1456 results about "Resin matrix" patented technology

The invention discloses a composition based on hollow glass beads and a preparation method thereof, and relates to the technical field of material science. The preparation method comprises the following steps: firstly, constructing a pre-composite functional microsphere with a specific hierarchical structure as a core basic functional unit, then matching with a plurality of components such as a thermosetting resin matrix, a latent curing system, a functional synergistic aid package and a composite solvent system, and matching with a preparation process which has a synergistic effect with the components. The composition based on the hollow glass beads is expected to realize uniform dispersion of the hollow glass beads in a coating system and strong bonding of a microscopic interface on the premise of ensuring the structural integrity of the hollow glass beads. Therefore, the high-performance composite coating material with ultra-light weight, high heat insulation efficiency, excellent mechanical strength and long-term service stability is obtained.

The invention discloses a high-refractive-index nano-composite optical adhesive and a preparation method thereof, and belongs to the technical field of optical transparent adhesives. The optical adhesive is prepared by taking a polyurethane acrylate oligomer with a specific structure as matrix resin, introducing surface-modified barium titanate and zirconium oxide core-shell nanoparticles as a functional filler, and matching with an active diluent, a photoinitiator and a silane coupling agent in a specific proportion. Through the design of the core-shell structure, the core problems that the high-refractive-index nanoparticles are easy to agglomerate in an organic resin matrix, the dispersion stability is poor and the bonding force with a matrix interface is weak are effectively solved. The prepared optical adhesive has a refractive index of more than 1.65, a light transmittance of more than 99% and a haze of less than 0.3% after being cured, has excellent bonding strength, weather resistance and long-term use stability, and is especially suitable for precise lamination of high-end display devices (such as OLEDs (Organic Light Emitting Diodes) and micro-lens arrays).

The invention provides a preparation method of a self-repairing resin-based composite material based on dynamic bonds. The self-repairing epoxy resin comprises one covalent dynamic bond of a Diels-Alder bond, a disulfide bond or a borate bond, and the preparation method of the self-repairing epoxy resin comprises the following steps: heating epoxy resin to a molten state, adding a curing agent component while stirring, and carrying out a prepolymerization reaction to obtain a prepolymer; the curing agent comprises a rigid diamine curing agent, a dynamic diamine monomer and a flexible chain segment regulator, and the dynamic diamine monomer contains a dynamic covalent bond; and carrying out curing molding on the prepolymer to obtain the self-repairing epoxy resin. And impregnating reinforced fibers or fabrics thereof with the prepared prepolymer, and heating and curing to obtain the self-repairing resin-based composite material. The invention provides a chemical molecule design, dynamic reversible chemical bonds are introduced into a resin matrix, and by constructing the dynamic bonds, the composite material has high performance of a traditional composite material and also has life-like self-healing ability.

The invention discloses a polyetherketoneketone high-temperature-resistant wear-resistant non-stick coating and a preparation method thereof. The coating is prepared from the following components in parts by mass: 13 to 30 parts of a resin matrix group (containing 12 to 25 parts of titanium modified polyether ketone ketone resin, 1 to 5 parts of fluorine-free viscous resin and 0.65 to 6 parts of aluminum oxide), 0.5 to 3 parts of a nano reinforced group (containing 0.5 to 3 parts of KH-550 modified nano titanium dioxide, 0.025 to 0.6 part of cerium dioxide and 0.5 to 3 parts of boron nitride) and 62 to 71 parts of an auxiliary agent group. The preparation method comprises the following steps: 1) taking diphenyl ether, paraphthaloyl chloride and isophthaloyl chloride as monomers, and synthesizing titanium modified polyether ketone ketone resins with different viscosities through segmented polymerization (1.5-2.0 hours or 3.0-4.0 hours); 2) respectively preparing a smooth bottom layer water dispersion slurry and a wrinkled surface layer water dispersion slurry; and (3) forming a compact bottom layer and a micro-wrinkle surface layer on the base material by adopting a layered spraying and stepped sintering process (280-320 DEG C, 10-20 minutes). The whole system of the coating is fluorine-free and has temperature resistance gt; the coating has the characteristics of high temperature resistance (350DEG C), wear resistance (Taber wear rate of 3-5mg / 1000r), non-sticking (contact angle gt, 100 DEG C) and heavy corrosion resistance, and is suitable for cooking utensils and chemical equipment.

