9799 results about "Polyol" patented technology

A fibrous insulation product comprising a plurality of randomly oriented glass fibers and a cross-linked formaldehyde-free binder composition at least partially coating the fibers is disclosed. The cross-linked formaldehyde-free binder composition is formed from an aqueous binder composition comprising 5.0% by weight to 37.0% by weight of at least one monomeric polyol having at least four hydroxyl groups and at least 50.0% by weight of a cross-linking agent comprising a polymeric polycarboxylic acid having at least two carboxylic acid groups, based on the total solids content of the aqueous binder composition. The glass fibers have an average fiber diameter in the range of 8 HT to 12 HT. The fibrous insulation product, after curing, has a density, when uncompressed, in the range of 0.30 pcf to 2.7 pcf.

The invention discloses an embolism part for peripheral arteriovenous vessels, the embolism part comprises an anchoring part and a blocking part fixedly connected with the anchoring part, the blocking part adopts polyurethane shape memory foam, the expansion rate of the polyurethane shape memory foam is 50-100 times, and a preparation method of the polyurethane shape memory foam comprises the following steps: step 1, preparing a polyurethane shape memory foam material; the preparation method comprises the following steps: preparing a polyurethane acrylate prepolymer from macromolecular polyol, diisocyanate, a chain extender containing disulfide bonds, other micromolecular chain extenders and an acrylate end-capping reagent; and 2, uniformly mixing the polyurethane acrylate prepolymer, a foaming agent, a foaming promoter and a photoinitiator to obtain a foaming solution, and sequentially carrying out light curing and foaming on the foaming solution to obtain the polyurethane shape memory foam. According to the embolism part, the polyurethane shape memory foam is adopted as the blocking part, the blocking part applies radial acting force to the wall of the blood vessel all the time based on the expansion trend of the blocking part, and the blocking part and the anchoring part jointly act and can be stably maintained in the blood vessel.

The invention belongs to the technical field of polyurethane elastomers, and particularly relates to a high-static-rigidity high-damping low-pressure-change polyurethane elastomer and a preparation method thereof. Comprising a polyol component and an isocyanate component, and the polyol component comprises polyol A, a chain extender, a stabilizer, a hydrolysis-resistant agent and a catalyst; the isocyanate component is prepared from isocyanate, polyhydric alcohol B and branched chain unit alcohol; the polyol A comprises amine ether polyol and polytetrahydrofuran ether polyol; the polyhydric alcohol B comprises bio-based hydrolysis-resistant polyhydric alcohol and polytetrahydrofuran ether polyhydric alcohol; the bio-based hydrolysis-resistant polyol is prepared by carrying out a reaction on sebacic acid, 1, 2-propylene glycol and 1, 4-butanediol; the branched-chain unit alcohol is prepared from tetrahydrofuran and isooctanol through a reaction. By introducing the bio-based hydrolysis-resistant polyhydric alcohol and branched chain monohydric alcohol, the damping effect is remarkably enhanced, and on this basis, through formula adjustment and raw material screening, the product toughness is greatly improved, the compression set is reduced, and the performance of the product in heavy haul railway application is effectively optimized.

The invention discloses a photopolymer type holographic recording medium and a preparation method and application thereof.The photopolymer type holographic recording medium comprises a writing monomer, film-forming resin, a photosensitive initiation combination agent and a catalyst, the writing monomer comprises nanoparticles and a polymerizable monomer, and the film-forming resin is prepared from the nanoparticles and the polymerizable monomer; the refractive index of the polymerizable monomer is smaller than that of the nanoparticles, and the difference between the refractive index of the nanoparticles and the refractive index of the polymerizable monomer is larger than 0.5. The film-forming resin includes a polyol compound and an isocyanate-based compound. The catalyst is used for catalyzing a polyol compound and an isocyanate compound to react to form a film. The photosensitive initiation combination agent is used for sensing light and inducing polymerization of the polymerizable monomer. According to the photopolymer type holographic recording medium disclosed by the invention, after exposure, the polymerizable monomers located in the bright area and the nanoparticles extruded to the dark area have relatively large refractive index difference, so that the refractive index modulation degree of the recording grating can be improved; the film-forming resin provides effective support for the nanoparticles, and the nanoparticles are not agglomerated.

