593 results about "Graphene quantum dot" patented technology

The invention relates to the technical field of high polymer materials, in particular to ethylene-vinyl acetate copolymer modified polypropylene high-toughness plastic particles and a preparation process thereof. The composite material is prepared from the following raw materials in parts by weight: 60 to 80 parts of polypropylene, 15 to 30 parts of ethylene-vinyl acetate copolymer, 5 to 10 parts of maleic anhydride-2-ethylhexyl acrylate copolymer grafted ethylene-vinyl acetate copolymer, 3 to 8 parts of nano silicon dioxide / graphene quantum dot composite filler, 5 to 12 parts of polyolefin elastomer, 0.5 to 2 parts of antioxidant and 0.5 to 2 parts of lubricant. The content of vinyl acetate in the ethylene-vinyl acetate copolymer is 20-33 wt%, the composite filler is modified through a silane coupling agent KH-560, the grafting rate of the grafted ethylene-vinyl acetate copolymer is 1.5-3.5 wt%, and the composite filler is prepared through a melt grafting method. Through multi-component collaborative design and process optimization, the low-temperature toughness, rigidity, heat resistance and aging resistance of the material are improved, the problems of rigidity and toughness imbalance, low-temperature brittleness, poor stability and the like of a traditional modification system are solved, and the material is excellent in comprehensive performance and wide in application range.

The invention discloses a biochar-based slow-release fertilizer and a preparation method thereof, and relates to the technical field of fertilizer production, the biochar-based slow-release fertilizer comprises a core, a carrier layer, a biological layer and a protective layer, the core is composed of macroelements, microelements and a nitrification inhibitor; the carrier layer comprises graphene quantum dot modified charcoal, chitosan, glycerol and cyclodextrin grafted starch; the biological layer is prepared from magnetic Fe3O4 and humic acid nanoparticles, alginic acid oligosaccharide and diatomite; the protective layer comprises a polylactic acid-polycaprolactone block copolymer, acetone, calcium lignosulphonate, a dynamic covalent cross-linking agent gelatin, nano cellulose and an anti-blocking agent. Therefore, by adopting the polylactic acid-polycaprolactone (PLA-PCL)-based segmented copolymer and the dynamic covalent network cross-linking agent, the self-repairing property is endowed. The slow-release fertilizer provided by the invention realizes precise regulation and control of the fertilizer efficiency release rate through a multi-level synergistic effect, has the functions of soil remediation and stress resistance, and significantly improves the utilization efficiency of the fertilizer and the crop adaptability.

The invention discloses a preparation method of a photocatalytic nanofiltration membrane based on IL-GQDs. The method comprises the following steps: pretreating bagasse, and applying the pretreated bagasse and imidazole ionic liquid (IL) to preparation of ionic liquid functionalized graphene quantum dots (IL-GQDs); the IL-GQDs are uniformly distributed on the surface of the base membrane by utilizing a vacuum-assisted low-temperature interfacial polymerization technology to form an ultrathin photocatalytic active layer; and finally, curing and cleaning to obtain the photocatalytic nanofiltration membrane based on the IL-GQDs. According to the prepared IL-GQDs, the membrane surface is endowed with high specific surface area and excellent photocatalytic activity, and meanwhile, an additional water transmission channel can be established under the condition that the pore diameter of the membrane is not changed, so that the problem of trade-off of a traditional membrane is solved. In addition, through combination of low-temperature and vacuum-assisted interfacial polymerization technologies, the membrane structure is more uniform and compact, defects on the surface of the membrane are reduced, and the stability and the anti-pollution capacity of the membrane are improved. The membrane disclosed by the invention shows relatively high water flux, salt recovery rate and long-term stability in water treatment application.

