412 results about "Graphene quantum dot" patented technology

The invention relates to the technical field of high polymer materials, in particular to ethylene-vinyl acetate copolymer modified polypropylene high-toughness plastic particles and a preparation process thereof. The composite material is prepared from the following raw materials in parts by weight: 60 to 80 parts of polypropylene, 15 to 30 parts of ethylene-vinyl acetate copolymer, 5 to 10 parts of maleic anhydride-2-ethylhexyl acrylate copolymer grafted ethylene-vinyl acetate copolymer, 3 to 8 parts of nano silicon dioxide / graphene quantum dot composite filler, 5 to 12 parts of polyolefin elastomer, 0.5 to 2 parts of antioxidant and 0.5 to 2 parts of lubricant. The content of vinyl acetate in the ethylene-vinyl acetate copolymer is 20-33 wt%, the composite filler is modified through a silane coupling agent KH-560, the grafting rate of the grafted ethylene-vinyl acetate copolymer is 1.5-3.5 wt%, and the composite filler is prepared through a melt grafting method. Through multi-component collaborative design and process optimization, the low-temperature toughness, rigidity, heat resistance and aging resistance of the material are improved, the problems of rigidity and toughness imbalance, low-temperature brittleness, poor stability and the like of a traditional modification system are solved, and the material is excellent in comprehensive performance and wide in application range.

The invention belongs to the technical field of building materials, and discloses a preparation method of reflective heat-insulation waterproof real stone paint, which comprises the following three process stages: core layer synthesis, shell layer loading and real stone paint integration: coating a continuous SiO layer on the surface of nano TiO in situ to form TiO-coated SiO particles; graphene quantum dots and a hindered amine light stabilizer are loaded on the surfaces of TiOatSiO particles to form a composite functional filler; adding the composite functional filler into the acrylic emulsion base material in batches at a low speed, and adjusting the rheological property with the aid to obtain a finished product. The preparation process disclosed by the invention is completely compatible with an existing real stone paint industrial production line, does not need to add special equipment, and has excellent reflective heat insulation, heat preservation, water resistance, weather resistance and aging resistance and large-scale industrial feasibility; the technical problems of resin oxidative degradation caused by TiO photocatalytic activity, rapid attenuation of solar radiation reflectivity, failure of waterproof and hydrophobic performance and easiness in damage and stripping of a coating structure of the existing nano TiO-based reflective heat-insulation real stone paint are solved.

The invention provides photovoltaic copper paste, a preparation method thereof and application of the photovoltaic copper paste in preparation of solar cells, and relates to the technical field of photovoltaic cell manufacturing, and the photovoltaic copper paste comprises gradient micron-sized copper powder, a nano conductive reinforcing material, an organic binder, glass powder, a reinforcer and an optional additive; the reinforcing agent comprises an antioxidant, a nano interface reinforcing agent, a passivating agent and an optional corrosion inhibitor; wherein the nanometer interface reinforcing agent comprises one or more of aluminum oxide nanoparticles, antimony nanoparticles and graphene quantum dots; the passivating agent is prepared from benzotriazole and a silane coupling agent. According to the improved copper paste formula, the contact resistance performance and oxidation resistance can be improved, and the uniformity of grid lines is improved.

The invention relates to the technical field of biomedical materials, and discloses an electret electrostatic therapy membrane and a preparation process thereof.The electret electrostatic therapy membrane is prepared from, by mass, 15%-20% of fluorinated polyether ester, 10%-20% of a composite nano-fiber material, 10%-20% of a composite nano-fiber material, 10%-20% of a composite nano-fiber material and the balance water. 1%-2% of carboxymethyl chitosan; 2-5% of nano cerium oxide particles with the particle size of 50-100 nm; 0.5-1.0% of graphene quantum dots, the particle size of which is 5-10 nm; 1%-2% of sodium hyaluronate; the components are prepared into a film through an electrostatic spinning method, electret performance is given to the film through a charge injection process, finally, the film body is attached to a flexible silica gel adhesion layer, and the flexible silica gel adhesion layer is externally coated with a peelable protective film so that the structural integrity can be kept before the flexible silica gel adhesion layer is used. The composite membrane body disclosed by the invention shows excellent adhesion, charge activation capability and thermal response performance in applications of electrostatic therapy, dielectric assisted stimulation and the like, and has good multi-scene adaptability and clinical application potential.

