4900 results about "Ether" patented technology

The invention provides a positive electrode, a low-temperature electrolyte, a low-temperature sodium-ion battery and a preparation method and application of the low-temperature sodium-ion battery, and belongs to the technical field of battery materials. The low-temperature sodium ion battery comprises a positive electrode, a negative electrode and a low-temperature electrolyte, wherein the positive electrode comprises a positive electrode active material, a binder, sodium salt containing fluorine and sulfur and conductive carbon; the positive electrode is improved by adding sodium salt containing fluorine and sulfur, sulfur / fluorine rich in anion derivatives can be formed on a contact interface of the positive electrode and an electrolyte to form a firm SEI film, the internal resistance of the battery is further reduced, and the coulombic efficiency of the battery during charging and discharging at normal and low temperatures is improved. The low-temperature electrolyte comprises an ester solvent and an ether additive, by adding the ether solvent, the physicochemical property of the electrolyte and the composition of an SEI film on a contact interface of an electrode and the electrolyte are optimized, the viscosity of the electrolyte at low temperature is reduced, the ionic conductivity is improved, and formation of the SEI film rich in sodium fluoride on the surface of a negative electrode can be promoted; and thus, the problem of low coulombic efficiency of battery charge-discharge cycle at low temperature is solved.

The invention belongs to the technical field of anion exchange membranes, and relates to a cross-linked polyaromatic piperidine anion exchange membrane and a preparation method thereof. The exchange membrane structure comprises a copolymer structure of the following repetitive structural units, the selected rigid main chain polyaromatic hydrocarbon can ensure the mechanical strength of the anion exchange membrane, meanwhile, the toughness of the anion exchange membrane is further enhanced by adopting a cross-linked structure, and a formed cross-linked network can reduce swelling of the anion exchange membrane, so that the anion exchange membrane is more stable in performance. The mechanical performance is improved; according to the invention, ether-free skeleton polyaromatic hydrocarbon is selected as a main chain and has the characteristic of strong alkali-resistant stability, six-membered nitrogen heterocyclic ions are adopted as functional groups, and a large steric hindrance structure can hinder nucleophilic substitution and elimination reaction, so that the alkali-resistant stability of the anion exchange membrane is improved, and the service life of the anion exchange membrane is prolonged. And in the # imgabs0 #, X is equal to 0.05 to 0.15.

The invention relates to the technical field of filling materials, and particularly discloses an ardealite-based high-strength anti-seepage filling material and a preparation process thereof, the ardealite-based high-strength anti-seepage filling material comprises 50%-65% of pretreated ardealite, 15%-25% of Portland cement, 5%-15% of superfine slag powder, 5%-10% of electrolytic manganese residues, 5%-8% of silica fume, 3%-6% of metakaolin, 2%-4% of a composite alkali activator and 0.5%-1.2% of a polycarboxylic acid water reducer, 0.3%-0.8% of an organic silicon water repellent and 0.05%-0.1% of cellulose ether; according to the invention, through chemical reaction of Mn < 2 + > in the electrolytic manganese residue and SO4 < 2-> in the phosphogypsum, micron-sized manganite crystals (MnAl2 (SO4) 4. 22H2O) are generated to actively fill internal micro-cracks of the material, so that a filling body is endowed with a self-repairing function and the impermeability is improved, and a composite alkali activator composed of NaOH and water glass is used for synergistically activating potential gelling activity of the superfine slag powder and the silica fume, so that the self-repairing filling material is prepared. And the formation of hydration products is accelerated, and 0.3-0.5 T of pulsed magnetic field is applied in the stirring process, so that the manganite crystals are guided to orderly grow along the expected stress direction of the filling body, and the compressive strength is improved.

The invention belongs to the technical field of polyurethane elastomers, and particularly relates to a high-static-rigidity high-damping low-pressure-change polyurethane elastomer and a preparation method thereof. Comprising a polyol component and an isocyanate component, and the polyol component comprises polyol A, a chain extender, a stabilizer, a hydrolysis-resistant agent and a catalyst; the isocyanate component is prepared from isocyanate, polyhydric alcohol B and branched chain unit alcohol; the polyol A comprises amine ether polyol and polytetrahydrofuran ether polyol; the polyhydric alcohol B comprises bio-based hydrolysis-resistant polyhydric alcohol and polytetrahydrofuran ether polyhydric alcohol; the bio-based hydrolysis-resistant polyol is prepared by carrying out a reaction on sebacic acid, 1, 2-propylene glycol and 1, 4-butanediol; the branched-chain unit alcohol is prepared from tetrahydrofuran and isooctanol through a reaction. By introducing the bio-based hydrolysis-resistant polyhydric alcohol and branched chain monohydric alcohol, the damping effect is remarkably enhanced, and on this basis, through formula adjustment and raw material screening, the product toughness is greatly improved, the compression set is reduced, and the performance of the product in heavy haul railway application is effectively optimized.

