This invention discloses a method for preparing a CuZnAlGa-based layered double hydroxide (TLH)-derived catalyst for methanol production from carbon dioxide-rich syngas. Using Cu, Zn, Al, and Ga metal salts as precursors, Na₂CO₃ and NaOH as precipitants, and a mixed alcohol-water solution as an auxiliary solvent, co-precipitation is performed under controlled temperature and pH to obtain a LDH-like catalyst precursor. After high-temperature calcination and in-situ reduction in a hydrogen atmosphere, a layered framework structure of Cu nanoparticles immobilized by oxides is obtained. The LDH-like structure provides lattice confinement, preventing Cu particle aggregation, and the interaction between Cu and the oxides enhances the catalyst surface's adsorption capacity for CO and CO₂, thereby improving the activity and stability of methanol production from carbon dioxide-rich syngas.

According to the monolithic catalyst packed bed process system and the corresponding method for fluidized carbonate reduction based on the monolithic catalyst, by adopting the monolithic catalyst, full contact of a gas phase, a solid phase and a solid phase is guaranteed, the efficiency of carbonate reduction reaction is improved, and the utilization rate of the catalyst is increased. Meanwhile, the problem of separation of a subsequently generated oxide solid product and a catalyst solid is avoided, and continuous operation of the system is realized. According to the present invention, the heating decomposition reaction of the metal carbonate and the hydrogenation reduction reaction of the in-situ carbon dioxide are coupled, and the monolithic catalyst is adopted to perform catalysis so as to obtain the high-value metal oxide and the synthesis gas or methanol product, and compared with the prior art, the process reaction temperature is substantially reduced so as to easily promote energy saving and emission reduction.

The present disclosure provides systems and methods for hydrogen production as well as apparatuses useful in such systems and methods, including steam generation systems and methods. Hydrogen is produced by reforming of a hydrocarbon in a plurality of reformers to achieve improved reforming efficiency. A CO2 convective reformer (CCR) and an oxygen secondary reformer (OSR) are used in series to convert hydrocarbon and steam to synthesis gas with substantially complete carbon capture. Steam generation is provided along separate pathways to provide separate steam streams of different composition.

The invention relates to the technical field of coal chemical industry, in particular to a coal gasification black water circulation and black water waste heat recycling system and method. The coal gasification black water circulation and black water waste heat recycling system comprises a synthesis gas washing tower, a high-pressure flash tank, a low-pressure flash tank, a black water heat exchanger, a vacuum flash tank, a settling tank, a grey water tank, a low-pressure flash steam stripping tower and a high-pressure flash steam stripping tower. The coal gasification black water treated by the coal gasification black water circulating and black water waste heat recycling system can be reused as circulating water of a synthesis gas washing tower, so that the cyclic utilization of water resources is realized, the use of fresh water and the discharge of waste water are reduced, and the production cost and the environmental pressure are reduced. Meanwhile, the problem that a black water pipeline is scaled and blocked due to high temperature is solved, waste heat of the black water can be fully replaced for effective utilization, carbon is reduced, energy is saved, the purpose of cooling the black water is achieved, the cooling cost of a vacuum flash evaporation system is saved, and continuous and reliable economic benefits are created for enterprises.

Systems and methods for producing green hydrogen from a source material (e.g., biowaste) are contemplated. The source material is at least partially dehydrated to produce a dried intermediate and recovered water. The dried intermediate is pyrolyzed to produce syngas and a char. The recovered water is electrolyzed to produce oxygen and green hydrogen.

The invention provides an improved ammonia production system based on a temperature swing adsorption principle. The improved ammonia production system comprises a water electrolysis hydrogen production module, a deep cooling air separation nitrogen production module, a multi-stage ammonia synthesis tower module and a double-bed circulating adsorption separation ammonia module, the water electrolysis hydrogen production module and the deep cooling air separation nitrogen production module provide raw material gas for the multi-stage ammonia synthesis tower module through a mixer, low-grade waste heat of a multi-stage ammonia synthesis tower serves as a heat source of the double-bed circulating adsorption separation ammonia module, and the double-bed adsorption separation ammonia module is connected with the multi-stage ammonia synthesis tower. The working conditions of an adsorption bed of the double-bed ammonia adsorption and separation module comprise an adsorption working condition and a desorption working condition, the adsorption bed alternately performs the adsorption working condition and the desorption working condition within the operation time, and low-grade waste heat from a multi-stage ammonia synthesis tower is used for driving to perform separation operation on ammonia synthesis gas so as to obtain high-purity ammonia; according to the invention, the operation pressure in an ammonia product separation project can be effectively reduced, circulation is formed, and the purity and the recovery rate of the obtained ammonia product are not reduced while the waste heat in the system is further utilized.

