4489 results about "Firming agent" patented technology

The embodiment of the invention discloses an epoxy molding compound, an epoxy molding film and an electronic component, the epoxy molding compound comprises epoxy resin and a zeolite imidazole framework material, and the zeolite imidazole framework material comprises imidazole ligands and metal ions. The zeolite imidazole framework material is used as a curing agent and a nano reinforced phase, imidazole groups on the surface of the zeolite imidazole framework material can be subjected to a ring-opening reaction with epoxy resin to form covalent bonds, the zeolite imidazole framework material can induce the epoxy resin to generate a microcrack deflection mechanism, and the zeolite imidazole framework material can promote curing of the epoxy resin, so that the epoxy resin is cured, and the curing effect is improved. Therefore, the thermal expansion coefficient of the epoxy molding compound is reduced, the fracture toughness of the epoxy resin is improved, and the thermal stability of the epoxy molding compound is improved.

The invention relates to the field of adhesives, in particular to a structural adhesive epoxy composition and a preparation method thereof. The structural adhesive epoxy composition is prepared from the following raw materials: epoxy resin, a toughening agent, a reinforcing agent, filler, a latent curing agent, a latent accelerant, a chemical foaming agent, a physical foaming agent and the like. Finally, the epoxy composition prepared by the invention can be used as a structural adhesive raw material, has ultrahigh expansion rate, low-temperature rapid curing capacity and structural adhesive property, and also has good mechanical properties and excellent comprehensive application effect, so that the complex requirements of the application field of the prior art on the structural adhesive raw material are met.

The invention relates to the field of coatings, in particular to an industrial anticorrosive coating and a preparation method thereof. The coating comprises film-forming resin, a curing agent, a solvent and an anti-corrosion composite nanofiller. The anti-corrosion composite nanofiller has a three-layer structure, wherein an inner core is mesoporous silica loaded with an organic corrosion inhibitor; the middle shell layer is an amino-functionalized metal organic framework material grown in situ; and the outer layer is a low-surface-energy layer formed by modification of a hydrophobic modifier.

The invention discloses a light telegraph pole cement material and a preparation method thereof, and relates to the technical field of cement concrete. The method comprises the following steps: firstly, carrying out acid pickling, silane coupling agent grafting and nanoparticle vacuum impregnation treatment on shale ceramsite to obtain modified light ceramsite; the preparation method comprises the following steps: ultrasonically dispersing graphene oxide, compounding with Portland cement clinker and modified fly ash, and reacting with epoxy resin emulsion, a curing agent and a silane coupling agent to prepare organic-inorganic composite modified cement; the bamboo skeleton is subjected to silane coupling agent pretreatment to obtain a modified skeleton; then, mixing composite cement, an additive and water into slurry, adding the modified ceramsite and aggregate, and performing high-speed stirring and ultrasonic dispersion to form homogeneous concrete slurry; and finally, putting the modified bamboo skeleton into a mold, injecting the slurry, and performing centrifugal forming, steam curing and natural curing to obtain the cement material. The prepared lightweight telegraph pole cement material has excellent mechanical strength.

The invention provides a preparation method of a self-repairing resin-based composite material based on dynamic bonds. The self-repairing epoxy resin comprises one covalent dynamic bond of a Diels-Alder bond, a disulfide bond or a borate bond, and the preparation method of the self-repairing epoxy resin comprises the following steps: heating epoxy resin to a molten state, adding a curing agent component while stirring, and carrying out a prepolymerization reaction to obtain a prepolymer; the curing agent comprises a rigid diamine curing agent, a dynamic diamine monomer and a flexible chain segment regulator, and the dynamic diamine monomer contains a dynamic covalent bond; and carrying out curing molding on the prepolymer to obtain the self-repairing epoxy resin. And impregnating reinforced fibers or fabrics thereof with the prepared prepolymer, and heating and curing to obtain the self-repairing resin-based composite material. The invention provides a chemical molecule design, dynamic reversible chemical bonds are introduced into a resin matrix, and by constructing the dynamic bonds, the composite material has high performance of a traditional composite material and also has life-like self-healing ability.

