7985 results about "Firming agent" patented technology

The invention discloses a high-temperature-resistant epoxy resin composite material and a preparation method thereof, and relates to the technical field of composite materials. The high-temperature-resistant epoxy resin composite material is prepared from the following raw materials in parts by weight: 70 to 80 parts of modified epoxy resin, 8 to 15 parts of high-temperature-resistant modifier, 15 to 30 parts of curing agent, 3 to 8 parts of nano reinforcing filler, 1 to 3 parts of coupling agent, 3 to 6 parts of carbon fiber, 2 to 5 parts of nano titanium dioxide, 5 to 10 parts of organic silicon rubber, 1 to 3 parts of conductive agent, 3 to 7 parts of flame retardant and 2 to 4 parts of zinc borate. The high-temperature-resistant epoxy resin composite material has outstanding advantages and strong thermal stability, and can bear high temperature; mechanical performance is excellent, and firmness and durability are achieved; the self-repairing capability is achieved, and the service cycle can be prolonged; the anti-permeability is good, and gas and liquid can be effectively blocked; the surface is smooth, the friction coefficient is low and the application prospect is wide.

The invention discloses a toughened epoxy resin and a curing method thereof, and relates to the technical field of epoxy resins, the toughened epoxy resin comprises the following components: 100 parts of an epoxy resin matrix, specifically a mixture of bisphenol A epoxy resin and alicyclic epoxy resin, 5-35 parts of a composite amine curing agent, and 5-20 parts of a nano toughening agent, in particular to core-shell rubber particles grafted with epoxy groups on the surfaces, the core layer of each core-shell rubber particle is cross-linked polybutadiene, the shell layer of each core-shell rubber particle is polymethyl methacrylate, 0.5-3 parts of an accelerant comprising a bi-component synergistic accelerant, 1-5 parts of an interface enhancer, and a mixture of gamma-glycidyl ether oxypropyl trimethoxy silane and a titanate coupling agent, a bisphenol A type epoxy resin and a specific proportion of alicyclic epoxy resin are combined to construct an epoxy resin matrix according to a mass ratio of 2: 1, the epoxy resin matrix is matched with a composite amine curing agent prepared by carrying out a special three-step reaction on long-chain polyether diamine, aromatic diamine and anhydride, and key parameters such as molecular weight, functionality and molar ratio of the components are accurately regulated and controlled.

The invention relates to a photo-thermal super-hydrophobic multifunctional anti-icing coating as well as a preparation method and application thereof. The photo-thermal super-hydrophobic multifunctional anti-icing coating comprises primer and finish paint, the primer comprises the following raw materials in parts by weight: 20-25 parts of bisphenol A type epoxy resin and / or fluorine modified epoxy resin, 10-20 parts of fluorine modified polyacrylic resin and / or polyurethane resin, 5-10 parts of a curing agent and 40-55 parts of a solvent; the finish paint comprises the following components in parts by weight: 2-5 parts of polytetrafluoroethylene, 1-3 parts of soluble polytetrafluoroethylene, 1-5 parts of polydimethylsiloxane and 85-90 parts of fluorinated MOF dispersion liquid. Compared with the prior art, the photo-thermal super-hydrophobic multifunctional anti-icing coating provided by the invention has the characteristics of super-hydrophobicity, rapid ice melting, wear resistance, reduction of ice adhesion strength and reduction of icing amount, can effectively solve the problem of icing of an aluminum conductor of a power transmission line of a power system, and can be applied to power equipment such as the aluminum conductor of the power transmission line.

The invention discloses a mixing and feeding electric control system with a liquid level sensing function, and relates to the field of control systems. An adaptive parameter configuration module; a multi-stage gradient stirring module; a real-time data twinning processing module; a remote cooperative monitoring module; a fault linkage processing module; and an energy-saving closed-loop control module. According to the system, the material characteristic pre-detection module is combined with the water content-viscosity-medicament dosage three-dimensional mapping table and the viscosity-rotating speed mapping table, so that real-time scanning and parameter quantitative matching of the granularity, the water content and the viscosity of the industrial waste are realized; according to the scheme, the stirring sufficiency of the high-viscosity industrial sludge is improved, the energy consumption of the low-viscosity material is reduced, the dosage of the medicament is automatically matched according to the three-dimensional mapping table, the utilization rate of the curing agent is improved, and the core problems of stirring waste and insufficient stirring are fundamentally solved.

