8106 results about "Molecular sieve" patented technology

The invention relates to the technical field of drug research and development, and discloses a drug-like molecule screening system and method based on deep learning, and the system comprises a physical and chemical characteristic analysis module which is used for calculating molecular descriptors of compounds and generating a visual characteristic distribution chart; and the drug-like molecule screening module integrates a Lipinski rule, a Veber rule, a Ghose rule and a Muegge rule, and supports a user to customize a screening rule. Compound characteristics are comprehensively analyzed through the physical and chemical characteristic analysis module, flexible screening is achieved through the drug-like molecule screening module, toxicity risks are accurately recognized through the toxicity assessment module, the affinity assessment module is combined to assess the binding capacity in multiple ways, and the synthesis feasibility assessment module plans an efficient and low-cost synthesis path. The dynamic feedback optimization module continuously improves the system performance; all the modules work cooperatively, the problems of scattered tools, insufficient precision, low planning efficiency, optimization deficiency and the like in the prior art are effectively solved, the medicine research and development efficiency is greatly improved, and the research and development risk and cost are reduced.

The invention relates to the technical field of adsorbents, and particularly discloses an aluminum oxide type adsorbent and a preparation method thereof.The preparation method comprises the following steps that lanthanum salt, cerium salt and a polyethylene glycol aqueous solution are mixed to be uniform, then the mixture is mixed with gamma-Al2O3 to be uniform, pH is adjusted, standing is conducted, solid-liquid separation is conducted, drying and roasting are conducted, and a double-doped carrier is obtained; dispersing the double-doped carrier in a mixed solution containing 2-methylimidazole, ferric salt and zinc salt, adjusting the pH value, carrying out heating reaction, solid-liquid separation and drying in an inert atmosphere, grinding to obtain powder, and carrying out molding treatment on the powder to obtain a composite carrier; uniformly mixing the Ag modified molecular sieve with silica sol, coating the surface of the composite carrier with the mixture, and drying to obtain an adsorbent precursor; dipping an adsorbent precursor in the dispersion liquid, and after dipping, solid-liquid separation and drying, reactivating to obtain the aluminum oxide type adsorbent; the prepared adsorbent can synergistically and efficiently remove multiple impurities and is excellent in corrosion resistance.

The invention discloses a split type vehicle-mounted intelligent oxygen supply system based on the VPSA technology and a control method, and the system comprises an air compressor which is arranged at the inner side of a wheel cover protection plate of a rear wheel of a vehicle and is used for compressing air and discharging the compressed air to a molecular sieve assembly; the molecular sieve assembly is arranged below a spare tire in a trunk of the vehicle and is used for separating nitrogen from oxygen in the air to generate oxygen; the oxygen conveying pipe is arranged on the inner side of the vehicle roof and connected with an oxygen outlet of the molecular sieve assembly, and an oxygen outlet is formed in the position, located above each seat, of the oxygen conveying pipe; the detection module comprises an altitude sensor and an oxygen concentration sensor, the altitude sensor is installed on the molecular sieve assembly, and the oxygen concentration sensor is arranged on a ceiling in a vehicle compartment; distributed arrangement is adopted, all parts of the oxygen supply system are installed at different positions of the vehicle, the space occupied by the oxygen generation system can be reduced, and meanwhile directional oxygen supply to specific seats is achieved through the distributed oxygen outlets.

The invention discloses a desulfurization adsorbent for low-carbon olefins and a preparation method of the desulfurization adsorbent, and belongs to the technical field of preparation of desulfurizers. The desulfurization adsorbent is a 13X molecular sieve with larger K < + > ion exchange aperture, so that the acting force between adsorbed molecules and cations is weak, the adsorption heat is obviously reduced, the olefin adsorption capacity is weakened, the polymerization reaction of olefin is obviously inhibited, the content of effective components can be further improved, and the adsorption capacity is improved; in the forming process of the adsorbent, a macromolecular polymer and a mesoporous high-thermal-conductivity material are added, local heat accumulation in the adsorption process is reduced, local temperature rise is relieved, meanwhile, heat is rapidly taken away, the adsorption temperature rise is small, and unexpected shutdown, olefin leakage and other dangers are avoided; in the forming process of the adsorbent, metal components are added, the adsorption sites of the adsorbent are further increased, the adsorption speed is higher, and the desulfurization efficiency is higher.

