4663 results about "Graphite oxide" patented technology

The invention discloses a positive electrode material for a zinc-bromine flow battery and a preparation method and application thereof, and belongs to the technical field of zinc-bromine flow batteries, the preparation method comprises the following steps: crushing and sieving an active carbon source, adding the active carbon source into a graphene oxide aqueous dispersion, stirring, centrifuging, removing supernate, drying, mixing with an activating agent, and activating in an inert atmosphere; washing to be neutral, drying and sieving to obtain a graphene / activated carbon composite material; and attaching the graphene / activated carbon composite material to a carbon-plastic bipolar plate to obtain the positive electrode material for the zinc-bromine flow battery. A graphene / activated carbon composite system is combined with a high-conductivity network, graded holes and surface functional groups, so that the reaction kinetics bottleneck of a traditional carbon material Br2 is broken through.

This application relates to an EPP material and a folding mat using this EPP material, which relates to the field of EPP material technology. The EPP material is formed into a plate by welding EPP particles, and the surface of the plate is coated with a hydrophobic antibacterial paint. The raw materials for preparing the EPP particles include 80-100 parts by weight of polypropylene resin, 1-3 parts by weight of a nucleating agent, 6-8 parts by weight of a modified graphene composite material, 5-10 parts by weight of a flame retardant, 5-15 parts by weight of a reinforcing agent, and 0.5-1.5 parts by weight of a surfactant. The raw materials for preparing the modified graphene composite material include hydrophobic modified graphene oxide, hydrophobic antibacterial nano-zinc oxide, and a modified ammonium polyphosphate coupling agent. The folding mat using this EPP material includes an EPP material, a surface layer, and a sewing thread, and the surface layer and the EPP material are fixedly connected by the sewing thread. This application has the effect of improving the flame retardancy, waterproofness, and antibacterial properties of EPP material, and the resulting tatami mat is environmentally friendly, comfortable, and has a good user experience.

The invention provides a polyaniline / modified graphene oxide composite material and a preparation method thereof. The preparation method comprises the following steps: dispersing purified graphene oxide, performing ultrasonic treatment, heating, adding a modifier for modification, centrifuging, taking precipitate, freezing, drying and grinding to obtain modified graphene oxide powder; mixing the powder with an aniline solution in doped acid to form a modified graphene oxide / aniline acid solution; dissolving ammonium persulfate in the doped acid to prepare an ammonium persulfate acid solution; and slowly dropwise adding the solution into the solution, carrying out in-situ polymerization, and carrying out suction filtration, washing and drying to obtain the composite material. According to the method, through chemical modification and in-situ polymerization processes, the problems that a single filler is poor in dispersity, a conductive network is discontinuous, and anti-corrosion and anti-static performance is difficult to synergistically improve are solved, and the process is simple and convenient and suitable for industrialization.

The invention relates to the technical field of ceramic substrates, and provides a high-toughness multilayer ceramic substrate and a preparation method thereof. Raw materials of the high-toughness multilayer ceramic substrate comprise the following components in parts by weight: 90-95 parts of aluminum oxide, 13-17 parts of a sintering aid, 2-5 parts of a plasticizer, 1-3 parts of a dispersant, 3-5 parts of a binder, 10-12 parts of an aid and 55-65 parts of water, the auxiliaries comprise boron carbide, copper-tin alloy powder and graphene oxide. According to the technical scheme, the problem of poor toughness of the multi-layer ceramic substrate in the prior art is solved.

The invention discloses a preparation method of a degradable transparent conductive polymer film, and belongs to the technical field of film preparation. Preparing dispersion liquid I through graphene oxide quantum dots; preparing a dispersion liquid II from polyaniline nanofibers; dissolving pyrrole and toluenesulfonic acid in N, N-dimethylformamide to prepare a reaction solution, adding the dispersion liquid I and the dispersion liquid II, stirring, and adding ferric chloride hexahydrate to obtain a reaction solution; adjusting the pH value of the reaction solution to 1.5, and heating to obtain a polypyrrole solution; preparing cellulose acetate, polyvinyl alcohol and N, N-dimethylformamide to obtain a cellulose acetate solution; mixing the polypyrrole solution and the cellulose acetate solution, adding glutaraldehyde to obtain a mixed solution, and pouring the mixed solution into a mold to prepare a composite wet film; and putting the composite wet film into a hot-pressing forming machine for hot-pressing to generate the polymer film. The conductive polymer film prepared by the invention can be applied to the fields of supercapacitor electrode materials, electromagnetic shielding materials, flexible sensors and the like, and provides a new high-performance material choice for the development of related fields.