The invention relates to a deicing super-hydrophobic coating based on MXene, a coating, a preparation method and application of the coating. The coating comprises the following components in percentage by mass: 2%-5% of a super-hydrophobic modified MXene photo-thermal material, 2%-5% of epoxy resin, 0.5%-1.5% of an epoxy resin curing agent, 0.5%-1.5% of PDMS, 0.05%-0.15% of a PDMS curing agent and 80%-90% of a diluent. Wherein the super-hydrophobic modified MXene photo-thermal material is MXene powder treated by fluorine-free long-chain silane, and the super-hydrophobic modified MXene photo-thermal material is a super-hydrophobic modified MXene photo-thermal material. MXene with excellent photo-thermal conversion performance is used as a photo-thermal material, fluorine-free long-chain silane is used for performing low-surface-energy hydrophobic modification on the MXene material, environmental pollution caused by perfluorinated or polyfluorinated organic compounds is avoided, photo-thermal performance and super-hydrophobic performance are integrated, the advantages of a super-hydrophobic coating and a photo-thermal coating are integrated, and the application prospect is wide. The deicing super-hydrophobic coating based on MXene can be used for passive ice prevention and active photo-thermal deicing.

The invention discloses an organic plugging agent, a preparation method thereof and application of the organic plugging agent to inhibition of SAGD steam cavity edge water invasion. The organic plugging agent is prepared from the following raw materials: epoxy resin, a curing agent, nano aerogel, mineral fibers, plant fibers, a reactive diluent, a heat stabilizer and water, the epoxy resin is at least one of glycidyl amine epoxy resin and alicyclic epoxy resin; the curing agent is at least one of amino resin, dicyandiamide and hydrazide; the heat stabilizer is at least one of thiourea, sodium thiosulfate and cobalt chloride. The organic plugging agent is excellent in high temperature resistance, mineralization resistance and plugging performance, the organic plugging agent, nitrogen and an inorganic plugging agent are injected into a water plugging system of an SAGD steam cavity edge well in a slug mode, the organic plugging agent is applied to SAGD high-temperature and high-leakage well conditions, and the SAGD production effect can be effectively improved.

The present invention relates to the technical field of composite materials. Provided are a glass fiber-reinforced epoxy resin composite material and a preparation method therefor. In the present invention, an epoxy silane coupling agent solution is used for performing surface modification on glass fibers. An epoxy silane coupling agent contains a hydrolyzable group and an epoxy group. Silicon hydroxyl generated when the hydrolyzable group is hydrolyzed can be connected to the glass fibers, so as to effectively modify the surfaces of the glass fibers. The epoxy group can react with an epoxy resin matrix, thereby improving the infiltration effect of the epoxy resin on the glass fibers and improving the bonding performance of the interface of the glass fiber-reinforced epoxy resin composite material, and thus improving the mechanical properties of the glass fiber-reinforced epoxy resin composite material. The epoxy resin is cured and modified by using a functional curing agent or nanoparticles, so as to improve the ductility or strength of the epoxy resin, thereby improving the mechanical properties of the prepared glass fiber-reinforced epoxy resin composite material.

The invention relates to the technical field of heavy anti-corrosion coatings, in particular to a graphene enhanced epoxy modified organic silicon resin heavy anti-corrosion powder coating. The coating is prepared from the following components in parts by weight: 42 to 58 parts of epoxidized epoxy modified organic silicon resin, 0.8 to 2.5 parts of hydroxylated graphene, 6 to 11 parts of nano zirconium dioxide coated boron nitride, 2.5 to 5.5 parts of lanthanum iso-octoate-titanate composite coupling agent, 1.5 to 3.5 parts of bis (3-triethoxysilylpropyl) disulfide, 4 to 7 parts of polyhedral oligomeric silsesquioxane, 5 to 8 parts of curing agent, 0.8 to 1.8 parts of flatting agent and 0.4 to 0.9 part of defoaming agent. 2.5 to 4.5 parts of polyether-ether-ketone micro powder and 1.2 to 2.8 parts of fluorine-containing phosphate ester. According to the invention, the resin is modified through chemical bridging, the modified graphene and the nano-coated powder are matched to construct a synergistic enhancement system, and the interface bonding is optimized by the composite coupling agent. The coating is excellent in adhesive force, corrosion resistance and mechanical property, good in processing fluidity and high in aging resistance and thermal stability, solves the problem that a traditional product is short in performance, and meets the industrial requirement.

