3085 results about "Resin matrix" patented technology

The invention discloses a toughened epoxy resin and a curing method thereof, and relates to the technical field of epoxy resins, the toughened epoxy resin comprises the following components: 100 parts of an epoxy resin matrix, specifically a mixture of bisphenol A epoxy resin and alicyclic epoxy resin, 5-35 parts of a composite amine curing agent, and 5-20 parts of a nano toughening agent, in particular to core-shell rubber particles grafted with epoxy groups on the surfaces, the core layer of each core-shell rubber particle is cross-linked polybutadiene, the shell layer of each core-shell rubber particle is polymethyl methacrylate, 0.5-3 parts of an accelerant comprising a bi-component synergistic accelerant, 1-5 parts of an interface enhancer, and a mixture of gamma-glycidyl ether oxypropyl trimethoxy silane and a titanate coupling agent, a bisphenol A type epoxy resin and a specific proportion of alicyclic epoxy resin are combined to construct an epoxy resin matrix according to a mass ratio of 2: 1, the epoxy resin matrix is matched with a composite amine curing agent prepared by carrying out a special three-step reaction on long-chain polyether diamine, aromatic diamine and anhydride, and key parameters such as molecular weight, functionality and molar ratio of the components are accurately regulated and controlled.

The invention relates to the technical field of epoxy resin composite materials, in particular to an epoxy resin-based composite material and a preparation method thereof. The epoxy resin-based composite material comprises modified carbon fibers and an epoxy resin base material impregnated on a modified carbon fiber matrix, and the epoxy resin base material comprises the following raw materials in parts by weight: 80-100 parts of epoxy resin, 4-18 parts of a toughening elastomer, 24-45 parts of a curing agent and 1-3 parts of an accelerant. The carbon fibers are subjected to surface grafting hyperbranched molecular modification, so that the interface action between the modified carbon fibers and an epoxy resin matrix can be remarkably enhanced, and meanwhile, the high strength and high temperature-resistant stability of the carbon fibers are utilized, so that the epoxy resin-based composite material has good toughening, reinforcing and temperature resistance improving effects.

Disclosed in the present invention are a PET release film base film having low surface roughness and a preparation method therefor. The release film base film comprises three layers which are stacked: a core layer and two surface layers located on both sides of the core layer. The release film base film is obtained via three-layer co-extrusion by means of taking an auxiliary extrusion resin as a raw material of the two surface layers and a primary extrusion resin as a raw material of the core layer; the auxiliary extrusion resin is obtained by mixing an anti-blocking agent PET masterbatch and a PET base material in a mass ratio of 1:5-1:15; and the primary extrusion resin is a pure PET base material. The release film base film of the present invention has low surface roughness, low haze and excellent overall performance. Since large-particle benzoic acid-modified nano aluminum oxide has the refractive index very close to that of PET base films, the present invention can effectively avoid adverse visual impacts caused by a difference in the refractive index at interfaces between nanoparticles having large particle diameters and resin matrixes, thus effectively reducing the haze.

The invention belongs to the technical field of engineering plastics, and particularly relates to a high-flame-retardant composite material and a preparation method thereof. The composite material comprises the following components: long-carbon-chain semi-aromatic nylon, a fiber reinforced filler, a flexibilizer, alkyl aluminum phosphinate, nano montmorillonite, a zinc ion ionomer, a coupling agent, a lubricant and an antioxidant. Alkyl aluminum phosphinate is used as a main flame retardant, and nano-montmorillonite and a zinc ion ionomer are used as auxiliary flame retardants. The nano-scale montmorillonite has certain adsorption performance, and can prevent the alkyl aluminum phosphinate flame retardant from being separated out in the processing process. The zinc ion ionomer is easier to disperse in a long-carbon-chain semi-aromatic nylon resin matrix relative to alkyl aluminum phosphinate and nano-montmorillonite, and ion groups contained in the zinc ion ionomer can generate an ionic crosslinking effect with ions in alkyl aluminum phosphinate and nano-montmorillonite, so that the mechanical property and the thermal stability of the composite material are improved; and moreover, the melt viscosity is improved, and the molten drop phenomenon during combustion is prevented.