The invention relates to the technical field of waterproof coatings, in particular to a polyurethane waterproof coating and a preparation process thereof. The polyurethane waterproof coating is prepared from the following raw materials: toluene diisocynate, polyether polyol, chlorinated paraffin, talcum powder, a latent curing agent, self-repairing microcapsules and temperature-sensitive polymer nanoparticles. According to the self-repairing capsule, hexamethylene diisocyanate serves as a core material, the outer layer of the self-repairing capsule is wrapped with a polyurethane / nano-silicon dioxide hybrid wall material or a urea-formaldehyde resin wall material, and the temperature-sensitive polymer nanoparticles are poly N-isopropylacrylamide. The self-repairing microcapsules and the temperature-sensitive polymer nanoparticles are used, the self-repairing capacity and the capacity of adapting to different environmental conditions of a coating film are improved, when tiny cracks occur in the coating film, the microcapsules are broken to release a repairing agent, the cracks are automatically filled, the integrity of the coating is recovered, and the self-repairing performance of the coating film is improved. And the temperature-sensitive polymer nanoparticles can expand when the temperature rises to further promote the flowing and curing of the repairing agent, so that the service life of the coating film is prolonged, and the maintenance cost is reduced.

The invention discloses a bio-based polyurethane coating and a preparation method thereof, and belongs to the technical field of coatings. The bio-based polyurethane coating comprises the following raw materials in parts by weight: 100 parts of vegetable oil polyol, 70-120 parts of isocyanate, 10-25 parts of a flame retardant, 30-40 parts of an organic solvent, 1-5 parts of a catalyst, 10-30 parts of a hydrophilic chain extender, 10-30 parts of a neutralizer and 20-40 parts of deionized water. The preparation method comprises the following steps: adding plant polyol, isocyanate, a flame retardant, an organic solvent and a catalyst into a container, mixing and reacting to obtain a prepolymer mixed solution, then adding a hydrophilic chain extender, mixing and reacting to obtain a polymer mixed solution, cooling, then adding a neutralizer for neutralizing, then adding deionized water for emulsifying to form a polyurethane emulsion, and finally adding a curing agent for curing. And performing reduced pressure distillation to obtain the bio-based polyurethane coating. According to the invention, biomass-sourced acid reacts with the organosilicon compound to generate the flame retardant, and the prepared bio-based polyurethane coating has good flame retardant property.

The invention discloses an easy-to-apply single-component polyurethane waterproof coating and a preparation method thereof, and belongs to the technical field of waterproof coatings. The easy-to-apply single-component polyurethane waterproof coating disclosed by the invention is prepared from the following raw materials: polyol, a plasticizer, a solid filler, isocyanate, a catalyst and a solvent, the polyol comprises polyether glycol and polyether triol; the plasticizer comprises acetyl tributyl citrate; the catalyst comprises a bismuth neodecanoate catalyst and a dimorpholine diethyl ether catalyst. According to the easy-to-apply single-component polyurethane waterproof coating disclosed by the invention, acetyl tributyl citrate is used for replacing traditional plasticizer chlorinated paraffin, and a bismuth neodecanoate catalyst and a dimorpholine diethyl ether (DMDEE) catalyst are compounded, so that the viscosity of the waterproof coating is effectively reduced, and construction is facilitated; meanwhile, the drying speed of the waterproof coating is increased.

An aqueous ultraviolet-absorbing resin emulsion, and an aqueous resin emulsion composition containing the emulsion is provided, wherein the emulsion is excellent in compatibility with a synthetic resin and light resistance. Also, the emulsion improves stability in blending with an aqueous emulsion of the synthetic resin, and prevents bleed out of the ultraviolet-absorbing resin on the surface of a coating film. Further, the aqueous ultraviolet-absorbing resin emulsion imparts excellent alkali or solvent resistance to a synthetic resin poor in alkali or solvent resistance. More specifically, an aqueous resin emulsion composition comprising (I) an aqueous ultraviolet-absorbing resin emulsion and (II) an other aqueous resin emulsion is provided, wherein the emulsion (I) is obtained by urethanizing (A) a polyol component having an ultraviolet-absorbing group {e.g., 1,1-bis[3-(2H-benzotriazol-2-yl)-4-hydroxy-benzeneethanol]methane}, (B) a polyol if necessary, (C) an alkyl or aryl dialkanolamine compound, and (D) an organic polyisocyanate in (E) an organic solvent, diluting the reaction mixture with (F) an organic solvent having a boiling point lower than 100° C. to give a resin solution, neutralizing the resin solution with (G) a neutralizing agent, and dispersing the resultant in water.