The invention discloses basalt fiber reinforced anti-crack road concrete and a preparation method thereof, and belongs to the technical field of concrete preparation, and the preparation method specifically comprises the following steps: transferring a concrete precursor into a mold, transferring the mold to a vibration table, vibrating for 1-2 minutes, scraping the raised part of the surface by using a scraper, covering the surface of the material with a preservative film, and drying to obtain the basalt fiber reinforced anti-crack road concrete. Performing post-treatment to obtain the anti-crack concrete. The preparation method comprises the following steps: cleaning basalt fibers, activating, carrying out surface modification, curing to obtain composite basalt fibers, hydrolyzing a borosilicate monomer to prepare modified borosilane with a double-bond structure, converting the double-bond structure into an epoxy group through an epoxidation reaction to obtain a modified curing agent, and preparing the composite basalt fibers by using the modified curing agent and the modified borosilane as additives. And mixing with cement and other materials to obtain the wear-resistant, fracture-resistant and corrosion-resistant anti-crack concrete.

The embodiment of the invention discloses an epoxy molding compound, an epoxy molding film and an electronic component, the epoxy molding compound comprises epoxy resin and a zeolite imidazole framework material, and the zeolite imidazole framework material comprises imidazole ligands and metal ions. The zeolite imidazole framework material is used as a curing agent and a nano reinforced phase, imidazole groups on the surface of the zeolite imidazole framework material can be subjected to a ring-opening reaction with epoxy resin to form covalent bonds, the zeolite imidazole framework material can induce the epoxy resin to generate a microcrack deflection mechanism, and the zeolite imidazole framework material can promote curing of the epoxy resin, so that the epoxy resin is cured, and the curing effect is improved. Therefore, the thermal expansion coefficient of the epoxy molding compound is reduced, the fracture toughness of the epoxy resin is improved, and the thermal stability of the epoxy molding compound is improved.

The invention relates to the field of adhesives, in particular to a structural adhesive epoxy composition and a preparation method thereof. The structural adhesive epoxy composition is prepared from the following raw materials: epoxy resin, a toughening agent, a reinforcing agent, filler, a latent curing agent, a latent accelerant, a chemical foaming agent, a physical foaming agent and the like. Finally, the epoxy composition prepared by the invention can be used as a structural adhesive raw material, has ultrahigh expansion rate, low-temperature rapid curing capacity and structural adhesive property, and also has good mechanical properties and excellent comprehensive application effect, so that the complex requirements of the application field of the prior art on the structural adhesive raw material are met.

The invention relates to the technical field of preparation of epoxy insulating materials, in particular to an epoxy resin material constructed by a multistage molecular chain cross-linked network and a preparation method, and the epoxy resin material realizes synergistic improvement of insulation and mechanical properties. Epoxy resin monomers with different rigid and flexible group contents and different chain lengths under the same chain structure are combined according to a certain proportion and are mixed into a homogeneous-phase resin matrix at a high temperature, and then the homogeneous-phase resin matrix and an anhydride curing agent are subjected to cross-linking curing at the high temperature to prepare the epoxy insulating material. The rigidity and flexibility of an epoxy cross-linked network are regulated and controlled by utilizing the multi-rigid group and multi-epoxy group of a short-chain resin monomer in a resin matrix and the multi-active hydroxyl and high-flexibility ether bond content of a long-chain resin monomer, and a charge barrier is constructed. Finally, the epoxy resin material with high mechanical property and high electrical insulation property is prepared, and the insulation property and the mechanical property are synergistically improved.

The invention discloses an epoxy resin-based NTC (Negative Temperature Coefficient) composite material containing ionic liquid and carbon black as well as a preparation method and application of the epoxy resin-based NTC composite material. The preparation method of the material comprises the following steps: mixing the ionic liquid and the epoxy curing agent, heating on a heating table, stirring and mixing at the same time, then adding the epoxy resin, the carbon black, the surfactant and the solvent, mechanically stirring and uniformly mixing, and heating in a vacuum oven to remove the solvent to obtain the material. And then carrying out hot pressing for a certain time through a press vulcanizer at a certain temperature to obtain the epoxy resin-based NTC composite material containing the ionic liquid and the carbon black. The epoxy resin-based NTC composite material containing the ionic liquid and the carbon black has the advantages of high B value, good mechanical strength, high heat conductivity coefficient, high crosslinking density and the like, and the preparation method is simple to operate, mild in reaction condition, low in raw material cost and suitable for large-scale industrial production and application.

