341 results about "Acridine" patented technology

The invention provides a hole transport material, a preparation method thereof and a perovskite solar cell. The chemical structural formula of the hole transport material is # imgabs0 #, wherein each A is independently a heteroatom. A thiophene-methoxy triphenylamine group and a thiophene-methylthio triphenylamine group are introduced into an acridine phosphate side chain, and a series of novel hole transport materials are provided. The hole transport material has higher decomposition temperature, better thermal stability and higher hole mobility, thereby being beneficial to hole extraction and transport. The hole transport material has a deep HOMO energy level matched with perovskite, and can be used in a perovskite solar cell without doping any additive, so that the perovskite solar cell has higher photoelectric conversion efficiency, photovoltaic performance and stability, and the material has repeatability.

The invention relates to the technical field of immunodetection and immunodiagnosis, in particular to a chemiluminescence substrate solution, a chemiluminescence detection kit and a detection method. The chemiluminescent substrate solution comprises a substrate solution 1, or comprises the substrate solution 1 and a substrate solution 2, the substrate solution 1 comprises sodium hydroxide, a surfactant and a blue light absorbent for absorbing blue light with the wavelength of 400-500 nm; the substrate solution 2 comprises inorganic acid and hydrogen peroxide. According to the application, the blue light absorbent is added into the chemiluminescent substrate liquid, so that blue light emitted by acridinium ester can be absorbed, a luminescent signal is reduced, and particularly, the luminescent value of a background caused by non-specific adsorption is reduced, so that the signal-to-noise ratio is increased.

The invention discloses a magnetic particle chemiluminiscence detection kit for human non-phosphorylated Tau217 protein and a preparation method of the magnetic particle chemiluminiscence detection kit. The kit comprises a micro magnetic particle coupled with a human non-phosphorylated Tau217 protein capture antibody, an acridinium ester labeled human non-phosphorylated Tau217 protein detection antibody, a human non-phosphorylated Tau217 protein calibration product and a quality control product. The direct chemiluminescence method established by the invention has the advantages of high sensitivity, strong specificity, accuracy, rapidness and short detection time, the detection result has higher accuracy and repeatability, and the kit can be used for various luminescence detection instruments.

The invention discloses a halogen-free low-splashing environment-friendly solder wire and a preparation method thereof, and relates to the technical field of electronic welding materials, and the halogen-free low-splashing environment-friendly solder wire is prepared from the following raw materials in percentage by mass: 1-4wt% of halogen-free scaling powder and the balance of lead-free solder; the lead-free solder is composed of the following components of Cu, Bi, Al, Ga, Ir, Ca, In and Sn. The halogen-free scaling powder comprises the following components: (3, 6-diamino acridine-9-yl) boric acid, glycerol triabietate, 3-(N-morpholinyl)-2-hydroxy propanesulfonic acid sodium salt, 3-trihydroxymethyl methylamino-2-hydroxy propanesulfonic acid, hexahydro-1, 3-ethoxy-s-triazine, a functional copolymer, a surface active agent, a corrosion inhibitor, a halogen-free activity reinforcing agent, an antioxidant, a solvent and rosin resin. The solder wire is low in splashing rate, high in surface resistivity and welding spot reliability, free of obvious corrosivity and good in weldability.

The inorganic quick-setting filling material comprises a material A and a material B. The material A is prepared from the following components in parts by weight: 25-35 parts of sulphoaluminate cement, 30-40 parts of blast furnace slag, 10-20 parts of waste gypsum, 1-3 parts of recycled alumina fiber, 5-10 parts of volcanic ash and 0.8-1.2 parts of (3, 6-diamino acridine-9-yl) boric acid. The material B is prepared from the following raw materials in parts by weight: 4 to 6 parts of functional water-soluble resin, 1 to 2 parts of sodium 3-(N-morpholinyl)-2-hydroxypropanesulfonate, 0.5 to 0.8 part of sucralose, 0.1 to 1 part of sodium lignin sulfonate, 0.8 to 1.2 parts of 1, 3, 5-triglycidyl-S-triazinetrione and 0.1 to 0.5 part of sodium N-(trimethoxysilylpropyl) ethylenediamine triacetate. The material is good in rapid hardening effect, high in compressive strength, good in flame-retardant and antistatic performance and long in service life.