The invention discloses a high-performance green and environment-friendly single-component polymer cement waterproof dry blend and a preparation method thereof, and relates to the technical field of building materials, the high-performance green and environment-friendly single-component polymer cement waterproof dry blend comprises the following components: an inorganic cementing material, latex powder, graded quartz sand, a functional filler, cellulose ether, an organic silicon defoamer, a polycarboxylic acid water reducer and compound fibers; the functional filler is modified waste glass powder prepared through mechanical activation and silanization modification; the compound fiber is a mixture of modified glass fiber and modified polypropylene fiber; the preparation of the modified glass fiber comprises tannic acid and polyethyleneimine combined modification and graphene oxide modification, and the preparation of the modified polypropylene fiber comprises plasma activation. The polymer cement waterproof dry blend prepared by the method adopts the glass powder to replace natural mineral filler, is energy-saving and environment-friendly, and the cement matrix is modified by various fibers, so that the prepared polymer cement dry blend is excellent in comprehensive performance.

The invention relates to the technical field of supercapacitors, and provides a cement-based supercapacitor, a preparation method and application. The cement-based supercapacitor comprises a cement-based electrolyte and two structural electrodes arranged on the two sides of the cement-based electrolyte. The cement-based electrolyte is prepared from cement, alkali, alkali metal salt, water and an additive, wherein the alkali metal salt comprises lithium salt; each structural electrode is composed of foamed nickel loaded with nitrogen-doped reduced graphene oxide. The lithium salt is added to construct an efficient ionic conductive network, so that the ionic conductivity of the cement-based electrolyte is enhanced, and the electrochemical performance is obviously improved. The reduced graphene oxide in the structural electrode is doped with nitrogen to enhance the electrostatic force between ions and the surface of the electrode, so that the electrochemical stability of the surface of the electrode is improved, and self-discharge is effectively inhibited. By improving an electrolyte and a structural electrode material, a cement-based supercapacitor with specific capacitance and mechanical properties is obtained and is combined with a building structure to realize building energy storage.

The invention discloses a photovoltaic POSS (polyhedral oligomeric silsesquioxane)-containing antireflection film coating liquid and a preparation method thereof, the coating liquid comprises the following raw materials in parts by weight: 80-100 parts of modified emulsion, 10-15 parts of modified graphene, 3-5 parts of sodium dodecyl benzene sulfonate, 1-3 parts of triethylene tetramine and 40-60 parts of deionized water, a modified additive in the coating liquid contains a polyhedral oligomeric silsesquioxane structure, the polyhedral oligomeric silsesquioxane structure can form uniformly-distributed nanopores and is matched with a two-dimensional honeycomb lattice structure in the graphene oxide, the surface roughness can be increased, the microstructure can scatter incident light and reduce specular reflection, so that the surface light transmittance is improved, and meanwhile, the modified additive molecule contains a fluoroalkyl structure, so that the surface light transmittance is improved. The fluoroalkane has a high refractive index, so that light reflection can be reduced, and the light transmittance is further improved.

The invention relates to the technical field of sole processing, in particular to a sole composite processing method, which comprises the following steps: according to the rigidity requirement of an arch support area, preparing high-density slurry in which silicon nitride ceramic powder accounts for 30-40%, forming # imgabs0 # crystal phase through microwave-assisted sintering, and controlling the porosity to be 10-20%; according to the energy rebound requirement of the forefoot buffer area, graphene oxide / carboxymethyl cellulose aerogel powder is added into the slurry until the concentration is 25%, and the porosity is increased to 40-60% by combining the honeycomb porous network design; a nano silicon dioxide reinforcing agent is introduced into a wear-resistant area of the heel to 15%, a diamond-like carbon coating is formed through plasma surface treatment, and the porosity is limited to be 5-15%. According to the invention, silane is encapsulated by adopting polyurea microcapsules, and is released only when the material is damaged, so that dynamic self-repairing is realized, the shoe sole is endowed with dynamic repairing capability, and the service life is prolonged.