The invention discloses a high-toughness conductive and thermal-conductive epoxy adhesive, a preparation method thereof and a conductive film, and belongs to the technical field of conductive materials. Comprising the following raw material components in parts by weight: 100 parts of epoxy resin, 4-25 parts of a latent curing agent, 0.5-5 parts of an accelerant, 200-600 parts of conductive filler, 5-15 parts of an epoxy-terminated polyurethane flexibilizer, 5-20 parts of a core-shell flexibilizer, 5-10 parts of a nitrile rubber flexibilizer, 2-10 parts of a reactive diluent, 0.5-2 parts of a coupling agent and 20-50 parts of a solvent. Through compounding of the over-end epoxy type polyurethane flexibilizer, the core-shell flexibilizer and the nitrile rubber flexibilizer, the prepared conductive adhesive has excellent toughness and bonding characteristics, and meanwhile, the shrinkage stress and thermal stress in the curing process can be reduced.

The invention discloses a high-temperature-resistant tough epoxy resin adhesive and a preparation method thereof, and relates to the technical field of epoxy resin, the high-temperature-resistant tough epoxy resin adhesive comprises the following components by mass: 30-60 parts of epoxy resin, 15-40 parts of a modified curing agent, 5-20 parts of a flexibilizer, 8-35 parts of an inorganic filler, 1-5 parts of a coupling agent, and 0.5-3 parts of an antioxidant; the epoxy resin is formed by compounding bisphenol A epoxy resin and novolac epoxy resin according to the mass ratio of (1-3): 1; the modified curing agent is prepared by modifying an imidazole curing agent with a silane coupling agent. The problem that high temperature resistance and toughness of an epoxy resin adhesive are difficult to consider at the same time can be solved.

The invention belongs to the technical field of epoxy resin coatings, and particularly relates to an epoxy resin insulating coating with high toughness and high ultraviolet aging resistance and a preparation method thereof. The epoxy resin insulating paint is composed of 2-5 g of a TiO2 (at) PDA (at) BTA nanometer material, 100 g of epoxy resin and 10-60 g of a curing agent, wherein the TiO2 (at) PDA (at) BTA nanometer material has a core-shell structure. The epoxy resin insulating paint is constructed on the basis of the multi-layer core-shell structure functional nanoparticles, so that the toughness of the material is improved, and the ultraviolet aging resistance of the paint is also improved.

The invention provides an antifouling self-cleaning fluorocarbon finish paint as well as a preparation method and application thereof, and particularly relates to the technical field of special coatings. The antifouling self-cleaning fluorocarbon finish paint is composed of a component A and a component B in a ratio of (80-87): 16, the component A is prepared from the following components in parts by weight: 560 to 580 parts of fluorocarbon resin, 30 to 35 parts of a first solvent, 20 to 40 parts of a second solvent, 180 to 220 parts of titanium dioxide, 90 to 110 parts of filler, 11 to 20 parts of a light stabilizer, 3 to 5 parts of a thickening agent and 13 to 28 parts of an auxiliary agent; the component B comprises the following components in parts by weight: 20-22 parts of fluorocarbon resin, 4-5 parts of a chain extender, 15-20 parts of a diamine curing agent, 15-20 parts of a polyamine curing agent and 25-35 parts of a second solvent. According to the finishing paint, on the basis of enhancing the self-cleaning capability, the weather resistance of a coating is improved, and the aging and damage of the coating are delayed, so that the service life of the coating is prolonged.

The application discloses a kind of ship super-long anticorrosion special nano powder coating, preparation method and application, belong to ship heavy anticorrosion material technical field.The preparation method of the ship super-long anticorrosion special nano powder coating is as follows: epoxy resin, graphene modified epoxy resin, core-shell structure ZnO@SiO2, modified 2,5-dimercapto-1,3,4-thiadiazole, borosilicate glass powder, flaky boron nitride, silane coupling agent modified silica, phenolic amine curing agent, 2-ethyl-4-methylimidazole, fumed silica, defoaming agent, ultraviolet absorber, high-temperature pigment are put into stirrer and stirred for 20-30min, then melt extrusion is carried out through double screw extruder, the extrusion temperature is 90-110 DEG C, grinds and sieves, and the ship super-long anticorrosion special nano powder coating is obtained.The coating prepared by the application has good anticorrosion performance and can be applied in the field of ship metal surface corrosion protection.

