The invention discloses an anti-
corrosion composite furnace lining material for
zircon sand fluidizing chlorination and a preparation method thereof.The anti-
corrosion composite furnace lining material comprises a base body layer and an anti-
chlorine-seepage
protection layer, and the preparation method comprises the steps of base body layer preparation,
coating liquid preparation, base body layer
surface coating,
coating curing, high-temperature firing,
chlorine seepage treatment and annealing. According to the method, the specially-made
coating liquid is adopted for enhancing the surface of the high-purity
corundum furnace lining for the first time, the permeability of the coating liquid to a base body layer is improved by means of matched
dissolution-
sedimentation of
chromium chloride and
phosphoric acid, pores are blocked by means of expansion caused by
dehydration and oxidation of CrCl3. 6H2O, densification of
surface layer Cr2O3,
spinel and
phosphate and
surface layer pore blocking are achieved, the
porosity is greatly reduced, and the
porosity of the high-purity
corundum furnace lining is improved. The
chlorine permeability is reduced, and the core problems of high permeability and short service life of the material in a high-temperature chlorine
corrosion environment are solved; according to the invention, a chlorination-annealing self-cleaning process is matched to realize deep removal of impurities, so that the product purity of the chlorination process is improved, and the purification cost is reduced.