The invention relates to the technical field of organic chemical synthesis, in particular to a preparation method of 3, 4 '-diaminodiphenyl ether.The preparation method comprises the steps that S1, under inert gas and in a first solvent, m-dinitrobenzene and p-acetamidophenol are subjected to a heating reaction under the condition of a weak base catalyst, and 3-nitro-4-acetamido diphenyl ether is prepared; s2, in a second solvent, the 3-nitro-4-acetamido diphenyl ether is subjected to a hydrogenation reduction reaction, and 3-amino-4-acetamido diphenyl ether is prepared; and S3, dissolving the 3-amino-4-acetaminodiphenyl ether in an alcohol solvent system, adding an aqueous solution of alkali, controlling the reaction temperature, carrying out a hydrolysis reaction, and after the reaction is finished, carrying out post-treatment to obtain the 3, 4 '-diaminodiphenyl ether. The preparation method provided by the invention has the advantages of easily available raw materials, low price, good selectivity and high product yield, and is more suitable for industrial production by comprehensively considering economical efficiency and safety.

The present disclosure provides a solid electrolyte composition that can suppress deterioration in ion conductivity of an ionic solid electrolyte material. The solid electrolyte composition according to the present disclosure contains a sulfur element-free ionic solid electrolyte material and an organic solvent, where the organic solvent includes at least one selected from the group consisting of a hydrocarbon and a compound having a functional group; and the functional group is at least one selected from the group consisting of an ether group, a halogen group, and a Si—O—C group.

The invention provides a modified coal gangue-based large-flow-state grouting and water plugging material and a preparation method thereof. Comprising 80-90 parts of a coal gangue sample, 1-5 parts of Portland cement, 1-5 parts of sulphoaluminate cement, 0.51-3 parts of a polycarboxylic acid water reducing agent, 1-4 parts of cellulose ether with the viscosity of 200w, 0.1-5 parts of a calcium oxide expanding agent, 0.5-5 parts of a plastic expanding agent, 0.5-1 part of redispersible latex powder, 0.5-5 parts of polyacrylamide with the molecular weight of 1000 and water, and the water-material ratio is 0.4. According to the modified coal gangue-based large-flow-state grouting and water plugging material and the preparation method thereof, the cement consumption can be remarkably reduced, the cost is reduced, the utilization rate of solid wastes (such as coal gangue) is increased, and the material has good flow-state performance and adjustable setting time; the method is suitable for deep and large shaft surrounding rock water seepage treatment in coal mining and other mine engineering.

The invention discloses a porphyrin-based covalent organic framework nano material, a preparation method and application of the porphyrin-based covalent organic framework nano material in polyurethane, and belongs to the field of functional nano materials and antibacterial materials. The porphyrinyl covalent organic framework nano material is prepared from 5, 10, 15, 20-tetra (4-aminophenyl) porphyrin and bis-(5-formyl furfuryl) ether through a Schiff base reaction, and the structural formula of the porphyrinyl covalent organic framework nano material is # imgabs0. The porphyrinyl covalent organic framework nano material prepared by the invention has relatively high photothermal conversion efficiency when being used as a photothermal agent, and has a relatively good sterilization effect under the condition of relatively low concentration. Besides, based on the porphyrin-based covalent organic framework nano material, a WPUS / Por-COF composite film is prepared, the composite film has excellent mechanical properties and excellent photothermal conversion efficiency, and has a good sterilization effect under the condition of relatively low concentration, bacteria can be inactivated within a short time, and the sterilization rate can reach 99% or above.

