883 results about "Physisorption" patented technology

The utility model relates to the field of physical adsorption hydrogen storage, and discloses a physical adsorption hydrogen storage tank which comprises a tank body and a tank cover, the tank body comprises a hydrogen inlet and outlet pipe, a porous heat exchange disc, a tank body, a low-temperature storage layer, a physical adsorption hydrogen storage material and a spiral heat exchange pipe. A plurality of porous heat exchange plates are arranged in the tank body, are sequentially mounted in the tank body and are connected with the low-temperature reservoir through guide pipes, the tank body is filled with a physical adsorption hydrogen storage material, a spiral heat exchange pipe is arranged in the tank body, and the spiral heat exchange pipe penetrates through the upper layer of the tank cover and penetrates out of the upper layer of the tank cover after passing through round holes of the porous heat exchange plates. And a heat insulation layer is arranged between the tank body and the low-temperature storage layer. The low temperature maintaining effect is improved, the low temperature in the tank is maintained, gas quickly enters the adsorption layer through the round holes, the gas distribution is more uniform, and when hydrogen needs to be released, a heat exchange medium is introduced into the spiral heat exchange pipe, so that the release of the hydrogen is accelerated.

The invention belongs to the field of nano-drug preparations, and discloses a multifunctional nano-enzyme platform and a preparation method and application thereof, and the multifunctional nano-enzyme platform is mainly composed of a nano-enzyme, a carrier material and a targeting substance. The synthesis of the nano-enzyme, the loading of the nano-enzyme on a carrier material and the modification of a targeting substance on the surface of the nano-enzyme are carried out through methods such as stirring synthesis, coprecipitation, strong acid oxidation, chemical reduction, covalent binding, a solvothermal method and physical adsorption. The targeting substance on the surface of the nano-enzyme platform can be accurately and efficiently positioned to an inflammation part, the meta-acid microenvironment of the inflammation part enables the targeting substance and the carrier material to be subjected to structural depolymerization, so that various nano-enzymes are released, and the nano-enzymes not only realize self-cascade and synergistic catalysis enhancement effects of the enzymes at the inflammation part, but also can be used for preparing the nano-enzyme. And a substrate self-circulation catalysis system is also formed, so that the effect of efficiently relieving and treating various inflammation-related diseases is achieved.

The invention discloses a phosphorus removal filler and a preparation method and application thereof, and belongs to the technical field of fillers. Sulphoaluminate cement, chitosan, sodium alginate and calcium peroxide are uniformly mixed in a nitric acid solution in an amino-containing coupling agent, then foaming and pore forming are performed under steam, and the phosphorus removal filler is prepared. And finally, uniformly mixing with titanium dioxide, sodium silicate, a ferrous sulfate solution and sodium borohydride to obtain the phosphorus removal filler with an excellent phosphorus removal effect, and the phosphorus removal filler has a rich pore structure and adsorption activity, can sufficiently perform physical adsorption on phosphorus elements, and has a good phosphorus removal effect. Meanwhile, the phosphorus removal filler further has excellent surface complexing activity and photocatalysis, insoluble salt precipitates can be generated through reaction of iron elements and calcium elements and phosphate in water, so that total phosphorus is removed, the material is ground after adsorption saturation and put into a fish pond to serve as a phosphorus supplementing material, resource recycling can be achieved, and the cost is reduced. Wide application prospects are realized.

The invention discloses a high-temperature-resistant inorganic adhesive for sealing a hollow-core optical fiber as well as a preparation method and application of the high-temperature-resistant inorganic adhesive. The high-temperature-resistant inorganic adhesive is prepared from the following raw materials in parts by weight: 46-55 parts of modified silica sol, 26-33 parts of aluminum dihydrogen phosphate, 3.5-5.8 parts of a functional additive and 0.9-1.4 parts of a curing agent. Modified silica sol, aluminum dihydrogen phosphate, a functional additive and a curing agent are used as raw materials and embedded into a colloidal network through physical adsorption and chemical bonding, a hydrophobic interface is built, capillary permeation is effectively inhibited, and the influence of water vapor on the bonding effect in practical application is greatly reduced; the inorganic adhesive can bear the high temperature of 600 DEG C and above for a long time, shows excellent bonding and sealing effects on hollow-core optical fiber sealing from normal temperature to the temperature of 600 DEG C and above, is compact and fine in structure and good in water resistance after being cured, can effectively block air and moisture from permeating in the hollow-core optical fiber drawing process, is short in curing time consumption, and has the characteristics of safety and environmental protection.