The invention relates to the technical field of composite materials, in particular to a high-strength epoxy resin composite material and a preparation method thereof, and the high-strength epoxy resin composite material comprises the following raw materials in parts by weight: 50-80 parts of a base material, 10-20 parts of a curing agent, 5-10 parts of modified carbon nanotubes, 3-10 parts of a reinforcing sheet, 3-6 parts of a reinforcing material and 1-3 parts of a flame retardant. In the preparation method, the modified carbon nanotubes are in chemical bond connection with the base material through surface modification, the interface bonding force is enhanced, stress is effectively transmitted, the unique layered structure and surface modification treatment of the enhanced sheet are enhanced, the enhanced sheet is firmly combined with the resin matrix, and a three-dimensional enhanced network is formed through the synergistic effect of mechanical interlocking and stress dispersion. The vermiculite sheet layer prevents crack propagation, and the modified carbon nanotubes and the reinforcing material effectively transfer stress, so that the tensile strength and bending strength of the composite material are greatly improved, and the high-strength application requirement is met.

The invention discloses a carbon fiber sizing agent composition suitable for thermoplastic resin, sized carbon fiber, a carbon fiber sizing agent as well as a preparation method and application of the carbon fiber sizing agent, belongs to the technical field of carbon fiber sizing agents, and solves the problem that a sizing agent in the prior art cannot meet excellent mechanical properties and high temperature resistance at the same time. The composition is prepared from the following components in parts by weight: 15 to 35 parts of modified polyaryletherketone resin matrix, 0.3 to 2 parts of neutralizer, 1 to 3 parts of emulsifier, 1.5 to 3 parts of defoaming agent and 57 to 80 parts of deionized water. The sizing agent containing the composition has good wettability and film-forming property on the surface of the carbon fiber, and meanwhile, the sizing agent is matched with other components with specific contents in the composition, so that the carbon fiber sizing agent containing the carbon fiber sizing agent composition has excellent heat resistance, can bear processing at the high temperature of 350 DEG C or above, and has good application prospects. And the composite material containing the sizing agent has excellent interlaminar shear strength.

The invention discloses a coating, a preparation method and application, and relates to the technical field of anticorrosive coatings. A dry film of the coating comprises 0.1 wt%-6wt% of a lamellar filler; the lamellar filler is prepared by loading magnetic nanoparticles on the surfaces of two-dimensional nanoparticles and coating a layer of high-molecular polymer. After the coating forms a film, a specific magnetic control orientation curing method is matched, so that high dispersion stability and planar orientation arrangement of the two-dimensional nano filler in a resin matrix are realized, and corrosion of water and oxygen to a base material can be effectively blocked. When the thickness of the coating dry film is only 1-2 microns, the coating dry film still has no obvious corrosion phenomenon after being subjected to a neutral salt spray test for 2000 hours. The metal base material with the thin coating thickness has heat conductivity, corrosion resistance and weather resistance, the preparation process is simple, the cost is low, and the metal base material has extremely high market application value.

The cBN resin superhard grinding wheel is prepared from the following raw materials in percentage by mass: 30 to 45 percent of cBN grinding material, 1 to 3 percent of nano yttrium oxide, 2 to 3 percent of nano zirconium oxide, 2 to 4 percent of coupling agent, 1 to 3 percent of silicon dioxide compound and the balance of phenolic resin. The phenolic resin matrix is jointly modified by the nano yttrium oxide, the nano zirconium oxide and the specific silicon dioxide compound, and the prepared grinding wheel has good wear resistance, hardness and temperature resistance.