The invention provides a flexible fluorescence sensor as well as a preparation method and application thereof. The flexible fluorescence sensor comprises TCTG particles and dual-network hydrogel, the TCTG particles are distributed in network pores of the dual-network hydrogel to form functional gel, the TCTG particles are formed by Ti3C2TxMXene nanosheets and graphene quantum dots, the dual-network hydrogel is formed by acrylamide and sodium carboxymethyl cellulose, and the TCTG particles are distributed in the network pores of the dual-network hydrogel to form functional gel. The functional gel is soaked in a hydrochloric acid glycol solution for treatment. The flexible fluorescence sensor provided by the invention can integrate the structural advantages of all the components, so that a synergistic coupling effect is possibly generated, a fluorescence detection function with excellent mechanical strength, frost resistance and high sensitivity is integrated into a multifunctional system, the food spoilage condition can be reliably monitored in real time under a harsh environmental condition, and the application prospect is wide. And health and economic risks caused by occupational exposure and environmental emission in an aquatic product supply chain are solved.

The invention provides a positive electrode active material and a preparation method thereof, a positive electrode, a battery and electric equipment, the positive electrode active material comprises lithium iron phosphate and graphene quantum dots, and the lithium iron phosphate comprises secondary particles formed by primary particles; the graphene quantum dots coat at least part of the surfaces of the primary particles. The positive electrode active material has relatively high electronic conductivity and ion mobility, and the low-temperature discharge performance of the battery can be effectively improved.

The invention relates to the technical field of coatings, in particular to an acrylate-epoxy resin composite coating and a preparation method thereof. According to the technical scheme, the coating is prepared from 25 to 35 parts of methyl methacrylate, 15 to 25 parts of butyl acrylate, 10 to 20 parts of epoxy resin E-5110, 8 to 15 parts of organic silicon modified acrylate prepolymer, 5 to 12 parts of fluorocarbon modified epoxy resin, 4 to 8 parts of core-shell structure corrosion inhibition nano container, 1 to 3 parts of functionalized graphene quantum dots and 4 to 10 parts of polyhedral oligomeric silsesquioxane maleimide modified amine curing agent. And 1-3 parts of a hindered amine light stabilizer. By integrating the core-shell structure corrosion inhibition nano container, the functionalized graphene quantum dots and the photo-thermal dual responsive curing agent component, the sensing, response and self-repairing of the coating on damage are realized, and long-acting corrosion resistance, weather resistance, bacteria resistance, mechanical property balance and intelligent maintenance are considered; and efficient and economical full-period protection is provided for equipment in an extreme environment.

The invention provides a magnetic confinement microwave plasma preparation method and system for coal-based graphene quantum dots, and relates to the technical field of graphene quantum dot preparation, and the method comprises the following steps: pretreating a coal raw material, removing impurities, and crushing the coal raw material to a preset particle size; detecting the coal quality parameters of the pretreated coal raw material, wherein the coal quality parameters at least comprise the contents of C, H and O elements; the coal quality parameters are input into a QYOA algorithm to be analyzed, and adjustment parameters of microwave power and reaction gas are obtained; feeding the pretreated coal raw material into a reaction cavity, and forming a three-dimensional confinement field in the reaction cavity through a magnetic confinement device; according to the method, magnetic confinement, microwave plasma, a QYOA algorithm and ultrasonic aftertreatment are organically combined to form a synergistic effect, dissociation of carbon clusters is promoted through the synergistic effect of the magnetic confinement and the microwave plasma, the yield of the coal-based graphene quantum dots is increased to 30% or above from less than 10% of a traditional method, the production efficiency is improved, and large-scale production is facilitated.

