418 results about "Benzophenone" patented technology

The invention discloses a synthetic method of a water soluble ultraviolet light absorber BP-9. The method mainly comprises the following process steps: (1) carrying out methylation on the main raw materials of 2, 2', 4, 4'-tetrahydroxyl benzophenone, a transition metal salt catalyst and a mixed solvent which is prepared from dichloroethane and anhydrous ethanol in equal parts by weight to obtain 2, 2'-dihydroxyl-4, 4'-dimethoxyl benzophenone; (2) carrying out sulfonation reaction on the main raw materials of methylate, sulfamic acid and C1-C3 halohydrocarbon to obtain 2, 2'-dihydroxyl-4, 4'-dimethoxyl benzophenone-5, 5'-disulfonic acid; and (3) carrying out neutral reaction on the main raw materials of sulfonated product, inorganic base and ethanol water to finally obtain the BP-9 product. The synthetic method disclosed by the invention is few in reaction step, low in cost, high in product purity and stable in quality, and raw materials are easily available.

The invention belongs to the technical field of coatings, and relates to a polysiloxane epoxy hybrid environment-friendly coating and a preparation method thereof. The coating belongs to an environment-friendly solvent type coating with low VOC content, modified epoxy resin is adopted as a base, auxiliaries such as a film-forming agent and a dispersing agent are added, and benzophenone and tertiary amine composite photoinitiator is supplemented, so that the prepared coating has good corrosion resistance, high temperature resistance and the like, and the coating can quickly form a film at normal temperature and under the UV illumination condition, shortens the curing period, and is suitable for large-scale popularization and application. The emission of VOC (volatile organic compounds) is reduced.

The invention relates to the technical field of transfer films, in particular to a graphene-containing far-infrared warm-keeping polyurethane transfer film and a preparation method thereof. The far-infrared warm-keeping polyurethane transfer film containing graphene comprises a three-layer structure including a supporting layer, a polyurethane transfer layer and a bonding layer, the polyurethane transfer layer is located on one side of the supporting layer, and the bonding layer is located on the other side of the polyurethane transfer layer; the polyurethane transfer layer is prepared from polyurethane resin, an organic solvent, an organic pigment and a composite modifier, the composite modifier is prepared from alkenyl modified graphene oxide, chloropropenyl modified hindered phenol and 4-allyloxy-2-hydroxybenzophenone, and the composite modifier is added, so that the polyurethane transfer layer is formed. The polyurethane transfer film has far infrared thermal insulation performance and good oxidation resistance and hydrolysis resistance.

The invention belongs to the technical field of polymer chemical production, and discloses a method for continuously and efficiently preparing polyether-ether-ketone. The method comprises the following steps: dissolving 4, 4 '-difluorobenzophenone and diphenyl sulfone in a first dissolving tank to obtain a 4, 4'-difluorobenzophenone solution; hydroquinone, a catalyst and diphenyl sulfone are placed in a second dissolving tank to be dissolved, and a hydroquinone solution is obtained; the preparation method comprises the following steps: injecting a 4, 4 '-difluorobenzophenone solution and a hydroquinone solution into a reactor for polymerization reaction to obtain a mixed solution; injecting the mixed solution into a separator through a heat exchanger for separation to obtain polyether-ether-ketone and liquid; distilling the liquid to obtain diphenyl sulfone and sodium fluoride, and returning the obtained diphenyl sulfone to participate in dissolution; all the steps are carried out in a protective atmosphere. The preparation process provided by the invention is a brand new PEEK production process flow, and realizes continuous PEEK production and efficient energy recycling.

The invention relates to the technical field of composite materials, in particular to a polyaryletherketone-based shape memory composite material and a preparation method thereof. Comprising a terpolymer, shape memory polyurethane, a first heat-conducting filler and a second heat-conducting filler, 4, 4 '-difluorobenzophenone and hydroquinone are firstly pre-polymerized to obtain a PEEK prepolymer, the PEEK prepolymer is terminated by a hydroxyl olefine acid ester monomer to obtain a terminated copolymer, and then an acrylate monomer and the terminated copolymer are subjected to double-bond addition to obtain the terpolymer; the first heat-conducting filler is a one-dimensional nano heat-conducting filler; the second heat-conducting filler is a zero-dimensional and / or two-dimensional heat-conducting substance; the prepared composite material has the shape fixing rate of 85% or above and the shape recovery rate of 87% or above, the recovery time is shorter than 25 seconds, and the good shape memory performance is achieved.

