3188 results about "Chemical bond" patented technology

This invention discloses a fluorene-based organic small molecule hole transport material and its applications. The general structural formula of the fluorene-based organic small molecule hole transport material is as follows: where n = 1-4, and R represents the hole transport capacity. This fluorene-based organic small molecule hole transport material is used as an undoped hole transport material in perovskite solar cell devices. By introducing dicarboxylic acid groups onto the fluorene-based organic small molecule hole transport material, when used in an inverted perovskite solar cell device, it can form chemical bonds with the hydroxyl groups of the glass conductive substrate, forming a directionally aligned self-assembled layer on the surface of the glass conductive substrate. This effectively improves the charge transport capability at the interface and increases the photoelectric conversion efficiency of the perovskite solar cell device. Furthermore, since this perovskite solar cell device does not contain lithium salts, it exhibits high water and oxygen stability. In addition, the synthesis process of this fluorene-based organic small molecule hole transport material is simple, and the raw materials are inexpensive and readily available, making it highly valuable for practical applications.

The embodiment of the invention provides a preparation method of a negative electrode active material, the negative electrode active material, a battery and equipment. Fluorine-containing gas is used as discharge gas, and discharge current is introduced into a plasma treatment device in the process of performing vibration dispersion treatment on a porous carbon substrate through the plasma treatment device; the fluorine-containing gas is used for carrying out plasma discharge treatment on the porous carbon matrix, so that the fluorine element provided by the fluorine-containing gas can react with carbon atoms on the surface of the porous carbon matrix to form chemical bonding, and the chemical bonding uniformity between the fluorine element and the carbon atoms on the surface of the porous carbon matrix can be improved; and the preparation cost of the negative electrode active material can be reduced, and the preparation efficiency of the negative electrode active material is improved, so that the battery capacity and the cycle performance of a secondary battery prepared from the negative electrode active material disclosed by the embodiment of the invention can be improved.

The invention relates to an antistatic MLCC release film base film and a preparation method thereof. The antistatic MLCC release film base film is prepared by melt blending and biaxial stretching of PET master batch, an antistatic composition and a nano filler, wherein the antistatic composition is prepared by compounding modified PET-PEG and thiophene modified aromatic polyamide; the nano filler is prepared by carrying out melt extrusion on KH550 modified talcum powder and MAH-g-PET (maleic anhydride-grafted polyethylene terephthalate). The antistatic composition disclosed by the invention has the beneficial effects that the antistatic composition is formed by interweaving two polymers, and a stable three-dimensional conductive network is constructed in the PET film, so that the antistatic performance is more efficient, lasting and stable. In addition, through chemically bonded modified talcum powder, the smoothness and low roughness are provided, and meanwhile reinforcing and toughening are achieved; and the single-layer extrusion process can realize ultrathin thin film, the production process is simplified, and the production cost is greatly reduced.

The invention provides a fresh food quality degradation pre-judgment method and system based on multi-modal dynamic coupling, and aims to solve the problem of prediction lag caused by data isolation and dynamic coupling deficiency in the traditional storage and transportation process. Specifically, sensory layer data, environment layer data and operation layer data are synchronously collected through a multi-source sensor, chromatic aberration quantification, chemical bond feature extraction and spatial chemical fusion processing are carried out on the sensory data, and a quality degradation feature tensor is generated; based on a graph network model and frequency domain analysis, constructing a dynamic coupling parameter set of quality degradation characteristics and environmental parameters; fusing the loading and unloading pulse trajectory tensor, the cold chain stability distribution and the coupling parameter set, and generating a degradation constraint distribution matrix through multivariable weight mapping; and finally, combining acoustic resonance mode coherence analysis and constraint matrix evolution, and outputting a four-stage quality label. According to the method, through multi-dimensional real-time sensing, dynamic coupling modeling and hierarchical management and control, the fresh food storage and transportation loss is remarkably reduced, and the cold chain management efficiency is improved.

