2112 results about "Electrospinning" patented technology

The invention discloses a hydrophobic-hydrophilic Janus water collecting film and an efficient preparation method thereof, and belongs to the field of water collecting materials. An electrostatic spinning process is adopted, and a hydrophobic polymer is accurately deposited on the surface of a hydrophilic substrate in the form of a nanofiber array, so that the Janus composite membrane with an asymmetric wetting gradient structure is successfully constructed. The unique double-sided wettability difference drives the liquid drops to realize directional transmission, and the core mechanism of the liquid drops is derived from capillary force regulation and control caused by interfacial wetting potential energy difference. The Janus membrane shows excellent performance in the aspect of air moisture trapping, the ultra-fast moisture absorption characteristic and the surface regeneration capacity are achieved, and compared with a traditional single-layer hydrophilic membrane, the water collecting efficiency is remarkably improved by 110%. A one-step forming process is adopted for preparation, the diameter of the nanofibers is controllable, complex post-treatment procedures are not needed, and energy consumption required by equipment is low. The high-performance water collecting film has important application value in the fields of atmospheric water taking in arid regions, dehumidification of precise instruments and the like.

The invention discloses a composite electrode material for a zinc-bromine flow battery and a preparation method and application thereof, and the preparation method comprises the following steps: S1, uniformly stirring a copper salt, a zinc salt, a sodium salt and distilled water at room temperature, aging in air, and then filtering, washing and drying to obtain a zinc-copper composite salt; s2, adding a polymer into an organic solvent under a stirring condition, and stirring under a water bath condition to obtain a spinning solution; then adding zinc-copper composite salt, stirring and then carrying out ultrasonic dispersion to obtain a composite spinning solution; s3, preparing the composite spinning solution into a precursor nanofiber material by utilizing high-voltage electrostatic spinning; and S4, carrying out pre-oxidation and carbonization treatment on the precursor nanofiber material in an atmosphere furnace, and cleaning and drying the carbonized material to obtain the composite electrode material for the zinc-bromine flow battery. According to the invention, the problems of low surface activity of bromine electrode reaction on an electrode material, unstable electro-catalytic performance, bromine permeation and the like in the zinc-bromine flow battery can be solved.

The invention provides an activated carbon fiber capable of efficiently removing formaldehyde and a preparation method thereof, the activated carbon fiber is of a composite material fiber structure of porous TiO2 derived from activated carbon and a metal organic framework (MOF), and the preparation method of the composite material comprises pretreatment of activated carbon, preparation of a Ti-MOF precursor and preparation of TiO2 / activated carbon fiber. According to the invention, the MOF-derived porous TiO2 / activated carbon composite fiber structure is constructed, physical adsorption and photocatalytic degradation functions are cooperated, and the limitation of single adsorption capacity is broken through; the interface bonding problem of the MOF derivative and the activated carbon is solved, and high-dispersion loading and stable and firm compounding of the active components are realized; a process path capable of realizing large-scale preparation is provided, and continuous production of the composite fiber is realized through an electrostatic spinning technology.

The invention discloses a glue solution for a copper-clad plate and a preparation method of the glue solution, and relates to the technical field of copper-clad plates. According to the prepared glue solution for the copper-clad plate, the composite epoxy resin, the curing agent, the accelerant, the solvent, the flexibilizer and the inorganic filler, the composite epoxy resin comprises bisphenol A epoxy resin, epoxy phenyl polysiloxane, itaconic acid polyaryletherketone and hydroxyl-terminated fluorine-containing vinyl polysiloxane, so that the interface bonding force with the copper plate is enhanced; the dielectric constant and the dielectric loss are effectively reduced, the peel strength and the toughness of the material are also remarkably improved, and the toughening agent is modified polyether sulfone microspheres; the modified polyethersulfone microspheres are prepared by coating polyethersulfone microspheres with hexamethylenediamine tetrapropionamide diamine, the hexamethylenediamine tetrapropionamide diamine is prepared by carrying out acylation condensation reaction on hexamethylenediamine tetramethyl propionate and ethylenediamine, and the polyethersulfone microspheres are prepared by carrying out electrostatic spinning on a spinning solution of polyethersulfone and vinylpyridine, so that the peel strength of the glue solution is remarkably improved.

