The application discloses a thermal / environmental barrier
coating with an interface
thermal expansion mismatch relieving layer and a preparation method and application thereof, and belongs to the technical field of
thermal protection coating materials. The
coating comprises, from outside to inside, a Si bonding layer, an RE12O3-2SiO2 environmental barrier coating, an interface
thermal expansion mismatch relieving layer formed by a
thermal shrinkage ceramic and an RE22O3-2MO-11Al2O3
ceramic composite, and an RE22O3-2MO-11Al2O3
thermal barrier coating. The coating is prepared by sequentially depositing the bonding layer, the environmental barrier coating, the interface
thermal expansion mismatch relieving layer and the
thermal barrier coating on the surface of a pretreated
silicon carbide ceramic matrix composite by means of an atmospheric
plasma spraying technology. The coating effectively relieves the thermal expansion mismatch problem at the interface between the
thermal barrier coating and the environmental barrier coating, has excellent
thermal cycle performance, can meet the long-time service requirement of an aero-engine hot end component under a high-temperature condition, and has wide application potential.