The invention relates to polyether-ether-ketone resin with extremely narrow molecular weight distribution as well as a preparation method and application of the polyether-ether-ketone resin. The preparation method of the polyether-ether-ketone resin comprises the following steps: uniformly mixing 4, 4 '-difluorobenzophenone, a phenolic monomer, a salt-forming agent and a solvent in an inert atmosphere, carrying out gradient heating, and then carrying out end capping; the gradient heating comprises the following steps: in the initial stage, the heat preservation temperature is 140-210 DEG C, in the transition stage, the heat preservation temperature is 250-280 DEG C, and in the final stage, the heat preservation temperature is 300-320 DEG C. The prepared PEEK resin has very narrow molecular weight distribution, the chemical, heat-resistant stability, anti-fatigue performance and mechanical performance of the PEEK resin can be remarkably improved, and the high-performance and high-quality requirements of PEEK in the high-end manufacturing field such as aerospace, medical treatment, electronics and semiconductors are met.

The present invention relates to a vinyl pyrrolidone copolymer of N-vinyl pyrrolidone and a maleic acid comonomer wherein the vinyl pyrrolidone copolymer is functionalized with a benzophenone substituent (BP) wherein the amount of maleic acid in the vinyl pyrrolidone copolymer is less than 1 mol%, preferably from 0.1 to 0.95 mol%, further preferably from 0.1 to 0.90 mol%, more preferably from 0.1 to 0.85 mol%, more preferably from 0.2 to 0.88 mol%, and the amount of N-vinyl pyrrolidone is less than 1 mol%, preferably from 0.1 to 0.95 mol%, further preferably from 0.1 to 0.90 mol%, more preferably from 0.1 to 0.85 mol%, more preferably from 0.2 to 0.88 mol%. The invention relates to the technical field of organic solvents, in particular to a method for preparing the organic solvents, which comprises the following steps of: preferably, 1-3mol%, more preferably, 0.3-0.88 mol%, more preferably, 0.4-0.88 mol%, even more preferably, 0.5-0.85 The vinyl pyrrolidone copolymer of the present invention is particularly suitable for use in coatings of medical devices and / or medical aids. Thus, the invention also relates to a composition comprising a vinyl pyrrolidone copolymer and optionally a cross-linking agent, and a medical device having a coating comprising a cross-linked vinyl pyrrolidone copolymer and optionally a cross-linking agent.

The invention relates to the technical field of nano-composite water-based resin system design and function coordinated regulation and control, in particular to environment-friendly high-gloss wear-resistant water-based epoxy floor paint and a preparation method thereof. The environment-friendly high-gloss wear-resistant water-based epoxy floor paint is prepared from self-emulsifying water-based epoxy resin emulsion, a modified water-based epoxy curing agent containing biguanidyl and the like; the preparation method comprises the following steps: carrying out synergistic modification on a three-dimensional composite wear-resistant filler containing nano silicon dioxide-carbon nanotube-graphene through a silane coupling agent and dopamine; the light response type composite light stabilizer is compounded by a titanium dioxide grafted hindered amine light stabilizer and a benzophenone light stabilizer; a phase change temperature adjusting microcapsule and a nano-silver-chitosan antibacterial agent can also be added, so that multiple functions are realized. According to the floor paint disclosed by the invention, through an innovative formula and process, wear resistance, luster and weather resistance are remarkably improved, and toughness and crack resistance are enhanced; and the preparation method is environment-friendly and efficient, meets the requirements of multiple scenes, and has high economic value.

The embodiment of the invention provides a compound, an adhesive, a laminated structure, a display module and electronic equipment, and relates to the field of materials. The hydrogen abstracting type free radical photoinitiator in the adhesive comprises a substituted benzophenone structure. The substituted benzophenone structure is not activated under ultraviolet irradiation of sunlight, and the adhesive has certain bonding force. Under the ultraviolet irradiation of a non-sunlight condition, the substituted benzophenone structure is activated, and the flexible optical cement in the adhesive can be initiated to crosslink, so that the adhesive strength of the adhesive is reduced, and the application flexibility of the adhesive is improved.