The invention belongs to the technical field of polymer composite materials, and discloses a carbon fiber interface modifier aided design method and system based on collaborative optimization, and the method is used for designing a carbon fiber interface modifier based on collaborative optimization of machine learning and molecular dynamics simulation. By constructing a closed loop iteration process of generation-prediction-verification-learning, interfacial modifier molecules meeting multi-target performance requirements are quickly and accurately obtained under the condition that a large amount of early-stage chemical synthesis and experimental screening are not needed. According to the method, through deep combination of high-throughput prediction of machine learning and virtual experiment verification of molecular dynamics, efficient and automatic design of the interface modifier molecules is achieved, experimental synthesis and trial and error links are greatly reduced, the research and development efficiency is improved, and the method is widely suitable for design and optimization of the interface modifier molecules of the carbon fiber / resin-based composite material.

The structural formula of the coating weather-resistant agent is shown in the specification, and a substituent group R1 is methyl, propyl, carbamoyl or phenyl. The invention also discloses a nano composite anticorrosive coating which is prepared from the following components in parts by mass: 30-45 parts of epoxy resin matrix, 3-8 parts of nano zinc oxide, 3-8 parts of nano titanium dioxide, 5-15 parts of mica powder, 3-8 parts of coalescing agent, 0.5-2 parts of silane coupling agent, 0.8-3 parts of dispersing agent, 0.5-2 parts of flatting agent, 0.5-2 parts of defoaming agent, 0.5-2 parts of weather-proof agent and 15-30 parts of solvent, and the weather-proof agent is a coating weather-proof agent. The invention also discloses a preparation method of the paint weather-resistant agent and the nano-composite anticorrosive paint. The invention effectively solves the problem that the coating is easy to age, crack and peel off.

The invention relates to a low-dielectric-loss high-thermal-conductivity epoxy resin composite material and a preparation method thereof, and the preparation method comprises the following steps: carrying out surface modification treatment on a thermal conductive filler: carrying out surface modification on the thermal conductive filler by adopting a chemical covalent bonding or physical adsorption mode, the heat-conducting filler is used for improving the compatibility of the filler and an epoxy resin matrix and reducing the interface thermal resistance, and comprises boron nitride with a two-dimensional sheet structure; epoxy resin, a curing agent and an optional modifier are evenly mixed, the epoxy resin is selected from epoxy resin with the low polarity characteristic, and the modifier comprises at least one of thermoplastic resin or elastomer. And the process is simple and controllable.

The invention relates to the technical field of basalt fiber reinforced composite material pipelines and preparation methods thereof, and discloses a pipeline named as a basalt fiber reinforced composite material pipeline and a preparation method thereof and a preparation method thereof. The invention aims to overcome the defects of continuity, interface bonding and mechanical properties of the conventional basalt fiber reinforced composite material pipeline. The pipeline is composed of a lining layer, a basalt fiber winding reinforcing layer and an outer protective layer, the reinforcing layer is formed by compounding basalt fiber bundles subjected to surface treatment and a resin matrix, and the reinforcing layer is of a multi-layer structure with different winding angles. The preparation method comprises the following steps: roughening the inner lining layer, infiltrating and accurately winding the fiber bundles, performing multi-section curing and forming the outer protective layer. According to the scheme, the macroscopic mechanical property of the pipeline is remarkably improved, the interface combination of fibers and a matrix is optimized, the integrity of the fibers is kept, efficient preparation is achieved, and the pipeline has the advantages of being excellent in corrosion resistance and ultraviolet resistance, long in service life and the like.