The invention relates to the technical field of reverse osmosis membranes, in particular to a polyamide reverse osmosis membrane for high-salinity wastewater treatment and a preparation method of the polyamide reverse osmosis membrane. The invention solves the problem that the polyamide reverse osmosis membrane cannot give consideration to both desalination rate and water flux. The polyamide reverse osmosis membrane comprises a polyester non-woven fabric layer, a polysulfone porous layer, a transition layer and a polyamide layer. The polysulfone porous layer is prepared, and the modified pore-forming agent is added to improve the water flux of the reverse osmosis membrane; the hydrophilicity of the reverse osmosis membrane is improved by preparing the transition layer and adding a hydrophilic auxiliary agent when the polyamide layer is prepared; the flux attenuation rate of the polyamide reverse osmosis membrane is reduced by preparing the polyamide layer; the desalination rate of the reverse osmosis membrane is improved by introducing a composite ion complexing agent and graphene quantum dots into the polyamide layer.

The invention relates to the field of electrode materials, in particular to an antimony-based composite material and a preparation method and application thereof.The preparation method comprises the steps that graphene quantum dots are dispersed in deionized water to obtain a water phase A, antimony trichloride is added into the deionized water and mixed to be uniform to obtain a water phase B, and the water phase B is prepared; the preparation method comprises the following steps: uniformly mixing a surfactant, n-butyl alcohol, an organic solvent and 1-aminopropyl-3-methylimidazole phosphate to obtain an oil phase, dividing the oil phase into two parts, namely an oil phase A and an oil phase B, respectively adding the water phase A and the water phase B into the oil phase A and the oil phase B, stirring to obtain a microemulsion A and a microemulsion B, mixing the microemulsion A and the microemulsion B, quickly stirring to obtain a mixed reaction solution, and drying to obtain a finished product. Transferring the mixed reaction solution into a hydrothermal reaction kettle, sealing, heating to 100-120 DEG C, reacting for 1-10 hours, recovering to room temperature after the reaction is finished, centrifuging, collecting a product, washing and drying, thereby obtaining the antimony-based composite material which is used as a sodium-ion battery negative electrode material and has excellent electrochemical performance.

The invention belongs to the technical field of building materials, and discloses a preparation method of reflective heat-insulation waterproof real stone paint, which comprises the following three process stages: core layer synthesis, shell layer loading and real stone paint integration: coating a continuous SiO layer on the surface of nano TiO in situ to form TiO-coated SiO particles; graphene quantum dots and a hindered amine light stabilizer are loaded on the surfaces of TiOatSiO particles to form a composite functional filler; adding the composite functional filler into the acrylic emulsion base material in batches at a low speed, and adjusting the rheological property with the aid to obtain a finished product. The preparation process disclosed by the invention is completely compatible with an existing real stone paint industrial production line, does not need to add special equipment, and has excellent reflective heat insulation, heat preservation, water resistance, weather resistance and aging resistance and large-scale industrial feasibility; the technical problems of resin oxidative degradation caused by TiO photocatalytic activity, rapid attenuation of solar radiation reflectivity, failure of waterproof and hydrophobic performance and easiness in damage and stripping of a coating structure of the existing nano TiO-based reflective heat-insulation real stone paint are solved.

The invention provides photovoltaic copper paste, a preparation method thereof and application of the photovoltaic copper paste in preparation of solar cells, and relates to the technical field of photovoltaic cell manufacturing, and the photovoltaic copper paste comprises gradient micron-sized copper powder, a nano conductive reinforcing material, an organic binder, glass powder, a reinforcer and an optional additive; the reinforcing agent comprises an antioxidant, a nano interface reinforcing agent, a passivating agent and an optional corrosion inhibitor; wherein the nanometer interface reinforcing agent comprises one or more of aluminum oxide nanoparticles, antimony nanoparticles and graphene quantum dots; the passivating agent is prepared from benzotriazole and a silane coupling agent. According to the improved copper paste formula, the contact resistance performance and oxidation resistance can be improved, and the uniformity of grid lines is improved.