The invention relates to a pitch carbon fiber reinforced resin-based composite material and a preparation method thereof. Pitch carbon fibers are subjected to electrochemical surface treatment in an acidic electrolyte and then treated with a silane coupling agent; blending and dispersing a polyfunctional epoxy resin matrix, inorganic nano heat-conducting particles treated by a silane coupling agent, a high-temperature curing agent and an organic solvent to obtain an epoxy resin matrix solution; winding the pitch carbon fiber and the epoxy resin matrix solution to prepare a prepreg, drying, cutting, paving, and hot-pressing and curing to obtain the high-compression high-thermal-conductivity pitch carbon fiber reinforced resin matrix composite material. The composite material has the unidirectional compression strength of 305-420MPa and the unidirectional thermal conductivity of 295-618W / (m.K), has excellent compression performance and thermal conductivity, can be used for preparing aerospace craft structures / functional parts, and can also meet the requirements of other industrial equipment fields on light-weight, high-strength, high-modulus and high-thermal-conductivity composite materials.

The invention belongs to the technical field of fiber reinforced composite material additive manufacturing, and discloses a continuous fiber composite material 3D printer tail end heating extrusion device. Aiming at the problems of poor fiber impregnation degree of a resin matrix, low process flexibility of a mode of directly printing pre-impregnated composite filaments and incapability of changing the fiber content in a composite material structure by adjusting process parameters in real time in an in-situ impregnation printing mode, the invention designs an in-situ impregnation printing method capable of ensuring the printing process flexibility and improving the printing efficiency. According to the tail end heating extrusion device, the continuous fiber reinforced composite material structure can be formed in a high-quality mode, the fiber impregnation degree can be remarkably improved, and the structure of a printing nozzle is optimally designed. Through the structural design of the internal channel and the outlet nozzle of the tail end heating device, the impregnation effect of a resin matrix on continuous fibers can be improved, scraping of the nozzle on the continuous fibers is relieved, and the quality of a printing component can be effectively improved.

The invention relates to the field of composite materials, and discloses an unmanned aerial vehicle carbon fiber shell preparation method, which comprises: carbon fiber surface modification treatment: carrying out surface cleaning, activation, chemical plating and surface functional modification on carbon fibers; preparing a resin matrix: mixing epoxy resin with a flexible toughening agent, a nano filler and a curing agent, and carrying out vacuum defoaming; carbon fiber laying: laying the modified carbon fiber cloth according to a set angle and sequence; vacuum bag forming: performing vacuum sealing on the laid carbon fiber composite material; and hot-pressing and curing: curing the composite material in an autoclave under the process conditions of set temperature, pressure and time. Through collaborative design of interface modification, matrix enhancement and process optimization, the comprehensive performance of the composite material is improved, so that the requirements of the unmanned aerial vehicle shell for high strength, fatigue resistance and impact resistance are met.

The invention relates to the technical field of power transmission, and discloses a composite single-core power cable, comprising: a composite core composed of carbon fibers, glass fibers and a resin matrix containing a self-repairing microcapsule, the self-repairing microcapsule being capable of releasing a repairing monomer and repairing a microcrack when the composite core generates the microcrack; the conductor layer is arranged around the composite core and is composed of an aluminum conductor containing nano graphene; the insulating layer wraps the conductor layer and is made of a temperature-sensitive polymer material; and the outer sheath wraps the insulating layer and is made of a waterproof corrosion-resistant material. The composite core of the cable can recover more than 90% of original strength (the loss of tensile strength after repair is only 3%, which is recovered from 580Ksi to 570Ksi) within 24 hours after microcracks (such as the depth of 10mu m) generated by mechanical stress or fatigue in the operation process, and the self-repairing mechanism does not need manual intervention or external equipment, so that the self-repairing performance is greatly improved. And the sudden failure of the traditional cable caused by micro-damage accumulation is avoided.