The invention discloses a preparation method of a high-temperature-resistant wave-absorbing honeycomb sandwich structure in the technical field of wave-absorbing materials, which comprises the following steps: synthesizing a transition metal modified polycarbosilane precursor under the protection of inert gas, and performing high-temperature cracking to obtain a magnetic silicon carbide wave-absorbing agent; blending and grinding the wave-absorbing agent and high-temperature-resistant resin to prepare a wave-absorbing glue solution; after a honeycomb core material is formed by adopting inorganic fiber cloth, a wave-absorbing glue solution is loaded through a repeated dipping-drying process, and the high-temperature-resistant wave-absorbing honeycomb is obtained through gradient heat treatment. And finally, compounding and curing with the wave-transparent skin and the carbon fiber composite material through a high-temperature-resistant adhesive film. The sandwich structure is prepared on the basis of the composite material, and the magnetic silicon carbide wave-absorbing agent has the characteristics of high temperature resistance, low density, oxidation resistance and adjustable dielectric property; the phthalocyanine resin matrix is adopted, so that excellent formability and high-temperature stability are guaranteed; honeycomb nodes are sewn and reinforced by silicon carbide fibers, so that the problem of node cracking in a high-temperature environment is solved.

The invention belongs to the technical field of fiber reinforced composite material recovery, and particularly relates to a full-process recovery method of a fiber reinforced composite material. The modified fiber is prepared by constructing a dynamic coordination crosslinking interface layer formed by Co < 2 + > and phenolic hydroxyl groups and amino groups in polydopamine on the surface of the fiber. And then, preparing the fiber reinforced composite material by taking the modified fiber and resin as raw materials. A fiber reinforced composite material is placed in a coordination competitor, cobalt-oxygen and cobalt-nitrogen coordination bonds of an interface layer are competitively dissociated and interface bonding is destroyed under the heating condition by utilizing the stronger coordination capacity of the coordination competitor to Co < 2 + >, and then ultrasonic treatment is assisted, so that efficient and nondestructive separation of fibers and a resin matrix is realized. The process method is simple, convenient to operate, green and environmentally friendly, and has important practical significance and industrial application prospects.

The invention discloses a sealing gasket for an energy storage hydrogen production electrolytic cell and a preparation method of the sealing gasket, and belongs to the technical field of sealing gasket production. Comprising the following steps: carrying out surface treatment on glass fibers, and carrying out hot-pressing mixing with a polyimide block copolymer to obtain a supporting layer; glass fibers are subjected to surface treatment and then hot-pressed and mixed with the polyimide block copolymer to obtain a supporting layer; the polytetrafluoroethylene, the triallyl isocyanurate and the nano silicon dioxide are mixed and stirred, and the sealing layer is obtained through injection molding after radiation crosslinking; the epoxy resin matrix, the modified fluororubber and the anti-aging agent are subjected to banburying and vulcanization to obtain the protective layer; and the supporting layer, the sealing layer and the protective layer are sequentially stacked, hot-pressed and compounded to obtain the sealing gasket. The sealing gasket for the energy storage and hydrogen production electrolytic cell is improved in structural stability and has good creep resistance and chemical resistance.

The invention provides a high-strength fiber composite material based on aramid 1414 fibers and a preparation method of the high-strength fiber composite material, and belongs to the technical field of composite materials. The composite material comprises 60%-80% of aramid 1414 fibers and 20%-40% of a resin matrix, the aramid 1414 fibers are subjected to surface treatment and size stabilization treatment through a specific process, and the compatibility of the fibers and the resin matrix and the overall performance of the composite material are fully improved. According to the invention, the characteristics of high strength and high modulus of the aramid 1414 fiber are utilized, so that excellent mechanical properties are provided; due to the low-density characteristic of the aramid 1414 fibers, the composite material is light while high strength is kept, and the performance requirements of light weight and high strength are met. The composite material disclosed by the invention not only has excellent mechanical properties, but also realizes the balance of cost effectiveness and production efficiency by optimizing a preparation process, and has a wide market application prospect.