The invention belongs to the technical field of power cables, and particularly relates to an anti-bending flexible cable and a preparation method thereof.The cable sequentially comprises a conductor, an insulating layer, a buffer layer, a shielding layer and a protective layer from inside to outside, the insulating layer is divided into an inner layer, a middle layer and an outer layer in the radial direction, and the inner layer of the insulating layer comprises the following components in parts by weight; 100 parts of crosslinked polyethylene, 6-10 parts of amino-modified photoresponse graphene quantum dots, and 2-4 parts of a plasticizer DOS; 2-3 parts of amino modified photoresponse graphene quantum dots, 100 parts of crosslinked polyethylene and 2-4 parts of a plasticizer DOS; the protective layer comprises the following components in parts by weight; the insulation layer comprises 100 parts of shape memory polyurethane, 15-22 parts of composite microspheres and 0.5-1.0 part of a light stabilizer, and the insulation layer adopts a cross-linked polyethylene, amino modified light response graphene quantum dot gradient distribution and plasticizer system; and three-channel co-extrusion and three-section type ultraviolet curing are matched, so that inner layer under-crosslinking / outer layer over-crosslinking is avoided.

The invention discloses an antistatic agent for polyolefin film material production and a preparation method thereof. According to the invention, through reasonable molecular structure design, raw material selection and synthesis process optimization, the antistatic agent has multiple functions of high-efficiency antistatic property, oxidation resistance, antibacterial property, mechanical property enhancement and the like. The polyolefin material added with the multifunctional antistatic agent has good antistatic performance under different environmental conditions, and the oxidation resistance, the antibacterial property and the mechanical property are also remarkably improved. The antistatic agent has good adaptability with processing of a polyolefin film material and has wide application prospects and market competitive advantages, and the comprehensive performance of the polyolefin film material is remarkably improved through multi-component collaborative design. The composite system of the polyolefin quaternary ammonium salt and the graphene quantum dots strengthens the long-term effect of the antistatic effect, and meanwhile, the synergistic effect of the hindered phenol and the phosphite strengthens the antioxidant stability of the material in the processing and using processes.

The present invention combines a fluorescence sensor with an array to provide a fluorescence sensing array detection platform and a detection method for multiple plasticizers. The fluorescence sensing array detection platform includes a B-doped graphene quantum dot solution using N,N-dimethylformamide as a solvent and a B-GQDs solution using cyclohexane as a solvent; the fluorescence intensity of the B-GQDs solution with DMF as the solvent at the fluorescence characteristic peak obtained under ultraviolet light excitation at a wavelength of 350 nm, and the fluorescence data at 391 nm, 413 nm, and 434 nm are used as array points 1, 2, and 3; the fluorescence intensity of the B-GQDs solution with CH as the solvent at the fluorescence characteristic peak obtained under ultraviolet light excitation at a wavelength of 350 nm, and the fluorescence data at 386 nm, 408 nm, and 430 nm are used as array points 4, 5, and 6; thus, a 3×2 fluorescence sensor array is constructed. The detection method using the fluorescence sensor array of the present invention has simple steps, and has satisfactory specificity, reproducibility, stability and practicability, and has application potential.

The invention discloses a preparation method and application of an amino-functionalized graphene quantum dot modified MXene loose nanofiltration membrane. The preparation method comprises the following steps: mixing an MXene nanosheet dispersion liquid with an aminated graphene quantum dot aqueous solution, and preparing an amino functionalized graphene quantum dot / MXene mixed dispersion liquid by adopting a self-assembly method; and filtering and depositing the obtained mixed dispersion liquid on the modified base membrane to obtain the MXene loose nanofiltration membrane. According to the preparation method disclosed by the invention, the zero-dimensional aminated graphene quantum dots are creatively embedded into the MXene nanosheets, so that the MXene loose nanofiltration membrane which is stable in structure and regular in stacking is prepared. The nanofiltration membrane has good separation performance on different dyes and inorganic salts while effectively inhibiting water swelling, is a next-generation separation membrane with high stability and high selectivity, is mild and simple in preparation process, and has a wide application prospect.