The invention provides a preparation method of an h-BN / PI high-temperature-resistant anticorrosive coating, and relates to the technical field of polymer composites.The preparation method of the h-BN / PI high-temperature-resistant anticorrosive coating comprises the steps that under the protection of inert atmosphere, aromatic diamine containing impurity element five-membered rings and aromatic dianhydride containing ether bonds are taken and subjected to a polymerization reaction in a polar aprotic solvent, and the h-BN / PI high-temperature-resistant anticorrosive coating is obtained. A polyamide acid solution is obtained; performing ultrasonic-assisted liquid phase stripping on the micron-sized hexagonal boron nitride to obtain single-layer hexagonal boron nitride; adding the single-layer hexagonal boron nitride into the polyamide acid solution for multiple times, and uniformly stirring to obtain a hexagonal boron nitride / polyimide composite solution; and coating the hexagonal boron nitride / polyimide composite liquid on a to-be-coated surface, and carrying out gradient heating curing to obtain the h-BN / PI high-temperature-resistant anticorrosive coating. The h-BN / PI high-temperature-resistant anticorrosive coating based on interaction of multiple hydrogen bonds has relatively good high temperature resistance, relatively good resistance mechanical property and excellent corrosion resistance.

The invention belongs to the technical field of oil and gas development, and particularly relates to an oil and gas well blocking remover and a preparation method thereof. The blocking remover comprises the following components: 5-8% of low-carbon composite organic acid, 5-7% of fluoboric acid, 6-9% of ammonium bifluoride, 4-6% of an anti-acid sludge mutual solvent, 2-4% of a corrosion inhibitor, 2-4% of polyoxypropylene polyoxyethylene propylene glycol ether, 8-12% of a permeation dispersion surfactant, 2-5% of a sulfur dissolving agent, 2-5% of a stable chlorine dioxide solution and the balance of water. The preparation method comprises the following steps: adding the low-carbon composite organic acid, the fluoboric acid and the ammonium bifluoride into water and stirring; adding an acid sludge resisting mutual solvent and a sulfur dissolving agent, and stirring; adding the corrosion inhibitor, the polyoxypropylene polyoxyethylene propylene glycol ether and the permeation dispersion surfactant, and stirring; and finally, reducing the stirring speed, adding the stable chlorine dioxide solution, and stirring to uniformly mix. The blocking remover provided by the invention is comprehensive in blocking removal function, very good in dissolving and dispersing performance on complex blocking substances, very small in corrosion damage to a shaft pipe wall and wide in applicability.

The invention provides solid-waste-based fluid-state solidified soil and a preparation method of the solid-waste-based fluid-state solidified soil. The solid waste-based flow state solidified soil comprises a filling material, a framework material and a reinforcing material, the filling material comprises the following components in parts by weight: 60-95 parts of engineering residue soil, 5-40 parts of alkaline waste residues, 5-30 parts of a cementing material, 1-10 parts of a polymer emulsion, 0.5-3 parts of silica fume, 0.1-1 part of cellulose ether, 0.1-1 part of a compound water reducing agent and 0.5-2 parts of an exciting agent. The framework material comprises waste concrete blocks and / or waste brick blocks; the reinforcing material comprises a waste safety net and / or fiber gridding cloth. The flow-state solidified soil can achieve rapid backfilling in a narrow space, is excellent in shrinkage cracking resistance and impermeability, simple in preparation method and convenient to apply and construct, effectively solves the problems that the flow-state solidified soil is large in shrinkage, prone to cracking and the like, improves the quality of a backfilling project, achieves in-situ resource utilization of construction waste, and reduces the construction cost. And the construction cost of engineering can be reduced, and the problems of land occupation, environment pollution and the like caused by solid waste stacking are reduced.

The present disclosure provides a solid electrolyte composition that can suppress deterioration in ion conductivity of an ionic solid electrolyte material. The solid electrolyte composition according to the present disclosure contains a sulfur element-free ionic solid electrolyte material and an organic solvent, where the organic solvent includes at least one selected from the group consisting of a hydrocarbon and a compound having a functional group; and the functional group is at least one selected from the group consisting of an ether group, a halogen group, and a Si—O—C group.