The invention discloses a preparation method of a cell inflammatory factor adsorbent, which comprises the following steps: mixing styrene, divinyl benzene and hydroxyethyl acrylate, and adding a pore-foaming agent and mesoporous SiO2 nano powder to prepare a porous microsphere carrier; the preparation method comprises the following steps: mixing chitosan and poly (N-isopropylacrylamide) in an acetic acid solution to obtain a temperature-sensitive chitosan hydrogel precursor solution; the preparation method comprises the following steps: activating the surface of a porous microsphere carrier by using 1-ethyl-(3-dimethylaminopropyl) carbodiimide and N-hydroxysuccinimide, mixing the activated porous microsphere carrier and a temperature-sensitive chitosan hydrogel precursor solution to obtain a water phase, and assembling, washing and drying in an oil phase to obtain the cell inflammatory factor adsorbent. Through the design of the core-shell structure and the addition of the mesoporous SiO2 nano powder, the temperature response characteristic and the recyclable characteristic are given to the cell inflammatory factor adsorbent, the adsorption capacity of cell factors is also improved, and a new solution is provided for physical adsorption of the cell inflammatory factors.

The invention provides a biochar composite porous material for heavy metal contaminated soil remediation and a preparation method and application of the biochar composite porous material. The preparation method comprises the steps that biomass raw materials are subjected to high-temperature pyrolysis carbonization and then smashed, ground and sieved, and biochar powder is obtained; dispersing in a phosphoric acid solution to obtain a biochar solution, and filtering, washing and drying after a hydrothermal activation reaction to obtain activated biochar; dispersing in a chitosan solution, carrying out ultrasonic oscillation, filtering, washing and drying to obtain modified charcoal; mixing sodium bentonite, attapulgite and deionized water, uniformly mixing the modified charcoal, the functional slurry and a sodium carboxymethyl cellulose solution to obtain composite slurry, performing compression molding to obtain a green body, and then drying and calcining the green body. The biochar composite porous material prepared by the invention can simultaneously play multiple roles of physical adsorption, chemical chelation, ion exchange and the like in a heavy metal contaminated soil treatment process, so that efficient fixation of various heavy metal ions is realized.

The invention provides phosphorus-doped hydrothermal synchronously-activated hierarchical pore green biochar, a preparation method thereof and application of the phosphorus-doped hydrothermal synchronously-activated hierarchical pore green biochar in formaldehyde adsorption, and belongs to the technical field of biomass resource high-value utilization and air pollution control. The preparation method comprises the following steps: mixing a biomass raw material with a phosphoric acid catalyst, carrying out hydrothermal carbonization reaction, carrying out solid-liquid separation on a reaction product after the reaction is finished, collecting a solid-phase material, drying, mixing with potassium hydroxide, activating, washing and drying the obtained product, and thus obtaining the phosphorus-doped hydrothermal synchronously-activated hierarchical porous green charcoal. Phosphoric acid is introduced in the hydrothermal stage to serve as a structure-directing agent and a doping source, uniform doping of phosphorus and coordinated regulation and control of a pore structure are achieved, a hierarchical pore channel system is formed in the subsequent activation process, and the physical adsorption and chemical fixation capacity of the biochar to formaldehyde molecules is greatly improved.

The invention discloses a hydroxyl-rich ruthenium / titanium dioxide catalyst as well as a preparation method and application thereof, and the preparation method comprises the following steps: step 1, loading a ruthenium precursor on a titanium dioxide carrier by adopting an impregnation method or a deposition-precipitation method, and drying and calcining to obtain a Ru / TiO2 catalyst; and step 2, placing the Ru / TiO2 catalyst in an atmosphere environment containing water vapor or forming a physical adsorption water film on the surface of the Ru / TiO2 catalyst, and performing ultraviolet irradiation treatment to obtain the Ru / TiO2 catalyst. According to the method, water is physically adsorbed through ultraviolet light dissociation, hydroxyl is directly generated on the surface of Ru / TiO2 in an in-situ mode, the method is easy to operate, complex liquid phase treatment is not needed, and the stability of the generated hydroxyl under the subsequent high-temperature gas-solid phase hydrogen-rich reaction condition is obviously superior to that of hydroxyl introduced through a traditional method. The stable hydroxyl enriched on the surface serves as an effective Lewis base site and cooperates with a Ru active site, adsorption and activation of CO2 molecules are remarkably promoted, and therefore the catalytic activity of the CO2 methanation reaction is greatly improved.