The invention relates to a fluoride-free polyimide-based film and a preparation method thereof. The method comprises the following steps: S1, preparing a polyamide acid solution; s2, fluorine-free organic silicon serving as a modifier is added into the polyamide acid solution and dispersed, a blended spinning solution is formed, and the solubility parameter difference value of the fluorine-free organic silicon and polyamide acid is 2.0 (MPa) 1 / 2 or below; s3, carrying out electrostatic spinning on the blended spinning solution to form a polyamide acid-based nanofiber layer; and S4, carrying out thermal imidization on the polyamide acid-based nanofiber layer to obtain the fluoride-free polyimide-based film. The film has a structure formed by three-dimensional cross-linking and winding of polyimide-based nanofibers, and the polyimide-based nanofibers are composed of a polyimide base material and fluorine-free organic silicon dispersed in the polyimide base material. The method does not involve fluorine-containing raw materials, and is environment-friendly and high in process compatibility. The film provided by the invention has excellent waterproofness, air permeability and mechanical properties at the same time.

The invention discloses a zirconium-based metal organic framework (Zr-MOF) composite semi-solid electrolyte material prepared based on an electrostatic spinning technology and application of the zirconium-based metal organic framework (Zr-MOF) composite semi-solid electrolyte material. The material is composed of a three-dimensional polymer fiber network, surface-coated Zr-MOF nanoparticles and an organic liquid electrolyte solution, a polymer matrix provides mechanical support, and Zr-MOF micropores and a liquid electrolyte form a multistage ion transmission channel. The preparation method comprises the processes of electrostatic spinning forming, in-situ Zr-MOF synthesis and gradient pressure electrolyte infiltration. The ionic conductivity of the material at 25 DEG C reaches 1.2 * 10 S / cm, the lithium ion transference number is 0.65, the capacity retention ratio after 500 cycles is greater than or equal to 90%, and the material is suitable for high-energy-density lithium ion batteries and flexible energy storage devices through acupuncture safety tests.

The invention relates to a preparation method of a hydrophobic and oleophobic PTFE membrane, and belongs to the technical field of PTFE membrane preparation. Aiming at the problems that an existing PTFE membrane is difficult to construct a micro-nano multi-stage coarse structure and has a synergistic effect with low chemical surface energy, the hydrophobic and oleophobic properties are insufficient and the structural stability is poor, the key points of the technical scheme provided by the invention are as follows: firstly, carrying out ethanol ultrasonic cleaning on a PTFE base membrane of 20-30 microns, and carrying out vacuum plasma treatment to form a nano coarse structure and oxygen-containing polar group active sites; then, under the protection of nitrogen, immersing into an ethanol solution containing perfluorodecyltriethoxysilane, dibutyltin dilaurate and nano cellulose whiskers, carrying out hot-pressing compounding with PET non-woven fabric, carrying out heat treatment, and finally, coating with a fluorine-containing polymer nano fiber layer through an electrostatic spinning process; the composite hydrophobic layer with the synergistic effect of a micro-nano multistage coarse structure and chemical low surface energy is formed, the water contact angle is larger than or equal to 155 degrees, and the oil contact angle is larger than or equal to 130 degrees. The PTFE film prepared by the preparation method can be used in the fields of waterproof breathable materials, self-cleaning surfaces, oil-resistant packaging and the like.