The invention discloses a graphene nanometer heavy anti-corrosion coating and a preparation method thereof, and belongs to the technical field of anti-corrosion coatings. The coating is prepared from the following components in parts by mass: 50 to 70 parts of diallyl bisphenol A type epoxy resin, 8 to 15 parts of histidine modifier, 12 to 20 parts of graphene nano composite modified filler, 5 to 10 parts of curing agent, 0.5 to 2 parts of flatting agent and 0.3 to 1 part of defoaming agent. The preparation method of the histidine modifier comprises the following steps: carrying out a Schiff base reaction on 1-palmitoyl-2-oleoyl ethanolamine and N-formyl-L-histidine to generate an intermediate A; reacting with a spiro quaternization reagent to form a quaternary ammonium salt intermediate B; and then compounding with aminopropyltriethoxysilane and silicotungstic heteropoly acid salt to obtain the product. The graphene nano-composite modified filler is prepared by modifying the surface of a graphene oxide / bentonite mutual intercalation layer structure through allyl trimethoxy silane. The graphene nano heavy anti-corrosion coating prepared by the invention forms a high-density cross-linked network, and has excellent barrier property, strong adhesive force, impact resistance and long-acting anti-corrosion performance.

The invention discloses a light telegraph pole cement material and a preparation method thereof, and relates to the technical field of cement concrete. The method comprises the following steps: firstly, carrying out acid pickling, silane coupling agent grafting and nanoparticle vacuum impregnation treatment on shale ceramsite to obtain modified light ceramsite; the preparation method comprises the following steps: ultrasonically dispersing graphene oxide, compounding with Portland cement clinker and modified fly ash, and reacting with epoxy resin emulsion, a curing agent and a silane coupling agent to prepare organic-inorganic composite modified cement; the bamboo skeleton is subjected to silane coupling agent pretreatment to obtain a modified skeleton; then, mixing composite cement, an additive and water into slurry, adding the modified ceramsite and aggregate, and performing high-speed stirring and ultrasonic dispersion to form homogeneous concrete slurry; and finally, putting the modified bamboo skeleton into a mold, injecting the slurry, and performing centrifugal forming, steam curing and natural curing to obtain the cement material. The prepared lightweight telegraph pole cement material has excellent mechanical strength.

The invention discloses an anti-aging flame-retardant polyvinyl chloride material and a preparation method thereof. The anti-aging flame-retardant polyvinyl chloride material comprises the following raw material components in parts by weight: 100 parts of PVC resin, 0.6-2.4 parts of a lubricant, 15-27 parts of a plasticizer and 14-25 parts of a composite flame-retardant anti-aging reinforcing filler, wherein the composite flame-retardant anti-aging reinforcing filler is obtained by sequentially carrying out antioxidant loading and polymer grafting modification on a compound of graphene oxide, basic magnesium sulfate whiskers and mesoporous alumina. The prepared polyvinyl chloride has excellent aging resistance, flame retardance and mechanical strength, is good in thermal stability and excellent in comprehensive performance, and has a wide market application prospect.

The invention relates to the technical field of insulating materials, in particular to insulating powder and a preparation method thereof. The invention discloses a flame-retardant coating which comprises the following components in parts by weight: 15-25 parts of epoxy resin, 10-20 parts of aluminum hydroxide, 5-12 parts of nano boron nitride, 1-3 parts of a silane coupling agent KH-560, 3-8 parts of polytetrafluoroethylene micro powder, 2-6 parts of fluorine-modified montmorillonite, 4-9 parts of melamine cyanurate, 2-5 parts of nano titanium dioxide, 1-4 parts of a fluorine-modified graphene oxide-polyaniline composite material and 0.5-2 parts of pentaerythritol stearate. The anti-corrosion coating is prepared from the following components in parts by weight: 1 to 3 parts of nano zinc oxide, 5 to 10 parts of glass fiber, 2 to 5 parts of polyhedral oligomeric silsesquioxane-polyimide copolymer, 1 to 4 parts of ferrocenyl epoxy resin and 0.5 to 2 parts of perfluorooctyltriethoxysilane. The insulation powder is high in corrosion resistance, excellent in insulation, heat dissipation and mechanical performance, environmentally friendly in processing, good in adaptability, capable of prolonging the service life of equipment and reducing the cost, suitable for special environments and wide in popularization prospect.