The invention discloses a carbon transaction-oriented biomass gas coupling coal-fired power generation full-life-cycle carbon emission accounting method. The method comprises the steps of determining accounting boundaries of collection and transportation, storage pretreatment, gas production and coupling power generation of covering raw materials; activity data are collected, space-time mapping of upstream batch data and unit side continuous operation data is established, and data quality grading and uncertainty measurement are carried out; when actually measured synthesis gas components or lower calorific values are missing, a soft measurement model is constructed based on operation data, batch characteristic feedforward coupling is introduced, and an estimated value and uncertainty are output; calculating an intermediate quantity based on a material-energy-carbon conservation mechanism model, performing dynamic correction by adopting a residual correction model containing physical consistency constraint, and adjusting a physical constraint weight according to uncertainty; and an emission list and an MRV data packet are generated in combination with the dynamic emission parameters, and are used for monitoring, reporting, checking and transaction settlement, so that the precision and the traceability are improved, and the physical consistency is ensured.

The invention provides a multistage coupling chemical looping hydrogen production device. The multistage coupling chemical looping hydrogen production device comprises a first-section reducer, a water vapor oxidation hydrogen production device, a second-section reducer, a methane converter and an air oxidizer, identical first oxygen carriers are arranged in the first-section reducer and the water vapor oxidation hydrogen production device, and identical second oxygen carriers are arranged in the second-section reducer, the methane converter and the air oxidizer; the methane converter is connected with the first-section reducer and is used for conveying synthesis gas after methane conversion to the first-section reducer; the second-section reducer is connected with the methane converter and is used for refluxing carbon dioxide or water vapor or both to the methane converter; the first-section reducer is connected with the second-section reducer and is used for conveying reduction tail gas containing carbon monoxide or hydrogen or the carbon monoxide and the hydrogen to the second-section reducer. Therefore, the invention provides the multistage coupling chemical looping hydrogen production device and method which can realize energy self-sustaining and do not need external energy input.

Ammonia, methanol, Fischer Tropsch products, and derivatives thereof are made by using hydrogen and oxygen supplied from an electrolyzer that is at least partially powered by renewable power, resulting in green process and systems that produce green products disclosed herein. A process using biomass and renewable energy includes producing an unshifted syngas from biomass and oxygen in a gasification unit, introducing water into an electrolyzer to produce an oxygen product and a hydrogen product, and introducing the oxygen product to the gasification unit. The electrolyzer is powered by renewable energy, and the oxygen product supplies at least a portion of the oxygen to the gasification unit.

It has been discovered that recycle content CO2 streams produced in a chemical recycling facility involving waste plastic pyrolysis can be converted into recycle content syngas (r-syngas), which can be used for various applications. More particularly, recycle content CO2 streams generated from a pyrolysis facility, a cracking facility, and / or an ethylene oxide facility may be recovered and converted into r-syngas. Moreover, recycle content methane, produced directly or indirectly from waste plastics, may also be used to produce flue gas streams, which provide additional recycle content CO2 streams to produce additional recycle content syngas. Thus, methods for producing a useful recycle content product (i.e., r-syngas) from conventional waste streams that are typically exhausted (i.e., CO2 streams) are provided herein.

The invention provides a process method and system for directly capturing carbon dioxide from air and converting and utilizing the carbon dioxide. The process method comprises the following steps: adsorbing raw material gas through a carbon dioxide trapping device, and heating and desorbing to obtain purified carbon dioxide gas; the purified carbon dioxide gas and the electrolyte are subjected to electrocatalytic conversion to obtain synthesis gas, oxygen and condensate water, and the condensate water is recycled through water treatment operation to be used for supplementing the electrolyte; the method comprises the following steps: carrying out Fischer-Tropsch synthesis reaction, hydrocracking and isomerization reaction on synthesis gas to obtain an isomerized oil-gas mixture, wherein heat energy generated by the reaction provides heating desorption heat; and carrying out gas-liquid separation on the heterogeneous oil-gas mixture to obtain combustible gas and an upgraded oil product, carrying out rectification operation on the upgraded oil product to obtain an SAF component and a heavy oil product, and carrying out oxygen-enriched combustion reaction on the combustible gas and oxygen to provide heating desorption heat or supply required heat energy. An integrated and flexible industrial technology platform is developed, carbon capture and conversion processes are seamlessly connected, full-chain optimization from CO2 removal to high-added-value product generation is realized, and self heat energy requirements and wastewater utilization can be met.