The invention discloses a chemiluminescence heparin binding protein kit and a determination method thereof. The kit comprises reagent components of a reagent R1, a reagent R2 and a reagent R3, as well as a matched calibrator, a matched quality control product, a matched pre-excitation liquid, a matched excitation liquid and a matched cleaning liquid, wherein the reagent R1 contains magnetic particles coated with streptavidin, and the reagent R2 and the reagent R3 are respectively monoclonal antibodies which are labeled by acridinium ester and biotin and are used for recognizing different epitopes of human HBP. The kit shows better sensitivity, wider detection range and high specificity, and can effectively reduce potential endogenous and exogenous interference in clinical samples of potential interference people.

The invention is suitable for the technical field of solar cells, and provides a perovskite solar cell module and a preparation method thereof. The perovskite solar cell module comprises an anode, a hole transport layer, a perovskite layer, an electron transport layer and a cathode which are sequentially laminated. An optical active material used for preparing the perovskite layer is metal halide perovskite, and the specific chemical formula is Cs0. 15FA0. 85PbI3; and a cathode interface material used for preparing the cathode interface layer is quinacridone derivative (DCNQA-PyBr). According to the invention, DCNQA-PyBr is used as the cathode interface material to be applied to the perovskite (such as a Cs0. 15FA0. 85PbI3 system) solar cell module, the thick film processing of the cathode interface material can be realized, the energy conversion efficiency of the perovskite solar cell module is improved, and the cathode interface material is suitable for large-scale production and can meet the requirement of large-area industrial production.

The invention provides a naphthalimide compound as well as a preparation method and application thereof, and belongs to the technical field of organic compounds. N-(4-tert-butylphenyl) naphthalimide is used as an acceptor unit (a group A), 9, 9-dimethyl acridine, 9, 9-diphenyl acridine, phenoxazine, phenothiazine, 7H-benzo [c] carbazole or 9H-dibenzo [a, c] carbazole is used as an electron donor unit (a group D), and the donor unit and the acceptor unit are connected through ortho-positions or meta-positions of benzene bridges or derivatives thereof; the formation of the 3CT state depends on the CT effect between the D group and the A group, the specific D group and the benzene bridge unit are selected to control the distance and the dihedral angle between the D unit and the A unit so as to realize the regulation and control of the service life of the 3CT state, and meanwhile, the fine adjustment of the energy of the 3CT state is realized by virtue of the substituent group on the benzene bridge unit, so that the service life of the 3CT state is prolonged. Therefore, the naphthalimide compound has a long charge transfer triplet state lifetime in a single molecule state.

The invention discloses a dual-band acridine formic acid anthracene methyl ester photocatalyst as well as a preparation method and application thereof, and belongs to the field of heterocyclic compounds. The invention designs and synthesizes a novel acridine formic acid anthracene methyl ester photocatalyst, which has good compatibility in two wavebands of 365 nm and 405 nm, can realize photocatalysis of disulfide compounds and aryl formyl peroxide compounds, and provides a new thought for preparation of sulfoxide compounds with asymmetric structures; the reaction conditions are mild, the reaction time is short, the photocatalyst can be recycled, the circulation loss is low, the circulation efficiency is high, the production efficiency is greatly improved, and the production period and cost are reduced; the product is free of transition metal residues and high in yield.