The invention relates to a concrete anti-cracking self-repairing agent in the technical field of building materials, and aims to solve the problem that concrete cracks are difficult to self-repair. According to the technical scheme, the self-repairing agent is characterized by comprising a microbial repairing unit formed by ZSM-5 type zeolite molecular sieve loaded bacillus pasteurii spores, mesoporous silica particles loaded with L-calcium aspartate and Fe3O4 (at) SiO2 core-shell nanoparticles which are fixed through an in-situ polymerization coating layer to form a magnetic thermal response capsule layer coating the surface of the microbial repairing unit, pLGA microspheres containing yeast extract are positioned on an interface of zeolite and hydrogel, and a trehalose-anhydrous calcium chloride eutectic compound is used as a directional mineralization accelerant. The concrete anti-cracking self-repairing agent provided by the invention is mainly used for intelligent identification and self-repairing of concrete cracks, and efficient repairing is realized through a microbial mineralization, calcium ion slow release and magnetic thermal response synergistic mechanism.

The invention relates to an SSZ-39 molecular sieve and preparation and application thereof.The preparation method comprises the following steps that 1, after water, an alkali source and a template agent are mixed, mesoporous Y zeolite and a silicon source are added, the mixture is stirred to be uniform, and the mixture is aged to be in a white gel shape; (2) transferring the obtained white gel into a reaction kettle, carrying out crystallization treatment, and filtering, washing, drying and calcining a crystallized product to obtain a Na-SSZ-39 molecular sieve; (3) carrying out ammonium ion exchange on the Na-SSZ-39 molecular sieve, filtering, washing, drying and calcining to obtain an H-SSZ-39 molecular sieve; and (4) carrying out copper ion exchange on the H-SSZ-39 molecular sieve, filtering, washing, drying and calcining to obtain the Cu-SSZ-39 catalyst. Aluminum used in the method is provided by mesoporous Y zeolite, the pure-phase SSZ-39 molecular sieve can be synthesized in a wide gel range, the crystallization time is shortened to 24 h, and after copper ion exchange, the pure-phase SSZ-39 molecular sieve shows high denitration activity in the selective catalytic reduction reaction of nitrogen oxide ammonia.

The invention discloses a preparation method of an adsorption and reduction bifunctional catalyst for denitration of tail gas of a diesel vehicle. The preparation method comprises the following steps: uniformly loading a Pd component and a Cu component on the surface of a molecular sieve to prepare a corresponding Pd-based molecular sieve and a corresponding Cu-based molecular sieve; and then coupling the Pd-based molecular sieve and the Cu-based molecular sieve according to a certain proportion by using a solid-phase grinding means to obtain the adsorption and reduction dual-functional Pd-Cu / SSZ-13 catalyst. The adsorption and reduction bifunctional Pd-Cu / SSZ-13 catalyst prepared by the method not only has excellent SCR activity at the temperature of 200 DEG C or above, but also has good PNA capacity at the temperature of 200 DEG C or below, can realize high-efficiency denitration of diesel vehicle tail gas in a full-temperature section, and can be widely applied to a diesel vehicle tail gas after-treatment system.

The invention relates to a phenolic resin modified carbon molecular sieve and a preparation method and application thereof, and belongs to the technical field of adsorbents. The technical problem to be solved by the invention is to provide the phenolic resin modified carbon molecular sieve, and the adsorption selectivity is improved. The method comprises the following steps: a, in-situ polymerization: mixing phenolic resin polymerization mother liquor with a carbon molecular sieve, standing for adsorption, and heating the adsorbed carbon molecular sieve for polymerization reaction to obtain a polymerization product; the phenolic resin polymerization mother liquor comprises a phenolic substance, an aldehyde substance and a solvent; and b, carbonization modification: roasting the polymerization product in a protective atmosphere to obtain the phenolic resin modified carbon molecular sieve. The carbon molecular sieve is modified through phenolic resin in-situ polymerization, and the method is simple, low in cost, high in reaction controllability and suitable for industrial production. The phenolic resin modified carbon molecular sieve has selective adsorbability, can be applied to an N2 / CH4 system, selectively adsorbs N2, and is high in separation ratio and good in stability.