The invention belongs to antibacterial materials, and particularly relates to antibacterial modified waterborne polyurethane and a preparation method and application thereof.The preparation method of the antibacterial modified waterborne polyurethane comprises the following steps that polyol and diisocyanate are mixed and subjected to a prepolymerization reaction, and a polyurethane prepolymer is obtained; mixing the polyurethane prepolymer and a chain extender, and carrying out chain extension reaction; in the chain extension reaction, adding the graft and carrying out esterification reaction to obtain a first intermediate; mixing the first intermediate with triethylamine and carrying out neutralization reaction to obtain a second intermediate; and emulsifying the second intermediate in deionized water to obtain the antibacterial modified waterborne polyurethane. Compared with the prior art, the antibacterial waterborne polyurethane has the advantages that the problems of poor intermiscibility, low durability and the like in physical addition and the problems of limited binding objects and weak antibacterial effect in covalent binding in the antibacterial waterborne polyurethane in the prior art are solved. According to the scheme, arginine and chitosan are grafted to a molecular chain of waterborne polyurethane, so that the waterborne polyurethane is endowed with a synergistic antibacterial property.

The invention discloses an INS film with excellent comprehensive performance, which comprises a surface protection layer, an upper base material layer, a printing ink layer, a bonding glue layer and a lower base material layer which are sequentially superposed from top to bottom, the surface protection layer is prepared from the following raw materials in parts by weight: 75-135 parts of polyester polyol resin, 30-60 parts of hydroxy acrylic resin, 2-25 parts of an isocyanate curing agent, 2-17 parts of a closed curing agent, 2-25 parts of a chain extender, 0.5-8 parts of a catalyst, 0.5-2 parts of an antioxidant and 0.5-3 parts of an ultraviolet light absorber. According to the surface protection layer of the INS film, the high-temperature condition of a high-temperature plastic uptake procedure of the INS film in preparation of INS parts is well utilized, so that the closed curing agent is effectively excited to perform secondary cross-linking curing reaction. The INS film is good in surface chemical reagent resistance, has the characteristics of high heat stretch rate, high hardness and scratch resistance, has excellent ultraviolet irradiation yellowing resistance, and is particularly suitable for the field of in-mold decoration.

The invention relates to the technical field of adhesives, and discloses an antibacterial mildew-proof water-based adhesive and a preparation method thereof. The preparation method of the antibacterial and mildew-proof water-based adhesive comprises the following steps: reacting 2, 2-dimethylolpropionic acid with castor oil to obtain hyperbranched bio-based polyol; modifying the hyperbranched bio-based polyol by using a modifier to obtain modified bio-based polyol; the preparation method comprises the following steps: preparing a waterborne polyurethane dispersion liquid by taking modified bio-based polyol, a hybrid modified BN / MOF composite material and hexamethylene diisocyanate as raw materials and 1, 4-butanediol as a chain extender; the preparation method comprises the following steps: mixing a waterborne polyurethane dispersion liquid, a wetting agent, a defoaming agent, a thickening agent and water to obtain a component A; an aliphatic curing agent is used as a component B; during use, the component A and the component B are mixed and stirred. The antibacterial and mildewproof water-based adhesive disclosed by the invention has excellent adhesion performance, water resistance, self-repairing performance and lasting antibacterial and mildewproof performance.

The invention discloses a preparation method and application of a conductive polypyrrole compound. The preparation method comprises the following steps: (1) preparing an emulsion system; (2) adding an oxidizing agent; (3) diluting and dropwise adding monomer pyrrole, and reacting for 6-24 hours; and (4) washing the product, and applying the product to preparation of the foamed conductive polyurethane foam. Comprising the following steps: 1, filtering a conductive polypyrrole compound; 2, carrying out synthesis post-treatment on the conductive polypyrrole compound; 3, effectively mixing the polypyrrole compound with a commercial polyurethane foaming component (firstly premixing with an isocyanate-containing component or a polyol-containing component, and then effectively mixing with another polyol-containing component or an isocyanate-containing component); and 4, carrying out one-time forming foaming to obtain the conductive product. The preparation method has the advantages that better dispersion can be realized by synthesizing the conductive polypyrrole compound which is microcosmically in a nano-scale dendritic shape, and the use amount of a conductive material is reduced; the foamed conductive polyurethane foam is simple and convenient to construct, can be foamed instantly, has high foaming rate, retains the original mechanical properties by more than 50%, and has good conductivity.