The invention provides wear-resistant and corrosion-resistant lubricating oil and a preparation method thereof. The wear-resistant and corrosion-resistant lubricating oil is prepared from the following raw materials in parts by weight: 88-92 parts of base oil, 3-6 parts of phosphate and ammonium phosphate co-grafted graphene oxide, 0.5-1 part of a purification dispersant, 0.5-1 part of an antirust agent, 2-4 parts of an antioxidant, 0.5-1 part of a defoaming agent and 0.5-1 part of a pour point depressant. The phosphate and the ammonium phosphate are jointly grafted with the graphene oxide, and the wear resistance and the corrosion resistance of the lubricating oil are synergistically improved by utilizing the'nano bearing 'effect of a phosphate group, an ammonium phosphate group and the graphene oxide; meanwhile, by utilizing the capacity of ammonium phosphate groups for neutralizing acidic substances and the chelation of phosphate groups and combining the high specific surface area and barrier property of the graphene oxide, the anti-corrosion and anti-oxidation effects are further enhanced. Through a multifunctional synergistic effect, the problem that a traditional additive is single in function is solved, and the service life of the lubricating oil in high-temperature, high-load and extreme environments is remarkably prolonged.

The invention discloses a novel photocatalyst for producing hydrogen from organic matter wastewater and a preparation method of the novel photocatalyst, and relates to the technical field of photocatalysis. The photocatalyst disclosed by the invention is combined with oxidation-reduction capability, and can effectively degrade and produce hydrogen under the irradiation of sunlight. Through combination of quaternized porous tungsten oxide and vanadate radicals, silver vanadate load growth is promoted, the sunlight utilization rate is increased, and the electron-hole recombination rate is reduced. Reduced graphene oxide is used for pretreatment, active groups are introduced, the reduced graphene oxide is compounded with tungsten oxide / silver vanadate, the binding force is enhanced through heat treatment, photo-induced electron-hole pair compounding is inhibited through the conductivity, and the visible light catalytic performance is improved. The adsorption effect of porous tungsten trioxide and reduced graphene oxide can accelerate the degradation of organic matters. By optimizing the proportion of silver vanadate, tungsten oxide and reduced graphene oxide, the visible light response and charge separation efficiency are enhanced, the degradation and hydrogen production performance is improved, and light corrosion is reduced.

The invention discloses a carbon fiber reinforced modified resin material and a preparation method thereof, and belongs to the technical field of high-molecular compound composition.The preparation method comprises the steps that 40-60 parts of acidified carbon fibers, 8-12 parts of silane coupling agent modified graphene oxide, 10-20 parts of polyethylene glycol and 3-8 parts of alkylphenol polyoxyethylene ether are ultrasonically mixed to be uniform with acetone as a solvent, and a mixture I is obtained; mixing 100 parts of epoxy resin and 30-50 parts of a curing agent, heating and stirring until the mixture is melted to obtain a mixture II; the mixture I and the mixture II are placed in a vacuum drying oven to be mixed and stirred, the obtained product is placed at the room temperature and then subjected to heating curing treatment, and the carbon fiber reinforced modified resin material is obtained, so that the interface bonding strength of the composite material is remarkably improved by optimizing the formula, and the composite material has excellent mechanical properties; the composite material has a wide application prospect in the fields of aerospace, automobile manufacturing, electronics and other high-performance composite material requirements.