The invention discloses a preparation process of polyether-ether-ketone, and relates to the technical field of preparation of inorganic compounds. The preparation process comprises the following steps: reacting 4, 4 '-difluorobenzophenone, sodium carbonate and hydroquinone to generate polyether-ether-ketone, taking a polyaryletherketone block oligomer as an end-capping reagent, reacting 4, 4'-difluorobenzophenone with 4, 4 '-dimercaptodiphenyl sulfone, and then reacting with pentaerythritol phosphate to obtain the polyaryletherketone block oligomer. The thioester bond reversibly breaks at the polymerization temperature, exposed active sulfenyl reacts with hydroxyl at the tail end of the polyether-ether-ketone to form a more stable covalent bond, volatilization of the end-capping reagent is avoided, meanwhile, the initial decomposition temperature of the end-capped polyether-ether-ketone is increased, and the stability of the end-capping reagent is improved. The polyether-ether-ketone generated in the polyether-ether-ketone resin product is subjected to treatment procedures of crushing, organic solvent extraction, water washing, filtering, drying and the like, so that the product polyether-ether-ketone is obtained, less three wastes are generated, the solvent can be recycled, the atom economy is relatively high, and the preparation process of comprehensive utilization of resources is realized.

The application belongs to the technical field of cable materials, and discloses a cold-resistant and anti-cracking type special cable made of silicone rubber, which comprises a conductor cable core, an inner protective sleeve and an outer protective sleeve from inside to outside, wherein the raw materials of the outer protective sleeve comprise end-vinyl diphenyl siloxane, methyl vinyl siloxane, silane modified nano silicon dioxide, polyborosiloxane, an inhibitor, hydroxyl silicone oil, modified anti-ultraviolet polyurethane, a platinum catalyst and tetra(dimethylsiloxane) silane; diphenyl siloxane with a diphenyl side chain is selected as a main chain, and the modified anti-ultraviolet polyurethane is grafted to effectively destroy the structural regularity, inhibit low-temperature crystallization and prevent cable cracking; 4,4'-diamino benzophenone with anti-ultraviolet function is used as a chain extender and benzotriazole is used as an end-capping agent to be grafted into the polyurethane chain, so that the anti-ultraviolet capacity can be improved and migration can be avoided.

The invention relates to the field of sheath materials, and discloses an anti-aging sheath material for an electronic wire and a preparation method thereof, the sheath material comprises low density polyethylene, an ethylene-vinyl acetate copolymer, an ethylene-octene copolymer, ethylene propylene diene monomer, a triazine ring derivative, ammonium polyphosphate, modified nano silicon dioxide and an auxiliary agent; according to the triazine ring derivative, N-butyl-2, 2, 6, 6-tetramethyl-4-piperidylamine reacts with cyanuric chloride to prepare a triazine ring monosubstituent, hydrazine hydrochloride is used as a bridging agent to react with the triazine ring monosubstituent, and the triazine ring derivative and piperazine are polymerized to prepare the triazine ring derivative. The modified nano silicon dioxide is prepared by enabling 3-(3, 5-di-tert-butyl-4-hydroxyphenyl) propionyl chloride and 4-propenyloxy-2-hydroxybenzophenone to react, and carrying out free radical polymerization on the reaction product on the surface of the nano silicon dioxide. The synergistic effect of mechanical property, thermo-oxidative aging resistance, ultraviolet aging resistance and flame retardant property is realized.

The invention provides a block copolymer toughening-based polyether-ether-ketone material and a preparation method thereof, and relates to the technical field of high polymer materials, the method is characterized in that a block copolymer PAEK-B with a specific sequence structure is synthesized by accurately controlling a ternary block copolymerization reaction of hydroquinone, 4, 4 '-difluorobenzophenone and biphenol, and the block copolymer PAEK-B with a specific sequence structure is obtained. And then the mixture is subjected to melt blending with PEEK, so that the toughness of the PEEK is effectively improved, the mechanical property is improved, and meanwhile, the original processing temperature is kept unchanged.

The invention discloses a preparation method of an antibacterial warm-keeping fabric, and relates to the technical field of textiles. When the antibacterial warm-keeping fabric is prepared, firstly, (E)-butyl-2-ene-1, 4-diamine, glyoxal, formaldehyde and butyric acid are used as raw materials to synthesize a polyimidazolium salt antibacterial agent, then the polyimidazolium salt antibacterial agent is copolymerized with polytetrahydrofuran ether glycol and diphenylmethane diisocyanate to prepare an antibacterial polyurethane spinning solution, and the antibacterial fabric is obtained through wet spinning and weaving. The preparation method comprises the following steps: reacting L-cysteine with 3-amino propyl triethoxy silane to prepare cysteamine acyl propyl triethoxy silane, reacting with formaldehyde and phosphorous acid to obtain flame-retardant modified silane, and further preparing a silicon dioxide solution from the flame-retardant modified silane and sol-gel such as methyltrimethoxysilane; finally, the antibacterial fabric is treated with a benzophenone solution and then soaked with a silicon dioxide solution, and the antibacterial thermal fabric is prepared through ultraviolet irradiation, standing gelation, aging and hexane washing. The prepared fabric has excellent antibacterial property, heat retention property and flame retardant property.