The invention discloses a functional polyester yarn and a preparation method thereof. The functional polyester yarn is formed by blending functional synthetic fibers and bamboo fibers according to the mass ratio of (3-5): 0.5. The functional synthetic fiber is prepared from the following raw materials: polyester chips, a functional copolymer, a compatilizer, an antioxidant, a lubricant, 1, 4-diamino-2, 3-dicyanoanthraquinone and (3, 6-diamino-9-acridinyl) boric acid. The functional copolymer comprises structural units introduced by the following monomers: diphenyl (4-vinyl phenyl) phosphine oxide, 4-methyl-5-vinyl thiazole, 1-allyl-3-methyl imidazole chloride, 3-(1, 1-difluoro-2-propylene-1-yl)-2 (1H)-quinoxalinone, and 1, 3-bis (oxiranyl methyl)-5-(2-allyl)-1, 3, 5-triazine-2, 4, 6 (1H, 3H, 5H)-triketone. The yarn is good in anti-ultraviolet performance, flame retardant performance and antibacterial performance.

The invention belongs to the technical field of in-vitro diagnosis, and discloses a chemiluminescence-based FGF21 detection kit and a preparation method thereof, and the kit comprises magnetic microspheres of which the surfaces are coupled with FGF21 specific antibodies, the FGF21 specific antibodies containing acridinium ester labels, a sample diluent, a luminescence pre-excitation liquid, an excitation liquid and FGF21 calibrators with different concentrations. According to the FGF21 detection kit disclosed by the invention, a method for preparing magnetic bead microspheres, carrying out surface modification and carrying out surface coupling on an FGF21 specific antibody is deeply explored, and the FGF21 specific antibody containing an acridinium ester label and a luminescence excitation system are matched, so that the prepared FGF21 detection kit can be used for accurately detecting FGF21 protein; and the detection kit has the advantages of high sensitivity, good accuracy, good repeatability and high automation degree of test operation, can treat a large batch of samples, further provides effective detection products and methods for clinical detection, and has strong practicability.

The invention relates to an acridine sulfonamide carboxylic acid derivative as well as a preparation method and application thereof, and the preparation method comprises the following steps: in an alkaline environment, acridine sulfonamide and amino acid or an amino acid derivative are subjected to amidation reaction in an organic solvent, and the acridine sulfonamide carboxylic acid derivative is obtained after purification; wherein the acridine sulfonamide carboxylic acid derivative has two acridine sulfonamide-like groups, and the two acridine sulfonamide-like groups are connected through the amino acid or the amino acid derivative. The yield of the preparation method exceeds 70%, and the luminous efficiency of the prepared acridine sulfonamide carboxylic acid derivative is higher and is about two times that of acridine sulfonamide NSP-SA-NHS.

The invention belongs to the photovoltaic field, and particularly relates to a hole transport layer compound, a hole transport layer, a photovoltaic device and a preparation method. The hole transport layer compound disclosed by the invention has a structure as shown in a formula I, wherein the definitions of X1, X2, A and L are described in the specification. The hole transport layer compound provided by the invention is an acridine derivative, has better film forming uniformity as a hole transport material, can improve the performance of a large-size perovskite photovoltaic device, and has very high commercial application prospects. # imgabs0 #

The invention discloses a method for preparing a biological hydrocarbon compound by organic photocatalysis higher fatty acid decarboxylation, which comprises the following steps: adding higher fatty acid, a hydrogen atom transfer catalyst and an acridine photocatalyst / solid-phase acridine photocatalyst into a reaction solvent, stirring and reacting for 12-24 hours under the conditions of blue light irradiation and room temperature to obtain a reaction solution, filtering, washing and drying to obtain the biological hydrocarbon compound. And removing the reaction solvent of the obtained reaction solution under reduced pressure, and purifying by thin layer chromatography / column chromatography to obtain the long-chain alkane compound after decarboxylation of the higher fatty acid. The method is simple in step, mild in reaction condition and high in product yield, does not use any metal compound, and has the characteristics of high atom economy and environmental protection. And for unsaturated carboxylic acid, olefin configuration before and after decarboxylation is not influenced. When solid-phase acridine is used as a photocatalyst for reaction, the catalyst can be recycled through simple washing, filtering and recycling, excellent catalytic activity can still be kept after the catalyst is recycled for more than 10 times, and the reaction cost is further reduced.

