1180 results about "Pyrene" patented technology

An organic electroluminescence device including a pair of electrodes and one or more organic compound layers therebetween, the one or more organic compound layers comprising an emitting layer,

wherein the emitting layer includes a pyrene derivative represented by the following formula (1) and the content of the pyrene derivative in the emitting layer is 50 to 100 wt %;

The present invention provides ratiometric fluorescent pH sensors for non-invasive, continuous monitoring of pH in such applications as fermentation processes. The ratiometric fluorescent pH sensors comprise a fluorescent dye that exhibits a shift in excitation wavelength with a corresponding shift in pH in the local environment of said fluorescent dye. Ratiometric measurements of the emission intensities at dual excitation maxima correlate to pH. Also provided is a fluorescent dye 6-methacryloyl-8-hydroxy-1,3-pyrene disulfonic acid (MA-HPDS). Further provided are systems and methods to non-invasively and continuously monitor pH.

An organic electroluminescence device of the present invention comprises a light emitting layer held between electrodes, the light emitting layer containing at least a host material and a dye or pigment. The light emitting layer further comprises an additive exhibiting an absorption edge of which energy level is higher than that of an absorption edge of the dye or pigment, but the difference of the energy levels being less than 120 kJ/mol, having no lone pair, and including at least two aromatic rings. The additive of the present invention is selected from a group consisting of phenyl-substituted anthracenes, naphthyl-substituted anthracenes, naphthyl-substituted naphthalenes, pyrenes, and a naphthacene derivatives.

A pyrene compound is provided. The pyrene compound is represented by Formula 1:

wherein A₁ and A₂ are as defined in the specification. Further provided is an organic electroluminescent device using the pyrene compound. The organic electroluminescent device has high color purity of blue light and shows long life characteristics. Therefore, the organic electroluminescent device is suitable for use in displays and lighting systems.

The invention relates to a preparation method of multicolor fluorescence fluorescent graphene quantum dots. According to the invention, pyrene with a low price is adopted as a precursor; oxygen functionalization is carried out on the surface of pyrene grains under low temperature; and low-temperature hydrothermal dehydrogenation, growth, and in-situ surface functionalization are carried out under the effect of a catalyst hydrazine and ammonia water. With the method provided by the invention, synthesized quantum dots can be stably dispersed in water. The quantum dots are brown under low concentration, and are approximately black under high concentration (the higher the concentration, the deeper the color). Light emitting color or wavelength is adjustable (blue to yellow, 450-535nm). The quantum dots provided by the invention show attractive application prospects in high-tech fields such as environmental protection, bio-nano technology, new energy, nano-device, and the like. The synthesizing method is simple and environment-friendly, and energy consumption is low. The method is suitable for industrial scale-up.

This organic electroluminescence element has an organic light-emitting layer between a positive electrode and a negative electrode, wherein the organic light-emitting layer contains a 1,3,6,8-tetrasubstituted pyrene compound having a specific structure as an organic light-emitting layer forming material. Provided are an organic light-emitting layer forming material that emits blue light with a high color purity, has a high luminous efficiency, and is stable for a long duration of operation, when used singly or as a guest, an organic EL element having a high luminous efficiency and a long operation lifetime, and a high-performance organic EL display that has a high luminous efficiency and a long operation lifetime.

The invention discloses a calixarene additive capable of simultaneously and optionally reducing benzo (a) pyrene and phenol contents in cigarette smoke and an application method thereof. In the invention, deep-cavity P-(1-(4-hydroxyphenyl)-1-methylethyl) calyx (8) aromatic compound is selected as the additive material, and the compound is added in a common and conventional filter tip which bettercan be suitable for a compound filter, with the additive amount being arbitrarily adjusted according to the needs. By using the molecular recognition function and the cavity size select effect of thecalyx (8) aromatic compound, the additive can be optionally combined with the benzo (a) pyrene and phenol molecules in the cigarette smoke. When the additive is added into the filler with the amount of 10mg/per cigarette, 33.2 percent of benzo (a) pyrene content and 41.4 percent of phenol content in the cigarette smoke can be simultaneously reduced, and other chemical compositions in the smoke arebasically not influenced, thus achieving the goal of selective harm reduction.