The invention belongs to the field of novel polyamide composite fiber materials, and particularly discloses a high-toughness polyamide fiber composite material and a preparation method thereof. The composite material is prepared from the following raw materials in parts by weight: 55-75 parts of long-chain polyamide PA610 resin, 10-25 parts of ultra-high molecular weight polyethylene fiber, 8-18 parts of polyether block amide elastomer, 1.5-4 parts of a compound nucleating agent, 0.8-2 parts of a titanate coupling agent and 0.3-1 part of a composite antioxidant. The preparation method is characterized by comprising the following steps: firstly, carrying out surface pretreatment on the ultra-high molecular weight polyethylene fiber by adopting a low-temperature plasma technology so as to improve the interfacial compatibility of the ultra-high molecular weight polyethylene fiber and a resin matrix; and then carrying out melt blending granulation on the pretreated fiber and other raw materials through a twin-screw extruder, wherein the fiber is added from a side feeding port to avoid excessive shearing and breaking. The obtained product has ultrahigh impact toughness, excellent rigidity, excellent low-temperature toughness and heat resistance, and is especially suitable for the fields of manufacturing automobile parts, sports protection equipment and the like with extremely high requirements on toughness and durability.

The invention provides a high-toughness plastic packaging film material and a preparation method thereof, and belongs to the field of metallocene polyolefin plastics. The high-toughness plastic packaging film material is prepared from the following chemical raw materials: 80 to 90 parts of metallocene polyethylene resin, 5 to 8 parts of supramolecular cross-linking agent, 6 to 10 parts of core-shell type modifier, 3 to 5 parts of ethylene-vinyl acetate copolymer, 2 to 4 parts of stearic acid modified nano calcium carbonate, 2 to 3 parts of polyolefin elastomer, 0.2 to 0.5 part of di (3, 4-dimethyldibenzylidene) sorbitol, 2 to 5 parts of thermotropic liquid crystal polymer and 0.4 to 0.7 part of antioxidant. 0.8 to 1.2 parts of a lubricant and 0.5 to 1.0 part of an antistatic agent. Through the compatibility design of a toughening mechanism, the synergistic balance of an enhancing mechanism and the optimization of transparency guarantee, the functions of all the components in a metallocene polyethylene resin matrix are complemented, and the ultrahigh toughness, high strength and high transparency of the film material are achieved.

The invention discloses a fiber-reinforced thermoplastic resin-based composite material based on dynamic reversible interface interaction and a preparation method and a recycling method thereof. The fiber-reinforced thermoplastic resin-based composite material comprises a modified thermoplastic resin matrix and a modified fiber reinforcement which are compounded with each other, the modified thermoplastic resin matrix and the modified fiber reinforcement are bonded and connected through dynamic bonds with dynamic reversible interface interaction. Through construction of dynamic reversible interface interaction in the fiber-reinforced thermoplastic resin-based composite material, infiltration compounding and interface bonding between a fiber reinforcement and a high-viscosity thermoplastic resin melt can be enhanced, and interface debonding and total-value recycling of the fiber reinforcement in the composite material recycling process can be effectively promoted; therefore, the bottleneck problems of poor wettability in the forming process, low bonding fastness at a heterogeneous interface, insufficient mechanical properties, low waste recovery value and the like confronted by the development of the fiber-reinforced thermoplastic composite material are effectively solved.

The invention belongs to the technical field of carbon fiber composite materials, and particularly relates to a carbon fiber reinforced composite material for an aerospace low-temperature storage tank and a preparation method of the carbon fiber reinforced composite material. The preparation method of the carbon fiber reinforced composite material for the aerospace low-temperature storage tank comprises the following steps: (1) preparing a polyamide acid prepolymer solution; (2) adding the polyamide acid prepolymer solution, a phosphorus-containing flame-retardant monomer and nano nitrile rubber into a solvent for reaction to prepare a sizing agent; (3) carbon fibers are soaked in the sizing agent, taken out and dried, and sized carbon fibers are obtained; and (4) mixing nano nitrile rubber with a resin matrix, and then carrying out prepolymerization and thermal imidization curing molding on the mixture and the sized carbon fibers to obtain the carbon fiber composite material. The carbon fiber reinforced composite material obtained by the invention not only has excellent liquid oxygen compatibility, but also can maintain excellent leakage resistance and mechanical properties in an extremely high and low temperature cycle environment, and provides technical support for application of aerospace low-temperature storage tanks.