The invention relates to the field of metal surface treatment, and discloses an efficient electroplating process for a cotton picker spindle and an electroplating liquid formula, the efficient electroplating process comprises the following steps: step 1, substrate pretreatment: sequentially carrying out alkali washing, acid washing and plasma activation on the spindle; step 2, preparing an electroplating solution: dissolving nickel sulfate, sodium hypophosphite, a composite nano additive and a complexing agent in water, and adjusting the pH value to 4.8-5.3; step 3, gradient pulse electroplating: carrying out pulse electroplating in three stages, including bottom layer deposition, transition layer deposition and composite layer deposition; 4, post-treatment is conducted, specifically, silane sealing and curing are conducted on the plating layer; the base body pretreatment in the first step comprises the following sub-steps of alkali washing and oil removal, wherein the picking ingot is soaked in a NaOH solution with the concentration being 45-55 g / L. According to the method, high-density hydroxyl active sites are constructed on the surface of the metal base material through a plasma activation process, strong chemical bonding is formed between a plating layer and the base material, and the interface bonding strength is remarkably improved.

The invention provides a composite reagent system and a chalcopyrite and sphalerite collecting method, and belongs to the technical field of mineral processing. The composite reagent system comprises a histidine derived functional group collecting agent and a black agent, and the histidine derived functional group collecting agent (containing a total sulfur ester group, a sulfydryl functional group and a side chain imidazole ring) serves as a core and is compounded with the black agent according to a specific proportion to form a target combination-synergistic interaction flotation mechanism. The histidine derivative collecting agent derives high-activity functional groups under the alkaline condition, and after sulfydryl is dissociated, stable chemical bonds are formed by the dissociated sulfydryl and metal ions on the surfaces of the chalcopyrite and the zinc sulfide. The black powder serves as an auxiliary collecting agent, and the collecting capacity of fine-grain or low-activity sulfide minerals is enhanced through chemical adsorption of dithiophosphate radicals and metal ions on the surfaces of the chalcopyrite and the sphalerite. After the two components are compounded, the selective enrichment efficiency of copper-zinc minerals in the flotation process is remarkably improved.

The invention provides a self-repairing EVA adhesive film and a preparation method thereof, and relates to the technical field of solar photovoltaic module packaging. According to the self-repairable EVA adhesive film disclosed by the invention, through Diels-Alder reactive group grafting and silane coupling agent microencapsulation technologies, a dual self-repairing mechanism of a photovoltaic module packaging adhesive film is realized, and the dual self-repairing mechanism comprises physical rearrangement repairing and chemical bonding repairing; while high light transmittance (more than or equal to 90%) and bonding strength (more than or equal to 96 N / cm) are maintained, the aging resistance (delta YI is less than or equal to 3) of the EVA adhesive film is remarkably improved, the service life of the EVA adhesive film is remarkably prolonged, and the problems that a traditional EVA adhesive film is easy to age in an extreme environment and is easy to suffer from micro damage caused by mechanical stress are solved; the preparation process disclosed by the invention is compatible with the existing production line, and has a relatively high industrial application value.

The invention discloses a coal seam chemical outburst elimination method based on molecular dynamics, which belongs to the field of coal mine safety, and comprises the following steps: sampling and analyzing to obtain the element proportion, group composition and chemical bond connection mode of a coal sample, constructing a real coal molecular skeleton, and reducing and optimizing the molecular structure of coal by molecular simulation; the method comprises the following steps: adding a surfactant, setting the real gas content, gas pressure and environment temperature of a coal seam, establishing a micro model after the surfactant is injected into the coal seam, simulating the occurrence state and reaction process of methane molecules in the coal seam under the action of the surfactant, and determining the methane content in the coal seam by combining the migration characteristics of the methane molecules and the energy change of the system. And the concentration of the injected surfactant is optimized, so that the engineering application of large-range industrial water injection outburst elimination of the coal seam is developed. According to the method, through molecular simulation, the complex occurrence characteristics of the coal seam are considered, the concentration of the injected surface active agent is optimized, and the hydraulic measure efficiency is improved.