The invention relates to a preparation method and application of an artificially synthesized exosome with an anti-aging effect, and belongs to the technical field of cosmetics and biology. The artificially synthesized exosome is prepared from hydrogenated lecithin, phytosphingosine, cholesterol, ceramide, squalane, sodium stearoyl glutamate, a surface modification structure, polyol, an active component and water. The preparation method comprises the steps of preparation of an alcohol phase, preparation of a water phase, preparation of a mixed solution and high-pressure homogenization treatment. The artificially synthesized exosome prepared by the preparation method provided by the invention is good in stability and high in anti-aging activity.

The invention provides a preparation method of a waterproof flame-retardant multifunctional fabric, and belongs to the technical field of functional textiles. The preparation method comprises the following steps: heating dihydric alcohol until the dihydric alcohol is completely melted, adding diisocyanate, a flame retardant and a catalyst, reacting to obtain a polyurethane prepolymer, adding a chain extender for chain extension, then adding an end-capping reagent for end capping, cooling, adding an emulsifier to obtain a waterproof flame retardant emulsion, adding water to form a finishing agent, soaking a polyacrylonitrile pre-oxidized fiber fabric in the finishing agent for treatment, and drying to obtain the waterproof flame retardant fabric. And pre-drying and baking to obtain the multifunctional fabric. Polyhydric alcohol with a long alkane chain is adopted to carry out chain extension on a polyurethane prepolymer, the obtained waterproof agent has good film-forming property, can be firmly fixed on the surface of a fiber without the help of a cross-linking agent or an adhesive during application, and endows a modified textile with excellent washing fastness.

The invention relates to polyurethane resin, synthetic leather and a preparation method and application thereof, and relates to the technical field of polyurethane, the polyurethane resin is prepared from the following raw materials: bio-based polyester polyol, polyolefin polyol, isocyanate, a chain extender, a pore-forming agent and a solvent; the bio-based polyester polyol is prepared from the following raw materials: bio-based dihydric alcohol, bio-based dibasic acid and micromolecular branched chain-containing dihydric alcohol. The polyurethane resin provided by the invention is high in bio-based content, micromolecular branched chain-containing dihydric alcohol is introduced into bio-based polyester polyol, a branched chain structure provides scratch resistance for the synthetic leather taking the polyurethane resin as a coating layer, the crystallinity of the polyurethane resin is reduced by compounding the polyolefin polyol, the synthetic leather is endowed with soft hand feeling, and the synthetic leather has the advantages that the synthetic leather is not prone to being scratched, and the service life of the synthetic leather is prolonged. Due to the addition of the chain extender and the pore-forming agent, the polyurethane has excellent foaming performance, the synthetic leather has excellent water absorption, and the hand feeling of the synthetic leather is further improved.

The invention relates to the technical field of drilling fluid cooling, and discloses a phase change microcapsule suitable for drilling fluid cooling and a preparation method thereof.The phase change microcapsule comprises a capsule wall stabilizing material and a capsule core phase change material, and the capsule wall stabilizing material comprises polyurethane, polyurea, polyamide, polyimide, polystyrene and a first organic solvent; the capsule core phase change material comprises paraffin, fatty acid, polyol, inorganic hydrated salt, polymer gel, expanded graphite, carbon nanotubes, metal nanoparticles and a second organic solvent, and the first organic solvent is at least one of toluene, xylene, cyclohexanone and the like. The temperature of the drilling fluid is kept at a relatively low level, the cooling of the drilling fluid is realized, so that the drilling efficiency is improved, harmful solvents and additives are not used in the preparation process of the phase-change microcapsules, the phase-change microcapsules are pollution-free to the environment, and the requirements of greenness and environmental protection are met.

