2530 results about "Resin matrix" patented technology

The invention discloses a toughened epoxy resin and a curing method thereof, and relates to the technical field of epoxy resins, the toughened epoxy resin comprises the following components: 100 parts of an epoxy resin matrix, specifically a mixture of bisphenol A epoxy resin and alicyclic epoxy resin, 5-35 parts of a composite amine curing agent, and 5-20 parts of a nano toughening agent, in particular to core-shell rubber particles grafted with epoxy groups on the surfaces, the core layer of each core-shell rubber particle is cross-linked polybutadiene, the shell layer of each core-shell rubber particle is polymethyl methacrylate, 0.5-3 parts of an accelerant comprising a bi-component synergistic accelerant, 1-5 parts of an interface enhancer, and a mixture of gamma-glycidyl ether oxypropyl trimethoxy silane and a titanate coupling agent, a bisphenol A type epoxy resin and a specific proportion of alicyclic epoxy resin are combined to construct an epoxy resin matrix according to a mass ratio of 2: 1, the epoxy resin matrix is matched with a composite amine curing agent prepared by carrying out a special three-step reaction on long-chain polyether diamine, aromatic diamine and anhydride, and key parameters such as molecular weight, functionality and molar ratio of the components are accurately regulated and controlled.

Disclosed in the present invention are a PET release film base film having low surface roughness and a preparation method therefor. The release film base film comprises three layers which are stacked: a core layer and two surface layers located on both sides of the core layer. The release film base film is obtained via three-layer co-extrusion by means of taking an auxiliary extrusion resin as a raw material of the two surface layers and a primary extrusion resin as a raw material of the core layer; the auxiliary extrusion resin is obtained by mixing an anti-blocking agent PET masterbatch and a PET base material in a mass ratio of 1:5-1:15; and the primary extrusion resin is a pure PET base material. The release film base film of the present invention has low surface roughness, low haze and excellent overall performance. Since large-particle benzoic acid-modified nano aluminum oxide has the refractive index very close to that of PET base films, the present invention can effectively avoid adverse visual impacts caused by a difference in the refractive index at interfaces between nanoparticles having large particle diameters and resin matrixes, thus effectively reducing the haze.

The invention relates to the field of composite materials, and discloses an unmanned aerial vehicle carbon fiber shell preparation method, which comprises: carbon fiber surface modification treatment: carrying out surface cleaning, activation, chemical plating and surface functional modification on carbon fibers; preparing a resin matrix: mixing epoxy resin with a flexible toughening agent, a nano filler and a curing agent, and carrying out vacuum defoaming; carbon fiber laying: laying the modified carbon fiber cloth according to a set angle and sequence; vacuum bag forming: performing vacuum sealing on the laid carbon fiber composite material; and hot-pressing and curing: curing the composite material in an autoclave under the process conditions of set temperature, pressure and time. Through collaborative design of interface modification, matrix enhancement and process optimization, the comprehensive performance of the composite material is improved, so that the requirements of the unmanned aerial vehicle shell for high strength, fatigue resistance and impact resistance are met.

The invention relates to the technical field of power transmission, and discloses a composite single-core power cable, comprising: a composite core composed of carbon fibers, glass fibers and a resin matrix containing a self-repairing microcapsule, the self-repairing microcapsule being capable of releasing a repairing monomer and repairing a microcrack when the composite core generates the microcrack; the conductor layer is arranged around the composite core and is composed of an aluminum conductor containing nano graphene; the insulating layer wraps the conductor layer and is made of a temperature-sensitive polymer material; and the outer sheath wraps the insulating layer and is made of a waterproof corrosion-resistant material. The composite core of the cable can recover more than 90% of original strength (the loss of tensile strength after repair is only 3%, which is recovered from 580Ksi to 570Ksi) within 24 hours after microcracks (such as the depth of 10mu m) generated by mechanical stress or fatigue in the operation process, and the self-repairing mechanism does not need manual intervention or external equipment, so that the self-repairing performance is greatly improved. And the sudden failure of the traditional cable caused by micro-damage accumulation is avoided.