The invention relates to the field of immobilized enzymes, in particular to immobilized lipase with graft-modified amino resin as a carrier and a preparation method thereof.The method comprises the steps that firstly, the amino resin is modified through the oxidative auto-polymerization characteristic of tannic acid, and first modified amino resin is obtained; and modifying the first modified amino resin by using fatty amine as a hydrophobic modifier to obtain second modified amino resin. Then lipase is fixed on the second modified amino resin through physical adsorption, the lipase is subjected to interfacial activation on an amphiphilic interface on the second modified amino resin, and a part of lipase is covalently bound with quinonyl in an activated state, so that the immobilized lipase with high activity and stability is obtained. The method is easy to operate, green and non-toxic, the prepared immobilized lipase is good in enzyme activity and stability, and the method can be used for preparing the immobilized lipase on a large scale, can be applied to the field of food and has industrial application potential.

The present application relates to wastewater treatment technical field, specifically to a kind of ammonia nitrogen wastewater treatment method, the composite modified zeolite material in the present application has excellent physical adsorption capacity to ammonia nitrogen by virtue of its unique pore structure and surface properties, ammonia nitrogen molecules in wastewater can be quickly captured, then through the synergistic effect of composite photocatalyst under light and ultrasonic, strong oxidizing free radicals are generated, ammonia nitrogen molecules not completely adsorbed by zeolite material are deeply degraded, through the synergistic effect of adsorption and photocatalysis, the removal efficiency of ammonia nitrogen is significantly improved;After adsorption and photocatalytic treatment, the ammonia nitrogen concentration in wastewater has been greatly reduced, and resin adsorption treatment is used as a subsequent step, which can selectively adsorb residual trace amounts of ammonia nitrogen and other impurities, thereby realizing deep purification of wastewater and ensuring that the effluent quality meets or exceeds relevant discharge standards.

The invention provides a microbial slow-release porous composite material for sewage treatment as well as a preparation method and application thereof. The preparation method comprises the following steps: dropwise adding an organic ligand solution into a precursor solution consisting of a nanocellulose solution and a cobalt source solution; mixing the reaction solution with polyvinyl alcohol, injecting the mixture into a mold, and performing directional freezing to obtain an aerogel matrix; carrying out hydrophobic modification on the aerogel matrix to obtain a modified aerogel matrix; mixing the microbial suspension with sodium alginate, and homogenizing at high pressure to obtain a gel precursor emulsion; the preparation method comprises the following steps: dropwise adding a calcium chloride solution to gelatinize to obtain gel particles, and then cross-linking and drying by glutaraldehyde to obtain sustained-release capsule particles; dispersing the sustained-release capsule particles in deionized water to obtain dispersion liquid; and dipping the modified aerogel matrix in the dispersion liquid. An aerogel matrix with a hierarchical porous structure is compounded with a sustained-release capsule with a pH response mechanism, so that physical adsorption, chemical catalysis and biodegradation for sewage treatment are realized.

The invention discloses a rapid and accurate detection method for pathogenic bacteria. The method comprises the following steps: immobilizing bacteriophages on the surfaces of magnetic nanoparticles through physical adsorption or chemical reaction, selectively enriching pathogenic bacteria in a complex sample by adopting the bacteriophage functionalized magnetic nanoparticles, quickly cracking the pathogenic bacteria on the surfaces of the magnetic nanoparticles by using CTAB (cetyltrimethyl ammonium bromide), releasing ATP in the bacteria, and quantitatively analyzing ATP by using bioluminescence. Further calculating the content of the pathogenic bacteria; the detection method is free of enrichment and amplification, can complete capture, enrichment and detection of pathogenic bacteria within 20 minutes, and can specifically detect viable bacteria of target bacteria in various complex matrix (such as food) samples due to the fact that bacteriophages are adopted as recognition molecules.