The invention discloses a super-wear-resistant super-hydrophobic coating in the technical field of coatings, the super-wear-resistant super-hydrophobic coating comprises a primer and a finishing coat, the primer comprises solvent-free aliphatic polyether polyol resin, micro-powder particles, di-tetratoluene diisocynate, fumed silica nanoparticles and a primer magnetic attraction material; the finishing paint comprises hydrophobic nanoparticles, a diluent, a finishing paint magnetic attraction material and a hydrophobic treatment agent, the primer magnetic attraction material is ferrite powder, and the finishing paint magnetic attraction material is nickel powder. The preparation method comprises the following steps: 1, preparing the primer; secondly, primer is sprayed; step 3, roughening the primer; 4, finish paint is manufactured; step 5, spraying finish paint; and step 6, detecting the performance of the coating. The preparation method is scientific and reasonable, the uniformity and stability of the coating in the preparation and coating process are ensured by optimizing the composition of the coating material, improving the preparation process and introducing a magnetic suction device, and therefore the wear resistance, hydrophobicity and adhesive force of the coating are improved.

The invention relates to the technical field of polyurethane adhesives, in particular to a quick-curing two-component hot-pressing adhesive as well as a preparation method and application thereof. Comprising a component A and a component B. The component A comprises, by weight, 20 to 60 parts of castor oil polyol, 40 to 80 parts of a filling material, 0.001 to 0.01 part of a catalyst and 0.001 to 0.006 part of an auxiliary agent, and the catalyst comprises a triethylene diamine-terminated heat-sensitive catalyst; and the component B comprises an isocyanate curing agent. The filler comprises heavy calcium carbonate and calcium oxide, and the weight ratio of the heavy calcium carbonate to the calcium oxide is (25-40): 1, so that not only can the cost be effectively reduced, but also the tensile-shear strength of the hot-pressing adhesive can be improved; and when the particle size of the filler is adjusted to be 500-2000 meshes, the tensile-shear strength after cementing can be effectively maintained within a relatively low curing time (3-5 minutes), and meanwhile, the storage stability of the sizing material is improved.

The invention relates to the technical field of antibacterial non-woven fabrics, and discloses an intrinsic antibacterial non-woven fabric and a preparation method thereof.The intrinsic antibacterial non-woven fabric is prepared by adopting a dip-coating method and by soaking a non-woven fabric in antibacterial slurry, taking out the non-woven fabric for drip drying and then drying the non-woven fabric to constant weight; wherein the antibacterial slurry is prepared by compounding antibacterial polyol with a synergistic antibacterial effect, nano titanium dioxide modified by a coupling functional phenolic hydroxyl Schiff base type antibacterial monomer and a branched antibacterial monomer. According to the intrinsic antibacterial non-woven fabric, the technical problems that in the prior art, an antibacterial agent is large in toxicity, prone to loss and insufficient in antibacterial spectrum coverage range are solved, and the intrinsic antibacterial non-woven fabric can also be applied to the field of filtering materials, the field of medical treatment and public health and the field of textile materials and has the beneficial technical effects of inhibiting bacterial growth and guaranteeing sanitation and safety.

The invention relates to the technical field of polyurethane foam, and discloses fireproof flame-retardant foaming polyurethane and a preparation method thereof.The foaming polyurethane comprises a component A and a component B. The component A comprises, by weight, 100 parts of polyether polyol, 25-50 parts of a flame-retardant chain extender and the like; and the component B is 62-86 parts by weight of an isocyanate compound. The flame-retardant chain extender contains a plurality of polymerization sites, so that the crosslinking density of a polyurethane molecular chain is improved, a stable crosslinking network is formed, and meanwhile, the flame-retardant chain extender contains a siloxane structural unit with structural stability, so that the foamed polyurethane has higher compression strength. The flame-retardant chain extender contains a phosphate flame-retardant group, and forms a phosphorus-silicon flame-retardant system with a siloxane structure, so that the combustion heat release rate peak value, the total heat release amount and the total smoke release amount of foam are reduced, and the flame-retardant chain extender has good fireproof and flame-retardant properties.

The invention provides a polyester polyol production method, a polyester polyol production device and application, according to the polyester polyol production method, single-stage gas-liquid separation in the prior art is improved, and at least two-stage series gas-liquid separation is carried out in the esterification reaction process, so that the total production time is shortened, the production efficiency is improved, and the production cost is reduced. By-products such as polyether can be effectively removed, and the product quality stability of the polyester polyol can be effectively improved.