The invention discloses a method for preparing a heat-expanding epoxy foam with electromagnetic shielding properties. In the process of processing the heat-expanding epoxy foam with epoxy resin as a substrate, before curing and foaming treatment, a conductive filler with heat-expanding microspheres grafted on the surface is added to the system. After the processing is completed, the heat-expanding epoxy foam with electromagnetic shielding properties is obtained; the minimum foaming temperature of the heat-expanding microspheres is 110-120°C, and the maximum foaming temperature is 140-150°C; the temperature of the curing and foaming treatment is 15-25°C higher than the minimum foaming temperature of the heat-expanding microspheres; during the curing and foaming treatment, the viscosity of the epoxy resin is less than 1Pa·s. The method of the invention solves the problem that the conductive filler is difficult to disperse in the resin matrix innovatively by introducing heat-expanding microspheres on the surface of the conductive filler. The obtained heat-expanding epoxy foam with electromagnetic shielding properties has good electromagnetic shielding performance and high use value and economic benefits.

The invention relates to a waterborne polyurethane sizing agent, a preparation method thereof and a carbon fiber, and belongs to the technical field of carbon fiber preparation. The preparation method of the waterborne polyurethane sizing agent comprises the following steps: S10, dispersing and mixing amino modified polydimethylsiloxane and graphene oxide in an organic solvent, carrying out grafting reaction, and carrying out vacuum drying to obtain amino modified polydimethylsiloxane grafted graphene oxide; s20, mixing polyether glycol, diisocyanate and a hydrophilic chain extender, and carrying out a first reaction to obtain a first reaction solution; mixing the first reaction liquid, a small molecule chain extender and amino modified polydimethylsiloxane grafted graphene oxide for second reaction to obtain a polymerization system; and carrying out a neutralization reaction on the polymerization system and a neutralizer, and dispersing in water to obtain the waterborne polyurethane sizing agent. The waterborne polyurethane sizing agent can effectively increase the surface roughness of carbon fibers and improve the interfacial shear strength between the carbon fibers and a resin matrix.

The present invention relates to the technical field of composite materials. Provided are a glass fiber-reinforced epoxy resin composite material and a preparation method therefor. In the present invention, an epoxy silane coupling agent solution is used for performing surface modification on glass fibers. An epoxy silane coupling agent contains a hydrolyzable group and an epoxy group. Silicon hydroxyl generated when the hydrolyzable group is hydrolyzed can be connected to the glass fibers, so as to effectively modify the surfaces of the glass fibers. The epoxy group can react with an epoxy resin matrix, thereby improving the infiltration effect of the epoxy resin on the glass fibers and improving the bonding performance of the interface of the glass fiber-reinforced epoxy resin composite material, and thus improving the mechanical properties of the glass fiber-reinforced epoxy resin composite material. The epoxy resin is cured and modified by using a functional curing agent or nanoparticles, so as to improve the ductility or strength of the epoxy resin, thereby improving the mechanical properties of the prepared glass fiber-reinforced epoxy resin composite material.

The invention provides an integrally-formed synthetic sleeper, a preparation process and a preparation device.The integrally-formed synthetic sleeper comprises a polyurethane resin matrix, continuous glass fibers are longitudinally arranged in the polyurethane resin matrix and used for longitudinal reinforcement of the synthetic sleeper, and a reinforcement layer composed of glass fiber fabric and polyurethane resin is arranged on the surface of the polyurethane resin matrix. The thickness of the reinforcing layer is 1 to 10 mm; the overall density of the synthetic sleeper is 0.64-1.4 g / cm < 3 >, and the polyurethane resin accounts for 35-50% of the total weight of the synthetic sleeper; the continuous glass fiber accounts for 35-60% of the total weight of the synthetic sleeper, and the glass fiber fabric accounts for 3-10% of the total weight of the synthetic sleeper; the overall strength of the composite sleeper can be remarkably improved, and transverse cracking is avoided; vOC generated in the production process of the synthetic sleeper and solid waste pollution caused by polishing are reduced.