Systems and methods of the present disclosure includes a mixer configured to mix air and hydrocarbons and a burner configured to receive the mixed air and hydrocarbons and to generate syngas. The system also includes a cooling system configured to receive the syngas and to cool the syngas to form cooled syngas. The system further includes a collector configured to collect carbon from the cooled syngas as soot. Moreover, the system includes a flare stack configured to receive the cooled syngas and to burn off at least part of the cooled syngas.

The invention discloses a system and a method for producing sponge iron by coupling a gasification furnace and a gas-based shaft furnace. The system comprises a coal pretreatment device for pretreating received raw material coal; the gasification furnace receives the raw material coal treated by the coal pretreatment device through a conveying device, and synthesis gas is obtained through reaction; the mixer receives furnace top gas generated by the gas-based shaft furnace, mixes the furnace top gas with synthesis gas to obtain mixed gas, and outputs the mixed gas to the dust remover; the high-temperature desulfurization device is used for carrying out desulfurization treatment on the dedusted mixed gas by using a high-temperature desulfurization agent, and the high-temperature decarbonization device is used for carrying out decarbonization treatment on the desulfurized mixed gas and outputting the decarbonized mixed gas to the gas-based shaft furnace; iron ore and / or oxidized pellets are / is arranged in the gas-based shaft furnace, the decarbonized mixed gas is received, and sponge iron is generated through reaction. According to the method, the synthesis gas is cooled by using the furnace top gas, additional cooling equipment is not needed, the cost is reduced, the energy utilization rate is increased, and cleaner and more efficient sponge iron production is realized.

The invention relates to the technical field of fuel gas mixing, and discloses a biological natural gas mixing control method and system.The method comprises the steps that a natural gas branch, a synthesis gas branch and a mixed gas outlet are each provided with a multi-mode sensor unit; carrying out data fusion on the detection data and the detection data of an on-line chromatographic instrument and a mixed gas rapid calorific value instrument, and estimating the low calorific value, the bloom index and the gas component percentage of the mixed gas in real time based on a constraint model and Kalman filtering; establishing a prediction controller, setting input to predict gas characteristics required by a future gas turbine, and outputting a synthesis gas valve opening degree and a natural gas valve fine tuning signal; calculating an allowable mixing proportion upper limit to form a dynamic mixing window, and adjusting the mixing proportion of the natural gas and the synthesis gas based on the dynamic mixing window when a hard boundary condition is met; and when the instability state occurs, the safety interlocking is triggered. According to the invention, rapid detection is realized, active adjustment of rapid working condition fluctuation is realized, and safety interlocking is arranged, so that the overall operation safety is improved.

A compression unit for ammonia comprising a multi-stage compressor, including a first set of compressor stages adapted to compress a syngas containing hydrogen and nitrogen; and a second set of compressor stages adapted to compress a refrigerant of a refrigerant circuit. Described herein is also an ammonia production system including the ammonia compression unit and a method.

The invention provides a polygeneration system and method for coupling wind-solar hydrogen production with CO2 capture and utilization, and relates to the technical field of green energy. The system comprises a renewable energy source driving subsystem used for providing green electric energy and preparing green hydrogen as an energy carrier and a synthetic raw material to be supplied to a multi-path utilization subsystem; the carbon source conversion and capture subsystem is used for receiving the biomass raw material, generating gasified synthesis gas and biomass charcoal through gasification reaction, and capturing and recycling CO2 in flue gas discharged by the system; the multi-path utilization subsystem is used for receiving H2, the gasified synthesis gas and CO2 and blending reaction components to realize synthesis of green methanol, conventional methanol and green ammonia; closed-loop circulation of carbon resources is formed among the subsystems through continuous conversion, capture and feedback paths of H2, CO2 and biomass charcoal. According to the scheme, efficient synergistic conversion of hydrogen and carbon resources and full-amount utilization of carbon elements can be achieved in regions with limited carbon sources.

The invention belongs to the technical field of metallurgy, and relates to a carbon reduction method for a direct reduction device, which comprises the following steps: step 1, feeding a carbon-containing raw material and an oxidant into a conversion unit for oxidation reaction to obtain crude synthesis gas; 2, feeding the crude synthesis gas into a direct reduction unit for ironmaking, and respectively feeding furnace top gas discharged by the direct reduction unit into a conversion unit and a tail gas discharge unit after dust removal by a dust removal unit; 3, a part of the furnace top gas and a carbon-containing raw material are subjected to a reforming reaction in a conversion unit to obtain synthesis gas, and the synthesis gas is fed into a direct reduction unit for ironmaking; and the other part of furnace top gas is discharged after being treated by the tail gas discharge unit. According to the method, a carbon dioxide closed-loop conversion system is constructed, efficient carbon reduction is achieved through a coupling mechanism of non-catalytic partial oxidation and autothermal reforming, and compared with a traditional hydrogen-based shaft furnace ironmaking method, the carbon reduction method has the advantage that the carbon dioxide emission is reduced by at least 25%.

