The invention discloses an in-situ capture heterogeneous catalytic reaction intermediate product device and a use method thereof. The device comprises a reaction gas control system, an in-situ infrared pool system and an analyzing and testing system. The device can be used for carrying out a temperature-variable heterogeneous catalytic reaction at low pressure (smaller than or equal to 1.0 MPa), a catalyst active species, the reaction intermediate product, a reaction product and the like in the catalytic reaction can be monitored and tracked in real time, the changes, such as the influence of matching of raw material gas, reaction temperature, reaction pressure and the like on the catalytic reaction, of the reaction process along with various catalytic reaction conditions can be observed online, reactants, an intermedium and the product in the catalytic reaction process can be subjected to qualitative and quantitative analysis through an in-situ infrared instrument, a gaschromatograph and the mass-spectrography, especially the intermedium and the product with low content (ppm grade) can be monitored online, and therefore the performance of catalysts can be compared, and the heterogeneous catalytic reaction mechanism can be studied. Compared with the prior art, data is precise, operation is easy, and the device has great significance on heterogeneous catalytic reaction mechanism study.