The invention relates to a high-thermal-conductivity epoxy resin conductive adhesive containing a composite conductive filler and a preparation method of the high-thermal-conductivity epoxy resin conductive adhesive. The high-thermal-conductivity epoxy resin conductive adhesive containing the composite conductive filler comprises 6-16% of graphene oxide modified epoxy resin, 0.6-3% of a curing agent, 0-1% of a curing accelerator, 2-7% of epoxidized soybean oil modified single-layer / multi-layer carbon nanotubes, 3-7% of carbon fibers, 3-7% of nano silver powder, 40-70% of micron silver powder, 5.0-15.0% of a surface treating agent, 0.3-2.7% of a coupling agent, 0.5-1.5% of a dispersing agent, 0.1-0.3% of an antioxidant and 0.1-0.3% of a lubricant. 0.5% and the balance of a solvent. The graphene oxide modified epoxy resin and the epoxidized soybean oil modified single-layer / multi-layer carbon nanotubes are utilized to improve the dispersion stability of the filler, the modified single-layer / multi-layer carbon nanotubes are adopted as a short-range conductive additive, the carbon fibers are adopted as a long-range conductive additive, and the graphene oxide modified epoxy resin and the epoxidized soybean oil modified single-layer / multi-layer carbon nanotubes and the carbon fibers cooperate to improve the conductivity. The conductive adhesive disclosed by the invention is high in heat conductivity, low in volume resistivity and high in tensile strength and bending strength, and has a wide application prospect in the fields of automotive electronics, wind power photovoltaics, LEDs (Light Emitting Diode), LCDs (Liquid Crystal Display) and the like.

The invention relates to a functional liquid metal-based temperature-responsive hydrogel material and a preparation method thereof, and belongs to the technical field of functional polymer hydrogel materials.The preparation method comprises the following steps that a temperature-responsive hydrogel composite material comprises a hydrophobic association polymer gel and a hydrogel monomer, the hydrophobic association polymer gel comprises a hydrophobic association polymer monomer, a functional filler and an initiator. The functional filler is liquid metal gallium with the edge modified by graphene oxide, and has triple functions: firstly, the functional filler is used as an electrostatic crosslinking node to form a crosslinking network with anionic ionic liquid; secondly, dynamic repair is promoted, and Ga < 3 + > is released to promote dynamic bond recombination. In addition, as a functional filler, the hydrogel is endowed with excellent photo-thermal and electro-thermal conversion performance, and the multi-stimulus response capability is enhanced. The composite material realizes structural assembly by means of hydrophobic association, shows reversible phase change and repeated self-assembly characteristics under various stimuli such as photo-thermal, electric heating, direct heating and the like, and has wide application potential.

The invention relates to the technical field of sensors, in particular to a high-sensitivity pressure-temperature dual-mode sensor and a preparation method thereof.The preparation method comprises the steps that a carbon nano tube is subjected to acid treatment and then reacts with a silane coupling agent KH550, and an aminated carbon nano tube is prepared; the method comprises the following steps: carrying out hydrothermal reaction on a phosphorus source and a graphene oxide aqueous solution to prepare phosphorus-doped reduced graphene oxide; the preparation method comprises the following steps: synthesizing Au-Ag heterojunction nano dispersion liquid through an Au nano seed method; mixing the three components and carrying out ultrasonic treatment to obtain mixed dispersion liquid; the preparation method comprises the following steps: modifying a PDMS substrate with KH560 and polyethylene glycol diamine to prepare a modified PDMS substrate; and coating the mixed dispersion liquid on a modified substrate to form a sensitive layer, and preparing an electrode to obtain the sensor. The aminated carbon nanotubes and the phosphorus-doped reduced graphene oxide construct a three-dimensional conductive network, so that high-sensitivity pressure detection is realized; the phosphorus-doped reduced graphene oxide and the Au-Ag heterojunction form a Schottky barrier, so that stable temperature sensing is realized; and the modified PDMS and the sensitive layer are strongly combined to improve the mechanical durability.