The invention discloses a copper-clad plate material containing elastomer resin and a preparation method of the copper-clad plate material, and belongs to the technical field of new materials. The method comprises the following steps: mixing a styrene-butadiene-styrene block copolymer with polybutadiene rubber, adding nano-montmorillonite, and carrying out intercalation modification through hexadecyl trimethyl ammonium bromide to prepare nano-modified elastomer resin; the preparation method comprises the following steps: mixing polybutylene terephthalate with nano silicon dioxide, and carrying out surface modification by gamma-aminopropyltriethoxysilane and hexamethyldisilazane to obtain a resin matrix; mixing the two phases, adding citric acid, and carrying out microwave heating and high-shear dispersion to obtain a discrete material; carrying out hot pressing on the dispersion, adding polyurethane and polylactic acid, uniformly mixing, adding polydimethylsiloxane and sodium dodecyl benzene sulfonate, and curing to obtain a cured product; and coating the surface of the cured product with a nano-copper layer. The material has the characteristics of high peel strength, low dielectric loss, low water absorption and low thermal expansion, and is suitable for the field of high-speed low-loss copper-clad plates.

The present application relates to the technical field of resin, and relates to a preparation method of high-whiteness resin, respectively preparing mesoporous SiO2@Eu 3+ The two whitening agents are mixed in a weight ratio of 1:1 to 1:4, surface modification is carried out, and then the whitening agents are melt-blended with a resin matrix; an intelligent control system is used to real-time regulate process parameters, so that the whiteness is greater than or equal to 96, and the thermal decomposition temperature is greater than or equal to 380 DEG C; the present application realizes the synergistic effect of the mesoporous SiO2@Eu 3+ The whitening agent and the TiO2 photonic crystal whitening agent synergistically act, and surface modification is carried out by using a silane coupling agent, so that the whitening agent is uniformly and stably dispersed in the resin matrix, the whiteness of the resin product is greater than or equal to 96, the risk of yellowing is reduced, and the visual appearance quality of the resin product is greatly improved.

The invention belongs to the technical field of continuous basalt fiber impregnating compounds, and particularly relates to an impregnating compound of a modified basalt fiber reinforced nylon composite material as well as a preparation method and application of the impregnating compound. The impregnating compound comprises the following effective components in percentage by mass: 70%-90% of a film-forming agent, 4.0%-8.0% of an organosilane coupling agent, 0.1%-1.5% of a lubricating agent, 1.0%-10% of a dispersing agent, 0.1%-1.0% of a wetting agent and 3%-10% of nano particle oxide. Related tests verify that the ablated basalt fiber which is not effectively treated is smooth in surface, and the nylon composite material reinforced by the ablated basalt fiber is in a state that the fiber is loosely bonded with a resin matrix and the surface is clean after the fiber is pulled out at a fracture interface, which shows that the interface bonding force is extremely weak and the stress transmission efficiency is low. Compared with the prior art, the basalt fiber treated by the nano ZnO modified impregnating compound provided by the invention has the advantages that the section form of a reinforced composite material is fundamentally improved: the fiber and resin interface bonding is very tight, and the fiber surface is coated by a large amount of resin, so that the obvious improvement of the interface bonding strength is clearly revealed.