The invention belongs to the technical field of protective coatings, and discloses an anti-corrosion, wear-resistant and high-temperature-resistant coating as well as a preparation method and application thereof. The coating comprises a primer, a middle transition layer and a finish; the raw materials of the primer comprise a primer material and a primer curing agent component; the primer material comprises modified epoxy phenolic resin, a primer functional filler, a first mixed solvent, a high-temperature-resistant coupling agent and an anti-settling agent; the raw materials of the middle transition layer comprise a middle transition layer material and a middle curing agent component; the materials of the middle transition layer comprise polyimide modified epoxy resin, a wear-resistant filler, a reactive diluent, a carbon nanotube, a first dispersant and a compatilizer; the raw materials of the finishing paint comprise a finishing paint material and a finishing paint curing agent component; the finishing paint material comprises organic silicon modified fluorocarbon resin, finishing paint functional filler, a second mixed solvent, a second dispersing agent and a flatting agent. According to the invention, a resin-based composite coating system is synergistically designed through multi-phase materials, so that optimal balance of corrosion resistance, wear resistance, toughness and high temperature resistance of the coating is realized.

The invention discloses a graphene nanometer heavy anti-corrosion coating and a preparation method thereof, and belongs to the technical field of anti-corrosion coatings. The coating is prepared from the following components in parts by mass: 50 to 70 parts of diallyl bisphenol A type epoxy resin, 8 to 15 parts of histidine modifier, 12 to 20 parts of graphene nano composite modified filler, 5 to 10 parts of curing agent, 0.5 to 2 parts of flatting agent and 0.3 to 1 part of defoaming agent. The preparation method of the histidine modifier comprises the following steps: carrying out a Schiff base reaction on 1-palmitoyl-2-oleoyl ethanolamine and N-formyl-L-histidine to generate an intermediate A; reacting with a spiro quaternization reagent to form a quaternary ammonium salt intermediate B; and then compounding with aminopropyltriethoxysilane and silicotungstic heteropoly acid salt to obtain the product. The graphene nano-composite modified filler is prepared by modifying the surface of a graphene oxide / bentonite mutual intercalation layer structure through allyl trimethoxy silane. The graphene nano heavy anti-corrosion coating prepared by the invention forms a high-density cross-linked network, and has excellent barrier property, strong adhesive force, impact resistance and long-acting anti-corrosion performance.

The invention relates to the field of coatings, in particular to an industrial anticorrosive coating and a preparation method thereof. The coating comprises film-forming resin, a curing agent, a solvent and an anti-corrosion composite nanofiller. The anti-corrosion composite nanofiller has a three-layer structure, wherein an inner core is mesoporous silica loaded with an organic corrosion inhibitor; the middle shell layer is an amino-functionalized metal organic framework material grown in situ; and the outer layer is a low-surface-energy layer formed by modification of a hydrophobic modifier.

The invention discloses a self-dispersing nano-diamond reinforced coating as well as a preparation method and application thereof, and belongs to the technical field of protective coatings. The self-dispersing nano-diamond reinforced coating provided by the invention comprises a component A and a component B. The component A comprises the following components in parts by mass: 15-35 parts of epoxy resin, 1-30 parts of nano-diamond, 5-15 parts of a solvent and 0.5-1 part of a defoaming agent; and the component B comprises the following component in parts by mass: 2-15 parts of a curing agent. The coating is simple in ingredient, has good effects in adhesive force, impact strength, flexibility, neutral salt spray test and alkaline soaking, is a multifunctional transparent coating with corrosion resistance, wear resistance and antifouling performance at the same time, and has wide application scenes and practical value.

The invention discloses an acrylate conductive composite pressure-sensitive adhesive and a preparation method thereof. The acrylate conductive composite pressure-sensitive adhesive comprises a raw material A and a raw material B, wherein the raw material A comprises 5-15 parts of acrylate polymer; 0.10 to 1.00 parts of epoxy resin; 1.0 to 10.0 parts of aniline; 0.1 to 1.0 part of an initiator; 1-5 parts of conductive particles; and 0.010 to 0.100 part of an amine curing agent. The acrylate conductive composite pressure-sensitive adhesive disclosed by the invention has excellent conductivity and capacitance sensing performance, and shows excellent capacitance stability and relatively high sensitivity in a pressure cycle test; on the basis of containing the conductive filler, the pressure-sensitive adhesive still has better hardness, adhesion strength and tensile strength, and the conductive filler is well dispersed and combined in a pressure-sensitive adhesive system.