The invention relates to the technical field of fibers, and discloses an antistatic warm-keeping fiber and a preparation method thereof. The preparation method comprises the following steps: carrying out graft modification on a far infrared material graphene oxide through functionalized POSS, introducing the modified graphene oxide and an ionic liquid into polypropylene, carrying out melt grafting to prepare an antistatic polypropylene master batch, introducing the master batch into polypropylene slices for spinning, and carrying out a synergistic antistatic effect of an inorganic antistatic agent graphene and an organic antistatic agent ionic liquid to prepare a composite material. The prepared fiber has antistatic performance and far infrared heating performance, and meanwhile, the POSS structure with excellent thermal stability is introduced, so that the heat resistance of the fiber is further improved.

The invention discloses design and application of a colorimetric-catalytic signal enhancement combined graphene oxide nano-enzyme rapid pesticide residue detection platform, and belongs to the technical field of immunochromatography detection. Graphene (GO) is used as a substrate, 30 nm Pt nanoparticles are adsorbed on the surface of the substrate to provide a colorimetric signal, and gaps of Pt NPs are filled with 5 nm AuIr nanoparticles to enhance the catalytic performance of the substrate, so that the colorimetric / catalytic dual-signal enhanced nano-enzyme is prepared. The GO (at) Pt30-AuIr nano-enzyme is synergistically assembled with Pt NPs and AuIr NPs by utilizing the large specific surface area, excellent stability and dispersibility of GO, so that the catalytic performance of the system is remarkably improved. The method has the beneficial effects that a GO-Pt30-AuIr-LFA-based detection system can realize high-sensitivity dual detection on heavy metal cadmium ions (Cd < 2 + >) and pesticide residue imidacloprid (IMI) within 20 minutes, and the detection limit reaches the level of pg / mL. The detection method provided by the research shows significant application potential in the aspect of rapid screening of small molecules in a complex matrix, and a new technical approach is provided for food safety monitoring.

The invention relates to the field of cables, and discloses a modified polyvinyl chloride composite material for cables and a preparation method thereof.The composite material comprises low-density polyethylene, polyvinyl chloride, ethylene-vinyl acetate copolymer, nitrile rubber, modified graphene oxide, modified nano calcium carbonate and auxiliaries; the modified graphene oxide is prepared by reacting acylating chlorination of graphene oxide with an anti-aging derivative, the anti-aging derivative is prepared by reducing a benzoxazole-containing intermediate generated by a reaction of 2-amino-4-bromophenol and 4-cyanobenzaldehyde to obtain an aminated benzoxazole-containing intermediate, then the aminated benzoxazole-containing intermediate reacts with p-phenylenediamine, and then the product reacts with 3-(3, 4-dichlorophenyl)-1, 2, 3-triazole-3-one to obtain the anti-aging graphene oxide. 2, 5-di-tert-butyl-4-hydroxyphenyl) propionyl chloride is subjected to a reaction to prepare the product. And the modified nano calcium carbonate is prepared by reacting phosphonitrilic chloride trimer with an amino silane coupling agent and 2-amino benzoxazole-5-borate and then grafting on the surface of the nano calcium carbonate. The composite material prepared by the invention has excellent flame retardance, heat resistance and long-acting oxidation resistance.

The invention relates to a high-barrier antibacterial polylactic acid packaging material and a preparation method thereof, and belongs to the technical field of biodegradable packaging materials. The technical problems that a traditional polylactic acid material is insufficient in barrier property, poor in antibacterial performance and difficult to meet the packaging requirements of livestock and poultry meat, food and medicine are solved. A graphene oxide lamellar material is subjected to copper ion functionalization treatment and is bridged with tannic acid molecules through copper ions to form a nano filler, and then the filler is blended with a plasticized polylactic acid solution to prepare the membrane. The preparation method comprises the following steps: preparing a copper ion functionalized dispersion liquid from graphene oxide and copper nitrate, self-assembling the copper ion functionalized dispersion liquid and tannic acid under the condition that the pH is 8-10 to generate a nanofiller, uniformly dispersing the nanofiller, mixing the nanofiller with polylactic acid, polyethylene glycol and glycerol according to a specific mass ratio, coating to form a film, and controlling solvent volatilization conditions to obtain the high-performance packaging material. According to the method, the oxygen barrier property and the antibacterial activity of the material are remarkably improved through uniform dispersion of the nanofiller and reinforcement of a coordination network. The obtained material is suitable for packaging foods such as livestock and poultry meat.