The invention relates to the field of manufacturing of multi-color sheath glass, in particular to glass and a preparation method of a multi-color sheath of the glass. The glass base layer comprises glass, a multicolor sheath layer and a surface self-cleaning layer. The surface self-cleaning layer of the glass has a novel composite structure of a nanocrystalline multicolor sheath layer and a quantum dot sensitized self-cleaning layer. The structure effectively solves the problem of color covering of a traditional thick coating. In addition, through cooperative modification of the carbon quantum dots and the graphene quantum dots, the photoresponse range of titanium dioxide is expanded from ultraviolet light to visible light, so that the photocatalytic efficiency of the titanium dioxide is remarkably improved.

The invention relates to the technical field of functional coatings, in particular to a graphene reinforced heavy-duty epoxy coating for a marine environment. The invention discloses a graphene-based epoxy resin coating which is prepared from the following raw materials in parts by weight: 60-80 parts of bisphenol A epoxy resin, 5-10 parts of aminated graphene-carbon nanotube composite powder, 3-6 parts of zinc-aluminum-cerium ternary composite phosphate, 3-6 parts of nano boron nitride / silicon dioxide core-shell particles, 15-25 parts of a polyamide-epoxy curing agent, 1-3 parts of a silane coupling agent KH-560 and 5-8 parts of cashew nut shell oil modified phenolic aldehyde amine. The anti-rust paint is prepared from the following components in parts by weight: 0.5-2 parts of carboxylated graphene quantum dots, 2-4 parts of organic montmorillonite, 0.1-0.5 part of a fluorocarbon surfactant, 8-15 parts of a composite anti-rust pigment and 10-20 parts of an organic solvent. The coating is excellent in corrosion resistance, capable of resisting marine corrosion for a long time, resistant to high temperature and resistant to cathodic disbonding, has the functions of aging tracing and biological adhesion resistance, is convenient to construct and stable in performance, and provides reliable protection for ocean engineering.

The invention discloses a preparation method of a high-barrier aluminum oxide composite film for food packaging, and relates to the technical field of food packaging materials. The high-barrier aluminum oxide composite film for food packaging comprises the following raw materials in parts by weight: a barrier layer: 60-90 parts of modified nano aluminum oxide and 20-30 parts of a silane coupling agent KH-560; the functional layer is prepared from the following components in parts by weight: 18 to 28 parts of nano silver, 16 to 22 parts of compound antioxidant and 4 to 10 parts of nano titanium dioxide; the heat sealing layer is prepared from 22 to 32 parts of modified polylactic acid, 2 to 6 parts of graphene quantum dots, 12 to 16 parts of methyl methacrylate-butadiene-styrene copolymer, 3 to 6 parts of dodecyl trimethyl ammonium chloride, 10 to 14 parts of resorcinol tetraphenyl diphosphate and 7 to 17 parts of stearic acid intercalation modified nano montmorillonite. The high-barrier aluminum oxide composite film for food packaging is prepared by modifying nano aluminum oxide and polylactic acid, the barrier ability to gas, water vapor and ultraviolet rays is greatly improved, and the high-barrier aluminum oxide composite film is oil-resistant and antistatic. The product is high in mechanical strength, high in processing adaptability, capable of adapting to complex scenes, environment-friendly and safe.