The invention discloses a light telegraph pole cement material and a preparation method thereof, and relates to the technical field of cement concrete. The method comprises the following steps: firstly, carrying out acid pickling, silane coupling agent grafting and nanoparticle vacuum impregnation treatment on shale ceramsite to obtain modified light ceramsite; the preparation method comprises the following steps: ultrasonically dispersing graphene oxide, compounding with Portland cement clinker and modified fly ash, and reacting with epoxy resin emulsion, a curing agent and a silane coupling agent to prepare organic-inorganic composite modified cement; the bamboo skeleton is subjected to silane coupling agent pretreatment to obtain a modified skeleton; then, mixing composite cement, an additive and water into slurry, adding the modified ceramsite and aggregate, and performing high-speed stirring and ultrasonic dispersion to form homogeneous concrete slurry; and finally, putting the modified bamboo skeleton into a mold, injecting the slurry, and performing centrifugal forming, steam curing and natural curing to obtain the cement material. The prepared lightweight telegraph pole cement material has excellent mechanical strength.

The invention discloses a glue solution for a copper-clad plate and a preparation method of the glue solution, and relates to the technical field of copper-clad plates. According to the prepared glue solution for the copper-clad plate, the composite epoxy resin, the curing agent, the accelerant, the solvent, the flexibilizer and the inorganic filler, the composite epoxy resin comprises bisphenol A epoxy resin, epoxy phenyl polysiloxane, itaconic acid polyaryletherketone and hydroxyl-terminated fluorine-containing vinyl polysiloxane, so that the interface bonding force with the copper plate is enhanced; the dielectric constant and the dielectric loss are effectively reduced, the peel strength and the toughness of the material are also remarkably improved, and the toughening agent is modified polyether sulfone microspheres; the modified polyethersulfone microspheres are prepared by coating polyethersulfone microspheres with hexamethylenediamine tetrapropionamide diamine, the hexamethylenediamine tetrapropionamide diamine is prepared by carrying out acylation condensation reaction on hexamethylenediamine tetramethyl propionate and ethylenediamine, and the polyethersulfone microspheres are prepared by carrying out electrostatic spinning on a spinning solution of polyethersulfone and vinylpyridine, so that the peel strength of the glue solution is remarkably improved.

The invention discloses a water-borne epoxy resin coating which comprises a component A and a component B, the component A is prepared from 60 to 80 parts of 50 percent modified water-borne epoxy resin emulsion, 5 to 15 parts of deionized water, 0.5 to 1 part of wetting dispersant, 0.2 to 0.8 part of defoaming agent, 5 to 10 parts of modified zinc phosphate, 3 to 5 parts of ion exchange antirust pigment, 4 to 6 parts of sericite powder, 3 to 5 parts of glass flake, 5 to 10 parts of precipitated barium sulphate, 1 to 5 parts of nano silicon dioxide and 0.5 to 1 part of rheological additive; 1 to 2 parts of modified organic bentonite slurry; 0.1 to 0.3 part of a pH conditioning agent; and 0.2 to 0.8 part of a flash rust inhibitor. The component B is prepared from 40 to 50 parts of waterborne epoxy-amine adduct, 20 to 30 parts of 50 percent modified polyamide curing agent, 5 to 15 parts of 60 percent Mannich base phenolic aldehyde amine curing agent, 0.5 to 1.5 parts of epoxy silane coupling agent, 1 to 2 parts of nonionic surfactant and 15 to 20 parts of deionized water. The emulsion stability of the waterborne epoxy resin coating is improved through a bisphenol A / F mixed epoxy emulsion and a grafted polyethylene glycol hydrophilic chain segment.

The invention relates to a degradable epoxy resin composite material with an adjustable curing speed, and a preparation method and a mild total recycling method thereof. Existing degradable epoxy resin has the problems of high cost, harsh degradation conditions and the like, and is difficult to meet the requirements of different application scenes on curing speed and temperature at the same time. The invention provides an epoxy resin composite material which comprises curing agent components (an epoxy resin amine curing agent and an ester-containing polythiol curing agent) and epoxy resin components (glycidyl ether epoxy resin, glycidyl amine epoxy resin and glycidyl ester epoxy resin). The cured composite material can be fully recycled through catalytic degradation under mild conditions by using a lewis acid and an amino group breaking ester bond mechanism, and the degradation product can be directly used as a curing agent, a toughening agent and a chain extender. The epoxy resin composite material disclosed by the invention not only has adjustable curing speed and high use performance, but also realizes environmental friendliness and resource recycling, and provides a new solution for sustainable development of epoxy resin.