The invention relates to a double-layer dressing for promoting wound healing and inhibiting scars and a preparation method and application thereof.The double-layer dressing comprises a hydrogel layer and a piezoelectric film layer compounded on the hydrogel layer, and the piezoelectric film layer is prepared by mixing an organic piezoelectric material, a ferroelectric material and an organic solvent and then conducting an electrostatic spinning technology; the hydrogel layer is formed by curing a methacrylic anhydride acellular extracellular matrix, methacrylic anhydride catechol chitosan and conductive nanoparticles under the action of a curing agent. The lower skin contact layer of the double-layer dressing is the hydrogel layer, so that the directional growth of fibroblasts is favorably induced; the upper dressing is a piezoelectric material composite ferroelectric material, is beneficial to piezoelectric stimulation re-induction function recovery after final skin repair and guidance of directional growth of wound cells, and has good skin wound induction repair and scar inhibition effects.

The invention provides a polyimide multilayer composite membrane material as well as a preparation method and application thereof, and belongs to the technical field of gas separation. According to the method, through collaborative design of a functional support layer, a gradient MOF layer and an ultrathin selection layer structure, the problems of support layer pore seepage, MOF agglomeration, weak interface bonding and the like in an existing composite membrane material are solved. The preparation method comprises the following steps: firstly, carrying out electrostatic spinning on a polyamide acid glue solution, and synchronously introducing dopamine by adopting a chemical imidization method to prepare a functionalized polyimide fiber membrane containing hydroxyl and amino on the surface, so that the mechanical property of a supporting layer and the MOF anchoring capability are remarkably improved; growing MOF layers with different particle sizes on the surface of the fiber membrane by regulating and controlling the concentration gradient of ligand / metal salt and the reaction time, and passivating through a silane coupling agent after each step of growth so as to avoid heterogeneous nucleation and construct a gradient structure; after the MOF gradient layer is subjected to Ar plasma pretreatment to introduce hydroxyl, the ultrathin polyamide selection layer is formed by utilizing interfacial polymerization of fluorine-containing acyl chloride and a macrocyclic amine monomer, and the ultrathin polyamide selection layer is suitable for gas separation work.

The invention relates to the technical field of biomedical materials, and discloses an electret electrostatic therapy membrane and a preparation process thereof.The electret electrostatic therapy membrane is prepared from, by mass, 15%-20% of fluorinated polyether ester, 10%-20% of a composite nano-fiber material, 10%-20% of a composite nano-fiber material, 10%-20% of a composite nano-fiber material and the balance water. 1%-2% of carboxymethyl chitosan; 2-5% of nano cerium oxide particles with the particle size of 50-100 nm; 0.5-1.0% of graphene quantum dots, the particle size of which is 5-10 nm; 1%-2% of sodium hyaluronate; the components are prepared into a film through an electrostatic spinning method, electret performance is given to the film through a charge injection process, finally, the film body is attached to a flexible silica gel adhesion layer, and the flexible silica gel adhesion layer is externally coated with a peelable protective film so that the structural integrity can be kept before the flexible silica gel adhesion layer is used. The composite membrane body disclosed by the invention shows excellent adhesion, charge activation capability and thermal response performance in applications of electrostatic therapy, dielectric assisted stimulation and the like, and has good multi-scene adaptability and clinical application potential.

The invention discloses a gradient membrane based on continuous distribution of PVDF-HFP-silicon dioxide electronic injection microspheres and a construction method of the gradient membrane, and belongs to the field of gradient membranes, an improved electrostatic spinning and electrostatic spraying technology is utilized, a PVDF-HFP fiber membrane is prepared through the electrostatic spinning technology, PVDF-HFP / SiO2 composite microspheres are electrostatically sprayed, and a collector receiving device is combined, so that the gradient membrane is obtained. The traction speed change of the substrate film is controlled on the blade electrode, and a wettability gradient film with the continuously-changed surface appearance is constructed; on the surface of the prepared fiber membrane, the distribution form of the polyvinylidene fluoride-hexafluoropropylene / silicon dioxide composite microspheres on the surface of the membrane is in gradient change, a microstructure with continuous change is constructed, the contact angle of the fiber membrane is increased from 128 degrees to 153 degrees along with the change of the surface position, and a gradient surface gradually changing from hydrophobicity to super-hydrophobicity is obtained. And the preparation method has an excellent application prospect in the field of gradient films, bubble transmission and bubble micro-reaction.