The invention discloses a double-site doped titanium lithium ion sieve adsorbent as well as a preparation method and application thereof. The adsorbent is a lithium removal product of a double-site doped titanium lithium ion sieve adsorbent precursor, the chemical general formula of the double-site doped titanium lithium ion sieve adsorbent precursor is Li (2-x) MxTi (1-y) NyOz, M is at least one of Na < + >, K < + >, Zn < 2 + >, Co < 2 + >, Ni < 2 + >, Mg < 2 + > and Al < 3 + > and occupies Li site, N is at least one of Cr < 3 + >, Fe < 3 + >, Zr < 4 + >, Nb < 5 + >, Ta < 5 + >, V < 5 + >, Mo < 6 + > and W < 6 + > and occupies Ti site, x is larger than or equal to 0.001 and smaller than or equal to 0.5, and y is larger than or equal to 0.001 and smaller than or equal to 0.5. Metal cations are introduced to replace Li sites and Ti sites at the same time, Li site substitution enlarges interlayer spacing and improves Li < + > diffusion rate, Ti site substitution regulates local chemical bond and electron distribution, stabilizes lattice structure and enhances electron conduction, and through double-site doping, 'ion-electron 'double channels are constructed, so that a collaborative optimization effect is achieved. The double-site doped titanium lithium ion sieve adsorbent disclosed by the invention is applied to adsorption and extraction of lithium in a Bayer process sodium aluminate solution, and the adsorbent shows excellent adsorption performance.

The invention belongs to the technical field of polymer composite materials, and particularly relates to an oil-resistant interior material. The material comprises a porous base material layer, a fluorine-containing polymer and organic silicon resin blended oil-resistant functional layer and a micro-nano structure layer with a periodic micro-bulge array, surface modified nanoparticles are distributed in the functional layer in a gradient manner, and the micro-bulge surface is covered with a perfluoropolyether / fluorinated silicon dioxide composite coating; through a synergistic effect of a low-surface-energy oleophobic interface formed through chemical bonding and curing and a micro-structure capillary lifting effect, anti-permeation barrier of high-viscosity grease is realized, and meanwhile, mechanical wear resistance and thermal stability are improved by virtue of a nano-particle enhanced cross-linked network; and continuous imprinting and an ultraviolet-thermal dual-curing process are combined to achieve high-efficiency manufacturing with zero solvent residue, and finally the interior material with long-acting oil resistance, high environmental tolerance and industrial mass production feasibility is obtained.

The invention provides a preparation method of a self-repairing resin-based composite material based on dynamic bonds. The self-repairing epoxy resin comprises one covalent dynamic bond of a Diels-Alder bond, a disulfide bond or a borate bond, and the preparation method of the self-repairing epoxy resin comprises the following steps: heating epoxy resin to a molten state, adding a curing agent component while stirring, and carrying out a prepolymerization reaction to obtain a prepolymer; the curing agent comprises a rigid diamine curing agent, a dynamic diamine monomer and a flexible chain segment regulator, and the dynamic diamine monomer contains a dynamic covalent bond; and carrying out curing molding on the prepolymer to obtain the self-repairing epoxy resin. And impregnating reinforced fibers or fabrics thereof with the prepared prepolymer, and heating and curing to obtain the self-repairing resin-based composite material. The invention provides a chemical molecule design, dynamic reversible chemical bonds are introduced into a resin matrix, and by constructing the dynamic bonds, the composite material has high performance of a traditional composite material and also has life-like self-healing ability.

The invention relates to the technical field of sodium-ion batteries, and discloses a super-crosslinked asphalt-based hard carbon material, a preparation method and application thereof, and a sodium-ion battery. Asphalt is subjected to super-crosslinking by adopting a mechanochemical method, and the asphalt, a crosslinking agent and a catalyst realize fracture and recombination of chemical bonds under the action of mechanical shearing force of grinding balls, so that the super-crosslinked asphalt-based hard carbon material is obtained. According to the present invention, the asphalt is subjected to segmented ball milling and super-crosslinking, and then carbonization sintering is performed, such that the asphalt cannot be subjected to molecular rearrangement so as to finally form the hard carbon material with the more suitable microporous structure and the more suitable interlayer spacing, such that the negative electrode ion embedding requirement of the sodium ion battery is met, the excellent sodium storage performance is represented, and the capacity and the first coulombic efficiency of the assembled battery are improved; the performance improvement of the sodium ion battery is integrally promoted. The method is low in energy consumption, short in time consumption, simple in parameter control and suitable for large-scale application and popularization.