The invention discloses a method for preparing a heat-expanding epoxy foam with electromagnetic shielding properties. In the process of processing the heat-expanding epoxy foam with epoxy resin as a substrate, before curing and foaming treatment, a conductive filler with heat-expanding microspheres grafted on the surface is added to the system. After the processing is completed, the heat-expanding epoxy foam with electromagnetic shielding properties is obtained; the minimum foaming temperature of the heat-expanding microspheres is 110-120°C, and the maximum foaming temperature is 140-150°C; the temperature of the curing and foaming treatment is 15-25°C higher than the minimum foaming temperature of the heat-expanding microspheres; during the curing and foaming treatment, the viscosity of the epoxy resin is less than 1Pa·s. The method of the invention solves the problem that the conductive filler is difficult to disperse in the resin matrix innovatively by introducing heat-expanding microspheres on the surface of the conductive filler. The obtained heat-expanding epoxy foam with electromagnetic shielding properties has good electromagnetic shielding performance and high use value and economic benefits.

The invention relates to a waterborne polyurethane sizing agent, a preparation method thereof and a carbon fiber, and belongs to the technical field of carbon fiber preparation. The preparation method of the waterborne polyurethane sizing agent comprises the following steps: S10, dispersing and mixing amino modified polydimethylsiloxane and graphene oxide in an organic solvent, carrying out grafting reaction, and carrying out vacuum drying to obtain amino modified polydimethylsiloxane grafted graphene oxide; s20, mixing polyether glycol, diisocyanate and a hydrophilic chain extender, and carrying out a first reaction to obtain a first reaction solution; mixing the first reaction liquid, a small molecule chain extender and amino modified polydimethylsiloxane grafted graphene oxide for second reaction to obtain a polymerization system; and carrying out a neutralization reaction on the polymerization system and a neutralizer, and dispersing in water to obtain the waterborne polyurethane sizing agent. The waterborne polyurethane sizing agent can effectively increase the surface roughness of carbon fibers and improve the interfacial shear strength between the carbon fibers and a resin matrix.

The present invention relates to the technical field of composite materials. Provided are a glass fiber-reinforced epoxy resin composite material and a preparation method therefor. In the present invention, an epoxy silane coupling agent solution is used for performing surface modification on glass fibers. An epoxy silane coupling agent contains a hydrolyzable group and an epoxy group. Silicon hydroxyl generated when the hydrolyzable group is hydrolyzed can be connected to the glass fibers, so as to effectively modify the surfaces of the glass fibers. The epoxy group can react with an epoxy resin matrix, thereby improving the infiltration effect of the epoxy resin on the glass fibers and improving the bonding performance of the interface of the glass fiber-reinforced epoxy resin composite material, and thus improving the mechanical properties of the glass fiber-reinforced epoxy resin composite material. The epoxy resin is cured and modified by using a functional curing agent or nanoparticles, so as to improve the ductility or strength of the epoxy resin, thereby improving the mechanical properties of the prepared glass fiber-reinforced epoxy resin composite material.

The invention discloses a heat insulation aluminum profile and a preparation method thereof, and belongs to the technical field of aluminum profile preparation. The heat insulation coating is electrostatically sprayed on the surface of the aluminum profile, the coating takes epoxy resin as a matrix, the aluminum profile is separated from the external environment, and the corrosion resistance and the heat insulation performance of the aluminum profile are improved; compared with common nano ATO, the prepared modified nano ATO has better compatibility with an epoxy resin matrix, the agglomeration phenomenon is obviously reduced, and the heat insulation performance of the coating can be greatly enhanced; the prepared modifier can significantly enhance the flame retardance and heat resistance of the coating, can promote curing of epoxy resin, is grafted on nano ATO, and is stable in performance and not prone to falling off; therefore, the prepared aluminum profile is excellent in heat insulation property and corrosion resistance, the coating sprayed on the surface of the aluminum profile has stable and efficient flame retardance and heat resistance, and the aluminum profile has important application value in the technical field of aluminum profile preparation.

The invention belongs to the technical field of preparation of wave-absorbing materials, and particularly relates to an epoxy resin wave-absorbing prepreg with strong low-frequency wave-absorbing performance and a preparation method of the epoxy resin wave-absorbing prepreg. The method comprises the following steps: mixing an epoxy resin matrix and a flexibilizer to obtain an epoxy resin system; the preparation method comprises the following steps: putting an epoxy resin system and flaky absorbents with different particle sizes into an internal mixer for internal mixing and coarse mixing, performing fine mixing by using an open mill after coarse mixing, and adding a curing agent in the fine mixing process to obtain a low-frequency wave-absorbing resin blank; putting the low-frequency wave-absorbing resin blank into a precision calender, and carrying out wave-absorbing adhesive film calendering, so as to obtain a wave-absorbing resin film after calendering; and thermally compounding the wave-absorbing resin film and the wave-transparent fiber prepreg to obtain the epoxy resin-based wave-absorbing prepreg. The wave-absorbing prepreg prepared by the invention is excellent in mechanical property after being cured, high in low-frequency wave-absorbing property and relatively high in reliability.