The invention discloses an injectable material for promoting bone regeneration through piezoelectric and conductive integrated nanofiber hydrogel with ultrasonic response and a preparation method of the injectable material. The injectable material is composed of piezoelectric and conductive nanofibers and hydrogel. Wherein the piezoelectric conductive nanofiber is prepared from an inorganic piezoelectric material and a piezoelectric polymer through electrostatic spinning, or is prepared from an inorganic / organic composite piezoelectric material and a biological material with conductive performance through electrostatic spinning.

The invention discloses a novel textile material with eiderdown wrapped by rainbow yarn nanofibers and a preparation method. The novel textile material comprises skeleton fibers located at the axis, an eiderdown component with a heat preservation effect and a rainbow yarn nanofiber reinforcing layer wrapping the outer surface of the eiderdown component. The wrapping reinforcing layer is of a three-dimensional network structure formed by continuous or quasi-continuous nanofibers in a winding, interweaving and lap joint mode, so that stable compounding and structural shaping of down feather components and skeleton fibers are achieved under the condition that the down feather components and the skeleton fibers do not depend on adhesive fixation. The preparation method comprises the following steps: cleaning, drying and opening down for pretreatment; performing melt differential electrostatic spinning on the polymer melt under a high-voltage electrostatic field to form rainbow yarn nanofibers; the down flocs are introduced into the coating area through the framework fibers, so that the rainbow yarn nanofibers are deposited and wound to form a coating reinforcing layer; after being gathered and shaped and twisted into yarns, the yarns can be continuously dragged and wound. The novel textile material has spinnability, structural stability and long-acting thermal insulation performance, and is suitable for spinning, weaving and knitting processing.

The invention belongs to the technical field of spinning, and particularly relates to atmosphere-controllable needleless electrostatic spinning equipment and a method for preparing micro-nano fibers. The equipment comprises a needleless electrode wire, a liquid brushing tank, a direct-current high-voltage power supply, a winding roller, a metal plate, an air inlet, a sliding rail, an air outlet and a closed outer cover. The needle-free electrode wire is connected with the liquid brushing groove in series and connected with the positive electrode of the direct-current high-voltage power source, the metal plate is arranged over the needle-free electrode wire and connected with the negative electrode of the direct-current high-voltage power source or grounded, and the air inlet can reciprocate on the sliding rail. The atmosphere-controllable needleless electrostatic spinning equipment is used for stabilizing jet flow, the fiber forming quality is improved, generated beads are reduced, it is ensured that fibers are uniform and fine, and the mechanical property and stability of the fibers are remarkably improved; one-step preparation of porous fibers and fibers needing secondary reaction modification is achieved, and the consistency of the fibers in the fiber membrane is improved.

The application relates to a continuous macro-preparation device and method of a soft and elastic ceramic superfine fiber material, which sequentially comprises a feeding and liquid preparation system, a multi-jet uniform electrostatic spinning system, a low-temperature calcination system and a winding system. Raw materials are mixed, low-temperature dispersed and vacuum concentrated to obtain a sol; the sol and a polymer flow into a polymer mixing device to be mixed and bubble removed; the mixed sol flows into an inorganic component content control device to be pumped by negative pressure to obtain a spinning solution; the spinning solution flows into a multi-jet electrostatic spinning module to adjust and control the temperature, humidity and multi-directional differential speed during spinning to obtain a fiber membrane material or a fiber flake material; the fiber material is sequentially transmitted to a drying area, a microwave pretreatment area, a polymer removal area, an oxygen-poor atmosphere heat treatment area and a cooling area to be calcined in multiple temperature zones to obtain the soft and elastic ceramic superfine fiber material; and winding and packaging are realized to realize the continuous macro-manufacture of the soft and elastic ceramic superfine fiber material.