The invention discloses an organic amine composite absorbent for carbon capture and application thereof, and belongs to the technical field of carbon dioxide capture, the organic amine composite absorbent for carbon capture is in a solution state and comprises the following components: a main agent, an auxiliary agent, an accelerant A, an accelerant B and water; wherein the mass ratio of the main agent to the auxiliary agent is 2: (1-2); the mass ratio of the auxiliary agent to the accelerant A is 2: (1-2); the mass ratio of the accelerant A to the accelerant B is 2: (1-2); the total mass concentration of the main agent, the auxiliary agent, the accelerant A and the accelerant B in the organic amine composite absorbent for carbon capture is 30-40 wt%; the main agent is selected from N-methyldiethanolamine or N, N-diethyl ethanolamine, the auxiliary agent is selected from piperazine or hydroxyethyl ethylenediamine, the accelerant A is selected from triethylene glycol monomethyl ether and / or ethylene glycol monomethyl ether, and the accelerant B is selected from ethyl butyl ether and / or isobutyl ether. The organic amine composite absorbent for carbon capture has a wide application prospect in removal of carbon dioxide in flue gas.

The invention relates to a construction method of a multi-class lipid retention time general prediction model and a prediction system. The method comprises the following steps: by taking experimental retention time tRE of a lipid compound in a training set as a dependent variable and characteristic structure parameters of the lipid compound as an independent variable, carrying out quantitative processing on the independent variable and then carrying out regression modeling analysis, the characteristic structure parameters comprise the total carbon number c and the total carbon-carbon double bond number d of a fatty acyl chain, an ether chain, an alkenyl ether chain or / and a sphingosine skeleton, the types of skeletons contained in the lipid compound and the number of corresponding skeletons, and the types of characteristic groups and residues in the lipid compound and the number of corresponding residues; carrying out numerical quantization on parameters according to the number of skeletons, characteristic groups or residues of the corresponding types; the QSRR general prediction model of the retention time of the multi-class lipid compounds is obtained by adopting regression modeling, a more accurate MRM data acquisition window can be set for the lipid compounds, and the sensitivity, stability and coverage can be improved.

The invention belongs to the technical field of refrigerants, and provides a mixed refrigerant for replacing R290 and a preparation method and application thereof, the mixed refrigerant comprises a first component, a second component and a third component; the first component is trans-1, 2-difluoroethylene, the second component is 2, 3, 3, 3-tetrafluoropropene, and the third component is trifluoromethyl methyl ether; compared with R290 refrigerants in the prior art, the mixed refrigerant has the advantages that flammable and explosive components do not exist, and high-risk combustible gas clusters cannot be formed due to density layering after leakage, so that the mixed refrigerant has high safety performance, and the safety level can be not lower than A2L; the mixed refrigerant has the environment-friendly characteristic of low GWP, the GWP is smaller than or equal to 150, and the environment-friendly requirement is met; the thermophysical property and the refrigeration and / or heating cycle performance of the mixed refrigerant are similar to or better than those of R290; the mixed refrigerant can be used for directly replacing an R290 refrigerant.

The invention relates to the technical field of purification of organic chemicals, in particular to an aroma purification method of leaf alcohol. Comprising the following steps: preparing a methanesulfonic acid magnetic catalyst; esterification of leaf alcohol; and alcoholysis and fractionation of the esterification solution. According to the method, acetic acid is used for esterification of leaf alcohol, then clear water and a sodium carbonate solution are used for washing, the clear water can effectively remove some water-soluble impurities and acidic byproducts, and the sodium carbonate solution not only can neutralize residual acidic substances, but also can promote siloxane impurities in initial leaf alcohol to be hydrolyzed and then taken away by a water phase, so that the content of the siloxane impurities in the leaf alcohol is reduced; in the subsequent process of producing leaf alcohol through alcoholysis of the organic phase I, pure water and ethanol, silyl ether impurities are hydrolyzed in a high-temperature and strong-alkali environment, products are dissolved in waste liquid to be removed, olefine aldehyde impurities with the boiling point lower than that of leaf alcohol are removed through azeotropic fractionation with ethanol, in conclusion, the impurities in the finished product leaf alcohol can be effectively reduced, and the yield of the finished product leaf alcohol is increased. And the prepared finished product leaf alcohol is high in purity and pure in fragrance.

The invention relates to the technical field of electronic materials, in particular to a preparation method of low-halogen alkali-soluble photosensitive resin and solder resist ink. Comprising the following steps: adding amino resin, alcohol olefin and a catalyst A into a solvent, mixing, and carrying out an ether exchange reaction to obtain an initial etherified product; adding peroxide into the initial etherification product, and carrying out epoxidation reaction to obtain an epoxy resin intermediate; adding an olefine acid compound, a catalyst B and a polymerization inhibitor into the epoxy resin intermediate, and carrying out ring-opening esterification reaction to obtain an epoxy acrylate intermediate; and adding acid anhydride into the epoxy acrylate intermediate, and carrying out carboxylation reaction to obtain the low-halogen alkali-soluble photosensitive resin. The problem of high halogen content of the existing alkali-soluble photosensitive resin is solved, and the solder resist ink prepared from the alkali-soluble photosensitive resin has high sensitivity, high resolution, high heat resistance, high acid and alkali resistance and high electrical insulation property.