The invention relates to the technical field of wastewater treatment, in particular to an ammonia-nitrogen wastewater treatment method.A composite modified zeolite material has excellent physical adsorption capacity on ammonia nitrogen by means of the unique pore structure and surface property of the composite modified zeolite material, ammonia nitrogen molecules in wastewater can be rapidly captured, and the ammonia nitrogen wastewater treatment effect is improved. Then, under the synergistic effect of illumination and ultrasonic waves, free radicals with strong oxidizing property are generated through the composite photocatalyst, ammonia nitrogen molecules which are not completely adsorbed by the zeolite material are deeply degraded, and the removal efficiency of ammonia nitrogen is remarkably improved through the synergistic effect of adsorption and photocatalysis; after adsorption and photocatalysis treatment, the concentration of ammonia nitrogen in the wastewater is greatly reduced, then resin adsorption treatment is adopted as a subsequent step, and residual trace ammonia nitrogen and other impurities can be selectively adsorbed, so that deep purification of the wastewater is realized, and the effluent quality is ensured to reach or be superior to related emission standards.

The invention relates to the technical field of phase change energy storage and heat management, and provides a heat insulation-heat conduction integrated phase change composite material and a preparation method thereof. The preparation method comprises the following steps: S1, preparing heat-conducting layer precursor mixed slurry; s2, preparing a heat insulation layer precursor mixed solution; s3, respectively pouring the two solutions into customized molds, directionally freezing and freeze-drying; s4, carrying out thermal imidization; and S5, partially impregnating the phase-change material, and packaging the phase-change material in a skeleton of the heat-conducting layer aerogel by adopting a physical adsorption method. The calcium ion regulator is introduced into the heat insulation layer precursor solution, so that the pore diameter structure of the polyimide aerogel can be regulated and controlled, and the calcium ion regulator can be used as a bridge to connect the heat insulation layer and the heat conduction layer, so that the integrated design of the material is realized.

The invention discloses an efficient and lasting multifunctional refrigerator deodorant which comprises the following components: (a) 50-85wt% of a porous adsorption material with a high specific surface area; (b) 5-30 wt% of a catalyst capable of effectively catalyzing and decomposing organic odor molecules in a low-temperature environment of 0-10 DEG C; and (c) 3 to 15 weight percent of long-acting slow-release type broad-spectrum antibacterial agent. According to the efficient and lasting refrigerator deodorant and the preparation method thereof, the dual effects of physical adsorption and low-temperature catalytic decomposition are utilized, multiple types of peculiar smell molecules can be rapidly adsorbed and thoroughly decomposed, and the deodorization efficiency is remarkably higher than that of a single adsorbent; the service life is greatly prolonged and is 3-5 times that of common activated carbon, the food decay speed is reduced, the food fresh-keeping period is indirectly prolonged, and food safety is guaranteed. The use process is safe and reliable, the use is convenient, external conditions such as illumination and heating are not needed, the device can be directly placed in a refrigerator, the replacement frequency is reduced due to long-term effect, and the comprehensive use cost is low.

The invention relates to a low-dielectric-loss high-thermal-conductivity epoxy resin composite material and a preparation method thereof, and the preparation method comprises the following steps: carrying out surface modification treatment on a thermal conductive filler: carrying out surface modification on the thermal conductive filler by adopting a chemical covalent bonding or physical adsorption mode, the heat-conducting filler is used for improving the compatibility of the filler and an epoxy resin matrix and reducing the interface thermal resistance, and comprises boron nitride with a two-dimensional sheet structure; epoxy resin, a curing agent and an optional modifier are evenly mixed, the epoxy resin is selected from epoxy resin with the low polarity characteristic, and the modifier comprises at least one of thermoplastic resin or elastomer. And the process is simple and controllable.

The invention discloses a composite activated carbon filter material and a preparation process thereof, and belongs to the technical field of water treatment materials. The filter material sequentially comprises a modified coconut shell activated carbon matrix, a bimetallic oxide and a biodegradable functional film from inside to outside, the modified coconut shell activated carbon matrix is prepared by a three-step process of acid leaching modification, microwave activation and nitrogen doping; the bimetallic oxide is Fe-Mn oxide nano particles; the biodegradable functional film is composed of a polyvinyl alcohol / polylactic acid blended film and a complex microbial inoculant, and the complex microbial inoculant comprises a mixed flora of pseudomonas, bacillus and nitrifying bacteria. Through the three-layer composite structure of the coconut shell activated carbon matrix, the bimetallic catalyst layer and the biodegradable film, the synergistic effect of physical adsorption, chemical catalysis and biodegradation is achieved. Through step-by-step superposition of the functional layers, the removal efficiency of complex pollutants such as organic matters, heavy metals, ammonia nitrogen and the like is remarkably improved.