The invention provides a heat-conducting wave-absorbing composite material with a three-dimensional interpenetrating network structure as well as a preparation method and application of the heat-conducting wave-absorbing composite material. The preparation method of the composite material comprises the following steps: impregnating carbon fibers in an ethanol dispersion liquid containing titanate, graphene quantum dots and polydopamine, carrying out low-temperature in-situ polymerization, and carrying out suction filtration and drying to obtain surface-functionalized carbon fibers; mixing the functionalized carbon fibers with an MXene / BNNS dispersion liquid, and performing freeze drying to obtain a functionalized carbon fiber three-dimensional honeycomb network skeleton; and impregnating the functionalized carbon fiber three-dimensional honeycomb network skeleton in a resin precursor solution containing a functional filler and a flame retardant to fill network gaps with resin, and heating and curing to obtain the composite material. The composite material completely meets the thermal management and electromagnetic compatibility requirements of 6G high-flux chip packaging; especially in a 6G AiP module, the material can effectively solve the problems of heat and electromagnetic interference generated by a high-power chip, and provides important support for commercial application of a 6G communication technology.

The invention discloses a polyurethane modified polytetrafluoroethylene ink formula and a preparation method thereof, and relates to the technical field of polytetrafluoroethylene processing, and the preparation method comprises the steps of raw material collection and preparation, auxiliary agent mixing, formula optimization and reaction post-treatment. The invention discloses a graphene quantum dot-modified waterborne polyurethane pigment which comprises the following raw materials: waterborne polyurethane, modified polytetrafluoroethylene, a pigment, nano titanium dioxide, a carbon nanotube, a dispersing agent, a toughening agent, a fluorosilicone modified acrylate emulsion and a cross-linking agent. The graphene quantum dot-modified waterborne polyurethane pigment has the advantages that graphene quantum dots are added in a pigment treatment link, and excellent optical performance of the graphene quantum dots is utilized, so that the dispersity of the pigment is remarkably improved; by adding the graphene quantum dots, the color saturation of the ink is improved, the printing color is brighter and more durable, the graphene quantum dots can enable the ink to have certain antistatic performance, the problems of ink dot splashing, pattern blurring and the like caused by static electricity in the printing process are effectively avoided, and the printing quality is improved; the surface hydrophobicity, the wear resistance and the chemical stability of the ink can be improved.

The invention provides a cyclodextrin-based nano anti-tumor medicine preparation as well as a preparation method and application thereof, and belongs to the technical field of medicines. The preparation method comprises the following steps: preparing a graphene quantum dot deposition gold nanocage modified by a silane coupling agent, carrying out a Schiff base reaction on the graphene quantum dot deposition gold nanocage and aldehyde substituted-beta-cyclodextrin to prepare a composite carrier, and coating a targeted peptide-drug compound through the reaction, thereby preparing the cyclodextrin-based nano anti-tumor drug preparation. According to the cyclodextrin-based nano anti-tumor medicine preparation prepared by the invention, the anti-tumor medicine effect is obviously improved, meanwhile, the medicine resistance of the medicine can be reversed, the damage to normal tissues is reduced, the use amount of the medicine is reduced, the side effect after the medicine is used is reduced, the compliance of a patient is improved, and meanwhile, the stability and biocompatibility of the medicine can be improved; wide application prospects are realized.

The invention relates to the technical field of corrosion prevention of oil field pipes, and particularly discloses electroplating liquid for a high-tungsten-content hydrogen sulfide corrosion resistant sleeve coating and a preparation process of the electroplating liquid. The invention discloses electroplating liquid for a high-tungsten-content hydrogen sulfide corrosion-resistant sleeve coating. The electroplating liquid comprises the following raw materials: 60-90 parts of a composite tungsten source; 40-70 parts of a nickel-cobalt main salt; 35-55 parts of a composite complexing agent; 1-5 parts of carboxylated graphene quantum dots; 1 to 5 parts of an aminated ZIF-8 derived carbon nanocage; 1-5 parts of a rare earth stabilizer; 1-4 parts of sodium hypophosphite; 1-4 parts of sodium citrate; 1-3 parts of a surfactant; 15 to 25 parts of a buffering agent; and 350 to 450 parts of deionized water. According to the single-layer electroplated layer, the interface stress of the multi-layer structure can be eliminated, so that other interface problems such as plating layer cracking caused by underground temperature fluctuation are avoided, it is guaranteed that the thickness of the plating layer reaches the standard, and then it is guaranteed that the plating layer has excellent corrosion resistance.