The invention relates to the technical field of biomedical materials, and discloses an electret electrostatic therapy membrane and a preparation process thereof.The electret electrostatic therapy membrane is prepared from, by mass, 15%-20% of fluorinated polyether ester, 10%-20% of a composite nano-fiber material, 10%-20% of a composite nano-fiber material, 10%-20% of a composite nano-fiber material and the balance water. 1%-2% of carboxymethyl chitosan; 2-5% of nano cerium oxide particles with the particle size of 50-100 nm; 0.5-1.0% of graphene quantum dots, the particle size of which is 5-10 nm; 1%-2% of sodium hyaluronate; the components are prepared into a film through an electrostatic spinning method, electret performance is given to the film through a charge injection process, finally, the film body is attached to a flexible silica gel adhesion layer, and the flexible silica gel adhesion layer is externally coated with a peelable protective film so that the structural integrity can be kept before the flexible silica gel adhesion layer is used. The composite membrane body disclosed by the invention shows excellent adhesion, charge activation capability and thermal response performance in applications of electrostatic therapy, dielectric assisted stimulation and the like, and has good multi-scene adaptability and clinical application potential.

The invention relates to a silicon-carbon composite material based on modified MXene, a preparation method of the silicon-carbon composite material, a negative electrode and a battery. MXene is prepared by etching an MAX phase through an etching agent; the preparation method comprises the following steps: preparing graphene quantum dots B-GQD and P-GQD + respectively; the graphene quantum dots B-GQD, the graphene quantum dots P-GQD + and the MXene are self-assembled through electrostatic adsorption, and a modified MXene material B / P-GQD / MXene is formed; preparing a porous carbon material deposited with silicon nanoparticles; the modified MXene material B / P-GQD / MXene is adopted to carry out liquid phase coating on the porous carbon material deposited with the silicon nanoparticles, and the silicon-carbon composite material based on the modified MXene is formed. The conductivity of the silicon-carbon composite material can be enhanced, and the rate capability of the lithium ion battery can be improved.

The invention provides a flexible fluorescence sensor as well as a preparation method and application thereof. The flexible fluorescence sensor comprises TCTG particles and dual-network hydrogel, the TCTG particles are distributed in network pores of the dual-network hydrogel to form functional gel, the TCTG particles are formed by Ti3C2TxMXene nanosheets and graphene quantum dots, the dual-network hydrogel is formed by acrylamide and sodium carboxymethyl cellulose, and the TCTG particles are distributed in the network pores of the dual-network hydrogel to form functional gel. The functional gel is soaked in a hydrochloric acid glycol solution for treatment. The flexible fluorescence sensor provided by the invention can integrate the structural advantages of all the components, so that a synergistic coupling effect is possibly generated, a fluorescence detection function with excellent mechanical strength, frost resistance and high sensitivity is integrated into a multifunctional system, the food spoilage condition can be reliably monitored in real time under a harsh environmental condition, and the application prospect is wide. And health and economic risks caused by occupational exposure and environmental emission in an aquatic product supply chain are solved.

The invention provides a positive electrode active material and a preparation method thereof, a positive electrode, a battery and electric equipment, the positive electrode active material comprises lithium iron phosphate and graphene quantum dots, and the lithium iron phosphate comprises secondary particles formed by primary particles; the graphene quantum dots coat at least part of the surfaces of the primary particles. The positive electrode active material has relatively high electronic conductivity and ion mobility, and the low-temperature discharge performance of the battery can be effectively improved.

The invention relates to the technical field of coatings, in particular to an acrylate-epoxy resin composite coating and a preparation method thereof. According to the technical scheme, the coating is prepared from 25 to 35 parts of methyl methacrylate, 15 to 25 parts of butyl acrylate, 10 to 20 parts of epoxy resin E-5110, 8 to 15 parts of organic silicon modified acrylate prepolymer, 5 to 12 parts of fluorocarbon modified epoxy resin, 4 to 8 parts of core-shell structure corrosion inhibition nano container, 1 to 3 parts of functionalized graphene quantum dots and 4 to 10 parts of polyhedral oligomeric silsesquioxane maleimide modified amine curing agent. And 1-3 parts of a hindered amine light stabilizer. By integrating the core-shell structure corrosion inhibition nano container, the functionalized graphene quantum dots and the photo-thermal dual responsive curing agent component, the sensing, response and self-repairing of the coating on damage are realized, and long-acting corrosion resistance, weather resistance, bacteria resistance, mechanical property balance and intelligent maintenance are considered; and efficient and economical full-period protection is provided for equipment in an extreme environment.

