The invention relates to the field of organic light-emitting materials, in particular to a blue thermally induced delayed
fluorescence polymer as well as a preparation method and application thereof. According to the
polymer with the structure shown in the formula 1, diphenyl
silicon of the
polymer is directly connected with
acridine in a TADF light-emitting unit, sp3 hybridized
silicon atoms can effectively break conjugation of a main chain of the polymer, and the triplet
energy level is improved. When an
alkyl substituent group is introduced to the ortho-position of a connecting site of diphenyl
silicon and a TADF unit, the torsion angle of an aromatic ring can be increased, the triplet
energy level is further improved, the
energy level difference between the
singlet state and the
triplet state is reduced, and meanwhile, the increase of molecular rigidity inhibits non-
radiative transition. Experimental results show that the polymer not only has a high triplet energy level, but also has high
fluorescence quantum efficiency, and presents efficient blue thermally induced delayed
fluorescence emission. In addition, the preparation method of the polymer provided by the invention is simple, and the obtained polymer has excellent
solubility and film-forming property.