The invention relates to the technical field of high-molecular polymers and surface chemical modification thereof, in particular to a low-dielectric-constant polyaryletherketone material and a preparation method thereof, and a flexible copper foil laminated structure and a preparation method thereof. The low-dielectric-constant polyaryletherketone material is obtained by taking a bisphenol monomer and difluorobenzophenone as reaction monomers and carrying out aromatic nucleophilic polycondensation reaction; wherein the bisphenol monomer is selected from a combination of C3-C8 normal or isomeric alkyl substituted hydroquinone and bisphenol containing at least one aryl group; the bisphenol containing at least one aryl group is selected from one or more of bisphenol AP, bisphenol BP, bisphenol Z and bisphenol fluorene; the low-dielectric-constant polyaryletherketone material forms a thin film, the surfactant treatment layer and the grafting layer are sequentially formed on the thin film, then the thin film is compounded with the copper foil, and the formed flexible copper foil laminated structure has high peel strength and low dielectric constant.

The invention discloses a catalyst for preparing benzophenone compounds and a preparation method and application of the catalyst, the catalyst is alkaline manganese oxide and is expressed as aZOx.bMnO2, Z is any one of lithium, potassium, sodium, magnesium and calcium; x is the number of oxygen atoms required by the oxidation state of the metal element Z; a and b are respectively the atom number of Z and Mn in the catalyst, and the atom number ratio of Z to Mn in the catalyst is 0.2-10. According to the catalyst provided by the invention, the preparation method is simple, the benzophenone or halogenated benzophenone can be prepared by catalyzing efficient oxidation of diphenylmethane and halogenated diphenylmethane containing a passivation group, the catalyst activity is high, the product selectivity is high, the product is easy to separate, and the catalyst can be recycled.

The invention discloses a polyolefin graft modification method based on coating and photochemical reaction, which comprises the following steps: step 1, raw material preparation: mixing 20-50 parts by weight of glycidyl methacrylate (GMA), 1-5 parts by weight of benzophenone (BP) and 1-2 parts by weight of triethylamine (TEA), and uniformly stirring to obtain a mixed solution; 2, coating: coating the surface of a polyolefin film with the mixed solution obtained in the step 1, wherein the coating weight is 1g / m < 2 >-3g / m < 2 >; the method has the beneficial effects that a peroxide initiator is not needed, the reaction is initiated by ultraviolet light, the reaction condition is mild, polyolefin degradation and side reaction are reduced, and the grafting rate is greater than 3.5%; ethyl acetate and other low-toxicity solvents are adopted, residual solvents can be removed through oven treatment, and the environment-friendly requirement is met; active groups such as an epoxy group are introduced into a grafted product, so that the compatibility with a polar material is remarkably improved, and the breaking strength is improved by more than 50% compared with that of common PP; the polyolefine can be used as an interface compatibilizer, a macromolecular coupling agent and the like, and the application of the polyolefine in the high-end field is expanded.

The invention relates to an activating and coloring method of a polypropylene non-woven fabric, and belongs to the technical field of fabric coloring. Polypropylene non-woven fabric is modified through polydopamine, then sodium borohydride is used for reduction decoloration, and finally a dye solution is used for coloring. After reduction and decolorization, a benzophenone quaternary ammonium salt compound can be further utilized for modification, so that the color fastness of dyeing is improved. By means of spontaneous polymerization of dopamine on the surface of the polypropylene non-woven fabric, the polypropylene non-woven fabric which is originally hydrophobic and inert is converted into a material with functional activity, the surface performance of the non-woven fabric is improved, the binding capacity of the non-woven fabric and dye is enhanced, and the dyeing uniformity is improved. Sodium borohydride is used for reducing and decolorizing the polydopamine modified polypropylene non-woven fabric, so that brown chromaticity can be effectively removed, follow-up dyeing interference is avoided, active functional groups on the surface of the non-woven fabric are reserved, and good surface performance and structure of the non-woven fabric are maintained.

The present invention provides a photoinitiator including at least one benzophenone group and a urethane bond, an adhesive composition including the photoinitiator, an adhesive film including an adhesive layer including a photocured product of the adhesive composition, and a method for preparing the adhesive film.