The invention discloses a low-temperature curing photoresist applied to a flexible display panel and a preparation method of the low-temperature curing photoresist, and belongs to the technical field of energy conservation and environmental protection. The photoresist is prepared by compounding a reactive organic-inorganic mixed nano filler, a photosensitive resin matrix, a benzocyclobutenyl silicone oligomer (BSA resin) and an additive. The preparation method comprises the following steps: preparation and surface modification of the nanofiller; synthesizing a photosensitive resin matrix; compounding the oligomer with an additive; dispersing the slurry and adding a nano corrugated template; spin coating, ultraviolet pre-curing, low-temperature baking and heat post-curing are carried out. The curing temperature of the photoresist is lower than 120 DEG C, the resolution ratio is superior to 3 microns, and the bending tolerance frequency is gt; the adhesion strength is gt after 20000 times; 15 Kgf / cm < 2 >, and the water vapor permeability is lt; 10 <-6 >, heat resistance gt; the temperature is 150 DEG C, and the dielectric constant is lt; 3.5, VOC (Volatile Organic Compounds) emission lt; the organic light-emitting material has excellent flexibility, thermal stability and environmental protection performance, is suitable for a pixel definition layer of an OLED flexible display panel, and improves the light extraction efficiency and the anti-fatigue performance.

The invention belongs to the technical field of polymer composite materials, and particularly relates to a high-strength bismaleimide resin material and a preparation method thereof. The bismaleimide resin composition comprises the following components in parts by weight: 50-60 parts of bismaleimide resin, 40-50 parts of an allyl compound, 1-3 parts of modified graphene and 0.1-0.5 part of a dispersing filler, the dispersing filler is prepared from modified inorganic nanoparticles and modified tetrapod-like zinc oxide whiskers in a mass ratio of (0.1-1): 1. Wherein the tetrapod-like zinc oxide whiskers can promote the dispersion of the graphene with a large lamellar structure from the macroscopic aspect, so that the graphene is uniformly dispersed in a bismaleimide resin matrix, and the inorganic nanoparticles can play a role in lubrication and isolation, so that the agglomeration among graphene lamellas in a small range is prevented. By adding the graphene composite reinforcing filler, the rigidity of the bismaleimide resin material is improved, and the toughness of the composite material can be improved at the same time.

The invention belongs to the technical field of coating compositions, and discloses an electrophoretic coating with high weather resistance and high salt mist resistance and a preparation method thereof. According to the coating, a composite pigment and filler system formed by compounding a surface-modified sheet-shaped physical shielding filler and a calcium / zinc double-ion exchange type corrosion inhibition filler is adopted, and the surface-modified sheet-shaped physical shielding filler forms a compact labyrinth structure to prolong a corrosion medium permeation path; the corrosion inhibition filler releases Ca < 2 + > / Zn < 2 + > under the stimulation of chloride ions to generate a composite precipitation membrane in situ to block electrochemical corrosion; the two components are co-ground and pre-dispersed and chemically bonded with a resin matrix through a silane coupling agent, so that the compactness, the adhesive force and the self-repairing capability of the coating are improved. The electrophoretic coating does not contain hexavalent chromium and is suitable for high-end protection scenes such as automobiles and ocean engineering.

The invention discloses organic silicon modified acrylic resin antifouling paint and a preparation method thereof, and particularly relates to the field of chemical paint. The antifouling paint is prepared from the following components in parts by mass: 8 to 12 parts of adamantane acrylate, 5 to 8 parts of trifluoroethyl acrylate, 2 to 3 parts of 2-hydroxyethyl acrylic phosphate, 0.8 to 1.2 parts of tert-butyl peroxypivalate, 4 to 6 parts of tridecafluorooctyltrimethoxysilane, 1 to 2 parts of isophorone diisocyanate, 3 to 6 parts of fluorosilane modified nano TiO2 and 1 to 2 parts of graphene oxide. 20-30 parts of deionized water, 0.5-1 part of a polyether modified polysiloxane defoaming agent, and 0.3-0.5 part of an ultraviolet light absorber UV-327 can be additionally added. The preparation method comprises the following steps: S1, preparing isocyanate modified fluorine-containing organic silicon; s2, preparing a ternary copolymer prepolymer; s3, preparing a modified resin matrix; s4, preparing a fluorosilane modified nano TiO2 / graphene oxide composite filler dispersion liquid; and S5, mixing the resin matrix and the dispersion liquid, and performing stirring and vacuum desolventizing to obtain a finished product. The coating has the characteristics of super-hydrophobicity, high hardness, strong adhesion, long-acting antifouling property, aging resistance and environmental protection.