The invention provides an anti-aging flame-retardant epoxy resin coating and a preparation process thereof, and belongs to the technical field of coating preparation. The preparation process comprises the following steps: preparing the flame-retardant additive; preparing a coated modified black phosphorus nanosheet; preparing modified hollow glass beads; preparing the epoxy resin coating. The preparation method comprises the following steps: dissolving 3, 4-dihydroxy benzaldehyde and 2-amino-4-methylphenol in absolute ethyl alcohol, carrying out a heating reflux reaction, carrying out dehydration condensation on an aldehyde group in the 3, 4-dihydroxy benzaldehyde and an amino group in the 2-amino-4-methylphenol to generate an imine bond-containing intermediate, respectively dissolving the intermediate and phosphonitrilic chloride trimer, and carrying out a reaction to obtain the phosphonitrilic chloride trimer. The preparation method comprises the following steps: firstly, adding phosphonitrilic chloride into an intermediate, then mixing for reaction, enabling phenolic hydroxyl groups in the intermediate and phosphonitrilic chloride trimer to be subjected to nucleophilic substitution reaction to generate the flame-retardant additive containing phosphorus and a Schiff base structure, and the flame-retardant additive has relatively good compatibility with an epoxy resin matrix, is not easy to separate out and can effectively improve the flame-retardant property of the epoxy resin coating.

The invention discloses a gradient gradual change type powder material as well as a preparation method and application thereof. The gradient gradual change type powder material comprises a non-metal core, a transition layer, a gradual change layer and a modification layer. The gradient powder material provided by the invention shows excellent strength-ductility synergistic effect, high fracture toughness and enhanced fatigue, wear and corrosion resistance, is good in metal wettability, can effectively reinforce a metal matrix and improve the performance of the metal matrix, can also be well dispersed in resin, and can be applied to the field of metal materials. The gradient powder material disclosed by the invention has a wide application prospect, and can be applied to the fields of heat dissipation of electronic devices, high-speed cutting tools, grinding material and grinding tool materials, high-temperature protection materials and the like.

The invention relates to the field of optical protection materials, and provides a transparent film with laser eavesdropping prevention performance and a preparation method thereof.The transparent film is composed of surface-modified doped tungsten oxide nanosheets, amino-isocyanate bifunctional lithium niobate nanowires, urethane acrylate, an ultraviolet light absorber, a silane coupling agent, a dispersing agent and a flatting agent; the molybdenum-doped tungsten oxide nanosheets are obtained through silane coupling modification after hydrothermal synthesis, and the lithium niobate nanowires are prepared through a gradient modification process of hydrothermal synthesis-silane coupling-isocyanate grafting-phenol end capping. A modified nano material is uniformly dispersed in a resin matrix through an ultrasonic dispersion composite technology, and through blade coating forming, ultraviolet curing and constant-temperature and constant-humidity post-treatment, compared with the prior art, the scheme overcomes the problems that a traditional protective film is insufficient in optical transparency, laser eavesdropping prevention function and dynamic viscoelasticity, and is suitable for the field of high-end security and protection.

The invention relates to the technical field of preparation of epoxy insulating materials, in particular to an epoxy resin material constructed by a multistage molecular chain cross-linked network and a preparation method, and the epoxy resin material realizes synergistic improvement of insulation and mechanical properties. Epoxy resin monomers with different rigid and flexible group contents and different chain lengths under the same chain structure are combined according to a certain proportion and are mixed into a homogeneous-phase resin matrix at a high temperature, and then the homogeneous-phase resin matrix and an anhydride curing agent are subjected to cross-linking curing at the high temperature to prepare the epoxy insulating material. The rigidity and flexibility of an epoxy cross-linked network are regulated and controlled by utilizing the multi-rigid group and multi-epoxy group of a short-chain resin monomer in a resin matrix and the multi-active hydroxyl and high-flexibility ether bond content of a long-chain resin monomer, and a charge barrier is constructed. Finally, the epoxy resin material with high mechanical property and high electrical insulation property is prepared, and the insulation property and the mechanical property are synergistically improved.

The invention discloses a food-grade high-temperature-resistant coating and a preparation method thereof. The high-temperature-resistant coating is prepared from 60-75% of matrix resin, 18-28% of surface hydrophobic modified nano functional filler and 10-20% of auxiliaries, and the nano functional filler is prepared from 10-15% of nano silicon dioxide, 5-8% of nano aluminum oxide and 3-5% of nano titanium dioxide. According to the food-grade high-temperature-resistant coating and the preparation method thereof, surface hydrophobic modification is carried out on nano particles through a silane coupling agent, the compatibility and dispersion stability of the nano particles in a resin matrix are remarkably improved, coating defects caused by agglomeration at high temperature are avoided, a hydrophobic barrier is formed by the modified nano filler, the moisture permeability is reduced, and the high-temperature-resistant performance of the food-grade high-temperature-resistant coating is improved. And the damp-heat aging resistance of the coating is enhanced.