A method of manufacturing a medical device made of polylactic acid (PLA) and hydroxyapatite (HA) aimed at the repair of fractures or considerable bone injuries, using 3D printing and electrospinning techniques.

The invention relates to the field of oral cavities, and particularly discloses a lasting antibacterial type composite tooth socket for medicine carrying and a preparation method thereof.The lasting antibacterial type composite tooth socket comprises an adsorption layer and an antibacterial membrane layer, the adsorption layer is used for adsorbing oral cavity treatment liquid medicine, and the antibacterial membrane layer comprises a nano-silver antibacterial layer and a chitosan antibacterial layer; the preparation method comprises the following steps: mixing a tea polyphenol-polylactic acid composite solution, a nano-silver-carboxylation modified cellulose compound and a polyvinyl alcohol solution, and carrying out electrostatic spinning to prepare a nano-silver antibacterial fiber membrane, so as to form the nano-silver antibacterial layer; mixing chitosan with hot water, adding cinnamyl aldehyde, glycerol and boric acid, stirring to obtain a mixed solution, coating one side of the nano-silver antibacterial layer with the mixed solution, and curing to form a chitosan antibacterial layer; the adsorption layer is attached to the side, away from the chitosan antibacterial layer, of the nano-silver antibacterial layer, and then the lasting antibacterial type composite tooth socket for carrying the medicine is prepared through hot-pressing compounding. The drug-loaded composite tooth socket has the characteristic of further improving the antibacterial property and the antibacterial durability of the drug-loaded composite tooth socket.

The invention belongs to the technical field of food preservation, and particularly discloses an aerogel fiber membrane with humidity response and capable of being used for food preservation and a preparation method of the aerogel fiber membrane. The preparation method comprises the following steps: mixing a shell film-forming substance with a first solvent to obtain a shell spinning solution; mixing a core layer gel substance, a biological preservative, a cross-linking agent and a second solvent to obtain a core layer gel spinning solution; and then carrying out coaxial electrostatic spinning on the obtained shell layer spinning solution and core layer gel spinning solution at 40-60% RH to obtain the aerogel fiber membrane which has humidity response and can be used for food preservation. The core layer with the porous aerogel structure is prepared in one step, preparation is simple, industrialization is easy to achieve, and good application prospects are achieved; the aerogel fiber membrane not only can solve the problem of juice seepage in the storage process of fresh food, but also can perform humidity response to the environment and intelligently release an antibacterial agent in a controlled mode, growth and reproduction of dominant putrefying bacteria in the storage process of the fresh food are inhibited, and the preservation period is prolonged.

The invention belongs to the field of composite materials, and particularly relates to a nanofiber radiation refrigeration heat insulation film with a bionic multilayer structure. The device sequentially comprises a bionic anti-reflection layer, a solar spectrum reflection layer, a nanofiber porous heat insulation layer and an atmospheric window radiation layer from outside to inside, the bionic anti-reflection layer is a sub-wavelength nano bulge array simulating a moth eye structure and is formed on the outer surface of the solar spectrum reflecting layer; the solar spectrum reflecting layer is a polymer film doped with high-reflectivity nanoparticles; the nanofiber porous heat insulation layer is a porous membrane formed by interweaving polymer nanofibers prepared by an electrostatic spinning technology; the atmospheric window radiation layer is a functional layer formed by coating or blending high-emissivity inorganic nanoparticles on the inner surface of the nanofiber porous heat insulation layer; the film integrates bionic antireflection, high sunlight reflection, efficient heat radiation and physical heat insulation, and efficient, stable and flexible daytime radiation refrigeration is achieved.