The invention discloses a method for synthesizing tetrahydrofuran from furfural in one step and a preparation method of a catalyst for the tetrahydrofuran. The catalyst is a bimetallic catalyst, bimetallic is M1 and M2, M1 is Pd, and M2 is selected from one of Pt, Rh, Ru, Ni, Cu, Co, Mn and Ce; the catalyst comprises an active component and a carrier, the bimetallic is the active component, and the carrier is selected from at least one of activated carbon, silicon dioxide, aluminum oxide, magnesium oxide, an S-1 molecular sieve, a ZSM-5 molecular sieve, a Beta molecular sieve, an MOR molecular sieve and a Y molecular sieve; based on the total weight of the catalyst, the loading capacity of M1 is 0.5-3.5%, and the loading capacity of M2 is 0.5-3.5%. The catalyst provided by the invention can be used in a reaction for preparing tetrahydrofuran through furfural hydrogenation, and can improve the conversion rate of furfural and the selectivity of tetrahydrofuran.

The invention discloses an acetonitrile hydrogenation catalyst and a preparation method and application thereof. The acetonitrile hydrogenation catalyst is a transition metal modified Pt supported catalyst. A transition metal precursor adopted in the transition metal improvement is an oxide containing transition metal elements; the transition metal element is selected from at least one of titanium, vanadium, manganese, iron, cobalt, nickel and copper; the acetonitrile hydrogenation catalyst also comprises a carrier; the carrier is selected from at least one of gamma-Al2O3, SiO2, an MOR molecular sieve and a ZSM-5 molecular sieve. The catalyst can effectively catalyze acetonitrile hydrogenation to prepare ethylamine under mild reaction conditions. The supported catalyst provided by the invention has excellent reaction performance such as high acetonitrile conversion rate in acetonitrile hydrogenation reaction, the reaction condition is mild, the operation is simple, and the catalyst is easy to prepare and can be recycled.

The invention discloses a method for preparing fuel from waste polyolefin through noble-metal-free low-temperature aromatization, which comprises the following steps: in the atmosphere of synthesis gas, carrying out catalytic cracking on polyolefin serving as a raw material by adopting a binary mixed catalytic system to obtain aromatic hydrocarbon; the binary mixed catalytic system comprises Zr-ZnO and a molecular sieve; the catalytic cracking temperature is less than or equal to 300 DEG C. According to the low-temperature aromatization method disclosed by the invention, methanol is generated in situ through the synthesis gas, and the methanol and olefin generated by polyolefin cracking are subjected to Prins reaction, so that the aromatization reaction can be realized at the pyrolysis temperature far lower than that in the prior art, precious metals are not needed, the additional value and the application range of a plastic recovery product are greatly enhanced, and the method is suitable for industrial production. And the cost of the recovery process is reduced.

The invention provides an organic waste gas treatment device based on zeolite molecular sieve adsorption and desorption treatment. The organic waste gas treatment device comprises an efficient pretreatment unit, a composite zeolite molecular sieve adsorption tower group, a plasma-assisted microwave-hot air regeneration unit, a multi-mode tail gas treatment unit, a digital twin intelligent regulation and control system and a modular expansion interface. By integrating the high-precision VOCs analyzer, the self-adaptive airflow controller, the infrared spectrometer, the multi-channel heat recoverer, the high-performance edge computing server and the intelligent pneumatic valve system, the optimized processing method realizes accurate execution of a formula, the VOCs removal rate is remarkably increased, and carbon loss and energy consumption are reduced. The method has the remarkable advantages in the aspects of VOCs removal rate, zeolite regeneration efficiency, energy consumption control and operation cost, meanwhile, through deep intelligent regulation and multi-mode treatment, the efficient, stable and low-cost VOCs treatment requirements under complex working conditions are met, and an innovative solution is provided for industrial waste gas treatment.