The invention relates to the technical field of ink, and discloses a preparation method of bio-based degradable water-based ink, which comprises the following steps: carrying out esterification polymerization on vanillin-based spiro acetal diglycidyl ether and diacid to obtain bio-based polyester resin, mixing and dispersing the bio-based polyester resin, petroleum-based resin, pigment, auxiliary agent and the like to obtain the bio-based degradable water-based ink. The bio-based degradable water-based ink is prepared. The bio-based resin contains a plurality of hydrophilic hydroxyl groups, has good solubility and dispersibility in the water-based ink, and generates denser hydrogen bonds and other cross-linking effects with the acrylic resin, so that the hardness of the ink is improved. Meanwhile, the polar hydroxyl groups also greatly enhance the hydrogen bond bonding and anchoring effect between the paint film and the base material, so that the adhesive force is improved. In addition, easily-hydrolyzed spiral acetal bonds, polyester structural units and other degradable chemical bonds in molecular chains of the bio-based resin provide more attack sites for water and microorganisms, the degradation rate is increased, and the degradable function is achieved.

The invention discloses a reprocessable solid-solid phase change material based on dynamic borate bonds and a preparation method of the reprocessable solid-solid phase change material. Based on the mechanism that boric acid ester is subjected to ester exchange during thermal stimulation, a dynamic cross-linking agent containing boric acid ester is adopted for cross-linking a polyurethane prepolymer, polyethylene glycol is cross-linked through chemical bonds, the tensile strength and the elongation at break of the phase change material are improved, and the problem that the phase change material is prone to leakage in the phase change process is solved; besides, borate bonds belong to associated dynamic covalent bonds and can keep the crosslinking density of the material unchanged when ester exchange occurs under thermal stimulation, so that the thermal stability of the material is relatively good; the solid-solid phase change material disclosed by the invention is excellent in mechanical property, has a relatively high enthalpy value, can be reprocessed, and has an application prospect in the fields of thermal management, energy storage, infrared stealth and the like.

The invention relates to a bio-based degradable UV-curable coating material for a microcapsule fire extinguishing agent, the microcapsule fire extinguishing agent and a preparation method and application of the bio-based degradable UV-curable coating material for the microcapsule fire extinguishing agent. The bio-based degradable UV-curable coating material for the microcapsule fire extinguishing agent is prepared from the following components in parts by weight: 100 parts of bio-based hyperbranched polyurethane / acrylate prepolymer; 10-150 parts of a reactive flame-retardant monomer, 0.1-5 parts of a photoinitiator and 0-70 parts of a solvent. The coating material for the microcapsule fire extinguishing agent is a thermal response type material, when the coating material is prepared into a shell layer of the microcapsule fire extinguishing agent and the environment temperature reaches a preset threshold value, the shell layer is rapidly broken due to thermal expansion coefficient difference and chemical bond fracture, internal fire extinguishing liquid is released, the process can be completed within 3 seconds or less, rapid response in the initial stage of a fire disaster is ensured, and fire extinguishing efficiency is improved. The thermal response speed is high, the microcapsule fire extinguishing agent can be rapidly broken in the early stage of a fire, rapid release of fire extinguishing liquid is achieved in the early stage of the fire, efficient fire extinguishing is achieved, a fire source is controlled in time, and fire spreading is effectively prevented.

The invention relates to the technical field of food fresh-keeping materials, in particular to a chitosan-curcumin nano-composite fresh-keeping agent and a preparation method thereof.The chitosan-curcumin nano-composite fresh-keeping agent comprises nano-particles of a chitosan-sodium alginate-oxidized sodium alginate interpenetrating network structure, according to the nanoparticles, protonated amino groups of chitosan and carboxyl groups of sodium alginate form a polyelectrolyte compound core, aldehyde groups of oxidized sodium alginate and amino groups of chitosan are subjected to a Schiff base reaction to form a chemical cross-linked network, and zinc ions, amino groups of chitosan, carboxyl groups of sodium alginate and carboxyl groups of oxidized sodium alginate form coordination cross-linking; curcumin and epigallocatechin gallate form a compound through a hydrogen bond and a hydrophobic effect, the compound is embedded in an interpenetrating network structure, beta-diketone groups of curcumin and zinc ions form chelating coordination, a chitosan-sodium alginate-oxidized sodium alginate ternary interpenetrating network is constructed, and the chitosan-sodium alginate-oxidized sodium alginate ternary interpenetrating network structure is formed. The stability is improved by utilizing the synergistic effect of triple mechanisms of electrostatic interaction, Schiff base chemical bonds and zinc ion coordination.