The invention discloses a multifunctional fully-degradable mulching film with water taking, slow release and soil improvement functions and a preparation method thereof, and belongs to the technical field of agricultural mulching films. The method comprises the following steps: preparing a PVA aqueous solution; the preparation method comprises the following steps: extracting a 3-8wt% nano cellulose solution from plant fibers by a two-step DES method; preparing a silicon source dispersion liquid; adding 10 parts of a nanocellulose solution, 1.25 parts of a silicon source dispersion liquid and 20 parts of glycerol into 100 parts of a PVA aqueous solution to obtain a film coating liquid; adding humic acid and an ion-based fertilizer into the film coating liquid, uniformly mixing, and carrying out curtain coating and drying to form a base film; the preparation method comprises the following steps: preparing 8-12wt% of a hydrophobic degradable material solution, and performing electrostatic spinning on a base film by using the solution to form a Janus structure, thereby obtaining the multifunctional full-degradable mulching film which can realize water extraction from air. The device has a function of taking water from air and a fertilizer slow release function, can release different fertilizers in a gradient manner, and meets the requirements of plants in different growth cycles. After being used, the soil conditioner can be directly turned into soil, the rest part directly acts with the soil, and PVA and humic acid synergistically improve the soil environment.

The invention relates to a micro-nano mullite reinforced zirconium oxide inorganic fiber, the phase of the micro-nano mullite reinforced zirconium oxide inorganic fiber is composed of two phases of tetragonal zirconium oxide and mullite, the fiber diameter is 0.1-1.5 [mu] m, and crystal phase stability, microstructure stability and fiber flexibility are maintained at the temperature from room temperature to high temperature of 1400 DEG C. The preparation method comprises the following steps: taking acidic aluminum sol, silica sol, zirconium sol and yttrium salt as metal sources, taking a high-molecular polymer as a spinning auxiliary agent, obtaining micro-nano mullite reinforced zirconium oxide precursor fibers through an electrostatic spinning technology, and carrying out heat treatment on the precursor fibers to obtain the mullite reinforced zirconium oxide inorganic fibers. The invention has the advantages of wide raw material source, cheap raw materials, stable system, good spinnability, high solid content, simple preparation process and the like. The prepared inorganic fiber has good high-temperature stability and flexibility in a wide temperature range from room temperature to high temperature of 1400 DEG C, and has application prospects in the fields of aerospace vehicle flexible heat insulation felts, high-temperature crystal growing furnaces and other high-temperature flexible heat insulation and heat preservation.

The invention discloses a preparation method of a noise-reducing anti-corrosion multifunctional coating, which comprises the following steps: mixing a polydimethylsiloxane prepolymer with a curing agent, casting on a glass sheet, curing, demolding to obtain a film substrate, and carrying out laser perforation treatment on the film substrate to obtain a low-frequency noise-reducing film substrate; taking the low-frequency noise reduction film substrate as a directional receiving plane, and performing electrostatic spinning treatment to obtain the low-frequency noise reduction film; uniformly mixing aliphatic isocyanate, polyether polyol, a chain extender, a catalyst, a conductive filler, a heat-conducting filler, porous titanium dioxide, a defoaming agent, a dispersing agent and a latent curing agent, and treating to obtain an anti-corrosion damping coating; the surface of a target base body is sequentially coated with the anti-corrosion damping coating, the low-frequency noise reduction film and the anti-corrosion damping coating, and the noise reduction and anti-corrosion multifunctional coating is obtained; the problems that in the prior art, due to separation of low-frequency noise reduction and anti-corrosion functions, construction is complex, cost is high, the effect is limited, and signal transmission quality and equipment durability are difficult to consider at the same time are solved.