The invention discloses a Pt-loaded hierarchical pore HY molecular sieve double-effect catalyst and a preparation method and application thereof.The preparation method comprises the steps that firstly, an acid solution and an HY molecular sieve are mixed, heated and stirred, and the hierarchical pore HY molecular sieve is obtained; then, Pt salt is loaded on the hierarchical pore HY molecular sieve through an impregnation method, and the hierarchical pore HY molecular sieve is dried, calcined and then reduced. The concentration of the acid solution is not higher than 0.1 mol / L; the catalyst is used for hydrocracking of polyethylene or polypropylene. According to the Pt-loaded hierarchical pore HY molecular sieve double-effect catalyst disclosed by the invention, Pt atoms have excellent C-H bond activation capability, meanwhile, the hierarchical pore HY molecular sieve carrier has an open connection mesoporous structure and an acid site, and the mesoporous structure constructed by acid pickling and dealumination is beneficial to diffusion of a reaction intermediate and improvement of the yield of a liquid product; more orifice acid can be exposed by surface erosion, so that the initial cracking of reaction raw materials is facilitated, and the catalytic performance is improved.

The invention discloses an oxygen consumption self-adaptive regulation and control method and system for a medical molecular sieve oxygen generation system, and belongs to the technical field of control. In the embodiment of the invention, demand dynamic fluctuation and environment change are dealt with through a data fusion and collaborative prediction mechanism, and meanwhile, the performance attenuation state of a molecular sieve is brought into an operation strategy optimization target; dynamic adaptation of oxygen demand prediction, performance evaluation and operation regulation and control is achieved, and the overall operation reliability and economical efficiency of the system are improved. Besides, the characteristics are combined to form a technical scheme for regulating and controlling the oxygen consumption of the medical molecular sieve oxygen generation system, the core of the technical scheme is to solve the coupling problem of demand fluctuation and environmental influence through a collaborative optimization mechanism driven by multi-source data, and technical support is provided for collaborative optimization of oxygen supply stability, equipment service life and energy consumption efficiency.

The invention provides a method for rapidly preparing an SSZ-13 molecular sieve membrane based on a double-template system, and belongs to the field of preparation and application of molecular sieve membrane materials. The polymer ammonium is introduced into the sol and seed crystal suspension, so that the nucleation and crystallization process in the synthesis system is obviously accelerated, the traditional synthesis time can be shortened by 50% or above, and the rapid growth of the SSZ-13 seed crystal on the surface of the porous carrier is realized. Based on the synergistic effect of the double template agents, the preparation repeatability of the SSZ-13 molecular sieve membrane is effectively improved, and large-scale application of high-quality membrane products is facilitated. The SSZ-13 molecular sieve membrane shows excellent separation performance in CO2 / CH4 mixed gas, and has remarkable industrial application value in the field of natural gas decarburization.

The invention belongs to the technical field of wastewater treatment, and particularly relates to a composite material as well as a preparation method and application thereof. According to the composite material, blended hydrogel of sodium alginate and polyvinyl alcohol is used as a matrix, zeolite molecular sieves, activated charcoal and zero-valent iron particles are embedded into the matrix to form microspheres, sulfate reducing bacteria are immobilized on the surfaces of the microspheres, the composite material is directly added into a mine water anaerobic reactor, the sulfate radical removal rate exceeds 92%, and the sulfate radical removal rate exceeds 92%. Heavy metals such as Cu, Pb and Cr in the mine water can be synchronously precipitated, and the treatment efficiency and stability of the anaerobic system are remarkably improved.

The invention provides an oriented ultrathin FER zeolite molecular sieve membrane as well as a preparation method and application thereof. The preparation method comprises the following steps: firstly, synthesizing a monodisperse FER zeolite nanosheet with a high length-depth ratio through a hydrothermal method; preparing a seed crystal liquid, and coating the surface of a porous carrier with the seed crystal liquid to form an oriented seed crystal layer; and carrying out hydrothermal epitaxial growth in a secondary growth solution. Through innovative design of seed crystal synthesis and epitaxial growth, the FER zeolite membrane prepared by the method has a structure with high alpha-axis preferred orientation, submicron controllable thickness, compactness and no defect. The membrane can be used for accurately screening gas molecules with small size difference by utilizing six-membered ring pore channels uniformly arranged along an a axis. When helium and methane or carbon dioxide are separated, the membrane shows permeation flux and separation selectivity far superior to those in the prior art, provides a brand new technical approach for efficient and low-energy-consumption recovery of helium and other high-value gases in the industry, and has great industrial application value.