The invention provides a garbage pyrolysis gasification multi-stage directional regulation-gas-solid phase reforming synergistic hydrogen production treatment process which comprises the following steps: first-stage regulation: pretreatment and graded feeding: crushing, sorting, drying and catalytic coating treatment are performed on garbage through a physical-chemical directional means; second-stage regulation and control: performing low-temperature pyrolysis directional dechlorination, and performing thermochemical directional conversion on plastic and biomass garbage at 350-450 DEG C; third-stage regulation and control: gasifying and melting are coordinated and oriented, and a gas-solid phase coupling reaction is realized in double fluidized beds at 800-900 DEG C; four-stage regulation and control: multi-stage gas-solid phase reforming is carried out, and the hydrogen yield is increased through catalysis-adsorption synergistic effect in a 700 DEG C moving bed; and five-stage regulation and control: deep purification and hydrogen purification, wherein the synthesis gas is selectively oxidized by utilizing chemical looping combustion to release hydrogen with the purity being greater than or equal to 99.99%. According to the invention, the molten ash is used as a catalytic carrier, and the Fe-Ce active sites of the molten ash are utilized to synchronously realize tar cracking and synthesis gas reforming, so that the conversion rate of tar is effectively improved.

A method includes heating a carbon dioxide feed stream in a first heat exchanger using a first cathode effluent from a cathode of an electrolyzer to generate a heated carbon dioxide effluent, heating a first steam feed stream in a second heat exchanger using a second cathode effluent from the cathode of the electrolyzer to generate a first heated steam effluent, heating a second steam feed stream in a third heat exchanger using an anode effluent from an anode of the electrolyzer to generate a second heated steam effluent, combusting, in a combustion unit, a tail gas stream to transfer heat from the combusting to the heated carbon dioxide effluent, the first heated steam effluent and the second heated steam effluent to generate a heated carbon dioxide and steam stream effluent, and passing the heated carbon dioxide and steam stream effluent to the cathode of the electrolyzer.

The invention provides a synthesis gas preparation method based on a double-circulation gasifier. The synthesis gas preparation method based on the double-circulation gasification furnace comprises the following steps: S1, feeding a biomass raw material and a gasification agent into the double-circulation gasification furnace for gasification; s2, performing primary separation on the synthesis gas generated by gasification, returning a solid material generated by the primary separation to the double-circulation gasification furnace, and performing secondary separation on the synthesis gas after the primary separation; and S3, returning the solid material generated by the second-stage separation to the double-circulation gasification furnace. According to the preparation method of the synthesis gas, the carbon conversion rate and the gasification efficiency can be effectively improved, the total concentration of carbon monoxide and hydrogen in the synthesis gas is greater than 65%, and the quality of the biomass gasification synthesis gas is greatly improved.

The utility model relates to a precooling system for methanol synthesis gas, and belongs to the technical field of gas precooling. Comprising a compressor, a filter, a precooler, an emptying valve, a temperature sensor and a controller. One part of the nitrogen compressed by the compressor is conveyed to the filter, and the other part of the nitrogen is conveyed to the precooler, so that the amount of the nitrogen passing through the precooler is small, impurities in the precooler are few, blockage in the precooler is avoided, the amount of the conveyed nitrogen and the cooling effect on a dehydrogenation tower and a decarburization tower are ensured, and the service life of the dehydrogenation tower and the decarburization tower is prolonged. And the cleaning period of the precooler is prolonged. After the precooler runs for a certain time, the controller opens the emptying valve, the nitrogen in the dehydrogenation tower and the decarburization tower is used for back flushing the interior of the precooler, so that the nitrogen is used for purging impurities remained in the precooler, the cleaning of the precooler is completed, in the purging process, the nitrogen can still be conveyed to the dehydrogenation tower and the decarburization tower through the filter for cooling, and the cleaning efficiency of the precooler is improved. And the influence on the cooling effect of the condenser of the dehydrogenation tower and the condenser of the decarburization tower is reduced.

A process for the production of carbon monoxide is described. The process involves the electrochemical desorption of carbon dioxide and oxygen from a solution containing a metal bicarbonate and the formation of carbon monoxide from the carbon dioxide. The carbon monoxide produced can be used in a process for the formation of syngas.