The invention discloses an epoxy resin tack coat oil material suitable for a steel bridge deck, which constructs a multi-scale toughening composite system through the synergistic effect of an epoxy-terminated polyurethane elastomer toughening agent (molecular-scale chemical grafting) and a nano-scale elastomer filler (nano dispersion toughening), and solves the problem of rigidity-flexibility imbalance of the traditional epoxy tack coat oil. The material has the advantages of fast curing (surface drying at 25 DEG C is less than or equal to 4 hours), high toughness (the elongation at break is greater than or equal to 250%) and excellent weather resistance (the performance retention rate is greater than or equal to 85% after ultraviolet aging for 500 hours), and is suitable for interlayer interface bonding of steel bridge deck pit slot and crack repair. According to the preparation method, uniform dispersion and interface chemical bonding of the nanofiller are achieved through a segmented stirring process, the comprehensive performance of the material is remarkably improved, and the important engineering application value is achieved.

The invention discloses a preparation method and application of an organic polymer solid electrolyte composite additive. According to the preparation method, a poly (ethylene glycol) diacrylate-mercaptopropyl trimethoxy silane-Li6PS5Cl composite additive material is prepared by adopting a click chemistry reaction; functional groups at two ends of a mercaptopropyl trimethoxy silane molecule are respectively coupled with chemical bonds of polyethylene glycol diacrylate and Li6PS5Cl inorganic electrolyte to construct a stable bonding interface of organic matrix-silane coupling agent-inorganic matrix under the action of chemical bond valence force. The problems that traditional inorganic additives are serious in particle aggregation, poor in compatibility with a polymer solid electrolyte body interface and the like are solved, and by starting with the stability of the internal interface of the additives and construction of ion channels, the organic polymer solid electrolyte is prepared by means of defect regulation and control between organic polymer functional groups and the inorganic additives. The interfacial compatibility and the efficient and rapid ion transmission capability of the material are obviously improved. According to the invention, efficient ion transmission and long-acting cycle stability of an internal interface of the organic polymer solid electrolyte can be realized.

The present invention provides a phycocyanin-collagen composite hydrogel and its preparation method and application. The present invention utilizes transglutaminase to catalyze the combination of phycocyanin and collagen to form a new, more stable collagen; transglutaminase acts between protein molecules, utilizes lysine and glutamic acid in phycocyanin and collagen to transfer acyl groups, and cross-links to form new chemical bonds, thereby enhancing the binding strength of phycocyanin and collagen; the hydrogel prepared by the present invention can be used to prepare medical materials and combined with skin injury sites to solve the problem that traditional dressings are easy to adhere to wounds and easily penetrated by tissue fluid and become infected. In addition to ensuring basic air permeability, it reduces the adhesion of the dressing, increases moisture retention and antioxidant properties, and avoids secondary damage when replacing a new dressing. The hydrogel prepared by the present invention has a certain antioxidant capacity and can be used to prepare products with antioxidant effects.

The invention discloses a high-density polyethylene silicon core pipe and a preparation method thereof, and relates to the technical field of silicon core pipes. The high-density polyethylene is subjected to modification treatment in different modes to obtain different modified high-density polyethylene; different modified high-density polyethylene is used as a main component, and a silicon core pipe outer-layer mixture and a silicon core pipe inner-layer mixture are prepared respectively; finally, the silicon core pipe outer layer mixture and the silicon core pipe inner layer mixture are subjected to melt co-extrusion, Si-O-C chemical bonding is generated on the inner layer and the outer layer, and the high-density polyethylene silicon core pipe is obtained. The high-density polyethylene silicon core pipe prepared by the invention is very high in interlayer bonding strength and very excellent in flame retardant property and mechanical property.

The invention discloses multi-solvent synergistically activated low-temperature semi-sintered copper paste and a preparation method and application thereof, and belongs to the technical field of conductive paste. The multi-solvent synergistically activated low-temperature semi-sintered copper slurry comprises the following raw material components in percentage by mass: 82-88% of conductive filler, 2-3% of a resin carrier, 4-7% of an activating solvent, 4-7% of a dispersing solvent and 2-3% of a curing agent. Through cooperation of multiple solvents, full-stage activation of the copper particles is achieved, pre-connection and sintering of the copper particles before resin is completely crosslinked and cured are promoted, densification of the overall structure is improved, the insulation barrier effect of the resin is effectively avoided, the resistivity is reduced, meanwhile, inhibition of the resin on sintering of the copper particles is solved, and the service life of the copper particles is prolonged. And good balance between conductivity and interface adhesion is realized. Through resin curing, chemical bonding between the slurry and the substrate can be enhanced, a metal bond network among copper particles is expanded, and mechanical connection stability and electrical performance are guaranteed.