The present invention belongs to the technical field of functional composite fibers, and discloses a wear-resistant nanofiber-reinforced and protected graphene fiber, a preparation method thereof and an application. The wear-resistant nanofiber-reinforced and protected graphene fiber comprises a graphene fiber bundle and nanofibers. The nanofibers coat the graphene fiber bundle in the form of a three-dimensional porous network to form a stress buffer layer; wear-resistant particles are uniformly loaded inside the three-dimensional porous network. The preparation method is as follows: fixing the surface-pretreated graphene fiber on an electrospinning nanofiber yarn machine, forming a nanofiber membrane by electrospinning and uniformly wrapping it on the surface-pretreated graphene fiber, then winding it into a roll, and then performing a hot roll treatment on the wound fiber bundle to obtain the wear-resistant nanofiber-reinforced and protected graphene fiber. The application is: used for weaving to obtain a graphene fiber fabric. The fiber prepared by the present invention and the fabric woven therefrom have excellent mechanical properties, wear resistance, electrical conductivity and thermal conductivity at the same time.

The invention provides an impurity deep removal and purification device in ES fiber solvent recovery. Relates to the technical field of electrostatic spinning process and solvent recovery, and comprises a pre-separation module used for removing fiber residues and solid particles larger than 5 microns in solvent-enriched gas; the multi-stage deep condensation module comprises two stages of condensers, and the two stages of condensers condense the solvent steam according to the gradually decreased temperature and intercept micro-droplet impurities; and the composite adsorption module is used for adsorbing residual organic trace impurities and removing water. The impurity deep removal and purification device in ES fiber solvent recovery has the advantages of being low in energy consumption, easy and convenient to maintain, stable in operation and capable of being continuously online for 72 h or above without shutdown, the solvent recovery rate is remarkably increased, the operation cost is reduced, and the potential risk of organic vapor emission to the environment and operation safety is effectively avoided.

The invention belongs to the field of intelligent wearing, and discloses a multifunctional wearable composite fiber membrane and a preparation method and application thereof. The multifunctional wearable composite fiber membrane is of a sandwich structure, the upper layer is a fullerene hybridized phosphorene modified polyacrylonitrile membrane, the lower layer is a polyurethane membrane, and the middle layer is a silver nanowire layer. The preparation method comprises the following steps: firstly, preparing fullerene hybridized phosphorene nanosheets, dispersing the fullerene hybridized phosphorene nanosheets into a solvent to obtain fullerene hybridized phosphorene dispersion liquid, adding the fullerene hybridized phosphorene dispersion liquid into a polyacrylonitrile solution, stirring to obtain a fullerene hybridized phosphorene / polyacrylonitrile spinning solution, and carrying out electrostatic spinning to obtain the fullerene hybridized phosphorene modified polyacrylonitrile fiber membrane. And then rolling or spraying a silver nanowire layer, covering one side of the silver nanowire layer with a polyurethane fiber membrane, drying and pressing to obtain the composite material. The composite fiber membrane prepared by the invention has good mechanical properties, air permeability, one-way moisture conduction performance, antibacterial performance, heat dissipation performance, electromagnetic shielding performance and flame retardant performance, and has a wide application prospect in the field of flexible wearable intelligent equipment.

The invention provides an ultralow-swelling artificial cornea imitating natural cornea fiber arrangement and a preparation method, and belongs to the technical field of biomedical materials.The preparation method comprises the steps that I-type collagen is dissolved in a PBS buffer solution, a photofunctionalization modified active reagent is added for chemical modification, stirring is conducted in a dark place, freeze drying is conducted, and photofunctionalization collagen is obtained; dissolving the photo-functionalized collagen, and then preparing a collagen fiber membrane through electrostatic spinning; and performing phase change DLP 3D biological printing on the biological ink and the collagenous fiber membrane to obtain the keratoprosthesis with the collagenous fiber sandwich structure. Multi-layer arrangement is achieved through DLP 3D biological printing, the fiber trend of the natural cornea is simulated, and the mechanical anisotropy is remarkably improved; through a composite phase change DLP 3D printing mode of GelMA / HA-DN and photo-crosslinking collagenous fibers, the composite phase change DLP 3D printing material has good manufacturability, maintains high light transmittance and maintains high mechanical strength.