The invention provides a compressible high-thermal-conductivity graphene thermal interface material and a preparation method thereof. The preparation method comprises the following steps: preparing a graphene oxide film with low structural unit thickness by adopting a centrifugal spin-coating film casting method, performing limited thermal expansion delamination, compounding with polysiloxane, and performing directional lamination to obtain a highly-oriented graphene / organic silicon composite material. And applying shear stress after pressurizing and densifying along the normal direction of the graphene sheet layer, so that the graphene structure unit forms a continuous buckling structure which is high in density and easy to compress. The densification process promotes the interaction among delamination structure units, broadens a phonon transmission channel, inhibits phonon-boundary scattering, enhances the comprehensive heat-conducting property, plays a role in promoting stress transmission among graphene, and ensures the formation of a continuous buckling structure under shear stress. A continuous buckling structure and a relatively low structure unit thickness (llt in the graphene structure unit; and the compression modulus of the densified vertical graphene array is jointly reduced by means of high density, high thermal conductivity and high compressibility of an existing thermal interface material, and the method can be applied to the fields of new energy automobiles, high-power chips, aerospace electronic equipment and the like, and the problem that high density, high thermal conductivity and high compressibility of the existing thermal interface material are difficult to consider at the same time is solved.

The invention discloses a light-moisture dual-curing underwater epoxy coating with a self-repairing function as well as a preparation method and a construction method of the light-moisture dual-curing underwater epoxy coating. The epoxy coating comprises a component A and a component B, wherein the mass ratio of the component A to the component B is (1.5-3.5): 1; the component A is prepared from the following raw materials: bisphenol F type epoxy resin, dynamic disulfide bond modified polysulfide rubber, boron nitride nanosheet and silicon carbide nanowire hybrid filler, a photoinitiator and a silane coupling agent; the component B is prepared from the following raw materials: moisture-cured polyether amine, a boric acid ester bond cross-linking agent and hydrophobic modified graphene oxide. According to the invention, a light-moisture dual-curing mechanism is adopted, ultraviolet irradiation initiates rapid surface curing, and then environmental moisture permeates to complete deep curing. The material provided by the invention has the advantages of rapid curing, excellent self-repairing function, significantly improved underwater adhesion and good thermal conductivity, and provides a new solution for rapid repairing and long-acting protection of underwater structures.

The invention discloses a mixed ion conductor layer for a lithium metal negative electrode, a preparation method of the mixed ion conductor layer and an all-solid-state battery, and belongs to the technical field of sulfide all-solid-state batteries. The preparation method comprises the following steps: synthesizing a sulfide electrolyte 70 (0.75 Li2S-0.25 P2S5)-30LiI through a liquid phase, introducing graphene oxide and a lithium salt precursor 2, 5-dihydroxy-1, 4-benzene diphosphate in the electrolyte preparation process, and carrying out heat treatment and pressing to obtain a mixed ion conductor layer; the graphene oxide can isolate the sulfide electrolyte layer from the lithium metal negative electrode, interface reaction is avoided, and a special porous and interlayer structure provides a transverse growth space for lithium metal deposition. And meanwhile, the lithium diphosphate-based MOF among the graphene layers ensures the rapid movement of lithium ions, enhances the bulk diffusion of lithium at the negative electrode end, reduces the local current density, plays a role in dredging the distribution of the lithium ions, and remarkably prolongs the cycle life of the sulfide all-solid-state battery.