The invention relates to a preparation method and application of an electrode, in particular to a preparation method and application of an anti-reverse current self-supporting electrode for anion exchange membrane water electrolysis hydrogen production. The self-supporting (NiCoFe) 9S8 electrode is constructed by adopting a directional solid-phase synthesis strategy to overcome the challenge of performance degradation of the electrolytic cell. The preparation method comprises the following steps: firstly, depositing a precursor solution of FeS2 and CoCl2 on a nickel felt substrate, and then carrying out annealing treatment to obtain uniformly grown (NiCoFe) 9S8; the method not only ensures uniform distribution of multiple metal components, but also constructs firm chemical bonding and efficient charge transfer between the catalyst layer and the conductive substrate through solid-phase interface reaction, and effectively avoids interface impedance caused by introduction of an additional binder. Therefore, high-current-density water electrolysis hydrogen production under intermittent fluctuation power supply is realized. In 1M KOH, the cell voltage is almost not attenuated when the electrode stably operates for 2000h at 500mAcm <-2 >.

The invention relates to the technical field of polymer composite materials, and discloses a nano-ceramic-based composite insulating coating and a preparation method thereof, and the coating is prepared from a composite resin matrix, a composite functional ceramic filler, a double-reactivity organosilicon linker and an initiator. Wherein the composite resin matrix is composed of vinyl-terminated polydimethylsiloxane and a vinyl ether functionalized fluorocarbon copolymer, and a soft and rigid interpenetrating network structure is formed. The composite functional ceramic filler is prepared from needle-shaped silicon nitride, flaky hexagonal boron nitride, nano silicon dioxide, nano cerium oxide and nano barium titanate. According to the invention, a chemical bonding interface is constructed between the inorganic filler and the organic resin, and the synergistic effect of the composite matrix and the multifunctional filler is optimized, so that the coating has excellent adhesive force, flexibility and thermal shock resistance, obtains high volume resistivity and breakdown strength, and meets the insulation protection requirements under harsh working conditions.

The invention discloses a preparation method and application of a ceramic glaze layer protecting and repairing material, and belongs to the technical field of cultural relic protection. The preparation method comprises preparation of a core-shell self-repairing nanocapsule, and the preparation of the core-shell self-repairing nanocapsule comprises the following steps: reacting a calcium chloride solution with a sodium hydroxide solution, then adding sodium polyacrylate and nano ZnO, and carrying out dispersion, centrifugation, washing and other operations to prepare the nano Ca (OH) 2-ZnO composite material. The nano Ca (OH) 2-ZnO composite material of the core-shell self-repairing nanocapsule can be rapidly released through the 3.5 nm aperture of the mesoporous SiO2 shell, glaze layer cracks are physically filled and react with CO2 in air to generate CaCO3 crystals, crack plugging is achieved, meanwhile, dynamic disulfide bonds of a PU layer are broken and recombined under stress stimulation, a crack interface is repaired through chemical bonding, and the performance of the core-shell self-repairing nanocapsule is improved. The 24-hour crack repair rate is greater than or equal to 96%, and the limitation of'one-time repair 'of a traditional material is solved.

The invention relates to the field of material surface treatment, and discloses a silica gel and metal combined treatment process which comprises the following steps: S1, ultra-short pulse laser is adopted to machine a three-dimensional micro-nano composite structure on the surface of a titanium alloy, the structure comprises a periodic groove array and surface nano holes, and the surface roughness Ra of the titanium alloy is larger than or equal to 5 microns; and S2, a titanium nitride transition layer and a siloxane self-assembly molecular layer are sequentially formed on the roughened titanium alloy surface through atomic layer deposition, and a gradient chemical interface is formed. According to the method, the micro-nano composite structure is processed through ultra-short pulse laser, the interface mechanical embedding area is remarkably increased, the two-dimensional rough limitation of a traditional sand blasting process is broken through, deep barb-shaped anchoring is achieved, the anti-stripping capacity is greatly enhanced, gradient chemical bonding is formed by the atomic layer deposition titanium nitride transition layer and the amino self-assembly molecular layer, and the anti-stripping performance is improved. The thermal expansion difference is effectively buffered, and the interface high-temperature resistance is improved.