The invention provides a polymer composite gel for heavy metal ion adsorption and a preparation method and application thereof, diatomite DE, chitosan CS, polyethyleneimine PEI and sodium alginate SA are used as raw materials, and polymer modification crosslinking is promoted through an ionic crosslinking method to form the composite gel. Compared with the prior art, SA is a biodegradable natural polysaccharide material, contains rich hydroxyl and carboxyl functional groups and is used as a controllable modification site, DE is used as an inorganic clay material, has a layered porous structure and contains rich active sites, and CS and PEI polymer surfaces have rich amino and hydroxyl groups and are used as ion adsorption sites. Meanwhile, PEI is used as a nucleation site and an ionic cross-linking agent to promote material modification and cross-linking to form composite gel. The composite gel is used as an ion adsorbent, can be adsorbed through chemical chelation between functional groups and ions, and can also be physically adsorbed through a porous structure, so that the composite gel shows efficient ion adsorption performance.

The invention relates to the technical field of conditioners, in particular to a conditioner for improving crop stress resistance and a preparation method thereof, and the conditioner comprises the following raw materials: plant hormones, trehalose, humic acid, a complex microbial inoculant, modified nano sodium alginate, modified nano zinc oxide, lactic acid, a green tea extract and a licorice extract. The modified nano-sodium alginate, the modified nano-zinc oxide and the lactic acid play a role through a synergistic effect, the modified nano-sodium alginate and nutrient substances form a modified nano-sodium alginate gel compound through physical adsorption and chemical effects, stress-resistant peptides on the surface of the compound directly activate immune systems of crops, synthesis of stress-resistant proteins is promoted, and the stress resistance of the crops is improved. The modified nano-zinc oxide enhances the absorption of nutrient substances by crop root cells, assists the activation of crop immune systems, and synergistically enhances the disease resistance and stress resistance of crops, and the lactic acid effectively stabilizes the pH value of the conditioner, relieves the oxidation pressure of crops under adverse conditions, and enhances the physiological stability of crops.

The invention provides an elastic microcarrier as well as a preparation method and application thereof, and belongs to the field of water, wastewater and sewage treatment, the elastic microcarrier comprises the following components in parts by mass: 50-75 parts of thermoplastic elastomer, 25-10 parts of diatomite, 10-5 parts of tourmaline and 15-10 parts of iron-carbon powder. The material has good elasticity, adsorbability, biocompatibility and electrochemical characteristics, and can form a microscopic primary battery effect. The elastic microcarrier is applied to sewage treatment with a membrane bioreactor, pollutants can be removed through physical adsorption, chemical action and biological enhancement, meanwhile, the surface of a membrane is kept clean in combination with flexible scraping, membrane pollution is remarkably slowed down, the running membrane flux is improved, and the service life of the membrane is prolonged. The mechanical damage of the traditional rigid filler to the membrane is avoided, and the service life of the membrane is prolonged. The preparation method of the elastic microcarrier is simple and easy to operate, the elastic microcarriers with uniform specifications can be prepared in batches, and the applicability is high.

The invention provides carbon-doped boron nitride for effectively adsorbing heavy metals in flue gas and a preparation method of the carbon-doped boron nitride, and belongs to the technical field of combined control of various atmospheric pollutants. According to the carbon-doped boron nitride, more carbon atoms are introduced into a boron nitride structure through carbon doping, the carbon atoms replace part of boron atoms, and the original structure of the boron nitride is changed; compared with boron nitride, the carbon-doped boron nitride has the advantages that the atom proportion of carbon atoms in the carbon-doped boron nitride is increased by 2.92%-58.22%, heavy metals in the flue gas are removed through the synergistic effect of physical adsorption and chemical adsorption, and simultaneous adsorption of more than one heavy metal in the flue gas is realized after 5 minutes. Compared with activated carbon as a heavy metal adsorbent, the preparation method is simple, the blank of adsorption capacity in high-temperature flue gas is filled, heavy metal substances such as Cd, Pd, Zn and Cu can be adsorbed at the same time, and the adsorbent is successfully applied to adsorption of heavy metal ions in the high-temperature flue gas.