It is an object of the present invention to provide a pyrene derivative that is unlikely to crystallize and is superior in quality in the case of forming a film. In addition, it is an object of the present invention to provide a light-emitting element from which stable light emission can be obtained for a long stretch of time by using the pyrene derivative.

A pyrene derivative represented by the general formula (1) is synthesized. By using vacuum deposition to deposit this material, a light-emitting element from which stable light emission can be obtained efficiently for a long stretch of time can be obtained.

An organic transistor is capable of emitting light at high luminescence efficiency, operating at high speed, handling large electric power, and can be manufactured at low cost. The organic transistor includes an organic semiconductor layer between a source electrode and a drain electrode, and gate electrodes shaped like a comb or a mesh, which are provided at intervals approximately in the central part of the organic semiconductor layer approximately parallel to the source electrode and the drain electrode. The organic semiconductor layer consists of an electric field luminescent organic semiconductor material such as compounds of naphthalene, anthracene, tetracene, pentacene, hexacene, a phthalocyanine system compound, an azo system compound, a perylene system compound, a triphenylmethane compound, a stilbene compound, poly N-vinyl carbazole, and poly vinyl pyrene.

Asymmetric pyrene derivatives having specific structure. An organic EL device comprising at least one organic thin film layer including a light emitting layer sandwiched between a pair of electrode consisting of an anode and a cathode, wherein the organic thin film layer comprises at least one kind selected from the aforementioned asymmetric pyrene derivatives singly or as a component of mixture thereof. An organic EL device exhibiting a great efficiency of light emission and having a long lifetime, and also asymmetric pyrene derivatives for realizing the organic EL device are provided.

Compositions and systems are provided for the high efficiency quenching small water-soluble oligomers, or oligofluors, of from about 1-10 kd in size, where the oligofluors comprise multiple excimeric or exciplex forming fluorophores arranged on a scaffold, which are efficiently quenched by a quencher entity linked to the oligomer through a cleavable moiety. Fluorophores of interest include, without limitation, aromatic fluorophores such as pyrenes, e.g. benzopyrene, perylene, pyrene, etc. In some embodiments the oligofluor/quencher combination provides for a Stern-Vollmer constant (K_SV) of greater than about 10⁶ M⁻¹, and may be greater than about 10⁷ M⁻¹, greater than about 10⁸ M⁻¹, or more. In some embodiments of the invention, the scaffold is a phosphodiester/glycoside backbone, e.g. an analog of a polynucleotide. The system of oligofluors and quenchers can be used in qualitative and quantitative screening and detection methods to detect any enzymatic, chemical or catalytic activity that can cleave the moiety between the quencher and scaffold.

The object of the present invention is to provide organic electroluminescent elements that are excellent in luminous efficiency, luminance, and color purity and exhibit long lifetime. The organic EL elements according to the present invention comprise an organic thin layer between a positive electrode and a negative electrode, and the organic thin layer comprises a 1,3,6,8-tetrasubstituted pyrene compound expressed by the formula (1) as the light emitting material,

• • wherein R¹ to R⁴ in the formula (1) may be identical or different each other, and are each a group expressed by the formula (2):
  • wherein R⁵ to R⁹ in the formula (2) may be identical or different each other, are each a hydrogen atom or a substituted group; and at least one of R⁵ to R⁹ is a substituted or unsubstituted aryl group.

The invention relates to a method for functionalizing a polymer on the surface of nano graphene oxide. The method comprises the following specific steps: preparing graphene oxide from natural graphite powder by an improved Hummers method, utilizing methoxy polyethylene glycol and pyrene acids to carry out esterification to generate polyethylene glycol with pyrenyl as the terminal group, and finally grafting the polyethylene glycol with pyrenyl as the terminal group on the surface of graphene oxide through pi-pi interaction between pyrenyl and the surface of graphene oxide, thus obtaining the graphene oxide with the functionalized polymer on the surface. The solubility of the prepared graphene oxide with the functionalized polymer on the surface is greatly improved. The method has the following advantages: a main process adopted in the experiment is as follows: a polymer with a complex structure is designed and prepared in advance and then is grafted on the graphene oxide, and the grafting reaction can be carried out at normal temperature and pressure, so the whole experiment process is very simple and convenient. Therefore, the study provides a direct method for modifying the graphene oxide and preparing the functionalized graphene oxide-polymer complex to form a new inorganic-organic hybrid material, thereby promoting the development and application of graphene oxide-based materials.