The invention discloses a temperature-resistant high-strength powder coating and a preparation method thereof, and belongs to the field of coatings. The invention relates to a temperature-resistant high-strength powder coating which is prepared from the following raw materials in percentage by weight: 40-50% of epoxy resin; 20-30% of polyester resin; 6-10% of a curing agent; 1-3% of a leveling agent; 1-2% of a filler; and the balance of pigment. According to the polyester resin, aliphatic diisocyanate reacts with polyether polyol and hydroxyl silicone oil to obtain a polyurethane prepolymer, and then the polyurethane prepolymer reacts with vinyl benzylamine, an acrylate monomer and an acrylic monomer to obtain the polyester resin. The powder coating has the advantage that the temperature resistance and the strength of the powder coating are improved.

The invention relates to a manufacturing method of high-density aviation fuel, in particular to an aviation fuel mixture based on monoterpenoids and a preparation method of the aviation fuel mixture. Comprising monoterpenoids, polyhydric alcohols and a catalyst which serve as raw materials, and the mass ratio of the raw materials to the polyhydric alcohols is 1: 1. The conversion rate is high, the treatment steps are reduced, the thermal stability and combustion gravimetric heat of the product are improved, and the method is suitable for preparing aviation fuel with high density, low viscosity and low-temperature performance; cyclization and hydrogenation are carried out through a one-pot method, a reaction container does not need to be transferred, and the operation is simple; according to the polyol solvent system, cyclization of the monoterpenoids becomes easier due to participation of polyol, and the conversion rate is increased; according to the dual-catalyst system, a combination of an acidic catalyst and a heterogeneous hydrogenation catalyst is used in a reaction container, so that efficient dehydration and hydrogenation reactions are ensured; the aromatic compound content in the fuel can be controlled by adjusting hydrogenation conditions.

The invention provides a polyurethane modified epoxy resin material for a prepreg and a preparation method of the polyurethane modified epoxy resin material. Comprising 10-35 parts by weight of polyester or polyether polyol, 1-10 parts by weight of isocyanate, 40-70 parts by weight of epoxy resin, 1-3 parts by weight of a light stabilizer, 1-2 parts by weight of an antioxidant, 1-2 parts by weight of an ultraviolet absorbent and 5-30 parts by weight of a chain extender and a curing agent. According to the invention, the intrinsic flexible epoxy resin is prepared by grafting modification of the polyurethane prepolymer, and is applied to a prepreg resin system and a medium-temperature cured carbon fiber prepreg, so that the brittleness of the epoxy resin is improved, and the elongation at break of the epoxy resin is improved, thereby realizing a toughening effect and a composite material forming process.

The invention provides a polyurethane material for leaking stoppage of coal mine spraying and a preparation method thereof, and belongs to the technical field of polyurethane. The preparation method comprises the following steps: pretreating a multi-walled carbon nanotube, coupling phytic acid and a silane coupling agent, reacting with UiO-66-NH2, coating the surface with a graphene oxide layer, mixing with polyether polyol, a catalyst and an antistatic agent, adding into water, adding a foaming agent and silicone oil, heating, stirring and mixing, transferring into a mold, adding diisocyanate, and after foaming is completed and the temperature of the material is reduced to room temperature, carrying out extrusion molding to obtain the composite material. And drying, heating and curing to obtain the polyurethane material for coal mine spraying air leakage stoppage. By adding the prepared wrinkled graphene oxide coated UiO-66-NH2 / modified multi-walled carbon nanotubes, the mechanical property and strength of the prepared polyurethane material for coal mine spraying air leakage stoppage can be obviously improved, the flame retardant property such as the oxygen index of the material is also obviously improved, the foam expansion is improved to a certain extent, the preparation method is simple, and the preparation method is suitable for industrial production. The flame-retardant and mechanical properties can be obviously improved, and the application prospect is wide.

The invention provides a preparation method of a nylon elastomer with good dyeing property, antibacterial property and antistatic property. The preparation method comprises the following steps: S1, preparing a dicarboxyl-terminated nylon hard segment from binary acid, diamine or lactam and an end-capping reagent; s2, reacting the dicarboxyl-terminated nylon hard segment with polyether polyol to generate a dicarboxyl-terminated nylon elastomer with a certain molecular weight; s3, reacting the double-carboxyl-terminated nylon elastomer with the double-amino-terminated aminoguanidine compound to generate a double-amino-terminated nylon elastomer with a guanidyl group; and S4, dipping the double-amino-terminated nylon elastomer with the guanidyl group by using an anionic antistatic agent solution. The novel nylon elastomer prepared by the invention has higher molecular weight, the dyeing property of the novel nylon elastomer is favorably improved by diamino-terminated end, guanidyl is introduced in a copolymerization manner, so that the novel nylon elastomer has good antibacterial property, and meanwhile, the guanidyl is combined with the anionic antistatic agent through an ionic bond, so that the nylon elastomer has firmer antistatic property.