The invention provides weather-resistant anti-freezing road concrete and a preparation method thereof, and belongs to the technical field of concrete. The concrete comprises the following components: sulphoaluminate cement, Portland cement, silica fume, fly ash, modified granite gravel coarse aggregate, medium sand fine aggregate, silica fume blended fiber, silica fume blended polyacrylonitrile fiber, a composite air entraining agent, a functional modifier, a composite antifreeze agent, pre-absorbent zeolite powder and the like. The preparation method comprises the following steps: modifying granite macadam with Al (H2PO4) 3, SiO2 and methoxypolyethylene glycol triethoxysilane, and modifying with a lithium silicate aqueous solution to obtain the modified granite macadam coarse aggregate. The composite air entraining agent comprises a JRY-Q air entraining agent and sodium alpha-olefin sulfonate. The functional modifier is prepared from gas phase method spherical nano silicon dioxide and nano alpha-Al2O3. The composite antifreeze agent comprises ethylene glycol butyl ether acetate and modified calcium carbonate. The modified calcium carbonate is obtained by sequentially modifying nano calcium carbonate with calcium chloride, a KH-550 silane coupling agent and stearic acid.

This invention provides a transdermal nanoparticle delivery system for skin anti-inflammation, comprising a protein-blue calyx methyl ether-polymer shell capsule composite structure. The protein has an affinity for the skin, blue calyx methyl ether is loaded within the protein, and the polymer layer coats the surface of the protein. The blue calyx methyl ether nanoparticle transdermal delivery system has a size of 30-80 nm, and the polymer shell thickness is 10-35 nm. The surface properties of the polymer shell can be controlled according to the required transdermal delivery depth, enabling the protein to penetrate the skin barrier and be efficiently delivered deep into the skin, where the blue calyx methyl ether is then slowly released, targeting and alleviating skin inflammation. This addresses the drawback of low therapeutic efficacy of blue calyx methyl ether in treating skin inflammation due to unsatisfactory transdermal effects.

The invention discloses a wear-resistant vehicle body film and a preparation method thereof, and relates to the technical field of films. The wear-resistant automobile body film prepared by the invention is prepared from polytetrahydrofuran ether glycol, isophorone diisocyanate, a catalyst, dihydric alcohol quaternary ammonium salt, a functional aid, modified silicon dioxide and a chain extender. The dihydric alcohol quaternary ammonium salt is obtained by reacting N, N '-dihexyl-N, N'-dimethyl propane-1, 3-diamine with monochloroacetone and then condensing with glycerol; the functional additive is obtained by reacting 2-boric acid thiophene-4-methyl acetate with 2, 7-dibromofluorene and then carrying out bromination hydrolysis; the modified silicon dioxide is obtained by reacting pretreated silicon dioxide with melamine and then reacting with sodium hypophosphite. The wear-resistant vehicle body film prepared by the invention has good anti-aging, wear-resistant, antibacterial and flame-retardant properties.

The invention relates to a hyaluronic acid-polyurethane composite material based on a double dynamic network and a preparation method and application thereof, and the preparation method comprises the following steps: carrying out hydrophobic modification reaction on hyaluronic acid and aminophenylboronic acid to obtain aminophenylboronic acid modified hyaluronic acid; the preparation method comprises the following steps: mixing polytetrahydrofuran ether glycol, polyethylene glycol and isophorone diisocyanate, carrying out a primary reaction, adding trimethylolpropane tri (3-mercaptopropionic acid) ester, carrying out a secondary reaction, adding tannic acid, and carrying out a third reaction to obtain tannic acid-terminated dynamic thionocarbamate polyurethane; and mixing the amino phenylboronic acid modified hyaluronic acid with the tannic acid terminated dynamic thionocarbamate polyurethane for reaction to obtain the hyaluronic acid-polyurethane composite material with the double dynamic networks. Compared with the prior art, by introducing a'thionocarbamate-borate 'double-dynamic network, high toughness, high strength, good self-repairability and repeatable processability in an extreme environment are realized, and the material is particularly suitable for manufacturing and repairing of key components in an LNG ship body and a heat insulation system thereof.