The invention discloses a composition based on hollow glass beads and a preparation method thereof, and relates to the technical field of material science. The preparation method comprises the following steps: firstly, constructing a pre-composite functional microsphere with a specific hierarchical structure as a core basic functional unit, then matching with a plurality of components such as a thermosetting resin matrix, a latent curing system, a functional synergistic aid package and a composite solvent system, and matching with a preparation process which has a synergistic effect with the components. The composition based on the hollow glass beads is expected to realize uniform dispersion of the hollow glass beads in a coating system and strong bonding of a microscopic interface on the premise of ensuring the structural integrity of the hollow glass beads. Therefore, the high-performance composite coating material with ultra-light weight, high heat insulation efficiency, excellent mechanical strength and long-term service stability is obtained.

The invention discloses a glass fiber reinforced epoxy resin composite material and a preparation method thereof, and relates to the technical field of composite materials, and the preparation method comprises the following steps: carrying out organic solvent immersion treatment, cleaning and drying on glass fibers to obtain pretreated glass fibers; respectively carrying out phytic acid modification treatment on the pretreated glass fibers and hollow alumina microspheres; performing plasma surface treatment on the glass fibers and the hollow aluminum oxide microspheres subjected to the phytic acid modification treatment; mixing and dispersing epoxy resin, a curing agent, the glass fibers subjected to plasma surface treatment and the hollow aluminum oxide microspheres according to a preset mass ratio; carrying out vacuum degassing on the mixture; and injecting the degassed mixture into a mold for step-by-step curing. The preparation method has the beneficial effects that active groups are introduced to the surfaces of the glass fibers through phytic acid treatment, the number of the active groups is further increased by combining plasma surface treatment, and the interface bonding capacity of the glass fibers and an epoxy resin matrix is remarkably improved.

The invention discloses a phosphate composite flame retardant and a preparation method thereof, and relates to the technical field of flame retardants. The phosphate ester composite flame retardant is prepared from phosphorus-nitrogen grafted and coated network-shaped silicon dioxide powder, a Co-MOF composite graphene oxide catalytic carrier and pentaerythritol phosphate ester, the phosphorus-nitrogen grafted coated network-shaped silicon dioxide powder is prepared from a network-shaped dispersion modifier, silicon dioxide, dopamine hydrochloride, phosphorus oxychloride and 4, 4-diaminodiphenyl methane, a Co-MOF composite graphene oxide catalytic carrier is filled with phosphorus-nitrogen grafted and coated network-shaped silicon dioxide powder and pentaerythritol phosphate, migration of components is effectively reduced, the thermal stability of a flame-retardant system is enhanced, meanwhile, the compatibility and dispersity in an epoxy resin matrix are improved, the phosphorus-nitrogen grafted and coated network-shaped silicon dioxide powder, the pentaerythritol phosphate and the phosphorus-nitrogen grafted and coated network-shaped silicon dioxide powder have a synergistic effect, and the flame-retardant effect is improved. A carbon residue layer after combustion is more compact and continuous, isolation and protection effects can be better played, and the flame retardant property is remarkably improved.

The invention discloses a high-refractive-index nano-composite optical adhesive and a preparation method thereof, and belongs to the technical field of optical transparent adhesives. The optical adhesive is prepared by taking a polyurethane acrylate oligomer with a specific structure as matrix resin, introducing surface-modified barium titanate and zirconium oxide core-shell nanoparticles as a functional filler, and matching with an active diluent, a photoinitiator and a silane coupling agent in a specific proportion. Through the design of the core-shell structure, the core problems that the high-refractive-index nanoparticles are easy to agglomerate in an organic resin matrix, the dispersion stability is poor and the bonding force with a matrix interface is weak are effectively solved. The prepared optical adhesive has a refractive index of more than 1.65, a light transmittance of more than 99% and a haze of less than 0.3% after being cured, has excellent bonding strength, weather resistance and long-term use stability, and is especially suitable for precise lamination of high-end display devices (such as OLEDs (Organic Light Emitting Diodes) and micro-lens arrays).