The invention relates to the technical field of resin materials, in particular to an epoxy anhydride composition capable of being chemically thickened and a preparation method thereof, and the epoxy anhydride composition consists of the following components in parts by weight: 35-45 parts of epoxy resin; 40-55 parts of a modified anhydride curing agent; 3-8 parts of a chemical thickening agent; 0.5 to 2 parts of a latent accelerator; 5 to 20 parts of a toughening agent; 0.5 to 5 parts of nano clay modified by a surfactant; 0.01 to 0.5 part of graphene quantum dots modified by a surface active agent; 0.1 to 1 part of a two-dimensional transition metal carbide / nitride modified by a surfactant; 0.1 to 2 parts of a thermally responsive polymer; 0.05 to 1 part of a photoresponsive molecule; 0.5 to 3 parts of nano particles; and 0-10 parts of high-performance fiber. The heat and humidity resistance, the size stability and the deformation resistance of the material are remarkably improved, the rapid heating and cooling circulation adaptability is enhanced, the good size stability is maintained, and the conductivity and the electromagnetic shielding performance can be enhanced.

The invention discloses a high-thermal-conductivity insulating electric power engineering material and a preparation method thereof, and relates to the technical field of insulating material preparation. The composite material is prepared from 40-60 parts of polyimide resin, 20-30 parts of boron nitride nanosheets, 10-15 parts of alumina micro powder, 5-10 parts of a silane coupling agent, 3-8 parts of a plasticizer, 2-5 parts of an antioxidant, 1-3 parts of carbon nanotube whiskers, 1-2 parts of graphene quantum dots and 0.5-1 part of rare earth yttrium oxide. The diameter-thickness ratio of the boron nitride nanosheet is 100-200, the particle size of the alumina micro powder is 1-5 [mu] m, the diameter of the carbon nanotube whisker is 5-20 nm, the length is 1-5 [mu] m, and the particle size of the graphene quantum dot is 2-10 nm; all the raw materials are synergistically matched, so that the material is expected to have high thermal conductivity and excellent insulating property and is suitable for the field of electric power engineering. The material has high thermal conductivity and excellent insulativity, the thermal conductivity coefficient is not lower than 5 W / (m.K), the volume resistivity is not lower than 1015 omega.cm, and the breakdown field strength is not lower than 30 kV / mm.

The invention provides a magnetic confinement microwave plasma preparation method and system for coal-based graphene quantum dots, and relates to the technical field of graphene quantum dot preparation, and the method comprises the following steps: pretreating a coal raw material, removing impurities, and crushing the coal raw material to a preset particle size; detecting the coal quality parameters of the pretreated coal raw material, wherein the coal quality parameters at least comprise the contents of C, H and O elements; the coal quality parameters are input into a QYOA algorithm to be analyzed, and adjustment parameters of microwave power and reaction gas are obtained; feeding the pretreated coal raw material into a reaction cavity, and forming a three-dimensional confinement field in the reaction cavity through a magnetic confinement device; according to the method, magnetic confinement, microwave plasma, a QYOA algorithm and ultrasonic aftertreatment are organically combined to form a synergistic effect, dissociation of carbon clusters is promoted through the synergistic effect of the magnetic confinement and the microwave plasma, the yield of the coal-based graphene quantum dots is increased to 30% or above from less than 10% of a traditional method, the production efficiency is improved, and large-scale production is facilitated.