The invention provides a toughened curing-controllable prepreg and a preparation method thereof, and belongs to the technical field of high-performance composite materials. Comprising the following components in parts by mass: 100 parts of epoxy resin, 100 parts of a thermoplastic resin toughening agent, 100 parts of an inorganic nanoparticle toughening agent, 100 parts of a latent curing agent, 100 parts of an organic urea accelerant, 100 parts of an imidazole accelerant and 100 parts of a reactive diluent, correspondingly, 1-5 parts by mass of a thermoplastic resin flexibilizer, 0-3 parts by mass of an inorganic nanoparticle flexibilizer, 4-8 parts by mass of a latent curing agent, 1-4 parts by mass of an organic urea accelerator, 0.1-0.5 part by mass of an imidazole accelerator and 5-20 parts by mass of an active diluent are added. The prepreg provided by the invention not only is endowed with fast curing and controllable curing time, but also is endowed with relatively long room-temperature storage period, high toughness and good impact resistance, and is especially suitable for the fields of low-altitude aircrafts, automobiles, ships and the like.

The invention discloses multi-solvent synergistically activated low-temperature semi-sintered copper paste and a preparation method and application thereof, and belongs to the technical field of conductive paste. The multi-solvent synergistically activated low-temperature semi-sintered copper slurry comprises the following raw material components in percentage by mass: 82-88% of conductive filler, 2-3% of a resin carrier, 4-7% of an activating solvent, 4-7% of a dispersing solvent and 2-3% of a curing agent. Through cooperation of multiple solvents, full-stage activation of the copper particles is achieved, pre-connection and sintering of the copper particles before resin is completely crosslinked and cured are promoted, densification of the overall structure is improved, the insulation barrier effect of the resin is effectively avoided, the resistivity is reduced, meanwhile, inhibition of the resin on sintering of the copper particles is solved, and the service life of the copper particles is prolonged. And good balance between conductivity and interface adhesion is realized. Through resin curing, chemical bonding between the slurry and the substrate can be enhanced, a metal bond network among copper particles is expanded, and mechanical connection stability and electrical performance are guaranteed.

The invention relates to the technical field of composite materials, in particular to a high-strength epoxy resin composite material and a preparation method thereof, and the high-strength epoxy resin composite material comprises the following raw materials in parts by weight: 50-80 parts of a base material, 10-20 parts of a curing agent, 5-10 parts of modified carbon nanotubes, 3-10 parts of a reinforcing sheet, 3-6 parts of a reinforcing material and 1-3 parts of a flame retardant. In the preparation method, the modified carbon nanotubes are in chemical bond connection with the base material through surface modification, the interface bonding force is enhanced, stress is effectively transmitted, the unique layered structure and surface modification treatment of the enhanced sheet are enhanced, the enhanced sheet is firmly combined with the resin matrix, and a three-dimensional enhanced network is formed through the synergistic effect of mechanical interlocking and stress dispersion. The vermiculite sheet layer prevents crack propagation, and the modified carbon nanotubes and the reinforcing material effectively transfer stress, so that the tensile strength and bending strength of the composite material are greatly improved, and the high-strength application requirement is met.

The invention discloses a polyurethane modified epoxy resin adhesive as well as a preparation method and application thereof, and the polyurethane modified epoxy resin adhesive is prepared from the following components in parts by mass: 7-10 parts of E51 type bisphenol A diglycidyl ether, 3.5 parts of a phenolic aldehyde amine T31 curing agent and 1-3 parts of synthetic polyurethane, the synthetic polyurethane is prepared from polyether triol, polyether amine, isophorone diisocyanate and glycerol carbonate, and a blending system of the synthetic polyurethane and bisphenol A diglycidyl ether is adopted to be subjected to covalent crosslinking with phenolic aldehyde amine T31, so that the adhesive has high toughness and strength guarantee; the synthetic polyurethane prepared by the method is obtained through simple, green and efficient solvent-free synthesis, and the synthesized product has certain fluidity at room temperature, so that the subsequent stirring preparation process of an adhesive is facilitated. And a solvent-free synthesis method is adopted, so that the use of a toxic organic solvent in the traditional polyurethane synthesis process is avoided, and the synthesis process is greener.

