The invention relates to the technical field of organic photoelectric functional materials, in particular to a
photon up-conversion material based on a
metal-free
photosensitizer and a
covalent organic framework and a preparation method of the
photon up-conversion material. The up-conversion material comprises a
cyanine dye
photosensitizer and a
covalent organic framework, the
cyanine dye
photosensitizer is assembled on the surface of the
covalent organic framework through a molecular anchor in the
structural formula of the
cyanine dye photosensitizer, and the
photon up-conversion material based on the
metal-free photosensitizer and the covalent organic framework is formed. According to the invention, through combination of a molecular anchor and a
crystal engineering strategy, two core problems of interface transfer and bulk
phase diffusion of excitons in
solid TTA-UC are cooperatively overcome, and a brand new thought and an
effective solution are provided for development of a high-performance
solid upconversion material. According to the preparation method, the
metal-free photosensitizer and the organic framework material are adopted,
precious metal and heavy metal
quantum dots are prevented from being used, better
biocompatibility and environment friendliness are achieved, meanwhile, the preparation cost is reduced, and large-scale production is facilitated.