The invention discloses a lightweight alumina foamed ceramic refractory material and a preparation method thereof, and relates to the technical field of ceramic materials. When the light aluminum oxide foamed ceramic refractory material is prepared, zirconium acetylacetonate, yttrium nitrate hexahydrate and aluminum nitrate nonahydrate are mixed to prepare a spinning solution for electrostatic spinning, nano aluminum titanate is loaded by using a nano spraying technology during spinning, and doped modified zirconium oxide fibers are prepared after high-temperature heat treatment and defibering and dispersing; mixing aluminum oxide micro powder, hollow aluminum oxide, a high-temperature foaming agent, doped modified zirconium oxide fibers and a sintering aid, and then performing ball milling and sieving to prepare aluminum oxide-based mixed powder; and carrying out mold pressing on the alumina-based mixed powder to prepare a green body, sintering, and cooling to prepare the lightweight alumina foamed ceramic refractory material. The light aluminum oxide foamed ceramic refractory material prepared by the invention has the advantages of light weight, low thermal conductivity, high compressive strength, high bending strength and good thermal shock resistance.

The invention provides a needle-base-free multi-needle electrostatic spinning nozzle which comprises a liquid conveying base, a liquid storage base, a conductive assembly and multiple spinning needles, the distance between every two adjacent spinning needles is 1-3 mm, the inner diameter of each spinning needle is 0.1-0.3 mm, and the outer diameter of each spinning needle is 0.3-0.5 mm. Compared with the prior art, the multiple spinning needle heads are directly connected with the current-conducting plate, so that the distance between the adjacent needle heads is shortened to 1-3 mm, and short-distance ordered array nanofiber preparation is achieved; a plurality of second through holes are formed in the current-conducting plate, so that the array mode of the spinning needle heads on the current-conducting plate can be flexibly adjusted according to production requirements to meet the preparation requirements of different nanofiber arrays.

The invention relates to the technical field of flexible electronic sensing, and particularly discloses a composite fiber membrane-based capacitive flexible pressure sensor integrated system and a preparation method thereof. The sensor is composed of a composite fiber membrane sensitive layer, an interlayer type electrode structure, a multi-channel signal acquisition module and an intelligent data processing system. Wherein the composite fiber membrane is prepared through an electrostatic spinning technology, polyvinylidene fluoride serves as a matrix, ionic liquid with the mass ratio of 40%-70% is evenly dispersed, a three-dimensional porous structure is formed, and a pressure signal is converted into capacitance change through the double-electric-layer capacitance effect; the signal acquisition module adopts a high-precision capacitance digital converter to cooperatively work with a microcontroller, 9-channel parallel data acquisition is realized, the resolution reaches 6aF, and data is transmitted through an anti-interference bus protocol; and the data processing system dynamically analyzes the pressure-capacitance relationship based on an exponential function model, suppresses noise to be below 0.1 aF RMS in combination with a filtering algorithm, and synchronously generates a visual pressure distribution map.

The invention discloses a preparation method and equipment of three-chamber eccentric parallel structure nanofibers. The preparation method comprises the following steps: simultaneously carrying out high-voltage electrostatic spinning on three spinning solutions; the two spinning solutions are respectively divided into microfluids to be led out through an array formed by two sets of series metal capillary tubes; the other spinning solution is divided into microfluids to be led out through a plurality of bottom through holes of the insulating container; the first series of metal capillary tubes are inserted into the second series of metal capillary tubes to form a series of metal capillary eccentric sleeves; the series of metal capillary eccentric sleeves penetrate through the insulating container and extend out of one side of the interior of the bottom through hole to form a combined eccentric outlet of three strands of spinning solutions; three spinning solutions are guided into a high-voltage electrostatic field in an eccentric parallel mode through the combined eccentric outlet, and the three-chamber eccentric parallel structure nanofiber is formed through single-step direct stretching. According to the method, the capability of preparing the three-chamber eccentric parallel structure characteristic nanofiber with a complete structure in a single-step, batch and large-scale manner is endowed.