The invention discloses an atmospheric NO3 free radical concentration measurement
system based on a double-cavity type cavity ring-down technology. The measurement
system utilizes two ring-down cavities to simultaneously measure the ring-down time and the background ring-down time, and includes a
function generator, a
diode laser device, an
optical isolator, a first ring-down cavity, a second ring-down cavity, a
narrowband color filter, a photoelectric
detector and a capture card. The external-modulation
diode laser device outputs a pulse
laser, the pulse laser passes through the
optical isolator and then is divided into two beams by a
beam splitter, the two beams of pulse lasers respectively go into the first ring-down cavity and the second ring-down cavity, and the two ring-down cavities are in rear-connection with the photoelectric
detector. The NO3 free radical ring-down time is extracted from an obtained ring-down
signal acquired by the first ring-down cavity; and at the same time, the NO3 free radical background ring-down time is extracted from the ring-down time obtained by the second ring-down cavity. Under the condition of a known NO3 free radical
absorption cross section sigma, the NO3 free radical concentration is obtained by calculation through the following formula as described in the specification, where RL and c are constants.