The invention provides an integrally-formed synthetic sleeper, a preparation process and a preparation device.The integrally-formed synthetic sleeper comprises a polyurethane resin matrix, continuous glass fibers are longitudinally arranged in the polyurethane resin matrix and used for longitudinal reinforcement of the synthetic sleeper, and a reinforcement layer composed of glass fiber fabric and polyurethane resin is arranged on the surface of the polyurethane resin matrix. The thickness of the reinforcing layer is 1 to 10 mm; the overall density of the synthetic sleeper is 0.64-1.4 g / cm < 3 >, and the polyurethane resin accounts for 35-50% of the total weight of the synthetic sleeper; the continuous glass fiber accounts for 35-60% of the total weight of the synthetic sleeper, and the glass fiber fabric accounts for 3-10% of the total weight of the synthetic sleeper; the overall strength of the composite sleeper can be remarkably improved, and transverse cracking is avoided; vOC generated in the production process of the synthetic sleeper and solid waste pollution caused by polishing are reduced.

The invention provides an anti-aging flame-retardant epoxy resin coating and a preparation process thereof, and belongs to the technical field of coating preparation. The preparation process comprises the following steps: preparing the flame-retardant additive; preparing a coated modified black phosphorus nanosheet; preparing modified hollow glass beads; preparing the epoxy resin coating. The preparation method comprises the following steps: dissolving 3, 4-dihydroxy benzaldehyde and 2-amino-4-methylphenol in absolute ethyl alcohol, carrying out a heating reflux reaction, carrying out dehydration condensation on an aldehyde group in the 3, 4-dihydroxy benzaldehyde and an amino group in the 2-amino-4-methylphenol to generate an imine bond-containing intermediate, respectively dissolving the intermediate and phosphonitrilic chloride trimer, and carrying out a reaction to obtain the phosphonitrilic chloride trimer. The preparation method comprises the following steps: firstly, adding phosphonitrilic chloride into an intermediate, then mixing for reaction, enabling phenolic hydroxyl groups in the intermediate and phosphonitrilic chloride trimer to be subjected to nucleophilic substitution reaction to generate the flame-retardant additive containing phosphorus and a Schiff base structure, and the flame-retardant additive has relatively good compatibility with an epoxy resin matrix, is not easy to separate out and can effectively improve the flame-retardant property of the epoxy resin coating.

The invention discloses a gradient gradual change type powder material as well as a preparation method and application thereof. The gradient gradual change type powder material comprises a non-metal core, a transition layer, a gradual change layer and a modification layer. The gradient powder material provided by the invention shows excellent strength-ductility synergistic effect, high fracture toughness and enhanced fatigue, wear and corrosion resistance, is good in metal wettability, can effectively reinforce a metal matrix and improve the performance of the metal matrix, can also be well dispersed in resin, and can be applied to the field of metal materials. The gradient powder material disclosed by the invention has a wide application prospect, and can be applied to the fields of heat dissipation of electronic devices, high-speed cutting tools, grinding material and grinding tool materials, high-temperature protection materials and the like.

The invention relates to the field of optical protection materials, and provides a transparent film with laser eavesdropping prevention performance and a preparation method thereof.The transparent film is composed of surface-modified doped tungsten oxide nanosheets, amino-isocyanate bifunctional lithium niobate nanowires, urethane acrylate, an ultraviolet light absorber, a silane coupling agent, a dispersing agent and a flatting agent; the molybdenum-doped tungsten oxide nanosheets are obtained through silane coupling modification after hydrothermal synthesis, and the lithium niobate nanowires are prepared through a gradient modification process of hydrothermal synthesis-silane coupling-isocyanate grafting-phenol end capping. A modified nano material is uniformly dispersed in a resin matrix through an ultrasonic dispersion composite technology, and through blade coating forming, ultraviolet curing and constant-temperature and constant-humidity post-treatment, compared with the prior art, the scheme overcomes the problems that a traditional protective film is insufficient in optical transparency, laser eavesdropping prevention function and dynamic viscoelasticity, and is suitable for the field of high-end security and protection.