The invention discloses a preparation method of a nano HZSM-5 molecular sieve, and belongs to the technical field of nano molecular sieve preparation, the preparation method comprises the following steps: 1, adding a silicon source, an aluminum source and a template agent into a supercritical crystallization reaction kettle, heating, stirring, and carrying out a melting reaction on the raw materials to obtain a seed crystal mixed material; introducing absolute ethyl alcohol into the seed crystal mixed material obtained by the melting reaction, heating, stirring, and carrying out crystallization reaction to obtain a reaction product; and cooling, washing, drying and roasting the obtained reaction product to obtain the nano HZSM-5 molecular sieve. According to the present invention, the melting reaction and the supercritical ethanol crystallization reaction technology are introduced into the preparation of the nanometer HZSM-5 molecular sieve for the first time, and the prepared nanometer HZSM-5 molecular sieve has advantages of small grain size, uniform distribution, large specific surface area and high yield.

The invention relates to an aromatic hydrocarbon isomer adsorbent containing a modified X-type molecular sieve. The outer surface area of the modified X-type molecular sieve is 9.5-19m < 2 > / g, and the sum of the pore volume of mesopores and the pore volume of macropores is 6%-18% of the total pore volume. The p-xylene adsorbent comprises 88-95% by mass of a modified X-type molecular sieve, 4-11% by mass of a crystal transformation X-type molecular sieve and 1-3% by mass of a matrix. The invention also relates to a preparation method of the adsorbent and application of the adsorbent in adsorption separation of p-xylene from mixed C8 aromatic hydrocarbons.

The invention relates to the field of caprolactam production, and discloses a green and efficient production process and device. The process comprises the following steps: continuously oximating cyclohexanone and hydroxylamine in a microreactor under the catalysis of mesoporous silica solid acid; carrying out gas phase rearrangement on cyclohexanone-oxime in the presence of a ZSM-5 molecular sieve under the assistance of microwaves; coupling, rectifying and purifying the crude product through a four-stage molecular sieve membrane; and performing catalytic cracking on the by-product to obtain N2 / H2O and recycling. The device comprises a micro-reaction unit, a microwave-radial reactor, a membrane coupling rectifying tower group and a tail gas cracking unit. Zero emission of ammonium sulfate is achieved, the product purity is larger than or equal to 99.95%, and energy consumption is reduced by 45%.

The invention discloses a method for preparing high-purity nickel acetate from crude nickel carbonate in the technical field of nickel compound purification, which comprises the following steps: mixing the crude nickel carbonate with deionized water to obtain a suspension, and adding glacial acetic acid to react to obtain a nickel acetate solution; then a specially-made hierarchical-pore titanium silicalite molecular sieve loaded bimetallic nanocluster material is added for purification treatment, the material is obtained through precise preparation, the method comprises the steps of carrier modification, bimetallic loading, hydrophobic modification, activation balance and the like, and the material has excellent impurity adsorption capacity and chemical stability; carrying out concentration crystallization and solid-liquid separation on the purified solution to obtain wet nickel acetate crystals; the mother liquor is subjected to adsorption treatment again, crystals in the mother liquor are recycled, and finally all the crystals are combined and dried to obtain a high-purity nickel acetate product. The process is simple and efficient, the purity of the prepared nickel acetate exceeds 98.5%, the content of each impurity is superior to the industrial standard, and the mother liquor can be recycled, is environment-friendly and is suitable for industrial production.

The utility model belongs to the technical field of carbon molecular sieve production equipment, and discloses a flower mud material crushing conveyor line which comprises crushing equipment, a bottom belt conveyor, an inclined lifting belt conveyor and a vibrating screen, a sunken main pit is formed in the workshop ground of a flower mud crushing station, the crushing equipment is installed in the main pit, and the inclined lifting belt conveyor is installed in the main pit. A feeding hopper of the crushing equipment is removed towards the outer side wall, and the bottom of the feeding hopper is connected through a horizontal steel plate, extends and is connected to the workshop ground in a lap joint mode. The bottom belt conveyor is horizontally connected below a discharge port of the crushing equipment, the bottom end of the inclined lifting belt conveyor is connected at the discharge end of the bottom belt conveyor, and the high end of the inclined lifting belt conveyor inputs crushed flower mud materials to a feed port of the vibrating screen. According to the flower mud material crushing conveying line, crushing equipment is installed in a pit mode, the feeding difficulty is lowered, and the operation safety is improved.