The invention belongs to the technical field of power cables, and particularly relates to an anti-bending flexible cable and a preparation method thereof.The cable sequentially comprises a conductor, an insulating layer, a buffer layer, a shielding layer and a protective layer from inside to outside, the insulating layer is divided into an inner layer, a middle layer and an outer layer in the radial direction, and the inner layer of the insulating layer comprises the following components in parts by weight; 100 parts of crosslinked polyethylene, 6-10 parts of amino-modified photoresponse graphene quantum dots, and 2-4 parts of a plasticizer DOS; 2-3 parts of amino modified photoresponse graphene quantum dots, 100 parts of crosslinked polyethylene and 2-4 parts of a plasticizer DOS; the protective layer comprises the following components in parts by weight; the insulation layer comprises 100 parts of shape memory polyurethane, 15-22 parts of composite microspheres and 0.5-1.0 part of a light stabilizer, and the insulation layer adopts a cross-linked polyethylene, amino modified light response graphene quantum dot gradient distribution and plasticizer system; and three-channel co-extrusion and three-section type ultraviolet curing are matched, so that inner layer under-crosslinking / outer layer over-crosslinking is avoided.

The invention discloses an antistatic agent for polyolefin film material production and a preparation method thereof. According to the invention, through reasonable molecular structure design, raw material selection and synthesis process optimization, the antistatic agent has multiple functions of high-efficiency antistatic property, oxidation resistance, antibacterial property, mechanical property enhancement and the like. The polyolefin material added with the multifunctional antistatic agent has good antistatic performance under different environmental conditions, and the oxidation resistance, the antibacterial property and the mechanical property are also remarkably improved. The antistatic agent has good adaptability with processing of a polyolefin film material and has wide application prospects and market competitive advantages, and the comprehensive performance of the polyolefin film material is remarkably improved through multi-component collaborative design. The composite system of the polyolefin quaternary ammonium salt and the graphene quantum dots strengthens the long-term effect of the antistatic effect, and meanwhile, the synergistic effect of the hindered phenol and the phosphite strengthens the antioxidant stability of the material in the processing and using processes.

The invention discloses an environment-friendly cooling anti-radiation refrigeration coating and a preparation method thereof, and belongs to the technical field of coating preparation. The raw materials are prepared from core materials, auxiliary materials and ingredients. The core material is prepared from a main raw material, hollow glass beads and environment-friendly resin, the auxiliary material is prepared from a nano additive and mineral pigment, and the ingredients are prepared from ferroferric oxide, nano titanium dioxide, diopside and polyvinylidene fluoride. The main raw materials comprise carbon quantum dots, carbon nanofibers, carbon nanospheres and graphene quantum dots; the environment-friendly resin base material is prepared from waterborne polyurethane resin, rosin resin, shellac resin and polytetrafluoroethylene; the nano additive is composed of silicon carbide, carbon black, carbon fibers, magnesium borate and carbon nanotubes. According to the coating, solar energy can be converted into light energy, the sunlight reflectivity of the coating is improved through the unique optical property of the coating, the sunlight reflectivity of the coating can be correspondingly improved along with increase of the sunlight intensity, and therefore the situation that a building absorbs excessive heat is avoided.

The present invention combines a fluorescence sensor with an array to provide a fluorescence sensing array detection platform and a detection method for multiple plasticizers. The fluorescence sensing array detection platform includes a B-doped graphene quantum dot solution using N,N-dimethylformamide as a solvent and a B-GQDs solution using cyclohexane as a solvent; the fluorescence intensity of the B-GQDs solution with DMF as the solvent at the fluorescence characteristic peak obtained under ultraviolet light excitation at a wavelength of 350 nm, and the fluorescence data at 391 nm, 413 nm, and 434 nm are used as array points 1, 2, and 3; the fluorescence intensity of the B-GQDs solution with CH as the solvent at the fluorescence characteristic peak obtained under ultraviolet light excitation at a wavelength of 350 nm, and the fluorescence data at 386 nm, 408 nm, and 430 nm are used as array points 4, 5, and 6; thus, a 3×2 fluorescence sensor array is constructed. The detection method using the fluorescence sensor array of the present invention has simple steps, and has satisfactory specificity, reproducibility, stability and practicability, and has application potential.