The invention relates to 6-methyl nicotine glycollate and a preparation method thereof, an atomization matrix, a buccal product and an electronic atomization device. The preparation method of the 6-methylnicotine glycollate comprises the following steps: mixing 6-methylnicotine, glycollic acid and a metal catalyst for reaction to obtain a reaction solution containing the 6-methylnicotine glycollate; and carrying out physical adsorption treatment on the reaction liquid to prepare the 6-methyl nicotine glycolate. 6-methylnicotine and glycollic acid react under the action of a metal catalyst, so that the conversion rate of a reaction substrate can be effectively promoted, and residues of the reaction substrate are effectively reduced; the obtained reaction liquid is further subjected to physical adsorption treatment, so that the residual catalyst in the reaction liquid can be effectively removed, and the prepared 6-methyl nicotine glycolate has less heavy metal residue.

The invention discloses a compound environment-friendly corrosion inhibitor as well as a preparation method and application thereof. The choline ionic liquid comprises choline ionic liquid and amino acid, the choline ionic liquid is choline cations; the amino acid is one or more of cysteine and tryptophan. The compound environment-friendly corrosion inhibitor has high corrosion inhibition efficiency, and the compound structure of the compound environment-friendly corrosion inhibitor further improves the protection performance of the compound environment-friendly corrosion inhibitor through a dual adsorption mechanism of the synergistic effect of physical adsorption and chemical adsorption on the metal surface. According to the compound environment-friendly corrosion inhibitor, a full-green ionic liquid corrosion inhibition system is constructed, the environment-friendly requirement is met, and a metal protection solution can be provided for industrial acid pickling and other strong acid working conditions. Not only is the progress of a corrosion inhibition technology promoted, but also more economic and environment-friendly anti-corrosion application can be provided for actual industrial scenes.

The invention belongs to the technical field of oil and gas exploitation, and relates to a nanometer desorbing agent for a gas well and a preparation method thereof.The desorbing agent is prepared by using biochar subjected to special pretreatment as a core carrier, loading bimetallic oxide nanoparticles in a specific proportion and carrying out surface modification with an environment-friendly surface active agent. Through the synergistic effect of the nanometer size effect, the catalysis / electron transfer effect of the metal oxide, the physical adsorption and pore transport effect of the biochar and the interfacial tension reduction effect of the surfactant, the adsorption energy barrier of gas molecules such as methane on the rock surface is remarkably reduced, and efficient desorption of the gas molecules is promoted. Meanwhile, all the components and the preparation process are environment-friendly and harmless to a human body.

The invention discloses a microbial decomposing inoculant for straws and a preparation method thereof, and belongs to the technical field of microorganisms. The microbial decomposing inoculant for straw is prepared from the following raw materials in parts by weight: 15-18 parts of functional microbial liquid, 3-5 parts of neutral protease, 1-3 parts of laccase, 20-25 parts of a nano-porous diatomite carrier, 5-7 parts of a humectant, 2-3 parts of humic acid chelated trace elements and 2-4 parts of an inducer. The preparation method comprises the following steps: screening talaromyces thermophilus, Guangxi thermoactinomycetes and arthrobacter habitualis to form a functional microbial liquid, adding a laccase-protease compounding system to cooperate with the physical adsorption effect of diatomite, and adding humic acid chelated trace elements to form an ion exchange network with polyglutamic acid; straw components are efficiently degraded through a triple mechanism of'enzymatic degradation-element supplementation-microenvironment regulation and control ', the decomposition process is accelerated, and the straw compost quality is improved.

The invention discloses a lithium manganese iron phosphate positive electrode material and a preparation method thereof, and relates to the technical field of lithium ion batteries, the lithium manganese iron phosphate positive electrode material comprises LiMn (1-X) FeXPO4 and an interception membrane material; wherein the interception membrane material is prepared from phenol type nano cellulose and a SiO2-nanotube; the surface of LiMn (1-X) FeXPO4 is provided with a carbon coating layer, and the interception film material is fixed on the surface of the carbon coating layer in a film form, so that the mechanical strength of the carbon coating layer can be improved, and the dissolution of manganese ions is prevented; the nano cellulose and the SiO2-nanotube are both of a porous structure with high specific surface area and porosity, so that the nano cellulose and the SiO2-nanotube have good physical adsorption performance and chemical reaction activity, free manganese ions can be adsorbed and fixed, and the purpose of intercepting dissolution of the manganese ions is achieved; bHA is grafted on the surface of the nanocellulose, the BHA contains a large amount of phenolic hydroxyl groups and tertiary butyl groups, and the phenolic hydroxyl groups can reduce the negative influence of free radicals on the battery; and the tert-butyl can generate a hindering effect on approaching of other groups or molecules, so that manganese ions are further intercepted, and the electrochemical performance of the battery is further improved.