The invention provides an SSZ-13 molecular sieve as well as a preparation method and application thereof, the preparation method comprises the following steps: mixing activated silica-alumina minerals, SSZ-13 seed crystals, a silicon source, a template agent and a second alkali source to obtain dry glue, and then carrying out crystallization treatment on the dry glue in the presence of water vapor to obtain the SSZ-13 molecular sieve. According to the preparation method, a solvent is not adopted, a small amount of deionized water is used for providing a steam phase, the utilization rate of the raw materials can be increased, the high solid yield is obtained, the loss of a solid phase is reduced, no alkaline wastewater is generated, and the synthesis cost of the SSZ-13 molecular sieve is remarkably reduced. When the SSZ-13 molecular sieve prepared by the method is used for CO2 / CH4 adsorption separation, the SSZ-13 molecular sieve has relatively high separation selectivity.

The application provides a method for grading diesel deep hydrodesulfurization catalysts, which comprises the following steps: loading catalysts containing AlPO4-5 phosphorus aluminum molecular sieves and catalysts containing ETS-10 titanium silicon molecular sieves in the upper and lower parts of a fixed bed hydrogenation reactor respectively according to a loading mass ratio of 1:3-3:1, so that diesel is subjected to hydrodesulfurization reaction through catalysts containing AlPO4-5 phosphorus aluminum molecular sieves first and then through catalysts containing ETS-10 titanium silicon molecular sieves; the carrier of the catalysts containing AlPO4-5 phosphorus aluminum molecular sieves comprises AlPO4-5 phosphorus aluminum molecular sieves and aluminum oxide powder, the carrier of the catalysts containing ETS-10 titanium silicon molecular sieves comprises ETS-10 titanium silicon molecular sieves and aluminum oxide powder, and the active components of the two kinds of catalysts respectively comprise a combination of two or three of nickel oxide, molybdenum oxide and cobalt oxide. The sulfur content of the hydrogenated diesel obtained through the method can be as low as 10 μg / g or below.

The invention discloses an MWW molecular sieve and a preparation method thereof, and the preparation method comprises the following steps: (a) mixing an alkali source, water, an aluminum source, a template agent and a silicon source to form a mixture A; (b) adding nano cellulose into the mixture A to form a mixture B, and pretreating, crystallizing and drying the mixture B to obtain the MWW molecular sieve. The preparation method disclosed by the invention is simple and convenient, easy to industrialize and wide in application prospect, and the MWW molecular sieve with the single-layer structure is prepared. The MWW molecular sieve with a single-layer structure can expose more active sites, promotes diffusion and mass transfer, shows excellent performance in many reaction processes, and particularly shows high activity and stability in a reaction with macromolecules as a substrate.

The invention discloses a preparation method of a mesoporous Zn-ZSM-5 molecular sieve for preparing aromatic hydrocarbon from methanol, and belongs to the technical field of synthesis of inorganic materials. Aiming at the problems that a conventional mesoporous Zn / ZSM-5 molecular sieve catalyst Zn blocks orifices, the mesoporous structure is disordered, the molecular sieve solid yield is low, a molecular sieve framework is seriously damaged and the like, the preparation method comprises the following steps: uniformly mixing zinc gluconate with an aluminum source, a silicon source and a template agent, putting the mixture into a closed reaction container, carrying out hydrothermal crystallization, and sequentially washing, drying and roasting to obtain the mesoporous Zn / ZSM-5 molecular sieve catalyst. The sodium type molecular sieve is obtained; the preparation method comprises the following steps: carrying out multiple ion exchange on a sodium type molecular sieve by using an ammonium chloride solution, and sequentially carrying out suction filtration, washing, drying and roasting to obtain the mesoporous Zn-ZSM-5 molecular sieve. According to the preparation method of the methanol-to-aromatic hydrocarbon Zn / ZSM-5 molecular sieve provided by the invention, the obtained molecular sieve is used in the methanol-to-aromatic hydrocarbon process, and has the characteristics of high carbon deposition resistance, high aromatic hydrocarbon selectivity, low Zn wastage rate and the like.