The invention relates to the technical field of preparation of epoxy insulating materials, in particular to an epoxy resin material constructed by a multistage molecular chain cross-linked network and a preparation method, and the epoxy resin material realizes synergistic improvement of insulation and mechanical properties. Epoxy resin monomers with different rigid and flexible group contents and different chain lengths under the same chain structure are combined according to a certain proportion and are mixed into a homogeneous-phase resin matrix at a high temperature, and then the homogeneous-phase resin matrix and an anhydride curing agent are subjected to cross-linking curing at the high temperature to prepare the epoxy insulating material. The rigidity and flexibility of an epoxy cross-linked network are regulated and controlled by utilizing the multi-rigid group and multi-epoxy group of a short-chain resin monomer in a resin matrix and the multi-active hydroxyl and high-flexibility ether bond content of a long-chain resin monomer, and a charge barrier is constructed. Finally, the epoxy resin material with high mechanical property and high electrical insulation property is prepared, and the insulation property and the mechanical property are synergistically improved.

The invention discloses a food-grade high-temperature-resistant coating and a preparation method thereof. The high-temperature-resistant coating is prepared from 60-75% of matrix resin, 18-28% of surface hydrophobic modified nano functional filler and 10-20% of auxiliaries, and the nano functional filler is prepared from 10-15% of nano silicon dioxide, 5-8% of nano aluminum oxide and 3-5% of nano titanium dioxide. According to the food-grade high-temperature-resistant coating and the preparation method thereof, surface hydrophobic modification is carried out on nano particles through a silane coupling agent, the compatibility and dispersion stability of the nano particles in a resin matrix are remarkably improved, coating defects caused by agglomeration at high temperature are avoided, a hydrophobic barrier is formed by the modified nano filler, the moisture permeability is reduced, and the high-temperature-resistant performance of the food-grade high-temperature-resistant coating is improved. And the damp-heat aging resistance of the coating is enhanced.

The invention discloses a composition based on hollow glass beads and a preparation method thereof, and relates to the technical field of material science. The preparation method comprises the following steps: firstly, constructing a pre-composite functional microsphere with a specific hierarchical structure as a core basic functional unit, then matching with a plurality of components such as a thermosetting resin matrix, a latent curing system, a functional synergistic aid package and a composite solvent system, and matching with a preparation process which has a synergistic effect with the components. The composition based on the hollow glass beads is expected to realize uniform dispersion of the hollow glass beads in a coating system and strong bonding of a microscopic interface on the premise of ensuring the structural integrity of the hollow glass beads. Therefore, the high-performance composite coating material with ultra-light weight, high heat insulation efficiency, excellent mechanical strength and long-term service stability is obtained.

The invention discloses a glass fiber reinforced epoxy resin composite material and a preparation method thereof, and relates to the technical field of composite materials, and the preparation method comprises the following steps: carrying out organic solvent immersion treatment, cleaning and drying on glass fibers to obtain pretreated glass fibers; respectively carrying out phytic acid modification treatment on the pretreated glass fibers and hollow alumina microspheres; performing plasma surface treatment on the glass fibers and the hollow aluminum oxide microspheres subjected to the phytic acid modification treatment; mixing and dispersing epoxy resin, a curing agent, the glass fibers subjected to plasma surface treatment and the hollow aluminum oxide microspheres according to a preset mass ratio; carrying out vacuum degassing on the mixture; and injecting the degassed mixture into a mold for step-by-step curing. The preparation method has the beneficial effects that active groups are introduced to the surfaces of the glass fibers through phytic acid treatment, the number of the active groups is further increased by combining plasma surface treatment, and the interface bonding capacity of the glass fibers and an epoxy resin matrix is remarkably improved.