The invention relates to the technical field of polyurethane, in particular to a bio-based polyurethane buffer material. The material is prepared by foaming and curing a bio-based polyurethane prepolymer. The bio-based polyurethane prepolymer is prepared by the following steps: modifying attapulgite with branched polyol containing quaternary ammonium salt and polytetrahydrofuran ether glycol, and then reacting with raw materials such as soybean oil-based polyol, polytetrahydrofuran ether glycol, isophorone diisocyanate and the like. The bio-based polyurethane buffer material provided by the invention has high compression strength and compression modulus, the hysteresis loss rate is lower than 20%, the elastic recovery rate is higher than 99%, and the bio-based polyurethane buffer material shows excellent rebound resilience and energy absorption capacity, and has excellent adaptability and durability in the fields of high rebound resilience and lightweight design.

The invention relates to the technical field of building materials, and provides washing gangue concrete with high slump loss resistance and a mixing process thereof. The high-slump-retaining washed gangue concrete is prepared from the following raw materials in parts by weight: 200 to 220 parts of cement, 140 to 150 parts of mineral powder, 60 to 65 parts of fly ash, 680 to 720 parts of machine-made sand, 950 to 970 parts of washed gangue, 150 to 160 parts of water, 16 to 17.5 parts of a water reducing agent, 0.15 to 0.3 part of a slump retaining agent and 4 to 4.3 parts of polyethylene glycol. The slump retaining agent is hydroxypropyl methyl cellulose ether; and the viscosity of the hydroxypropyl methyl cellulose ether is 100 thousand mPa.s to 300 thousand mPa.s. According to the technical scheme, the problems of poor slump retaining performance and low compressive strength of washed gangue concrete in the prior art are solved.

The invention discloses a method for preparing dimethyl carbonate through reaction of CO and methyl nitrite, belongs to the technical field of preparation of dimethyl carbonate, and aims to solve the problem that in the prior art, in the process of preparing dimethyl carbonate through catalysis of reaction of CO and methyl nitrite, the reaction time is short. The preparation method specifically comprises the following steps: in an inert gas atmosphere, mixing and stirring isocyanatopropyltriethoxysilane and N, N-dimethylformamide, raising the temperature of a reaction system to 50-60 DEG C, carrying out a reaction for 1-2 hours, and carrying out a reaction for 1-2 hours, so as to obtain a reaction solution; and 3-aminopropionic acid is added into the reaction system. According to the method, silicon-aluminum coating, potassium modification and 18-crown-6-ether modification are sequentially performed after a halogen-free palladium-copper catalytic system is prepared, so that the conversion rate of impurities and the chromatic value of a product are reduced, the conversion rate of methyl nitrite is effectively increased, and the service life of the catalyst is effectively prolonged.

The invention discloses a two-phase absorbent and application thereof. The two-phase absorbent comprises the following components in percentage by mass: 10-35% of a main absorbent, 20-50% of a phase-splitting agent, 0-15% of an accelerant and 0-70% of water, wherein the total mass of the two-phase absorbent is 100%; wherein the main absorbent is polyamine, the polyamine contains more than three amino groups, more than three carbon atoms are arranged between the adjacent amino groups, and at least one of the more than three amino groups is a tertiary amino group; the phase splitting agent is an alcohol ether compound. The two-phase absorbent provided by the invention has better absorption performance, can reduce the generation of oxidative degradation, and has higher oxidation stability.

The invention discloses a modified organic silicon marine antifouling paint and coating based on dynamic crosslinking of boric acid ester, and the modified organic silicon marine antifouling paint based on dynamic crosslinking of boric acid ester comprises the following components in parts by weight: 20-40 parts of a component A; 4-10 parts of a component B; 1-3 parts of a component C; wherein the component A comprises hydroxyl-terminated polydimethylsiloxane, borate modified polysiloxane, an auxiliary agent, a pigment filler and a first solvent, the component B comprises a curing agent and a second solvent, and the component C comprises a catalyst and a third solvent. Hydrolysis of boric acid ester bonds increases the hydrogen-bond interaction between the coating and a base material, and meanwhile, ether groups are introduced to strengthen the hydrogen-bond interaction effect, so that the coating can be firmly adhered to the intermediate paint in a seawater soaking environment.