The invention relates to the technical field of preparation of heat-conducting epoxy composite materials, in particular to a graphite / carbon fiber felt / epoxy composite material with a three-dimensional heat-conducting network, which is prepared by forming a graphite / carbon fiber felt three-dimensional heat-conducting network by graphite and a carbon fiber surfacing felt and then compounding the graphite / carbon fiber felt three-dimensional heat-conducting network with an epoxy resin matrix. The preparation method disclosed by the invention has the characteristics of simple and convenient process and easiness in operation mastering, and the obtained composite material shows good convenience in the aspect of processing and is relatively low in cost. Experimental results show that the in-plane heat conductivity of the prepared heat-conducting composite material can reach 0.763 W / mK, and compared with a pure epoxy resin matrix, the heat conductivity of the heat-conducting composite material is improved by about 302%, and the heat-conducting composite material shows excellent heat-conducting property.

The invention relates to the technical field of PET optical films, and particularly discloses a high-light-transmittance blue-light-resistant PET optical film and a preparation method thereof, and the high-light-transmittance blue-light-resistant PET optical film is prepared from the following raw materials by weight: 70-85% of a polyethylene glycol terephthalate resin matrix; 3%-8% of a benzotriazole anti-blue light agent; 5%-12% of a silicon dioxide nano anti-reflection agent; 2%-6% of nano zinc oxide or nano cerium oxide; 1.5% to 4% of a polycarbodiimide cross-linking agent; 0.5%-3% of an anti-blocking agent; 0.4%-1.5% of an antioxidant; 0.4%-1.0% of an ultraviolet light absorber; the balance is a processing aid; the preparation method comprises the following steps: S1, pretreating the raw materials; s2, a mixing procedure; and S3, extruding and coating. The PET optical film provided by the invention has high optical properties of high light transmittance, blue light resistance and low haze, and has the advantages of high light transmittance and blue light blocking rate of the optical film and improvement of the application range of the optical film.

The present invention discloses a low-temperature conductive adhesive, which is prepared by weight using raw materials including 70-80 parts of silver powder, 20-30 parts of resin matrix, 1-10 parts of curing agent, 0.1-0.5 parts of silane coupling agent, 0.1-0.5 parts of stabilizer, and 0.1-0.5 parts of metal salt. The present invention introduces an organic metal salt into the resin matrix to reduce the contact resistance of the colloid, and after wet heat aging, maintains a lower contact resistance increase rate. The present invention adopts a combination of epoxy resin, acrylate and modified epoxy acrylic resin, and the weight of epoxy resin and acrylate is less than or equal to the weight of modified epoxy acrylic resin, so that low-temperature curing can be achieved. The present invention can achieve 60-80 ° C, 20-40 min curing, and the conductive adhesive elongation at break obtained can reach more than 8%, and before and after wet heat aging, there is a more stable and relatively small contact resistance, which is particularly suitable for the electronic field with high requirements for contact resistance.

The invention discloses a preparation method and application of a pulsed electric field induced high-thermal-conductivity epoxy-based composite material, and relates to the technical field of preparation of epoxy resin composite materials. The invention aims to solve the problem that the thermal conductivity of the epoxy resin-based composite material is not obviously improved under the condition of low filling amount at present. According to the method, the h-BN is induced to be oriented in an epoxy resin matrix by utilizing a pulsed electric field, then the epoxy resin is cured, and the oriented structure is reserved. Compared with blindness of construction of a direct doping heat conduction path, the h-BN is enabled to face a specific direction by utilizing an induction effect of a pulsed electric field, so that the probability of mutual lap joint of the h-BN is increased, and construction of the heat conduction path is promoted. The preparation method and application of the high-thermal-conductivity epoxy composite material induced by the pulsed electric field can be obtained.

The invention discloses a compound yeast agent for anaerobic degradation of biodegradable plastics. The compound yeast agent comprises the following components in percentage by mass: 0.5-3% of fenpropathrin, 1-6% of nitrite, 1-4% of ammonium molybdate, 5-10% of PLA, 5-10% of nano starch, 3-6% of nano calcium carbonate, 1-5% of carbamide and the balance of a biodegradable resin carrier. The production method comprises the following steps: 1, dispersion treatment; 2, centralization processing; 3, carrying out structured treatment; 4, carrying out carrier implantation treatment; and 5, plasticizing and granulating. The compound yeast agent is added into the plastic, and the addition amount is 1-5%, so that the anaerobic degradation plastic is formed. According to the invention, anaerobic degradation can be regulated and controlled, and more importantly, anaerobic degradation also realizes that the degradable plastic disclosed by the invention is in a normal use condition, the plastic cannot be degraded quickly in light and oxygen environments, the aging property of the plastic is equivalent to that of a resin matrix of the plastic, and the physical and mechanical properties are ensured.