The invention discloses a Fe-Beta molecular sieve for N2O catalytic decomposition and a preparation method of the Fe-Beta molecular sieve. According to the method, chitosan and metal Fe < 3 + > ions are complexed to form a chitosan Fe < 3 + > complex, and then the complex, a silicon source, an aluminum source and a template agent are used as raw materials to prepare the Fe-Beta molecular sieve in one step through a hydrothermal method. Hydroxyl, amino and other groups rich in a chitosan molecular chain can effectively complex metal Fe < 3 + > ions to form a stable chitosan Fe < 3 + > complex, and the stable chitosan Fe < 3 + > complex is used as a Fe source to realize uniform dispersion of Fe species in the molecular sieve and effectively reduce formation of FexOy clusters and Fe2O3 nanoparticles, so that the N2O decomposition catalytic performance of the Fe-Beta molecular sieve is improved. Inorganic alkali metal ions are not introduced, so that a large amount of ammonia-nitrogen wastewater generated in a subsequent tedious ammonium exchange process can be avoided, the synthesis period is effectively shortened, and energy consumption, material consumption and environmental pollution are reduced.

The invention provides a Pt-Sn bimetallic catalyst and a preparation method and application thereof.The preparation method comprises the steps that 1, a Y molecular sieve is placed in a mixed solution of KOH and methyl alcohol, centrifugation and washing are conducted till the Y molecular sieve is neutral after stirring, drying and roasting are conducted, and a non-acid KY molecular sieve is obtained; the silica-alumina ratio of the Y molecular sieve is 3-100; 2) taking the non-acidic KY molecular sieve as a carrier, and loading Sn by adopting an atomic layer deposition technology to obtain a Sn-modified non-acidic KY molecular sieve; and 3) loading Pt by using the Sn-modified non-acidic KY molecular sieve as a carrier and adopting an atomic layer deposition technology to obtain the Pt-Sn bimetallic catalyst. According to the preparation method provided by the invention, spatial distribution of Pt and Sn is accurately regulated and controlled by combining an atomic layer deposition technology, so that the electronic state of Pt species is adjusted, alkane is promoted to be dehydrogenated into an olefin intermediate, and the aromatization catalytic activity and the aromatic hydrocarbon selectivity of alkane are improved.

The invention discloses a method for performing tar steam reforming by coupling low-temperature plasma with a nickel-loaded hydrogen type molecular sieve composite catalyst. The method comprises the following steps: preparing the nickel-loaded hydrogen type molecular sieve composite catalyst; the mass of Ni in the nickel-loaded hydrogen type molecular sieve composite catalyst accounts for 5-30% of the mass of the catalyst; introducing tar and water vapor into a dielectric barrier discharge plasma reactor filled with the nickel-loaded hydrogen type molecular sieve composite catalyst; starting the dielectric barrier discharge plasma reactor, and carrying out a tar steam reforming reaction; wherein the temperature of the tar steam reforming reaction is 150-525 DEG C, and the power of the tar steam reforming reaction is 30-90 W. The catalyst disclosed by the invention is coupled with a low-temperature plasma technology, so that good tar reforming performance, target product selectivity and system stability are realized.

The invention discloses a self-forming A-type molecular sieve foam material taking rectorite as a raw material as well as a preparation method and application thereof, and belongs to the field of green synthesis of molecular sieve foam materials. The preparation method comprises the following steps: 1) grinding and sieving rectorite to obtain rectorite powder, and calcining at 950-1000 DEG C for 2-4 hours to prepare activated rectorite powder as a solid-phase raw material; and 2) mixing the solid-phase raw material and an alkaline activator according to a mass ratio of (0.82-1.13): 1, fully and uniformly stirring, adding a seed crystal inducer, then adding a foaming agent, uniformly stirring, pouring into a mold, sealing, and crystallizing to obtain the self-forming A-type molecular sieve foam material. According to the invention, only the natural mineral rectorite is utilized, no chemical reagent is added as a silicon-aluminum source, the self-forming A-type molecular sieve foam without a binder is obtained, and when the foam is used as an adsorbent, the problems of pore channel blockage, molecular sieve effective site dilution, guest molecule transmission limitation and the like can be effectively avoided.