The invention belongs to the technical field of polyurethane waterproof coatings, and particularly relates to a single-component fluorine-free high-hydrophobicity polyurethane waterproof coating and a preparation method thereof, and the single-component fluorine-free high-hydrophobicity polyurethane waterproof coating comprises the following raw materials by weight: 60-80 parts of composite polyether polyol; 20 to 40 parts of silane modified polyether polyol; 11 to 17 parts of diisocyanate; 2-5 parts of a chain extender; 50 to 70 parts of a plasticizer; 50 to 70 parts of filler; 0.15 to 0.2 part of a catalyst; and 3-5 parts of an auxiliary agent. A polyoxypentene ether chain segment, a castor oil-based structure and a silane group are introduced into the molecular structure of the waterproof coating through chemical modification, the intrinsic hydrophobic and mechanical properties of the material are improved, the migration defect caused by addition of a hydrophobic agent and silicone oil in a traditional preparation method is overcome, and the invention further provides a preparation method of the waterproof coating.

The invention relates to an in-situ curing gel structure electrolyte as well as a preparation method and application thereof. The preparation method comprises the following steps: (1) mixing a resin matrix with a pore-forming agent, then adding a curing agent for mixing to obtain a mixed solution, and pouring the mixed solution into a closed mold for curing to obtain a resin film; soaking and drying the resin film to obtain porous resin; and (2) mixing 4-styrene sulfonyl (phenylsulfonyl) imide lithium salt, polyethylene glycol methyl ether acrylate, polyethylene glycol dimethacrylate, ethylene carbonate and azodiisobutyronitrile to prepare a mixed solution, and soaking the porous resin in the mixed solution to react and cure, thereby obtaining the in-situ curing gel structure electrolyte. The preparation method is simple, and the prepared in-situ curing gel structure electrolyte can improve the mechanical property, the battery capacity and the cycle performance of the in-situ curing gel structure electrolyte.

The invention provides a binder, negative electrode slurry, a negative electrode plate and a battery. The adhesive comprises a polymer, the polymer comprises an acrylic acid structural unit, a structural unit containing quaternary ammonium salt, a phenolic ether structural unit and a flexible structural unit, and the mass ratio of the acrylic acid structural unit to the structural unit containing quaternary ammonium salt to the phenolic ether structural unit to the flexible structural unit is (30-70): (1-10): (0.5-5): (5-20); the phenolic ether structural unit comprises at least one of an aromatic phenol structural unit and an aromatic ether structural unit. The binder provided by the invention synergistically provides a triple dispersion mechanism of electrostatic stability, surface adsorption and hydrophobic anchoring through the acrylic acid structural unit, the structural unit containing quaternary ammonium salt and the phenolic ether structural unit, so that the negative electrode slurry can form a long-term stable aqueous slurry system without depending on an additional dispersant. The binder forms a bactericidal and bacteriostatic barrier in the slurry, has a stable anticorrosion structure network, and is stable in electrochemical performance.

The invention discloses a crown ether grafted polyarylether sulfone ion separation membrane as well as a preparation method and application thereof, and belongs to the technical field of ion separation membranes, collaborative optimization is realized through crown ether accurate grafting and ultrathin ordered membrane formation: a main chain of polyarylether sulfone is grafted with 4 '-aminobenzo-12-crown-4 to form an inherent channel adapted to Li, and the specific surface area of the main chain is increased; the ultrathin film is prepared by a water surface spreading method, and the ion transmission path is shortened. Finally, in a LiCl / MgCl system, Liion flux has high selectivity, high permeation-high selectivity cooperation is preliminarily realized, the chemical synthesis step can be amplified to a kilogram level, and after a DPAES-g-CE / dichloromethane solution is dropwise added to the water surface, the DPAES-g-CE / dichloromethane solution is rapidly spread to form a film without precise equipment; the raw materials are industrial-grade monomers and have no toxic residues, the membrane can be recycled and reused through dichloromethane, the equipment cost is reduced by about 90%, and industrialization is easy; the main chain of the polyaryl ether sulfone is high in rigidity and resistant to high temperature and chemical corrosion; crown ether grafting avoids molecular chain agglomeration, and the swelling rate is far lower than that of a traditional sulfonated membrane.