The embodiment of the utility model provides zero-emission methanol preparation equipment based on garbage gasification and water electrolysis. The equipment comprises a water electrolysis hydrogen production unit, a garbage gasification unit, a first methanol synthesis unit, a second methanol synthesis unit and a gas separation unit, the water electrolysis hydrogen production unit is respectively connected with the garbage gasification unit, the first methanol synthesis unit and the second methanol synthesis unit; the gas separation unit is respectively connected with the garbage gasification unit, the first methanol synthesis unit and the second methanol synthesis unit; the water electrolysis hydrogen production unit generates hydrogen and oxygen through electrolysis; the garbage gasification unit is used for carrying out gasification reaction by using oxygen provided by the water electrolysis hydrogen production unit to prepare synthesis gas containing carbon monoxide, carbon dioxide and hydrogen; the gas separation unit is used for separating carbon monoxide, carbon dioxide and hydrogen in the synthesis gas introduced from the garbage gasification unit, the carbon monoxide and the hydrogen are introduced into the first methanol synthesis unit, and the carbon dioxide is introduced into the second methanol synthesis unit for preparing methanol respectively.

The invention provides a biomass gasification system and a fluidized bed gasification process, the system comprises a fluidized bed gasification furnace, a cyclone separator and a material returning leg, the fluidized bed gasification furnace is provided with a gasification cavity and a gas chamber, and a fluidized bed formed by bed materials is arranged in the gasification cavity. Bed materials are added into the gasification furnace in a spiral feeding and pneumatic conveying combined mode, a fluidized bed is established, biomass particles are added after temperature rise, the pressure in the gasification furnace is kept to be certain, and an auxiliary gasification agent enables the biomass particles to be in a fluidized state. According to the invention, the melting characteristic of biomass ash can be effectively improved, the problem of easy slag bonding during biomass gasification is solved, the gasification temperature is effectively increased, and the methane content in the synthesis gas is reduced. The bed material can catalytically crack tar generated in the biomass gasification process, the quality of synthesis gas is optimized, the synthesis gas is prevented from being bonded and attached to the metal wall of a downstream device, the yield of the synthesis gas and the stability of the device are improved, and the heat exchange efficiency of a downstream waste heat recovery unit is enhanced.

A system comprising a gasifier comprising one or more burners configured to accept a carbonaceous fuel and an oxidant to produce a syngas and a molten slag; a throat configured to accept the syngas and molten slag from the gasifier; and a radiant syngas cooler positioned below the gasifier configured to accept the syngas and molten slag from the throat; wherein the throat comprises an outer wall and one or more fins extending radially inwards from the outer wall.

The invention relates to the technical field of organic solid waste treatment, in particular to a process system for hydrogen production and co-production of biological natural gas from biological crude synthesis gas, which comprises a purification unit, a hydrocarbon regulation unit, an acid removal unit, a methane upgrading unit, a hydrogen recycling and purifying unit and a methane recycling and purifying unit which are connected in sequence. The purification unit is used for removing impurities through pre-impurity removal, compression, dry-process impurity removal and wet-process desulfurization to produce purified synthesis gas and sulfur; the hydrocarbon adjusting unit is pressurized through a centrifugal compressor and adjusts the hydrogen-carbon ratio; the acid removal unit is used for removing acid gas and organic sulfur; the methane upgrading unit is used for converting CO / CO2 into methane through methanation reaction; and the recycling unit purifies hydrogen through pressure swing adsorption and recycles methane by using a membrane separation technology to produce biogas. The problems of low purity and insufficient raw material utilization rate of the traditional process are solved through the circulation process, the co-production of high-purity hydrogen and biogas is realized, and the additional value of resources is improved.

The invention discloses a system and method for producing hydrogen-rich fuel gas by coupling concentrating solar energy with biomass chemical looping gasification, and the system comprises a concentrating module which is used for concentrating solar energy to a fuel reactor; the fuel reactor is arranged at the focal plane of the condensation module and is used for reacting the biomass with the oxygen carrier solid particles to obtain synthesis gas and reduced oxygen carrier solid particles; the water vapor reactor is used for oxidizing the reduced oxygen carrier solid particles to generate hydrogen and oxidized oxygen carrier solid particles, and feeding the oxidized oxygen carrier solid particles into the fuel reactor to circulate and react with the biomass; and the synthesis gas regulator is used for receiving the synthesis gas and the hydrogen to obtain hydrogen-rich fuel gas. Energy is provided for the fuel reactor through the condensation module, oxygen carrier regeneration cycle is completed through the water vapor reactor, and the problems of nitrogen mixing and synthesis gas dilution caused by the fact that energy is provided by an air reactor in the prior art are solved.