The invention belongs to the technical field of polymer insulating materials, and particularly discloses a high-toughness and high-insulating-strength epoxy insulating material and a preparation method thereof. Single-end amine-terminated straight-chain alkyl groups with different chain lengths in a specific molar ratio are grafted to fluorine-containing epoxy resin to construct a side chain structure, and then a step curing process is adopted to form a three-dimensional cross-linked network with a curing agent under the action of an accelerant. The fracture toughness is remarkably improved by utilizing an epoxy body chain extension effect in a side chain grafting process and a uniform microphase separation structure formed by self-assembly of a long alkyl side chain in a curing process; meanwhile, through the synergistic effect of steric hindrance of a short alkyl side chain and a fluorine atom charge trap, delocalized electron transmission of a benzene ring conjugated structure is inhibited, and the insulating property is synchronously enhanced. Compared with a traditional toughening technology, insulation deterioration caused by toughening modification is effectively avoided, and an epoxy resin material with mechanical reliability and insulation stability is provided for high-voltage electrical equipment.

The invention belongs to the technical field of high polymer chemical materials, and particularly relates to a self-repairing composite waterproof board and a preparation method thereof. The invention relates to a high-temperature-resistant graphene coating which is prepared from the following raw materials: bisphenol A diglycidyl ether, fluorosilane modified nano SiO2, graphene slurry, polydimethylsiloxane, epoxy-terminated polydimethylsiloxane, a urea-formaldehyde prepolymer, a silane coupling agent, sodium dodecyl benzene sulfonate, an FSO-100 fluorocarbon surfactant, a CTBN adhesive, a curing agent, an epoxy accelerator DMP-30 and a diluent. Through the collaborative design of the gradient structure of the hard framework and the soft coating, low-surface-energy filler chemical anchoring, microcapsule local material supplementing and thermal triggering dynamic bond rearrangement, the board obtains balance among the bearing strength, long-term hydrophobicity, weather-proof barrier and repeatable thermal self-repairing; and meanwhile, the common defects that room-temperature self-repairing is difficult to realize, hydrophobic particles are easy to agglomerate, a coating is easy to layer and the like are avoided.

The invention relates to a heat-resistant, water-resistant and flame-retardant backboard composite material as well as a preparation method and application thereof. The heat-resistant, water-resistant and flame-retardant backboard composite material comprises a phosphorus-containing epoxy acrylate oligomer, common epoxy resin, toughened epoxy resin, phosphorus-containing epoxy resin, a filler, an additive flame retardant, a dicyandiamide curing agent, an accelerant, nitrogen-containing phenolic resin, a latent curing agent, a UV absorbent and an antioxidant. The phosphorus content in the material is improved by synthesizing the phosphorus-containing epoxy acrylate oligomer, so that the flame retardant property of the product is improved, and the problem of low flame retardant efficiency caused by direct addition of a phosphorus flame retardant is solved.

The invention discloses a modified amine curing agent and a preparation method thereof, and an epoxy resin composite material and a preparation method thereof, and belongs to the field of resin and composite materials. According to the curing agent, a C2-C8 alkyl chain is grafted to a methylene site of 4, 4 '-diaminodiphenylmethane (MDA) through free radical substitution and alkylation reaction, and a molecular structure with a flexible alkyl chain and a rigid benzene ring is formed. The preparation method comprises the following two steps: generating a halogenated intermediate from MDA and a halogen simple substance under certain reaction conditions, alkylating the halogenated intermediate with a Grignard reagent (RMgX), and purifying. The curing agent and epoxy resin are compounded, heated and cured, so that the epoxy resin composite material has relatively high impact strength and fracture toughness, has good tensile strength and hardness, has double functions of reinforcing and toughening, and solves the problem that reinforcing and toughening of traditional epoxy resin are difficult to be compatible; the method is suitable for the fields of aerospace, composite material adhesives and the like with harsh requirements on mechanical properties.

