The application belongs to the technical field of battery materials, and discloses a kind of secondary ball positive active material, the primary particle of the secondary ball positive active material is doped with Sb and S.By the common
doping of S and
Sb element, the primary particle of the secondary ball is reduced, the uniformity of the primary particle is improved, which is beneficial to reduce the migration resistance, improve the cycle performance and the first
coulomb efficiency of the material.The preparation method of the secondary ball positive active material is also disclosed, the S-containing compound and the Sb-containing compound are added simultaneously in the primary mixing process, which can effectively control the size of the primary particle, and the simultaneous addition of the two elements can make the primary particle smaller and more close to the spherical particle, and the uniformity of the primary particle is also very good.The primary particle can be made smaller and the particle is more inclined to
spherical morphology, which is beneficial to reduce the
lithium intercalation dynamics characteristics of the material in the charging and discharging process, and thus improve the first
coulomb efficiency of the material.