The invention discloses a corrosion-resistant polysilsesquioxane modified polyurethane emulsion and a preparation method thereof, and belongs to the technical field of emulsions.The preparation method comprises the steps that gamma-aminopropyltriethoxysilane, namely APTES, is subjected to hydrolytic condensation under the catalysis of tetraethylammonium hydroxide, and POSS is prepared; the preparation method comprises the following steps: carrying out hydrolytic condensation reaction on APTES, synchronously adding phenyltrimethoxysilane in the hydrolytic condensation reaction, forming phenyl-amino difunctional POSS (Polyhedral Oligomeric Silsesquioxane) according to a molar ratio of phenyltrimethoxysilane to APTES of 1: 4, and grafting POSS and graphene oxide GO in dimethyl sulfoxide through amidation reaction to prepare a POSS / GO composite material; dispersing POSS / GO / Zn in the polyurethane prepolymer, adding a curing agent and a solvent, and stirring to form a homogeneous emulsion; through phenyl trapezoid polysilsesquioxane modification and dynamic reversible self-repairing network design, the wear resistance of the coating is improved, microcracks can be closed at the temperature of 60 DEG C, and the maintenance requirement is reduced; laser micro-nano structured base material treatment is combined, the adhesive force is increased to be larger than or equal to 20 MPa, and meanwhile a gamma-butyrolactone low-VOC solvent is adopted.

The invention provides a preparation method and application of polypyrrole graphene oxide hydrogel with an anisotropic structure. The preparation method comprises the following steps: adding sodium hydroxide and urea into water according to a certain proportion, adding microcrystalline cellulose into an alkali urea solution, uniformly stirring, and repeatedly freezing and thawing to obtain a cellulose solution; adding graphene oxide into water for cell disruption and dispersion to obtain a uniform graphene oxide solution; adding the graphene oxide solution into the cellulose solution, then adding an epichlorohydrin cross-linking agent, and carrying out stirring treatment, centrifugation and low-temperature standing to form gel; and pre-stretching the hydrogel to a certain length, immersing the hydrogel into a dilute sulphuric acid solution, taking out the hydrogel, adding pyrrole, carrying out polymerization growth in a closed environment, taking out the hydrogel, soaking the hydrogel in water, and washing the hydrogel to obtain the anisotropic polypyrrole graphene oxide hydrogel. The anisotropic polypyrrole graphene oxide cellulose hydrogel disclosed by the invention has excellent solar photo-thermal water evaporation performance and also has excellent thermal management performance.

The invention discloses a composite coated silicon-carbon negative electrode material as well as a preparation method and application thereof, and relates to the technical field of lithium ion batteries. The method comprises the following steps of: oxidizing and etching graphite in mixed gas of air and nitrogen at the temperature of between 400 and 500 DEG C to form graphite oxide; the preparation method comprises the following steps: dispersing water-soluble asphalt, graphene, nano silicon, melamine and monoammonium phosphate in water to form a composite liquid; and then mixing the composite liquid with graphite oxide, and then carrying out carbonization treatment. The high-performance silicon-carbon composite negative electrode material is prepared through graphite oxidation etching and a composite coating process, nano silicon is uniformly dispersed in carbon pores which are stably combined on the surface of graphite and have rich mesoporous structures, graphene and a nitrogen-doped carbon layer form a three-dimensional conductive network, and the composite negative electrode material is applied to lithium ion batteries and can be applied to lithium ion batteries. And the lithium ion battery has good low-temperature charging proportion, first efficiency and cycle performance.

The invention provides a waterproof and windproof warm-keeping fabric and a production process thereof, and relates to the technical field of textile fabrics, the waterproof and windproof warm-keeping fabric comprises a protective surface layer, a windproof temperature-locking middle layer and a skin-friendly warm-keeping inner layer which are sequentially arranged from outside to inside, and the three layers are compounded through a gradient hot melt adhesive; the protective surface layer is a graphene oxide modified polyester fiber fabric treated by a composite hydrophobic finishing liquid; the windproof temperature-locking middle layer sequentially comprises a non-swelling environment-friendly TPU film, a polytetrafluoroethylene microporous film and a Cs0. 33WO3 modified PA6 / 66 hollow fiber net from outside to inside, and the three are laminated and compounded into an integrated structure through hot pressing; and the skin-friendly warm-keeping inner layer is a bamboo pulp fiber-cotton-skin-friendly antibacterial polyester fiber blended fabric loaded with phase change microcapsules. The fabric disclosed by the invention integrates excellent waterproof, windproof and warm-keeping properties, is suitable for outdoor and cold-proof clothes, and has both functions and comfort.