The invention provides a reflective thermal insulation coating based on three-dimensional porous resin as well as a preparation method and application of the reflective thermal insulation coating. The coating is prepared from the following raw materials in parts by weight: 15 to 60 parts of polymer resin emulsion, 1 to 15 parts of good solvent, 1 to 15 parts of poor solvent, 5 to 15 parts of reflective filler, 2 to 5 parts of nano kaolin and 1 to 5 parts of silicon dioxide aerogel. The reflective filler is hollow glass microspheres jointly modified by a silane coupling agent and titanium n-butoxide. The chemical reaction between the silane coupling agent and the surfaces of the glass microspheres can enhance the binding force between the silane coupling agent and the resin matrix, and avoids the problems of aggregation and sedimentation in the coating, thereby improving the uniformity and stability of the coating. Meanwhile, titanium n-butoxide is introduced, a TiO2 coating layer is generated through a hydrolysis reaction, heat can be effectively reflected through the high reflectivity of TiO2, heat absorption of the coating is reduced, and the heat insulation effect is improved. Therefore, the double-modified hollow glass microspheres can play a better heat insulation role in the coating, and the overall heat insulation efficiency of the coating is improved.

The invention provides a preparation method of a self-repairing resin-based composite material based on dynamic bonds. The self-repairing epoxy resin comprises one covalent dynamic bond of a Diels-Alder bond, a disulfide bond or a borate bond, and the preparation method of the self-repairing epoxy resin comprises the following steps: heating epoxy resin to a molten state, adding a curing agent component while stirring, and carrying out a prepolymerization reaction to obtain a prepolymer; the curing agent comprises a rigid diamine curing agent, a dynamic diamine monomer and a flexible chain segment regulator, and the dynamic diamine monomer contains a dynamic covalent bond; and carrying out curing molding on the prepolymer to obtain the self-repairing epoxy resin. And impregnating reinforced fibers or fabrics thereof with the prepared prepolymer, and heating and curing to obtain the self-repairing resin-based composite material. The invention provides a chemical molecule design, dynamic reversible chemical bonds are introduced into a resin matrix, and by constructing the dynamic bonds, the composite material has high performance of a traditional composite material and also has life-like self-healing ability.

The invention discloses a stress whitening resistant polyamide composite material, which comprises the following components by weight: 74-86 parts of polyamide; 0.1-1 part of rice bran wax metal salt; 5-30 parts of a toughening agent; and 0.3 to 0.8 part of carbon black and 0.1 to 0.5 part of aniline black. The rice bran wax salt is used as a nucleating agent to reduce the grain size of the crystal, the aniline black can improve the tinting power to a crystalline region to reduce light reflection at a stress whitening position, the carbon black can also adjust the tinting power to the crystal and an amorphous region, and under the cooperation of the three, the grain size of the crystal is reduced to be smaller than the wavelength of visible light to realize absorption of visible light. Light reflection caused by tiny gaps generated by separation of the flexibilizer and a polyamide resin matrix after the polyamide composite material is bent under stress is improved, and the defect of stress whitening of the polyamide composite material is remarkably reduced.

The invention relates to a high-flame-retardant, high-thermal-conductivity and high-toughening epoxy resin packaging adhesive and a preparation method thereof. A self-developed flame retardant containing nitrogen, phosphorus and sulfur is added into an epoxy resin system, rich carbon residues hinder mass and heat exchange in the combustion process and also hinder combustible gas from being released to a combustion area, free radicals containing phosphorus and sulfur can capture active free radicals (H * and OH *), and the chain reaction of combustion is ended. The surface modifier is used for modifying the layered graphene composite boron nitride micro-powder heat-conducting filler, so that the interface interaction between the filler and the resin matrix is synergistically enhanced, and the compatibility and the heat-conducting effect of the filler and the resin matrix are improved. And the modified toughening agent is added to ensure that the epoxy resin packaging adhesive has good toughness. In addition, through further exploration and innovation, the specific proportion range of the nitrogen-phosphorus-sulfur flame retardant, the modified layered graphene composite carbon nitride micro powder and the flexibilizer is determined. The epoxy resin packaging adhesive prepared by the invention has excellent flame retardance, heat conductivity and toughness.