The invention relates to the technical field of peep-proof film manufacturing, and discloses a high-light-transmittance peep-proof film based on surface modification and a preparation method of the high-light-transmittance peep-proof film. The preparation method comprises the following steps: sequentially carrying out plasma activation, ALD atomic layer deposition and HEMA carboxyl-based layer polymerization on a PET film to obtain a modified PET film; coating the modified PET film with a dispersion liquid prepared from a polystyrene-polymethylacrylic acid solution and graphene quantum dots to form a peep-proof layer; depositing a TiO2 layer and a SiO2 layer on the modified PET film to form a high refractive index layer; diamond particles, MoS2 nanosheets and resin are mixed and coated on the high-refractive-index layer to form the wear-resistant layer. The PET film is modified through plasma activation, atomic layer deposition and free radical polymerization, the physical adsorption limitation of a traditional coating is broken through, chemical covalent binding with a subsequent functional layer is achieved, meanwhile, a light scattering path is optimized by preparing a TiO2 / SiO2 alternating layer, and the peep-proof effect and the optical stability are improved.

The invention discloses a high-density ceramic coating and a preparation method thereof, and relates to the technical field of polymer coatings, the high-density ceramic coating comprises, by mass, 33-35 parts of silica sol, 43-45 parts of a solvent, 0.35-0.42 part of a weak acid buffer agent and 18.5-19.9 parts of an auxiliary agent; wherein the solvent is prepared from the following components in parts by mass: 25.5 to 26.5 parts of MTMS, 0.5 part of deionized water and 16 to 19 parts of ethanol; the silica sol comprises 25.5-26.5 parts by mass of 45nm SiO2 sol and the balance of 15-20nm SiO2 sol, and the SiO2 sol is modified silica sol which is loaded by a metal organic framework or is subjected to in-situ growth of graphene quantum dots. The wear-resistant and high-temperature-resistant valve has the effects of wear resistance, high temperature resistance and long service life.

The invention relates to the technical field of composite coating preparation materials for battery diaphragms, in particular to a composite coating for a battery diaphragm as well as a preparation method and application. The invention discloses a graphene quantum dot / carbon nanotube composite material, which is prepared from the following components in percentage by weight: 3 to 8 percent of aminated graphene oxide-polydopamine graft, 10 to 18 percent of polyimide-polyetheretherketone-nano SiO2 hybrid, 2 to 5 percent of hydroxyapatite-montmorillonite core-shell particles, 0.5 to 3 percent of zinc borate-melamine cyanurate compound, 1 to 3 percent of graphene quantum dot-carbon nanotube hybrid, 2 to 6 percent of sodium carboxymethyl cellulose and 50 to 70 percent of deionized water. 0.5 to 2 percent of barium strontium titanate nanocrystalline or 1 to 3 percent of polyethylene glycol-polypropylene glycol segmented copolymer can also be added. All the components are combined through molecular-level reaction to construct a high-performance protection network. The composite coating is good in high temperature resistance and mechanical strength, high in ionic conduction efficiency, excellent in flame retardant effect and good in interfacial compatibility, the preparation process is environmentally friendly and easy to industrialize, the composite coating is suitable for various batteries, and the comprehensive performance of the composite coating is superior to that of a traditional coating.