The invention discloses a grapheme type fiber cigarette filter and a preparation method thereof. The filter comprises a fiber carrier, wherein the fiber carrier is provided with a grapheme type material for absorbing harmful components in smoke. The filter loads the grapheme type material on a carbon fiber or acetate fiber carrier; and the carrier is added in the filter by adopting the binary filter production mode in the existing industries to produce a compound filter for absorbing harmful substances in the smoke which is generated when cigarettes are smoked. The filter applies unique phi absorption characteristics and higher surface active atom ratio of novel two-dimensional nanometer materials to efficiently absorb benzo [a] pyrene, volatile aldehyde ketone type cancer promoting molecules, phenol and HCN (Hydrogen Cyanide) under the condition of smaller adding quantity, so that the filter is environment-friendly and has no additional poison; as the amount is small and the effect is high, the harm of the cigarettes to human bodies is reduced under the condition of not influencing the inherent sensory quality of the cigarettes. And at the same time, the method has the advantages of simple technique, large-scale production and low cost, and has wide application foreground in the cigarette field of harm reduction and tar reduction.

The invention relates to a fluorescent ion probe (I) with high selectivity and high sensitivity in detection and the application of the fluorescent ion probe in identifying and detecting heavy metal ion and transition metal ion, wherein, the Y is an organic conjugate group with fluorescence transmitting function such as pyrene, naphthalene, 4-amidogen-1, 8-naphthyl imide, Dan sulfonamide, anthracene, carbazole, benzimidazoins, benzoxazoles, boron fluoride bipyrrole (BODIPY), fluorescein, 3, 4, 9, 10-perylenetetracarboxylic diimide or rhodamine B; the X is acylamino group, sulfoamino group or ester group. The fluorescent ion probe uses the fluorescence peak of fluorescence chromophore aggregate as the response signal to identify metal ion, thereby effectively avoiding the quenching effect of transition metal ion and heavy metal ion on fluorophore; moreover, the fluorescent ion probe realizes selective identification of heavy metal ion and transition metal ion in various solvents and aqueous solution in particular.

The invention relates to a preparation method of platinum nanoparticle loaded graphene, comprising the following steps: (1), ultrasonically disperse restored graphene in a glycol solution, and adding the glycol solution of 1-pyrene methylamine, wherein the ratio (mg: ml: ml) of the graphene to the glycol to the glycol solution of the 1-pyrene methylamine is 1: (8-20): (1-1.5), and the concentration of the glycol solution of the 1-pyrene methylamine is 10<-3> M; stirring for 20-120 minutes to assemble the 1-pyrene methylamine on the surface of the graphene; and (2), adding Nml of a 0.048M chloroplatinic acid glycol solution, wherein the ratio (mg: ml) of the graphene to the Nml is 1: (0.8-1.5); adjusting the pH value of the glycol solution in the step (1) to be 8-9 with 0.1 M sodium hydroxide, continuing to stir, reacting for 2 hours in the oil bath at the temperature of 160 DEG C to obtain the high-density platinum nanoparticle loaded graphene, and cleaning and performing freeze-drying.

The present invention relates to an organic thin-film light emitting device containing an organic compound represented by formula (1) and a donor compound. the light emitting device ca achieve both of the low-voltage driving operation and high luminance efficiency.

YA¹-Ar)_{n<sup2>1</sup2>}  (1)

(Y represents either substituted or unsubstituted pyrene, or substituted or unsubstituted anthracene. A¹ is selected from the group consisting of a single bond, an arylene group, and a hetero arylene group. Ar is selected from the group consisting of a carbazolyl group, a dibenzofuranyl group, and a dibenzothiophenyl group. These groups may be substituted or unsubstituted, and n¹ is an integer of 1 to 3.)