The preparation method comprises the following steps: mixing 20-40 parts by mass of substituted hydroxymethyl glycoluril, 45-85 parts by mass of mercaptocarboxylic acid and 0.5-3 parts by mass of an acidic catalyst, stirring and reacting for 1-10 hours at the temperature of 50-150 DEG C under the pressure condition of-0.01 to-0.1 MPa, adding 300-800 parts by mass of an organic solvent for diluting after the reaction is finished, washing and purifying with deionized water, and collecting an organic layer, thereby obtaining the mercaptan curing agent. Concentrating and drying to obtain the mercaptan curing agent. According to the thiol curing agent, the rigid glycoluril group is introduced, so that the rigidity of a cured product structure is improved, and the mechanical property, the adhesive property, the heat resistance and the damp-heat aging resistance of a cured product are improved; four tertiary amine groups in the substituted glycoluril have a certain self-promotion effect on a thiol curing epoxy reaction, and the curing reaction temperature is reduced under the condition that an accelerant is not added; the glycoluril-containing thiol epoxy resin curing agent disclosed by the invention has good application value and development prospect.

The invention relates to the technical field of coatings, and discloses a wear-resistant waterborne polyurethane finish paint and a preparation method thereof. The wear-resistant waterborne polyurethane finish paint comprises a component A and a component B in a mass ratio of (4-7): 1, the component A is prepared from the following components in parts by mass: 50 to 60 parts of waterborne polyurethane, 10 to 15 parts of hyperbranched polysiloxane, 2 to 3 parts of polyoxyethylene fatty acid, 0.8 to 1.2 parts of a de-foaming agent, 6 to 8 parts of color paste and 10 to 15 parts of water; and the component B comprises an isocyanate curing agent. The wear-resistant waterborne polyurethane finish paint prepared in the invention has excellent adhesion strength and wear resistance.

The invention discloses a carbon fiber reinforced modified resin material and a preparation method thereof, and belongs to the technical field of high-molecular compound composition.The preparation method comprises the steps that 40-60 parts of acidified carbon fibers, 8-12 parts of silane coupling agent modified graphene oxide, 10-20 parts of polyethylene glycol and 3-8 parts of alkylphenol polyoxyethylene ether are ultrasonically mixed to be uniform with acetone as a solvent, and a mixture I is obtained; mixing 100 parts of epoxy resin and 30-50 parts of a curing agent, heating and stirring until the mixture is melted to obtain a mixture II; the mixture I and the mixture II are placed in a vacuum drying oven to be mixed and stirred, the obtained product is placed at the room temperature and then subjected to heating curing treatment, and the carbon fiber reinforced modified resin material is obtained, so that the interface bonding strength of the composite material is remarkably improved by optimizing the formula, and the composite material has excellent mechanical properties; the composite material has a wide application prospect in the fields of aerospace, automobile manufacturing, electronics and other high-performance composite material requirements.

The invention relates to a high-thermal-conductivity epoxy resin conductive adhesive containing a composite conductive filler and a preparation method of the high-thermal-conductivity epoxy resin conductive adhesive. The high-thermal-conductivity epoxy resin conductive adhesive containing the composite conductive filler comprises 6-16% of graphene oxide modified epoxy resin, 0.6-3% of a curing agent, 0-1% of a curing accelerator, 2-7% of epoxidized soybean oil modified single-layer / multi-layer carbon nanotubes, 3-7% of carbon fibers, 3-7% of nano silver powder, 40-70% of micron silver powder, 5.0-15.0% of a surface treating agent, 0.3-2.7% of a coupling agent, 0.5-1.5% of a dispersing agent, 0.1-0.3% of an antioxidant and 0.1-0.3% of a lubricant. 0.5% and the balance of a solvent. The graphene oxide modified epoxy resin and the epoxidized soybean oil modified single-layer / multi-layer carbon nanotubes are utilized to improve the dispersion stability of the filler, the modified single-layer / multi-layer carbon nanotubes are adopted as a short-range conductive additive, the carbon fibers are adopted as a long-range conductive additive, and the graphene oxide modified epoxy resin and the epoxidized soybean oil modified single-layer / multi-layer carbon nanotubes and the carbon fibers cooperate to improve the conductivity. The conductive adhesive disclosed by the invention is high in heat conductivity, low in volume resistivity and high in tensile strength and bending strength, and has a wide application prospect in the fields of automotive electronics, wind power photovoltaics, LEDs (Light Emitting Diode), LCDs (Liquid Crystal Display) and the like.