The invention relates to a high-efficiency
nitrogen removal method based on
coupling of anaerobic
hydrogen production and
hydrogen type autotrophic
denitrification, which comprises the following steps: S1, using high-concentration organic
wastewater with the COD (
Chemical Oxygen Demand) concentration of more than or equal to 5000mg / L, carrying out
mechanical crushing and homogenization treatment to ensure that the particle size of particles is less than or equal to 1mm, and carrying out ultrasonic treatment to enhance the
dissolution of organic matters; s2, firstly inoculating acid-producing
bacteria into the
wastewater, and carrying out continuous stirring
fermentation at 34-38 DEG C, so that the acid-producing
bacteria convert complex organic matters into volatile
fatty acid (VFA), and the concentration of the VFA reaches 2000-3000mg / L; adjusting the pH value to 5.5-6.5, inoculating hydrogenogens, and fermenting to produce
hydrogen; s3, absorbing
tail gas generated in the
fermentation process with alkali liquor to obtain purified hydrogen, and collecting the purified hydrogen; and S4, loading a filler in an up-flow
packed bed reactor, inoculating hydrogen autotrophic
denitrifying bacteria, injecting hydrogen into the reactor through a
hollow fiber membrane gas distribution device, enabling the bubble
diameter to be less than or equal to 50 microns, controlling the
water temperature to be 30-35 DEG C, and controlling the HRT to be 4-12 hours.
Hydrogen is obtained through
fermentation of organic waste and used for a
denitrification system, the hydrogen
utilization rate is increased,
energy consumption is reduced, and the green circulation target of treating waste with waste is achieved.