The invention discloses a high-strength hoop and a processing method thereof in the technical field of mechanical connection fasteners. The high-strength hoop comprises the following raw materials: modified carbon fibers, a modified epoxy resin matrix, chopped glass fibers, an antioxidant and an aluminate coupling agent. Cleaning the modified carbon fibers with acetone to remove oil stains, oxidizing the modified carbon fibers with concentrated nitric acid at 80-85 DEG C to generate polar functional groups containing hydroxyl and carboxyl, washing the modified carbon fibers with water until the modified carbon fibers are neutral, drying the modified carbon fibers, immersing the modified carbon fibers into an absolute ethyl alcohol solution of an aluminate coupling agent for ultrasonic dispersion, and curing the modified carbon fibers at 100-105 DEG C; the modified epoxy resin matrix is prepared by heating and melting epoxy resin, adding nano montmorillonite, stirring and dispersing, adding polyamide, an accelerant and a flexibilizer, and carrying out vacuum defoaming at 100-105 DEG C. The hoop has the advantages of high strength, weather resistance and the like by modifying and enhancing interface bonding and matrix toughness, and is suitable for connection under complex working conditions.

The invention discloses a degradable armed acetal epoxy monomer and a preparation method thereof, the acetal epoxy monomer has the following molecular structure general formula: # imgabs0 #, in the formula, R1, R2, R3 and R4 are independently selected from one of hydrogen, methoxyl and ethyoxyl. The degradable acetal epoxy monomer is prepared through the aldol condensation reaction, the thermosetting epoxy resin prepared from the epoxy monomer and the curing agent can be rapidly degraded under the normal-pressure, mild and specific conditions, and huge economic and environmental advantages are achieved for recycling and reusing of the thermosetting resin. When the prepared degradable epoxy resin is used in thermosetting epoxy resin, under the degradation condition provided by the invention, a thermosetting epoxy resin matrix is degraded into alcohol and aldehyde with relatively small molecular weight, the mixture can be dissolved in an organic solvent, and a degradation product can be extracted through simple separation, so that the purpose of recovering the resin is achieved.

The invention provides a universal light-cured resin preparation method, and relates to the technical field of light-cured resin preparation, and the method comprises the following steps: S1, preparation of microcrystalline wax-LMA; s2, preparing an acrylic resin matrix; s3, adding microcrystalline wax-LMA and other fillers into the acrylic resin matrix, and stirring and mixing; s4, then adding a diluent and other additives, and stirring and mixing; and S5, adding a compound photoinitiator, and stirring and mixing to obtain a finished product. Through the compound photoinitiator, the surface and the deep layer of the material are synchronously cured, and almost no curing stress exists, so that the material can be cured into a sheet layer without any buckling deformation in a sunken DLP (Digital Light Processing); and secondly, the microcrystalline wax-LMA forms a microphase separation structure in the material, so that the shrinkage and cracking of the material are greatly reduced, and the effects of improving the strength and the toughness can be achieved.

The invention discloses a preparation method of a WS2 / MXene / HBPSi synergistically enhanced epoxy resin composite material. The preparation method specifically comprises the following steps: preparing a WS2 / MXene hybrid from few-layer MXene powder, WCl6 and a sulfur source precursor; the preparation method comprises the following steps: uniformly mixing tetraethoxysilane, neopentyl glycol and triethanolamine, and carrying out gradient heating reaction to obtain HBPSi; epoxy resin EP is used as a resin matrix, DDS is used as a curing agent, a WS2 / MXene hybrid is used as a lubricating additive, HBPSi is used as a toughening agent, and the epoxy resin composite material is prepared by combining a melt blending process with a staged heating curing method. According to the method, the toughness and the interface bonding strength of the material are remarkably improved by introducing HBPSi, the friction coefficient of the material is effectively reduced and the wear resistance is improved through the synergistic effect of WS2 and MXene, and cooperative regulation and control of structural strengthening and friction performance improvement are achieved.