The application relates to the technical field of biological composite materials, and particularly relates to a preparation method of a double-dynamic-network-crosslinked biological-based
composite material, which comprises the following steps: S1, stirring an ENR
emulsion, and simultaneously adding 3 phr of
tartaric acid and 6 phr of 3-amino
phenylboronic acid in rubber
dry weight, and stirring until no obvious
solid particles are observed in the
emulsion to obtain an E-TA / APBA composite
emulsion; S2, adding
curdlan into deionized water to prepare a water dispersion; S3, adding the water dispersion into the E-TA / APBA composite emulsion to obtain an E-T3A6Ca
mixed solution, wherein a represents the component of
curdlan in the rubber
dry weight, and a is one of 3, 6, 9 or 12; and S4, pouring the E-T3A6Ca
mixed solution into a mold, water-bath heating and curing, and air-
drying until the weight is constant to obtain the biological-based
composite material. The application can realize network rearrangement at a relatively low temperature, and the
composite material has the properties of recycling, self-repairing and shape memory. The introduction of functional fillers such as carbon nanotubes and
ammonium polyphosphate endows the biological-based composite material with the properties of
electromagnetic shielding,
flame retardation and photo-thermal conversion.