The invention discloses a self-repairing graphene-based wind driven generator blade protection film and a preparation method thereof, and relates to the technical field of wind power generation equipment protection. The protection film adopts a gradient structure of a bonding buffer layer, a self-repairing functional layer and a multifunctional protection layer; the self-repairing functional layer comprises a hybrid network formed by hydroxylated functionalized graphene and elastomer particles and bionic packaging microcapsules, inner layer capsules containing graphene quantum dot reinforced resin and a latent catalyst curing agent are packaged in the microcapsules, multiple times of repairing of the same damaged area can be achieved, and the repairing strength is high; the multifunctional protective layer endows the coating with super-hydrophobic, anti-icing and ultraviolet-resistant functions through fluorinated graphene and nano TiO2 (at) ZnO composite particles; the preparation process is mature, the comprehensive protection performance is excellent, and the coating is suitable for wind driven generator blade protection in the severe environment.

The invention discloses a graphene quantum dot material as well as a preparation method and application thereof, and belongs to the technical field of biomedical materials. The preparation method comprises the following steps: S1, carrying out hydrothermal reaction on a mixed solution of mesoporous SiO2 and a carbon source to obtain a product I; s2, the product I and a fluoride solution are mixed to remove SiO2, and a product II is obtained; and S3, refining the product II to obtain the graphene quantum dot material. The carbon source is selected from at least one of triammonium citrate, diammonium hydrogen citrate, citric acid, folic acid, urea, thiourea and dicyanodiamine; the fluoride is selected from ammonium bifluoride and / or hydrogen fluoride. The particle size of the graphene quantum dot material provided by the invention is 15-30nm, the distribution is controllable, and the raw materials are easy to obtain; the prepared platinum nanoparticle / graphene quantum dot composite nanomaterial is high in solubility, stable in physical and chemical properties and remarkable in chemotherapy effect.

The invention discloses a dust-free environment purification method for biological pharmacy. Comprising the following steps: constructing three layers of metal filter screens, realizing particle interception through a conical micro-column array, an Al2O3 / TiO2 composite ceramic layer and a diamond-like carbon film, fixing lysozyme by adopting a crystal face regulated ZIF-8 crystal, and realizing dual inactivation of microorganisms by combining dielectric barrier discharge of a spiral plasma channel. The electrostatic adsorption HEPA filter paper adopts a BaTiO3-graphene quantum dot composite electret substrate, and a TiO2 / graphene heterojunction catalytic layer is decomposed by a Pt-Co bimetallic nanocluster and a photocatalysis-plasma-ozone-thermocatalysis quadruple oxidation system; and 0.1 mu m organic aerosol triggers graded reverse pulse cleaning based on differential pressure integration and a particle concentration threshold value, and the honeycomb flow guide structure drives a shutter and a gradient density sintering metal flow guide plate through piezoelectric ceramics to maintain laminar flow uniformity. According to the scheme, the limitation of a traditional technology is broken through, the purification efficiency of 0.1 micron particles is improved, and a high-stability solution is provided for a biopharmaceutical clean room.

The invention relates to the technical field of preparation of carbon dioxide adsorbents, and discloses a carbon dioxide solid adsorbent and a preparation method and application thereof, the carbon dioxide solid adsorbent comprises 10-15 parts of aminated montmorillonite, 5-8 parts of modified chitosan, 20-25 parts of desulfurized gypsum, 3-5 parts of a composite water-retaining agent, 1-2 parts of a functional buffer agent and 0.5-1 part of an ammonia adsorption accelerant. According to the invention, the aminated montmorillonite is adopted to replace traditional streptomycin, so that the raw material cost is reduced, and the risk of antibiotic residue is thoroughly eliminated; chitosan is modified through graphene quantum dots, the excellent oxidation resistance of the graphene quantum dots is utilized, an antioxidant does not need to be additionally added, the environment burden is reduced while the preparation process is simplified, and the degradation rate of the adsorbent in the natural environment is increased. All the components in the adsorbent have a synergistic effect, the aminated montmorillonite provides abundant adsorption active sites, the modified chitosan enhances the mechanical strength and stability of the adsorbent, the composite water-retaining agent and the buffer agent guarantee the stability of an adsorption environment, and the ammonia adsorption accelerant accelerates CO2 adsorption kinetics.