The invention discloses a high-temperature-resistant benzimidazolone polyamide imide battery binder as well as a preparation method and application thereof, and belongs to the technical field of battery materials. The high-temperature-resistant benzimidazolone polyamideimide battery binder with uniformly distributed amide segments and imide segments is prepared through a method for activating aromatic diamine on one side of trimethylchlorosilane and changing the activity of amino groups on the two sides, the comprehensive performance of the high-temperature-resistant benzimidazolone polyamideimide battery binder is excellent, the defects that a traditional binder is poor in heat resistance and insufficient in chemical stability are overcome, and the service life of the high-temperature-resistant benzimidazolone polyamideimide battery binder is prolonged. The introduction of high-polarity groups can improve the wettability and ion transmission capability of the electrolyte, improve the solubility of the electrolyte so as to facilitate electrode forming, and can also form strong chemical bonds or physical adsorption with positive and negative inorganic active materials during application, thereby reducing the structural damage in the cycle process and improving the electrochemical performance of the battery. The lithium ion battery electrode can keep a stable structure in a high-temperature environment, the thermal runaway risk caused by high temperature is remarkably reduced, and the application requirements of the lithium ion battery in a fast charging or high-temperature energy storage scene are well met.

The invention discloses a fly ash nano magnetic bead flocculant, which is composed of the following raw materials in parts by weight: 1-30 parts of fly ash, 0.5-1 parts of nano silicon dioxide, 2-5 parts of dispersant, 1-2.5 parts of tetramethylpropylenediamine, 0.1-0.5 parts of polyacrylamide, and 1-5 parts of surfactant. At the same time, the invention also discloses a preparation method of the flocculant. The flocculant has high physical adsorption performance, has good chelation effect on metal ions, is not easy to deposit in water, can fully react with sewage, and has good adsorption and flocculation effect on suspended matter in sewage sludge.

A design method of an SPR grating type sensor based on FPCL-DCNN is a method for carrying out molecular-level adaptive characteristic design on a Kretschmann type SPR grating sensor, belongs to the field of sensors and artificial intelligence, and is characterized by comprising the following steps: (1) carrying out chemical reaction modification on active groups of molecules to be detected on the surface layer of a bio-based membrane; (2) introducing a Langmuir physical adsorption model; (3) determining components of the bio-based membrane which reacts with the molecules to be detected; (4) defining initial model parameters; (5) constructing a DCNN multi-mode convolutional neural network optimization model; and (6) designing a loss function and an output layer. The problem that in the prior art, interaction of a to-be-detected substance on the surface of the sensor and the to-be-detected substance cannot be accurately controlled is solved, physical and chemical modification is carried out on the to-be-detected substance, to-be-designed parameters of the sensor are input into the DCNN model, optimal SPR sensor parameters are output through a linear activation function of the output layer, and the accuracy of the SPR sensor is improved. And a new method is provided for SPR grating type sensor parameter design.

The invention relates to the technical field of biomedical materials, and discloses an antibacterial hemostatic material and a preparation method thereof, the antibacterial hemostatic material comprises the following components by weight: 2-3 parts of amino acid terminated polyurethane, 1-3 parts of thiolated chitosan, 3-5 parts of sodium alginate, and 2-4 parts of a polyvinyl alcohol solution. Through the synergistic effect of amino acid terminated polyurethane-sulfhydrylated chitosan-sodium alginate, a dual hemostatic mechanism of physical adsorption-chemical coagulation promotion is constructed: sodium alginate as a natural polysaccharide has strong hydrophilicity and cation adsorption capacity, can quickly absorb moisture in wound blood, concentrate platelets and coagulation factors, and has a good hemostatic effect; thrombin activation is accelerated, and the blood coagulation time is shortened; the antibacterial hemostatic material disclosed by the invention has relatively good antibacterial and hemostatic effects.