The invention discloses a high-activity graphene quantum dot and a preparation method thereof, and relates to the technical field of oilfield chemistry, and the preparation method comprises the following steps: uniformly ground carbon source and nitrogen source are mixed, heated, fully reacted and cooled, uniformly dispersed in deionized water by ultrasonic waves, and then subjected to suction filtration, dialysis and freeze drying to obtain the nitrogen-containing graphene quantum dot. The preparation method comprises the following steps: dispersing nitrogen-containing graphene quantum dots, fatty alcohol-polyoxyethylene ether carboxylic acid and a catalyst in absolute ethyl alcohol, carrying out ultrasonic oscillation for 30 minutes, carrying out reflux reaction, and carrying out reduced-pressure rotary evaporation, thereby obtaining the nitrogen-containing graphene quantum dots. The prepared high-activity graphene quantum dots are small in particle size, high in activity and capable of entering small pores to peel crude oil, so that the recovery efficiency can be remarkably improved, the point injection allocation process is simple, the high-activity graphene quantum dots can be rapidly dispersed into injected water, an additional injection allocation device is not needed, and the construction cost is low.

The invention discloses a preparation method and application of an amino-functionalized graphene quantum dot modified MXene loose nanofiltration membrane. The preparation method comprises the following steps: mixing an MXene nanosheet dispersion liquid with an aminated graphene quantum dot aqueous solution, and preparing an amino functionalized graphene quantum dot / MXene mixed dispersion liquid by adopting a self-assembly method; and filtering and depositing the obtained mixed dispersion liquid on the modified base membrane to obtain the MXene loose nanofiltration membrane. According to the preparation method disclosed by the invention, the zero-dimensional aminated graphene quantum dots are creatively embedded into the MXene nanosheets, so that the MXene loose nanofiltration membrane which is stable in structure and regular in stacking is prepared. The nanofiltration membrane has good separation performance on different dyes and inorganic salts while effectively inhibiting water swelling, is a next-generation separation membrane with high stability and high selectivity, is mild and simple in preparation process, and has a wide application prospect.

The invention discloses a hydrophilic graphene dispersion liquid for PCB hole metallization, and belongs to the technical field of circuit board processing, the hydrophilic graphene dispersion liquid comprises the following components by mass: 1-5% of boron-doped graphene, 1-5% of boron-doped graphene quantum dots, 10-40% of polypyrrole, 0.5-1% of a dispersant, and 0.5-2% of a surfactant. The second purpose of the invention is to provide a preparation method of the hydrophilic graphene dispersion liquid for PCB hole metallization, the dispersion liquid is subjected to boron doping treatment on graphene and graphene quantum dots, so that the overall conductivity is enhanced, the hydrophilicity is enhanced, the dispersion liquid has excellent dispersity, and the hydrophilicity of the dispersion liquid is improved. Through the synergistic effect of polypyrrole, boron-doped graphene and boron-doped graphene quantum dots, the stability and adhesion of the composite material are further enhanced.

The invention relates to the field of manufacturing of multi-color sheath glass, in particular to glass and a preparation method of a multi-color sheath of the glass. The glass base layer comprises glass, a multicolor sheath layer and a surface self-cleaning layer. The surface self-cleaning layer of the glass has a novel composite structure of a nanocrystalline multicolor sheath layer and a quantum dot sensitized self-cleaning layer. The structure effectively solves the problem of color covering of a traditional thick coating. In addition, through cooperative modification of the carbon quantum dots and the graphene quantum dots, the photoresponse range of titanium dioxide is expanded from ultraviolet light to visible light, so that the photocatalytic efficiency of the titanium dioxide is remarkably improved.