The invention relates to a cigarette additive and cigarette prepared by the additive. The additive can lower the tar contents in cigarette flue gas and can selectively absorb harmful substances such as polycyclic aromatics, phenols and the like in cigarette flue gas. The additive is carbon nanometer pipe preparation dispersed in water solution of surface active agent. The preparation is taken as cigarette cut tobacco additive and is sprayed on tobacco leaves in the cigarette production material feeding technique process according to 1 to 25% of the weight of the cut tobacco, and carbon nanometer pipes are evenly and dispersedly absorbed on the surface of the cut tobacco after silk drying processing. The additive can remove 6.2-38.8% of polycyclic aromatics such as Benzo(a)pyrene and the like and 3.0 to 28.3% of carbolic acid and catechol in cigarette main flow flue gas, and also can lower the tar contents in flue gas for 3.4 to 20.4%, and the original color and flavor of cut tobacco are not changed basically.

The invention discloses a raman reinforced substrate material, preparation and application methods thereof. A preparation method comprises the following steps: firstly, preparing a TiO2 nanometer tube array; depositing graphene on the TiO2 nanometer tube array; and lastly, dropwise adding nanometer silver sol to the surface of a substrate, thereby forming a compound material after the nanometer silver sol is dried. The convenient and quick detection for various harmful substances in an environmental sample, especially for benzo (a) pyrene, can be realized by using a raman reinforced substrate. A new method for detecting the benzo (a) pyrene is provided according to an application method of the raman reinforced substrate material. Compared with a traditional method, a surface reinforced raman detection method using the raman reinforced substrate material has the advantages of short detection time and simple sample treatment.

The invention discloses a sulfur-doping graphene quantum dot, a preparation method of the sulfur-doping graphene quantum dot and application of silver ion detection. The preparation method comprises the following steps of dissolving a carbon source compound and a sulfur source compound into water; performing a hydro-thermal reaction; preparing the sulfur-doping graphene quantum dot, wherein the carbon source compound is 1,3,6-trinitro pyrene, and the sulfur source compound is sulfydryl fatty acid with the carbon atom number being 3 to 4. The prepared sulfur-doping graphene quantum dot has good fluorescence property; when the pH is greater than 4, the stable fluorescence emission is realized; the excitation wavelength independence is realized; when the excitation wavelength of 320 to 360nm is used for excitation, the fluorescence emission peak position is not changed; the result proves that the sulfur-doping graphene quantum dot synthesized by the method provided by the invention has high quality; the obvious selective recognition capability on silver ions is realized; the fast detection on trace silver ions can be realized.

Disclosed is a compound of Formula 1 and an organic light emitting device using the same.

In Formula 1, R1, R2, and R3 each independently is selected from the group consisting of a phenyl group, an 1-naphthyl group, a 2-naphthyl group, and a pyrene.

The invention provides a preparation method of a metal organic framework material. The metal organic framework material is synthesized by virtue of a hydrothermal method or a heating reflux method and is a metal organic framework MOF(Fe) material. The invention also discloses a cigarette filter tip added with the metal organic framework MOF(Fe) material. According to the preparation method and application of the metal organic framework material, by adding the metal organic framework MOF(Fe) material into the cigarette filter tip, the contents of harmful ingredients such as ammonia and benzo[a]pyrene in cigarette mainstream smoke can be effectively decreased; the environmental friendliness is achieved and the safety to a human body after the material is added into the cigarette is ensured. Meanwhile, the metal organic framework MOF(Fe) material has super-strong adsorption capacity to organic dye pollutants and is worthy of popularization and application.

The invention relates to a composite filter tip containing a biological composition. A filament bundle filter stick of the filter tip comprises the biological composition, and after the biological composition is stuck to a carrier, when the filament bundle filter stick is formed, the carrier to which the biological composition is stuck is added into the filament bundle filter stick, wherein the biological composition comprises cobalt porphyrin and ginkgo leaf extract with the mass ratio being 1:1-80. The filter tip can not only obviously reduce the release amounts of harmful ingredients such as free radical, benzo[a]pyrene, peculiar nitrosamines of tobacco, and the like in smoke of cigarettes but also can enable the acute toxicity, subchronic toxicity, cytotoxicity and mutagenicity of the cigarettes to be lower as compared with comparison cigarettes, and at the same time has no adverse effects on the smoking quality of the cigarettes.