The invention discloses a normal-temperature curing ablation-resistant coating and a preparation method thereof, the normal-temperature curing ablation-resistant coating comprises a component A, a component B and a component C, the component A comprises the following raw materials by weight: 20-30 parts of epoxy resin, 30-40 parts of liquid nitrile rubber, 27-50 parts of an ablation-resistant filler, 10-20 parts of a heat-insulating functional filler, and 200-300 parts of toluene; the component B is a curing agent; and the component C is a curing accelerator. By selecting the high-performance polymer-based resin material and adding the ablation-resistant filler and the heat-insulating functional filler, the ablation-resistant and heat-insulating coating protection construction of the equipment under the normal-temperature curing condition is realized; the problems of ablation-resistant coating construction and thermal protection when a fragile cover, a launcher and the like in a launching system cannot use a high-temperature curing system ablation-resistant coating are solved. The coating can realize military technology and civil use, and can be widely applied to fire prevention and heat insulation construction of buildings.

The invention relates to the technical field of coatings, discloses a high-solid epoxy seal primer suitable for a wet base surface and a preparation method of the high-solid epoxy seal primer, and aims to overcome the defect of poor application performance of the wet base surface in the prior art. A water-responsive curing system, dynamic interface modification components and a synergistic mechanism of precise cross-linking regulation are constructed, a special curing agent with anti-protonation characteristics is adopted and matched with a modified molecular sieve to adsorb water on a basal plane so as to weaken water interference, interface bonding is enhanced through a coupling agent containing dynamic covalent bonds and a composite filler, and the water-based composite material is prepared. The rheology regulation and control auxiliary agent is supplemented to optimize the construction performance, the environment-friendly component is fused to give consideration to the characteristic of low volatility, efficient curing of a high-water-content base plane is achieved, the interface stability and long-acting protection capacity of a coating and a base material are improved, the coating is suitable for industrial large-scale production, and the coating requirement in a humid environment is met.

The invention relates to the technical field of coatings, in particular to a corrosion-resistant coating material and a preparation method thereof. The corrosion-resistant coating material comprises the following components in parts by mass: 80-100 parts of epoxy resin, 5-20 parts of a modified phenolic aldehyde amine curing agent, 2-5 parts of a waterproof agent, 5-10 parts of a corrosion inhibitor and 40-55 parts of a lubricant. The modified phenolic aldehyde amine curing agent is obtained by carrying out Mannich reaction on phenol, thymol, aliphatic polyamine and formaldehyde. The phenol provides a rigid benzene ring structure, and endows a cured product with good heat resistance and chemical resistance. Thymol improves the flexibility and adhesive force of the cured product and enhances the hydrophobicity of the cured product at the same time. The epoxy resin and the modified phenolic aldehyde amine curing agent are polymerized, the waterproof agent, the corrosion inhibitor and the lubricant are wrapped, and the obtained coating material has good adhesive force and corrosion resistance.

The invention relates to the technical field of anticorrosive coatings, in particular to a waterborne epoxy resin composite anticorrosive coating with MXene-NiO-PPy as filler and a preparation method of the waterborne epoxy resin composite anticorrosive coating. The invention discloses a water-borne epoxy resin composite anticorrosive coating taking MXene-NiO-PPy as a filler. The water-borne epoxy resin composite anticorrosive coating is prepared from a water-borne epoxy resin emulsion, a modified amine adduct curing agent, MXene-NiO-PPy, a microencapsulated corrosion inhibitor, a dispersing and leveling aid, nano cellulose, nano silicon dioxide aerogel powder and deionized water. The waterborne epoxy resin composite anticorrosive coating with MXene-NiO-PPy as a filler is prepared by pre-dispersing slurry, microencapsulating and stirring at a low speed, has physical shielding property, active chemical passivation property, excellent mechanical toughness and good construction performance, and effectively solves the problems that the traditional waterborne epoxy coating is insufficient in shielding property, easy to crack and only passive in protection.