The invention relates to a Fenton-like functional filler which is prepared from 10-20% of iron particles coated with a carbonized film, 10-20% of aluminum sulfate modified straw, 20-30% of PBAT-coated calcium peroxide, 20-30% of diatomite and 10-30% of an adhesive. A processing method of a Fenton-like functional filler comprises the following steps: uniformly mixing iron particles coated with a carbonized film, aluminum sulfate modified straws, PBAT-coated calcium peroxide and diatomite, then adding an adhesive, mixing isocyanate serving as the adhesive with polyol according to a volume ratio of 1: 5, and continuously and uniformly mixing; then the mixed raw materials are injected into a mold coated with a release agent in advance, the mold temperature ranges from 40 DEG C to 60 DEG C, the foaming curing time ranges from 15 min to 20 min, and the Fenton-like functional filler can be obtained. The invention relates to an application of a Fenton-like functional filler in constructed wetlands. The method has the beneficial effects that the method is not influenced by temperature, and the removal effect of the constructed wetland on nitrate nitrogen and refractory COD (Chemical Oxygen Demand) can be obviously enhanced.

The invention discloses a chlorine-resistant and acid-resistant composite nanofiltration membrane and a preparation method thereof, and belongs to the technical field of membrane separation. A polyhydric alcohol or / phenol compound monomer containing no less than two hydroxyl groups is subjected to interfacial polymerization with cyanuric chloride, so that a relatively loose network structure can be formed, and selective separation of dye and salt is realized. As a hydrochloric acid (HCl) byproduct can be generated in the reaction process, an alkaline compound is added as an acid-binding agent to neutralize HCl and promote the interfacial polymerization reaction, the formed composite nanofiltration membrane structure does not contain amino groups and polyamide bonds sensitive to active chlorine, the reaction sites of the active chlorine are reduced, and the chlorine-resistant stability of the membrane is good. Meanwhile, the polymer film contains a triazine ring structure, and a formed ether bond has good chemical stability, so that the acid-resistant stability of the film is good. The prepared composite nanofiltration membrane has good nanofiltration separation performance, shows good chlorine-resistant and acid-resistant stability, and can be used for separation of dyes / salts.

The invention discloses a method for preparing a platinum-based alloy catalyst by using a plasma enhanced chemical vapor deposition low-temperature technology, relates to a preparation method of a platinum-based alloy catalyst, and aims to solve the technical problems that a carbon layer is not uniformly coated and metal particles of the catalyst are easy to agglomerate in a high-temperature calcination process in the existing platinum-based alloy catalyst prepared by carbon coating. The method comprises the following steps: 1, preparing Pt / C by a polyhydric alcohol reduction method; 2, pre-treating a Pt / C catalyst; 3, preparing M-Pt / C by a dipping evaporation method; 4, PECVD carbon shell coating is carried out; (5) alloying; and 6, removing a part of carbon shell to obtain the platinum-based alloy catalyst. When the Pt / C catalyst is used for preparing a membrane electrode of a proton exchange membrane fuel cell, the peak power density can reach 1.72-1.89 W / cm < 2 > under a hydrogen-air condition, which is improved by 20.3% and 32.2% compared with a membrane electrode of a commercial 20% Pt / C catalyst, and the Pt / C catalyst can be used in the field of proton exchange membrane fuel cells.

The invention discloses a low-temperature-resistant hydrolysis-resistant polyurethane protector material and a preparation method thereof. The low-temperature-resistant hydrolysis-resistant polyurethane protector material is prepared from a component A and a component B through cross-linking and curing, wherein the component A is prepared from polyether polyol, bifunctional hydroxyl-terminated polysiloxane, modified polyborosiloxane, a cross-linking agent, a chain extender, a foaming agent, a foam stabilizer, a catalyst and a pore opening agent, and the component B is isocyanate. The protective clothing prepared from the material has excellent buffer energy absorption performance, low temperature resistance and hydrolysis resistance, and meets the use requirements in extremely cold weather.