The invention relates to the technical field of preparation of high polymer materials and intelligent response materials, in particular to a preparation method of polyacrylamide for treatment. And constructing a quaternary polymerization system with acrylamide, a temperature-sensitive monomer and a zirconium-based metal organic framework-graphene quantum dot composite material. Magnetic response interpenetrating network gel is formed by induction of a photo-magnetic synergistic field, bacterial cellulose nanofibrils and a calcium silicate layered structure are introduced through a biomimetic mineralization technology, and the hierarchical porous carrier is prepared by combining a microfluidic crushing technology and a supercritical drying technology. Finally, through an intelligent regeneration mechanism of bimetal coordination activation and high-frequency magnetic field triggering, the material is endowed with multiple stimulation response characteristics, high adsorption capacity and in-situ regeneration capacity, and the mechanical strength and the salt resistance are remarkably improved through a pearl-layer-like micro-nano laminated structure. The method is suitable for industrial wastewater advanced treatment and emergency pollution repair scenes.

Suspension or colloid comprising liquid metal droplets bound with graphene-based particles, wherein the liquid metal is gallium or a gallium alloy, and the graphene-based particles are selected from a list of graphene, graphene oxide, reduced graphene oxide, graphene quantum dots, carbon nanotubes, or combinations thereof; respective ink, transparent stretchable conductor and obtention processes thereof; also a conductor obtainable by applying a coating of suspension, colloid, network, or ink according to any of the previous claims over a substrate, and laser sintering said coating, in particular the conductor being an electrode or a circuit trace or a circuit. Applications include optoelectronic devices, pressure or strain sensitive piezo resistive composited, pressure or strain sensors, temperature sensors, electroluminescent devices, photovoltaic devices, memory devices or electrodes for energy storage devices.

The invention discloses a CO2 detection device and method based on double TFBGs. The device comprises an optical fiber, and an optical fiber cladding is arranged on the outer side of a fiber core of the optical fiber; a tilted fiber grating TFBG1 and a tilted fiber grating TFBG2 which are spaced from each other are formed on the fiber core, a composite sensitive layer is arranged between the TFBG1 and the fiber cladding, and an inert protective layer is arranged between the TFBG2 and the fiber cladding; the composite sensitive layer sequentially comprises a porous silicon dioxide layer, a hydrophobic MOF intermediate layer and a graphene quantum dot (GQD) enhancement layer from inside to outside; a gas inlet hole is formed in the optical fiber cladding and is used for introducing gas of CO2 to be detected. Through a composite sensitive layer structure, a dual-channel self-compensation light path and a low-cost demodulation system, high-precision and low-drift CO2 detection is realized, and a reliable solution is provided for the field of environmental monitoring.

The invention relates to the technical field of preparation of polymer composite materials and surface modification of inorganic non-metallic materials, in particular to modified calcium carbonate and application of the modified calcium carbonate in plates, and the modified calcium carbonate is prepared from various raw materials such as calcium carbonate, a silane coupling agent and a graphene quantum dot-carbon nanotube compound. A dynamic cross-linked network is constructed through hydrolytic condensation of a silane coupling agent and multiple reactions of polydopamine, the composite material contains special composite reinforcements, core-shell structure particles and phase change microcapsules, all the raw materials have definite particle sizes and proportion ranges, and multifunctional modification is achieved. According to the modified calcium carbonate, the mechanical property of the board is remarkably improved, and the tensile and bending strength is improved by 40-60%; the plate is endowed with functions of ultraviolet resistance, flame retardance, temperature control and the like, and has antibacterial property; the interface compatibility is improved, the processing is convenient, the environment-friendly and recoverable effects are realized, and the economic and social benefits are outstanding.