The invention relates to a high-strength wear-resistant archaized brick and a preparation method thereof, and belongs to the technical field of archaized bricks, the high-strength wear-resistant archaized brick comprises the following raw materials: 25-30 parts of fly ash, 30-35 parts of superfine slag powder, 30-35 parts of clay, 8-10 parts of coke powder, 10-12 parts of diatomite, 12-15 parts of potassium feldspar, 10-15 parts of a modified binder and 8-12 parts of a reinforcing agent; according to the technical scheme, a polyhydroxy compound is combined with a silanization reinforcing filler, then combined with an anhydride compound and then combined with novolac epoxy resin, then an amine curing agent is added, and curing is conducted to obtain the modified binder; fly ash, superfine slag powder, clay and coke powder are subjected to ball milling, diatomite, potassium feldspar, a modified binder and a reinforcing agent are added, and the high-strength wear-resistant archaized brick is obtained through stirring, calcining and compression molding. The mechanical property, thermal stability and wear resistance of the archaized brick are improved on the whole, the densification degree of the archaized brick is enhanced, and the comprehensive performance is good.

The invention discloses an inorganic sepiolite nanofiber prepared from epoxy grafted modified sepiolite, and the structural formula of the inorganic sepiolite nanofiber is shown in the specification, wherein R represents a group of epoxy resin; the sepiolite is subjected to multiple modification, so that the specific surface area of the sepiolite is increased, and the stability, dispersity and compatibility of the sepiolite in an organic polymer are improved. The surface of the modified sepiolite has rich epoxy groups, when the sepiolite is used for a waterborne epoxy coating, epoxy on the surface of the modified sepiolite and waterborne epoxy can be reacted and combined together as long as a curing agent is added, the binding force of the sepiolite and the epoxy is further enhanced, the modified sepiolite is dispersed more uniformly in the demulsified epoxy, and the enhancement effect is better. And the modified sepiolite can also be directly used as a coating, only the curing agent needs to be added at the moment, and the curing agent can react with epoxy grafted with the modified sepiolite to form a consolidated sepiolite fiber network.

This anticorrosive coating composition comprises a main agent (I) and a curing agent (II), wherein: the main agent (I) contains an epoxy resin (a); the epoxy resin (a) contains at least one of a bisphenol A epoxy resin (a-11) and a novolac epoxy resin (a-12) each having a weight average molecular weight of 6,000-12,000; the curing agent (II) contains a polyamine (b) and an alkylphenol (c); the polyamine (b) contains an alicyclic polyamine (b-1) having a cyclic aliphatic hydrocarbon group to which an amino group is bonded and contains a non-alicyclic polyamine (b-2) having no cyclic aliphatic hydrocarbon group to which an amino group is bonded; at least one of the main agent (I) and the curing agent (II) includes a vinyl-based defoaming agent (d) that has a constituent unit derived from at least one monomer selected from the group consisting of alkyl (meth)acrylates, alkyl vinyl ethers, and olefins and that has a number average molecular weight of 30,000-100,000 or 300,000-2,000,000; the content of the alicyclic polyamine (b-1) is 30%-80% by mass of the solid content of the curing agent (II); the content of the non-alicyclic polyamine (b-2) is 2%-45% by mass of the solid content of the curing agent (II); the content of the alkylphenol (c) is 5%-60% by mass of the solid content of the curing agent (II); and the content of the vinyl-based defoaming agent (d) is 0.005-3 parts by mass with respect to 100 parts by mass of the anticorrosive coating composition.

The invention provides a resin composition, a magnetic film and application thereof. The resin composition comprises the following components: (A) magnetic filler, (B) epoxy resin, (C) a curing agent, (D) a flexibilizer and (E) polyester polyol, the number average molecular weight of the (E) polyester polyol is 2000 to 3000. According to the resin composition provided by the invention, through screening and synergistic compounding of specific components, the resin composition has relatively high magnetic conductivity and relatively low magnetic loss under high frequency after being cured, and meanwhile, the binding force with a copper layer is relatively high.