The invention relates to the technical field of glass fiber felts, in particular to a high-strength fire-resistant glass fiber felt and a preparation method thereof. The high-strength fire-resistant glass fiber felt is characterized by comprising a fire-resistant glass fiber felt base material prepared by mixing glass fibers and chopped basalt fibers, and the mass ratio of the glass fibers to the chopped basalt fibers is (4-5): 1; the glass fibers and the chopped basalt fibers are subjected to oxygen plasma treatment. The glass fiber and the short-cut basalt fiber are compounded according to a specific proportion, and the performance advantages of the glass fiber and the short-cut basalt fiber are combined. The glass fibers provide high modulus and corrosion resistance, and the basalt fibers enhance high temperature stability and impact resistance. Active groups are introduced to the fiber surface through oxygen plasma treatment, and chemical bonding with resin is enhanced. The optimized fiber mixing ratio remarkably improves the tensile strength and high temperature resistance of the base material, meanwhile, the binding force of the fibers and the resin is enhanced through oxygen plasma treatment, internal pores of the material are reduced, and the material is more compact and durable.

The invention discloses an alkaline electrolyzed water diaphragm based on nickel oxyhydroxide and a preparation method and application of the alkaline electrolyzed water diaphragm, and relates to the technical field of composite diaphragms.The alkaline electrolyzed water diaphragm is prepared through a phase inversion method, and nanometer nickel oxyhydroxide NiOOH particles are selected as inorganic nanometer filler; the mass percent of the nickel oxyhydroxide in the membrane casting solution is 15-30%. A strong chemical bond formed by nickel ions and hydroxyl in the hydroxyl nickel oxide crystal endows the material with excellent structural stability, and the material shows excellent solubility resistance, hydrolysis resistance and structural collapse resistance in a strong alkaline electrolysis environment and can tolerate high-concentration OH <-> erosion for a long time; meanwhile, the intrinsic high-oxidation-resistance characteristic is achieved.

The invention relates to a preparation method of a magnetic field-electric field synergistically driven Fe3O4-loaded graphene three-dimensional interlocking network / metal composite material, and belongs to the field of electronic packaging materials. An alternating magnetic field and a direct-current electric field are applied in the solidification process of metal melt, Lorentz force is used for driving graphene nanosheets loaded with Fe3O4 to rotate directionally and be arranged vertically, meanwhile, the electric field induces dissociation of graphene edge functional groups, chemical bonding with a metal matrix is enhanced, and a space interlocking heat conduction network is formed. The graphene reinforced metal composite material is obviously superior to a traditional graphene reinforced metal composite material and is suitable for a heat dissipation substrate of aerospace electronic equipment.

The invention relates to a composite binder, an electrolyte membrane, a preparation method and a battery. The composite binder comprises a binder main material and cross-linked molecules, the binder main material has a first functional group; the cross-linked molecule comprises a main chain and second functional groups, the main chain comprises a dynamic cross-linked structure sensitive to heat, the dynamic cross-linked structure comprises at least one of reversible chemical bonds and heat-sensitive functional groups, and the two ends of the main chain are provided with the second functional groups which are combined with the first functional groups in a reaction mode. The problem of poor mechanical property of the binder in the related art can be solved.

The invention relates to the technical field of composite materials, in particular to a high-strength epoxy resin composite material and a preparation method thereof, and the high-strength epoxy resin composite material comprises the following raw materials in parts by weight: 50-80 parts of a base material, 10-20 parts of a curing agent, 5-10 parts of modified carbon nanotubes, 3-10 parts of a reinforcing sheet, 3-6 parts of a reinforcing material and 1-3 parts of a flame retardant. In the preparation method, the modified carbon nanotubes are in chemical bond connection with the base material through surface modification, the interface bonding force is enhanced, stress is effectively transmitted, the unique layered structure and surface modification treatment of the enhanced sheet are enhanced, the enhanced sheet is firmly combined with the resin matrix, and a three-dimensional enhanced network is formed through the synergistic effect of mechanical interlocking and stress dispersion. The vermiculite sheet layer prevents crack propagation, and the modified carbon nanotubes and the reinforcing material effectively transfer stress, so that the tensile strength and bending strength of the composite material are greatly improved, and the high-strength application requirement is met.