The invention discloses a phosphate composite flame retardant and a preparation method thereof, and relates to the technical field of flame retardants. The phosphate ester composite flame retardant is prepared from phosphorus-nitrogen grafted and coated network-shaped silicon dioxide powder, a Co-MOF composite graphene oxide catalytic carrier and pentaerythritol phosphate ester, the phosphorus-nitrogen grafted coated network-shaped silicon dioxide powder is prepared from a network-shaped dispersion modifier, silicon dioxide, dopamine hydrochloride, phosphorus oxychloride and 4, 4-diaminodiphenyl methane, a Co-MOF composite graphene oxide catalytic carrier is filled with phosphorus-nitrogen grafted and coated network-shaped silicon dioxide powder and pentaerythritol phosphate, migration of components is effectively reduced, the thermal stability of a flame-retardant system is enhanced, meanwhile, the compatibility and dispersity in an epoxy resin matrix are improved, the phosphorus-nitrogen grafted and coated network-shaped silicon dioxide powder, the pentaerythritol phosphate and the phosphorus-nitrogen grafted and coated network-shaped silicon dioxide powder have a synergistic effect, and the flame-retardant effect is improved. A carbon residue layer after combustion is more compact and continuous, isolation and protection effects can be better played, and the flame retardant property is remarkably improved.

The present invention relates to the technical field of composite materials. Provided is a preparation method for a resin matrix toughened with a silane coupling agent solution-modified nanomaterial. A specific silane coupling agent (KH560) solution is used to modify the nanomaterial, which is then used to toughen the resin matrix. KH560 has two reaction groups, which can effectively modify the surface of the nanomaterial and reduce agglomeration, while a molecular chain connecting to the surface of the nanomaterial contains an epoxy group capable of reacting with resin. By means of the molecular chain, efficient bonding between the inorganic nanomaterial and the resin matrix is achieved, the compatibility between the nanomaterial and the resin is improved, and the toughening effect of the nanomaterial on the resin is fully implemented. Moreover, in a curing process, the epoxy group does not occupy a reaction bond position between a curing agent and the resin, improving the post-curing crosslink density of the resin, and further improving the mechanical properties of the resin matrix.

The invention discloses a high-refractive-index nano-composite optical adhesive and a preparation method thereof, and belongs to the technical field of optical transparent adhesives. The optical adhesive is prepared by taking a polyurethane acrylate oligomer with a specific structure as matrix resin, introducing surface-modified barium titanate and zirconium oxide core-shell nanoparticles as a functional filler, and matching with an active diluent, a photoinitiator and a silane coupling agent in a specific proportion. Through the design of the core-shell structure, the core problems that the high-refractive-index nanoparticles are easy to agglomerate in an organic resin matrix, the dispersion stability is poor and the bonding force with a matrix interface is weak are effectively solved. The prepared optical adhesive has a refractive index of more than 1.65, a light transmittance of more than 99% and a haze of less than 0.3% after being cured, has excellent bonding strength, weather resistance and long-term use stability, and is especially suitable for precise lamination of high-end display devices (such as OLEDs (Organic Light Emitting Diodes) and micro-lens arrays).

The invention relates to the technical field of preparation of heat-conducting epoxy composite materials, in particular to a graphite / carbon fiber felt / epoxy composite material with a three-dimensional heat-conducting network, which is prepared by forming a graphite / carbon fiber felt three-dimensional heat-conducting network by graphite and a carbon fiber surfacing felt and then compounding the graphite / carbon fiber felt three-dimensional heat-conducting network with an epoxy resin matrix. The preparation method disclosed by the invention has the characteristics of simple and convenient process and easiness in operation mastering, and the obtained composite material shows good convenience in the aspect of processing and is relatively low in cost. Experimental results show that the in-plane heat conductivity of the prepared heat-conducting composite material can reach 0.763 W / mK, and compared with a pure epoxy resin matrix, the heat conductivity of the heat-conducting composite material is improved by about 302%, and the heat-conducting composite material shows excellent heat-conducting property.

The invention discloses a carbon fiber composite material as well as a preparation method and application thereof. Based on the structural design of the liquid crystal polymer with different dimensions, a liquid crystal polymer molecule assembly layer is constructed on the surface of the carbon fiber, the roughness and surface activity of the surface of the carbon fiber are improved, and meanwhile, the interface performance of the composite material is improved through the efficient redirectionality of the liquid crystal polymer under the microcosmic mesocrystal domain structure and the load. Besides, based on the high orientation of the liquid crystal polymer in the interface phase of the composite material, a multi-dimensional heat conduction network is constructed, the dominant vibration mode of the carbon fiber and the resin matrix in the phonon heat transfer process is effectively coupled, the possibility of carrier phonon scattering at the interface is reduced, the interface thermal resistance is greatly reduced, and the thermal conductivity of the composite material is improved. Therefore, the heat-conducting property of the composite material is improved.