The invention relates to a low-dielectric-loss high-thermal-conductivity epoxy resin composite material and a preparation method thereof, and the preparation method comprises the following steps: carrying out surface modification treatment on a thermal conductive filler: carrying out surface modification on the thermal conductive filler by adopting a chemical covalent bonding or physical adsorption mode, the heat-conducting filler is used for improving the compatibility of the filler and an epoxy resin matrix and reducing the interface thermal resistance, and comprises boron nitride with a two-dimensional sheet structure; epoxy resin, a curing agent and an optional modifier are evenly mixed, the epoxy resin is selected from epoxy resin with the low polarity characteristic, and the modifier comprises at least one of thermoplastic resin or elastomer. And the process is simple and controllable.

Provided is a heat-curable acrylic resin composition which is capable of suppressing the generation of ultra-fine bubbles when cured under heat and pressure, and which has excellent adhesiveness. A thermosetting acrylic resin composition which contains (A) an acrylic copolymer having a carboxyl group and (B) a phenolic resin, and which is characterized in that: when the acrylic copolymer (A) is an acrylic copolymer (A-1) having a glass transition temperature of-35 DEG C or less, the phenolic resin (B) is a phenolic resin; the thermosetting acrylic resin composition contains a specific content of an epoxy curing agent (C-1), contains a specific content of a novolac phenolic resin (B-1) or a self-crosslinking phenolic resin (B-2) as the phenolic resin (B), and contains a specific content of a novolac phenolic resin (B-1) or a self-crosslinking phenolic resin (B-2) when the novolac phenolic resin (B-1) is contained as the phenolic resin (B). The thermosetting acrylic resin composition also contains a specific content of an amine curing agent (C-2).

The invention provides a method for optimizing the proportion of industrial waste residues and a microbial composite curing agent, and belongs to the technical field of building materials.The method comprises the steps that the industrial waste residues are ground into superfine powder with the specific surface area of 350-450 m < 2 > / kg, meanwhile, bacillus is cultured at the temperature of 30-35 DEG C until the concentration of bacillus is 108-109 / mL, and a mixture is obtained; a pH meter and a dissolved oxygen meter are adopted to monitor the state of a microbial solution in real time, the aeration intensity and nutrient solution supplement are automatically adjusted according to critical value judgment, a composite curing agent is prepared according to the calculation proportion, the interface bonding strength and compressive strength are tested, and the curing effect is evaluated through a strength development equation and a durability prediction equation. According to the comprehensive performance indexes, the matching parameters are dynamically adjusted, the testing and adjusting process is repeated until the results are stabilized in the target performance interval for five continuous times, the final matching is determined, and the technical problem that the matching of the industrial waste residues and the microbial composite curing agent is difficult to accurately optimize is solved.

The invention discloses an epoxy resin modified emulsified asphalt micro-surfacing mixture and a preparation method thereof.The preparation method comprises the steps that matrix asphalt is subjected to gradient heating to 75-90 DEG C, nano silicon dioxide is added, stirring and shearing are conducted, and activated matrix asphalt is obtained; preparing a water-borne epoxy resin emulsion with the solid content of 45-50%, and controlling the mass ratio of epoxy resin to an emulsifier to be (8-10): 1 to form a stable dispersion system with the particle size of less than or equal to 1 mu m; preheating the mineral aggregate, adding the activated matrix asphalt while stirring, and continuing stirring; adding the water-borne epoxy resin emulsion, and continuously stirring; adding a vinylamine curing agent, continuously stirring to ensure that the curing agent is uniformly dispersed and avoid partial incomplete reaction, finally adding cement and water, and continuously stirring to form a uniform micro-surfacing mixture. The pavement performance such as high-temperature stability, low-temperature crack resistance and the like is remarkably improved through raw material system upgrading and process innovation, VOCs emission is greatly reduced, and green and environment-friendly effects are achieved.