The invention relates to the technical field of functional coatings, in particular to a graphene reinforced heavy-duty epoxy coating for a marine environment. The invention discloses a graphene-based epoxy resin coating which is prepared from the following raw materials in parts by weight: 60-80 parts of bisphenol A epoxy resin, 5-10 parts of aminated graphene-carbon nanotube composite powder, 3-6 parts of zinc-aluminum-cerium ternary composite phosphate, 3-6 parts of nano boron nitride / silicon dioxide core-shell particles, 15-25 parts of a polyamide-epoxy curing agent, 1-3 parts of a silane coupling agent KH-560 and 5-8 parts of cashew nut shell oil modified phenolic aldehyde amine. The anti-rust paint is prepared from the following components in parts by weight: 0.5-2 parts of carboxylated graphene quantum dots, 2-4 parts of organic montmorillonite, 0.1-0.5 part of a fluorocarbon surfactant, 8-15 parts of a composite anti-rust pigment and 10-20 parts of an organic solvent. The coating is excellent in corrosion resistance, capable of resisting marine corrosion for a long time, resistant to high temperature and resistant to cathodic disbonding, has the functions of aging tracing and biological adhesion resistance, is convenient to construct and stable in performance, and provides reliable protection for ocean engineering.

The invention discloses high-power artificial graphite as well as a preparation method and application thereof, and belongs to the technical field of new energy. The invention discloses a preparation method of high-power artificial graphite, which comprises the following steps: S1, mixing a carbon-based raw material, phenolic resin and a pore-forming agent in an organic solvent, and graphitizing; the carbon-based raw material comprises at least one of petroleum coke powder, needle coke powder and pitch coke powder; the pore-forming agent comprises at least one of alkali metal nitrates; s2, dipping a product obtained in the step S1 in a solution containing graphene quantum dots, and drying; 3, adopting a CVD (chemical vapor deposition) method to generate graphene on the product obtained in the step S2 in situ; and S4, coating the surface of the product obtained in the step S3 with a carbon layer. According to the preparation method provided by the invention, the high-power use stability of the artificial graphite can be effectively improved. The invention also provides the high-power artificial graphite prepared by the preparation method and application of the high-power artificial graphite.

The invention relates to an anti-blue light optical protective film and a preparation method thereof, belonging to the technical field of anti-blue light optical elements. The protective film comprises 0.2-1.4 parts of a blue light absorber, 9-27 parts of ultrapure water and 1-3 parts of polyvinyl alcohol, and the blue light absorber consists of 0.07-0.09 parts of graphene quantum dots, 110-130 parts of anhydrous ethanol, 0.05-0.07 parts of aminonitrobenzene compounds, 1-2 parts of 1-(3-dimethylaminopropyl)-3-ethylcarbodiimide and 0.3-0.6 parts of N-hydroxysuccinimide. The preparation method comprises the following steps: mixing polyvinyl alcohol and ultrapure water, swelling and dissolving the mixture in sequence to obtain a polyvinyl alcohol solution; then mixing the polyvinyl alcohol solution and the blue light absorber to obtain a mixed material; and finally coating the mixed material on a glass substrate and then drying the mixture to obtain the anti-blue light optical protective film. The anti-blue light optical protective film prepared by using the blue light absorber will not change the high light transmittance of the optical film itself in the visible light region, and can also absorb harmful blue light.

The invention discloses a preparation method of a high-barrier aluminum oxide composite film for food packaging, and relates to the technical field of food packaging materials. The high-barrier aluminum oxide composite film for food packaging comprises the following raw materials in parts by weight: a barrier layer: 60-90 parts of modified nano aluminum oxide and 20-30 parts of a silane coupling agent KH-560; the functional layer is prepared from the following components in parts by weight: 18 to 28 parts of nano silver, 16 to 22 parts of compound antioxidant and 4 to 10 parts of nano titanium dioxide; the heat sealing layer is prepared from 22 to 32 parts of modified polylactic acid, 2 to 6 parts of graphene quantum dots, 12 to 16 parts of methyl methacrylate-butadiene-styrene copolymer, 3 to 6 parts of dodecyl trimethyl ammonium chloride, 10 to 14 parts of resorcinol tetraphenyl diphosphate and 7 to 17 parts of stearic acid intercalation modified nano montmorillonite. The high-barrier aluminum oxide composite film for food packaging is prepared by modifying nano aluminum oxide and polylactic acid, the barrier ability to gas, water vapor and ultraviolet rays is greatly improved, and the high-barrier aluminum oxide composite film is oil-resistant and antistatic. The product is high in mechanical strength, high in processing adaptability, capable of adapting to complex scenes, environment-friendly and safe.