The invention provides an epoxy resin composition, a preparation method thereof and a composite material. The epoxy resin composition comprises the following raw material components in parts by mass: 50-100 parts of a resin matrix; 11 to 15 parts by mass of thermoplastic toughening particles; 25-35 parts by mass of an aromatic amine curing agent; 2-8 parts by mass of a reactive diluent; and the molar ratio of the amino group in the aromatic amine curing agent to the epoxy group in the resin matrix is 1.0-1.3. By adjusting the content of each raw material component in the epoxy resin composition, the content of the thermoplastic toughening particles, the resin matrix and the aromatic amine curing agent is in a proper range, and the molar ratio of amino in the curing agent to epoxy group in the resin matrix is controlled. Therefore, the polymer formed by the resin composition has good strength and toughness. Besides, the reactive diluent can reduce the viscosity of the resin matrix, so that the thermoplastic toughening particles can be well dispersed in the resin matrix in the dispersion stage, and the impact resistance of a polymer formed by the resin composition is improved.

The invention relates to the technical field of PET optical films, and particularly discloses a high-light-transmittance blue-light-resistant PET optical film and a preparation method thereof, and the high-light-transmittance blue-light-resistant PET optical film is prepared from the following raw materials by weight: 70-85% of a polyethylene glycol terephthalate resin matrix; 3%-8% of a benzotriazole anti-blue light agent; 5%-12% of a silicon dioxide nano anti-reflection agent; 2%-6% of nano zinc oxide or nano cerium oxide; 1.5% to 4% of a polycarbodiimide cross-linking agent; 0.5%-3% of an anti-blocking agent; 0.4%-1.5% of an antioxidant; 0.4%-1.0% of an ultraviolet light absorber; the balance is a processing aid; the preparation method comprises the following steps: S1, pretreating the raw materials; s2, a mixing procedure; and S3, extruding and coating. The PET optical film provided by the invention has high optical properties of high light transmittance, blue light resistance and low haze, and has the advantages of high light transmittance and blue light blocking rate of the optical film and improvement of the application range of the optical film.

The invention provides a fiber resin-based composite material with an interlayer wave lock structure and a preparation method of the fiber resin-based composite material, and relates to the technical field of fiber resin-based composite materials. The fiber resin-based composite material with the interlayer wave lock structure comprises a plurality of layers of unidirectional fiber resin cloth and a plurality of layers of fabric fiber resin cloth which are laminated and combined through hot pressing, the resin in the unidirectional fiber resin cloth is the same as that in the fabric fiber resin cloth; the unidirectional fiber resin cloth and the fabric fiber resin cloth are formed by unidirectional fiber resin-based prepreg cloth and fabric fiber resin-based prepreg cloth through hot-pressing dipping and hot-pressing curing in sequence. The composite material provided by the invention has good impact resistance and compression resistance, and is not prone to layering damage when subjected to loads such as impact and compression.

The present invention discloses a low-temperature conductive adhesive, which is prepared by weight using raw materials including 70-80 parts of silver powder, 20-30 parts of resin matrix, 1-10 parts of curing agent, 0.1-0.5 parts of silane coupling agent, 0.1-0.5 parts of stabilizer, and 0.1-0.5 parts of metal salt. The present invention introduces an organic metal salt into the resin matrix to reduce the contact resistance of the colloid, and after wet heat aging, maintains a lower contact resistance increase rate. The present invention adopts a combination of epoxy resin, acrylate and modified epoxy acrylic resin, and the weight of epoxy resin and acrylate is less than or equal to the weight of modified epoxy acrylic resin, so that low-temperature curing can be achieved. The present invention can achieve 60-80 ° C, 20-40 min curing, and the conductive adhesive elongation at break obtained can reach more than 8%, and before and after wet heat aging, there is a more stable and relatively small contact resistance, which is particularly suitable for the electronic field with high requirements for contact resistance.