An epoxy concrete stirring device is used for solving the problems that underwater epoxy repairing materials are stored in a layered mode, the mixing time is uncontrollable, and underwater operation is inconvenient. The device comprises a stirring kettle, a kettle cover and an internal partition plate, wherein the partition plate divides a cavity into an upper-layer curing agent storage area and a lower-layer mortar mixing area; a seepage mechanism is arranged in the center of the partition plate, a movable plug is in linkage with an inner wall bayonet lock through a threaded groove in the outer wall of a stirring shaft, the stirring shaft rotates to drive the movable plug to move upwards, seepage holes in the outer wall of a liquid collecting groove are opened, and controllable inflow of a curing agent into mortar is achieved; the feeding port and the discharging port are controlled to be opened and closed through a hydraulic valve, a hydraulic machine and a hydraulic clamp respectively. According to the device, advanced reaction of components is avoided through layered isolation, mixing is accurately triggered through mechanical linkage, hydraulic driving adapts to underwater operation, it is ensured that the low consistency and high uniformity of materials are kept, and the reliability of underwater repair construction and the performance stability of the materials are improved.

The invention relates to the technical field of building materials, and particularly discloses an efficient and energy-saving building thermal insulation material and a preparation method. The material is prepared from modified aerogel, composite mineral fibers, phase change energy storage microcapsules, nano silicon dioxide, waterborne epoxy resin, a polyamide curing agent, expanded perlite, hollow glass beads, hydroxypropyl methyl cellulose, amino modified polyurethane microspheres and nano boron nitride, and the functions of all the components are complemented to form a synergistic system. The preparation method sequentially comprises the following steps: pretreatment of the composite mineral fibers, activation of the amino modified polyurethane microspheres, synergistic dispersion of multiple components, preparation of a bonding system, gradient mixing of materials and molding post-treatment. The material can be widely applied to heat preservation and insulation scenes such as building outer walls and roofs, and has the core advantages of being excellent in heat preservation and insulation, stable in mechanical strength and reliable in long-acting performance; the preparation method disclosed by the invention is refined in process, controllable in parameters, high in repeatability, capable of ensuring uniform product performance and beneficial to industrial large-scale production.

The invention relates to the technical field of epoxy resin, in particular to self-repairing epoxy resin and a preparation method thereof. The self-repairing epoxy resin is prepared from the following raw materials in parts by mass: 80 to 120 parts of bisphenol A type epoxy resin, 20 to 40 parts of bisphenol F type epoxy resin, 5 to 15 parts of 1, 6-hexanediol diglycidyl ether, 1 to 3 parts of 3, 5-dimethylphenylboronic acid, 1 to 5 parts of furyl maleimide, 10 to 20 parts of dodecanedioic acid, 5 to 15 parts of butanetetracarboxylic acid, 1 to 3 parts of catalyst, 10 to 15 parts of nano silicon dioxide, 1 to 2 parts of boron nitride nanosheet and 1 to 2 parts of hyperbranched polyamidoamine. The curing agent is prepared from the following components in parts by weight: 20-30 parts of epoxy resin, 1-2 parts of sulfydryl-terminated polysiloxane, 20-30 parts of amine curing agent, 5-15 parts of reinforcing filler and 0.5 According to the invention, the balance among self-repairing capability, mechanical property and heat resistance is successfully realized; in the microcrack propagation process, fracture and recombination mechanisms of dynamic covalent bonds effectively prevent further propagation of cracks.

The invention discloses a corrosion-resistant anti-cracking cable sheath material and a preparation method thereof, and belongs to the technical field of cable materials. The sheath material is prepared by adopting ethylene-vinyl acetate rubber and ethylene-propylene-diene monomer rubber as matrixes, adding graphene modified conductive carbon black and self-repairing microcapsules in a specific proportion, and carrying out banburying premixing, open milling feeding, dynamic vulcanization and other multi-step processes. Graphene and carbon black form a stable conductive network according to a specific ratio under the action of a silane coupling agent, urea resin is taken as a wall material of the self-repairing microcapsule, epoxy resin and a curing agent in a core material are in a specific ratio, and the repairing efficiency is ensured. The tensile strength retention rate of the material is greater than or equal to 92% and the elongation at break retention rate is greater than or equal to 88% after the material is aged for 1500 hours in a salt mist environment, the strength recovery rate of microcracks reaches 85% or above after the microcracks are subjected to heat treatment at 70 DEG C for 2 hours, and the material has excellent corrosion resistance, cracking resistance, self-repairing function and static dissipation capacity and is particularly suitable for cable protection in severe environments such as marine transportation and chemical engineering.