The invention provides a heat-conducting wave-absorbing composite material with a three-dimensional interpenetrating network structure as well as a preparation method and application of the heat-conducting wave-absorbing composite material. The preparation method of the composite material comprises the following steps: impregnating carbon fibers in an ethanol dispersion liquid containing titanate, graphene quantum dots and polydopamine, carrying out low-temperature in-situ polymerization, and carrying out suction filtration and drying to obtain surface-functionalized carbon fibers; mixing the functionalized carbon fibers with an MXene / BNNS dispersion liquid, and performing freeze drying to obtain a functionalized carbon fiber three-dimensional honeycomb network skeleton; and impregnating the functionalized carbon fiber three-dimensional honeycomb network skeleton in a resin precursor solution containing a functional filler and a flame retardant to fill network gaps with resin, and heating and curing to obtain the composite material. The composite material completely meets the thermal management and electromagnetic compatibility requirements of 6G high-flux chip packaging; especially in a 6G AiP module, the material can effectively solve the problems of heat and electromagnetic interference generated by a high-power chip, and provides important support for commercial application of a 6G communication technology.

The present invention discloses a nanocellulose graphene quantum dot high-sensitivity humidity sensor and its green preparation process, comprising: a porous composite humidity-sensitive membrane prepared by mixing nanocellulose, graphene quantum dots and polydimethylsiloxane in proportion, wherein the porous composite humidity-sensitive membrane constitutes a sensing surface; a polydimethylsiloxane layer coated on the side of the porous composite humidity-sensitive membrane; a flexible electrode adhered to the side of the porous composite humidity-sensitive membrane through the polydimethylsiloxane layer; and a wire connected to the flexible electrode. The humidity sensor of the present invention has a sensing medium layer, which is a porous composite humidity-sensitive membrane prepared by nanocellulose, graphene quantum dots and polydimethylsiloxane. Nanocellulose and graphene quantum dots are interlaced and combined to form a flexible three-dimensional porous network structure with a large specific surface area, and polydimethylsiloxane improves the stability of the porous network structure, thereby effectively promoting the conduction and penetration of water molecules on the surface of the composite humidity-sensitive membrane, thereby improving the sensitivity and sensing performance of the sensor.

The invention discloses a polyurethane modified polytetrafluoroethylene ink formula and a preparation method thereof, and relates to the technical field of polytetrafluoroethylene processing, and the preparation method comprises the steps of raw material collection and preparation, auxiliary agent mixing, formula optimization and reaction post-treatment. The invention discloses a graphene quantum dot-modified waterborne polyurethane pigment which comprises the following raw materials: waterborne polyurethane, modified polytetrafluoroethylene, a pigment, nano titanium dioxide, a carbon nanotube, a dispersing agent, a toughening agent, a fluorosilicone modified acrylate emulsion and a cross-linking agent. The graphene quantum dot-modified waterborne polyurethane pigment has the advantages that graphene quantum dots are added in a pigment treatment link, and excellent optical performance of the graphene quantum dots is utilized, so that the dispersity of the pigment is remarkably improved; by adding the graphene quantum dots, the color saturation of the ink is improved, the printing color is brighter and more durable, the graphene quantum dots can enable the ink to have certain antistatic performance, the problems of ink dot splashing, pattern blurring and the like caused by static electricity in the printing process are effectively avoided, and the printing quality is improved; the surface hydrophobicity, the wear resistance and the chemical stability of the ink can be improved.