The invention discloses a method for detecting beta-amyloid protein in urine by magnetic particle chemiluminescence based on acridinium ester. The method comprises the following steps: (1) coupling carboxyl magnetic beads with an A beta 42 N-terminal antibody; (2) labeling acridinium ester and a Lec antibody; and (3) respectively diluting the A beta calibrator, the urine sample to be detected, the magnetic bead compound and the acridinium ester-Lec antibody compound, and carrying out luminescence detection on a luminescence instrument.

The invention discloses an acridine-derived thermally activated delayed fluorescent material and an electroluminescent device thereof, and belongs to the technical field of organic luminescent materials. According to the fluorescent material, any electron withdrawing group is used as a receptor, an acridine derivative is used as a donor, nitrogen atoms of the acridine derivative are directly connected with the receptor, a dihedral angle between an electron donor and the electron receptor is increased, the dihedral angle is kept at an angle close to 90 degrees, meanwhile, the large-rigidity donor structure further reduces intramolecular vibration relaxation, and the fluorescence intensity is improved. In addition, HOMO delocalization can be further realized through side conjugation modification of acridine, so that large antiintersystem crossing rate and radiation decay rate are realized, the luminescence property of molecules is further improved, and the efficiency roll-off is reduced. The material provided by the invention can be used as an active material to be applied to organic electroluminescent devices.

The invention discloses an electrolytic adhesive tape, which relates to the technical field of adhesives and sequentially comprises a first release film layer, a first electrolytic adhesive layer, an aluminum foil base material layer, a second electrolytic adhesive layer and a second release film layer from top to bottom, the first electrolytic adhesive layer and the second electrolytic adhesive layer are mutually independently prepared from the following raw materials in parts by weight: 100 parts of functional copolymer, 6-15 parts of metal lithium salt, 1-2 parts of surfactant, 4-6 parts of amphoteric organic ion salt, 3-5 parts of (3, 6-diamino acridine-9-yl) boric acid, 0.3-1 part of flatting agent and 30-50 parts of solvent. The electrolytic adhesive tape is small in ion exudation amount, good in bonding strength before energization, low in bonding strength after energization and free of adhesive residues during stripping.

The invention belongs to the technical field of photocuring, and particularly relates to an acridine-anthracene compound and a photosensitizer or photoinitiator containing the acridine-anthracene compound. Specifically, the structure of the compound disclosed by the invention is shown as a formula (I), and compared with the existing commercial sensitizer, the compound disclosed by the invention has the advantages of higher curing hardness, no frosting phenomenon and excellent solubility and photosensitive activity, and can be applied to the field of photocuring as a sensitizer or a photoinitiator.

The invention relates to a kit for jointly detecting markers A beta 1-40 and A beta 1-42 as well as a preparation method and application of the kit, and relates to the technical field of immunodetection. The kit comprises a first reagent and a second reagent, the first reagent comprises a magnetic bead working solution and a magnetic microsphere coated with an A beta polyclonal antibody; and the second reagent comprises a labeled antibody diluent and an acridinium ester labeled anti-A beta antibody. According to the method, an anti-A beta 1-40 antibody and an anti-A beta 1-42 antibody with high specificity are adopted, and the ratio of A beta 1-40 to A beta 1-42 is calculated; a magnetic bead working solution and a labeled antibody diluent are adopted, so that the sensitivity and the stabilizer of the kit are further improved; the detection time is 8 minutes, the result can be obtained, the repeatability is within 4%, the lowest detection limit of A beta 1-40 is 1.08 pg / ml, and the lowest detection limit of A beta 1-42 is 1.08 pg / ml.

The invention relates to an acridone-based self-assembly material, a perovskite solar cell and a preparation method, the self-assembly material has the following structure: # imgabs0 #, in which X1 and X2 are respectively and independently selected from hydrogen or halogen elements; l is alkylene or phenylene; a is a phosphate group; according to the acridone-based self-assembly material disclosed by the invention, the pi electron conjugation effect on a benzene ring is utilized, carbonyl groups are increased, the interaction with perovskite is enhanced, and the passivation effect on defects in a perovskite absorption layer can be improved, so that the non-radiative recombination of carriers is effectively reduced, the perovskite defects are fewer, the crystallinity is enhanced, the quality is higher, and the performance of the material is improved. The photoelectric conversion efficiency and filling factors of the cell are further improved, and the overall performance of the cell is improved.