The invention relates to the technical field of photovoltaic adhesive films, and discloses an anti-radiation photovoltaic packaging adhesive film, a preparation method thereof and a photovoltaic module. The adhesive film is of a multi-layer co-extrusion composite structure formed by co-extrusion molding and irradiation, and comprises an upper surface layer, a middle functional layer and a lower surface layer, the upper surface layer is a radiation-resistant polymer matrix (such as EVA-g-St, EVA-g-(alpha-MeSt), POE-g-St and an EVA / POE-aromatic resin blend); the middle functional layer comprises a packaging resin matrix, an anti-radiation agent (which is a nano-scale radiation protection material such as a rare earth oxide, a heavy metal oxide, a boron-containing compound and a polymer derivative of a benzotriazole type ultraviolet absorbent) and a stabilizer; and the lower surface layer is a bonding surface layer formed by light-transmitting bonding resin. The adhesive film is good in radiation resistance, the light transmittance, the cohesiveness, the elongation at break retention rate, the yellowing resistance, the power attenuation resistance of a component and the like after accelerated radiation are obviously improved, and the service life of the component under strong radiation can be prolonged.

The invention discloses a fiber composite material based on hydrogen bond self-repairing and conductive self-diagnosis and a preparation method of the fiber composite material, and belongs to the technical field of intelligent diagnosis and self-repairing fiber reinforced resin-based composite materials and preparation of the intelligent diagnosis and self-repairing fiber reinforced resin-based composite materials. According to the method, the problem that the self-healing effect cannot be timely obtained on the internal damage of the material due to the fact that the damage area cannot be accurately positioned and identified before the damage of the existing fiber composite material is repaired is solved. According to the invention, a quantum tunnel effect and a three-dimensional conductive skeleton are constructed by using a micro-nano multi-stage conductive filler composed of a nano carbon nanotube, micron flake graphite powder and unidirectional short carbon fiber, a damage occurrence position is realized based on an electro-mechanical corresponding relation, a self-sensing function is given, and accurate positioning of the damage is realized (the error is less than 1mm). A multiple reversible hydrogen bond system formed by acrylamide, polyethyleneimine and epoxy resin is further utilized, the self-repairing effect of the composite fiber material is achieved, and the test result shows that the self-repairing efficiency of at least 90% or above is achieved at the normal temperature.

The invention discloses a bamboo-based composite unmanned aerial vehicle radome and a manufacturing method thereof.The radome comprises a cover-shaped body and an extension part, the peripheral wall of the tail end of the cover-shaped body integrally extends to form a limiting ring, one end of the extension part is arranged and riveted to the peripheral wall of the limiting ring in a sleeving mode, and the other end of the extension part extends outwards in a divergent mode; the cover-shaped main body is formed by a cover-shaped braided fabric formed by a bamboo fiber reinforced resin matrix composite material, and the extension part is formed by any one of an extension braided fabric formed by the bamboo fiber reinforced resin matrix composite material or an extension layering structure formed by the bamboo fiber reinforced resin matrix composite material; a plurality of layers of cover-shaped braided fabric, extension braided fabric and extension layering structures are laid and stacked according to angles, and the radome is obtained through bamboo material treatment, bamboo material preparation, bamboo material weaving and layering, vacuum resin filling and post-treatment. The radome not only has the characteristics of light weight and high strength, but also is relatively low in cost, good in environmental protection performance and good in wave transmission rate.