The present invention relates to the technical field of organic light-emitting materials, and provides a tetradentate cyclometalated platinum (II) complex based on an oxygen atom linkage and containing phenyl acridine and an application thereof. The tetradentate cyclometalated platinum (II) complex has the structure as represented by general formula (I). (I) The cyclometalated platinum (II) complex in the present invention adopts a tetradentate ligand, is high in rigidity, and can improve the light stability of a light-emitting material. At the same time, the complex molecule can strongly emit light, and therefore can be used as a light-emitting material in an OLED device.

The invention relates to the technical field of solar cells, in particular to a self-assembled monomolecular hole transport material, a preparation method and application thereof, a perovskite solar cell, a preparation method thereof and a photovoltaic module. The self-assembled monomolecular hole transport material provided by the invention has a structure as shown in a formula I. In the formula I, A1, A2 and A3 are respectively and independently anchor groups or hydrogen atoms; the anchoring groups are independently selected from phosphate groups respectively; g is selected from a substituted or unsubstituted carbazolyl group, a substituted or unsubstituted acridinyl group, a substituted or unsubstituted phenothiazinyl group, and a substituted or unsubstituted phenoxazinyl group. The self-assembled monomolecular hole transport material provided by the invention has stronger anchoring binding capacity, conjugation in molecules is enhanced through the aromatic connection unit, and transport of carriers is facilitated; polyphosphonic acid anchoring in the self-assembled monomolecular hole transport material provided by the invention can enhance adsorption and uniformity of molecules, and a formed hole transport interface has better charge transport and defect passivation effects.

The invention provides a photosensitive resin composition containing an acridine methylene quaternary ammonium salt photosensitizer and application of the photosensitive resin composition, quaternary ammonium group substituted methylene is introduced to the ninth position of a structural main body acridine ring of the photosensitizer, and acid radical or halogen is adopted as equilibrium anion. According to the photosensitizer, a quaternary ammonium salt group is introduced to the 9 site of an acridine ring, so that the problems that a traditional 9-phenylacridine photosensitizer is poor in compatibility, prone to crystallization and precipitation, insufficient in water solubility, weak in antistatic performance and the like in a formula are effectively solved. The photosensitive resin composition disclosed by the invention shows excellent dispersion stability, high sensitivity and high resolution, and can be used for remarkably reducing precipitates in a developing process and reducing poor lamination caused by static accumulation. The photosensitive dry film prepared based on the composition is suitable for fine pattern manufacturing in the fields of dry films, paints, coatings, printing ink, forming materials and the like, and has high yield and production efficiency.

The invention discloses a nopinic alkyl acridine fluorescent probe for detecting hydrazine and viscosity as well as a preparation method and application of the nopinic alkyl acridine fluorescent probe. The probe is 2-(2-(5-(4-(3, 3-dimethyl-1, 2, 3, 4-tetrahydro-2, 4-methylene acridine-9-yl) phenyl) furan-2-yl) vinyl)-1, 1, 3-trimethyl-1H-benzo [e] indoleonium iodized salt, which is called TA-PFV-BI for short. The probe can detect the viscosity of a solution, and red fluorescence emitted by the probe is gradually enhanced along with the improvement of the viscosity of the solution under the irradiation of ultraviolet light with the wavelength of 365 nm. The probe can also have a specific reaction with hydrazine, so that the fluorescence color of a probe solution is changed from colorless to bright blue, the detection range is 0-90 mu M, the response time is within 5 seconds, the detection limit is 4 * 10 <-8 > M, and the applicable pH range is 5-10. The probe TA-PFV-BI, as a bifunctional fluorescent probe capable of simultaneously detecting hydrazine and viscosity, has the advantages of good selectivity, high sensitivity, fast response, wide application range and the like, and shows a good application prospect.

The invention discloses an MALDI-MSI method for visually analyzing distribution of active ingredients of rhizoma smilacis glabrae in tissues in a rat body. The space metabolism distribution characteristics of the rhizoma smilacis glabrae bioactive components in a rat body are analyzed by utilizing an MALDI-MSI mass spectrum imaging technology, 9-aminoacridine is creatively used as a matrix based on the characteristics of the rhizoma smilacis glabrae active components, and the concentration of the 9-aminoacridine matrix and MALDI mass spectrum parameters are optimized, so that the sensitivity of the rhizoma smilacis glabrae bioactive components is improved. The ion inhibition effect of the matrix on the glabrous greenbrier rhizome active component is eliminated, the signal response of the glabrous greenbrier rhizome active component is obviously enhanced, the mass spectrum imaging quality level is improved, and the in-situ visual detection of the glabrous greenbrier rhizome active component in different tissues and organs of rats is successfully realized.

The invention belongs to the field of chemiluminescence, and particularly relates to a preservation solution of an acridinium ester marker, a kit and a preparation method and application of the preservation solution. According to the preservation solution of the acridinium ester marker, the sodium caseinate and the BSA are adopted as protein stabilizers, and the specific surfactant, the preservative and the neutral salt range are matched to serve as the preservation solution, so that the stability of the acridinium ester and the marked object of the acridinium ester can be kept. In addition, when the preservation solution acridinium ester marker is adopted for dilution, the diluted reagent can be placed for at least 8 days at 37 DEG C, background signals can be effectively detected, and the detection sensitivity can be improved.

This invention relates to toners. A toner comprises toner particles containing a binder resin, wherein the toner particles further comprise a compound represented by formula (1) and a pigment having a quinacridone structure; wherein, in formula (1), R represents a straight-chain or branched alkyl group having 4 to 22 carbon atoms, and n is an integer from 1 to 4.

The application belongs to the technical field of medicine, and relates to N-methyl-2-(9-oxoacridin-10(9H)-yl)acetamide compounds and a preparation method and application thereof. The preparation method of the compound is as follows: taking o-aminobenzoic acid as a starting material, performing substitution reaction, condensation reaction, alkylation reaction and hydrolysis reaction to generate a key intermediate acridone acetic acid, and finally performing condensation reaction on the acridone acetic acid and substituted pyrimidine in the presence of TCFH and NMI condensing agents to obtain the target compound. The preparation method of the N-methyl-2-(9-oxoacridin-10(9H)-yl)acetamide compound provided in the application is simple and feasible, and good results are shown in in-vitro anti-tumor activity tests, and the compound has excellent anti-proliferation ability on human breast cancer cells BT-549 and MDA-MB-231 in particular.

Provided herein are methods, systems, and kits for determining the concentration or level of an analyte of interest using a competitive and sandwich immunoassay. Also provided herein are acridinium-containing and acridone-containing compounds for use in assays to detect the presence of or determine the concentration or level an analyte of interest in a sample, e.g., a biological sample.

The application discloses an acridinium ester labeled complex, which comprises a body, and a labeling group labeled on the body, wherein the body is an antibody, and the labeling group is an acridinium ester group. A preparation method of the acridinium ester labeled complex comprises the following steps: sucking a labeling buffer into a centrifugal tube; sucking an antibody to be labeled into the centrifugal tube and mixing to generate a first mixed solution; adding an acridinium ester solution and mixing, and then performing reaction at 25 DEG C in the dark for 2 hours to generate a second reaction solution; adding a termination buffer and mixing, and then performing reaction at 25 DEG C in the dark for 30 minutes to generate a third reaction solution; performing desalting purification on the third reaction solution to generate a fourth mixed solution; and filtering the fourth mixed solution with a 0.22 mu m filter membrane to generate the acridinium ester labeled complex. According to the preparation method, the labeling efficiency of the acridinium ester and the antibody is higher, the reactivity is stronger, the non-specific adsorption is lower, the sensitivity is higher, the repeatability and stability are better, and the labeling method is simple, rapid and easy to repeat.