The present invention provides a polyimide film and a method for manufacturing the polyimide film, wherein the polyamic acid solution is obtained by imidizing a dianhydric acid component comprising two or more selected from the group consisting of benzophenone tetracarboxylic dianhydride (BTDA), biphenyltetracarboxylic dianhydride (BPDA), and pyromellitic dianhydride (PMDA), and a diamine component comprising paraphenylene diamine (PPD), wherein, based on a total content of 100 mol% of the diamine component, the content of paraphenylene diamine is 70 mol% or more and 100 mol% or less, and based on a total content of 100 mol% of the dianhydric acid component, the content of biphenyltetracarboxylic dianhydride is 50 mol% or more and less than 100 mol%, the dielectric loss rate (Df) is 0.003 or less, and the light transmittance at a wavelength of 550 nm is 15% or more and 50% or less.

The invention discloses a medium-matte polyester film which is composed of a base material layer A, a surface matte layer B and a matte coating C sprayed on the outer side of the surface matte layer B. The base material layer A is composed of polyethylene glycol terephthalate and silicon dioxide nanoparticles. The surface matte layer B is composed of polyethylene glycol terephthalate, polytetrafluoroethylene and polyethylene glycol nanoparticles; the matte coating C is prepared from polyurethane acrylate, organic silicon silicon dioxide particles, triethylene glycol tripropoxy acrylate, benzophenone, polyether siloxane and polydimethylsiloxane. According to the medium-matt-degree polyester film, by optimizing the proportion of components such as PET, SiO2, PTFE and PEG, the good mechanical strength, wear resistance and matt effect are balanced, and the medium-matt-degree polyester film has excellent light transmittance and ultraviolet resistance. The film not only has low glossiness and high haze, but also shows excellent chemical resistance, scratch resistance and long-term stability, and is suitable for high-end applications such as polaroid release films and optical devices.

The invention relates to the technical field of ketone processing, in particular to a multifunctional treatment box for synthesizing 2-fluoro-benzophenone.The multifunctional treatment box comprises a processing treatment box, and a plurality of sets of processing treatment cavities used for synthesizing 2-fluoro-benzophenone are arranged in the processing treatment box from top to bottom; the processing treatment cavity comprises a mixing and dissolving reaction cavity which moves up and down along the upper side area in the processing treatment box, and a contact heating cavity and a water bath cooling cavity which are fixed in the processing treatment box are separately arranged on the upper side and the lower side of the mixing and dissolving reaction cavity at intervals; the bottom of the water bath cooling cavity is communicated with a washing cavity for washing the cooled solution in a pressing manner, the bottom of the washing cavity is communicated with a separation cavity for separating the washed solution, and the bottom end of the separation cavity is communicated with a concentration cavity for rotationally evaporating the separated solution in a control manner; the bottom end of the concentration cavity is communicated with a purification cavity in an automatic detection opening and closing manner. The treatment box can be used for automatically processing ketone in an energy-saving manner, and meanwhile, the low-cost operation is kept.

A process for the preparation of a compound of the sterically hindered alkoxyamine class is described, the process comprises the step of alkylating a sterically hindered hydroxylamine compound to a corresponding sterically hindered alkoxyamine by reacting said sterically hindered nitroxyl compound with a compound capable of producing a carbon-central alkyl radical, typically a territorial or secondary alkyl radical, the compounds capable of generating carbon-center alkyl radicals are selected from thermal radical initiators that form radical species in the temperature range of 40 DEG C to 200 DEG C, and from photoinitiators that undergo light excitation when irradiated with UV light or visible light in the range of 180 to 700 nm, in particular UV light in the range of 180 to 380 nm, the compounds capable of generating carbon center alkyl radicals are typically selected from the class of organic peroxides, azo compounds, benzoyl derivatives, benzophenone derivatives, thioxanthone derivatives, benzoin derivatives, benzoyl phosphine oxide derivatives, and the like. The invention relates to a peroxide, for example, selected from the group consisting of diacyl peroxides of formula (A), peracid esters of this formula (A), and oxalic acid peracid esters of formula (D) R-CO-O-O-Z-R (A), r-Z ''-X-CO-CO-O-O-Z''-R (D) wherein each R independently represents a primary or secondary alkyl or cycloalkyl group, preferably comprising from 1 to 15 carbon atoms, and X is oxygen-O-or peroxy-O-O-, Z represents CO or an alkylene group bonded to a quaternary carbon atom, the quaternary carbon atom being an alkylene group of formula (C) R '-C-R' (C), wherein each R'is selected from alkyl groups having 1 to 15 carbon atoms, and Z "represents the alkylene group bonded to a quaternary carbon atom having the formula (C). The described process produces the corresponding O-alkylated derivatives of the sterically hindered hydroxylamines, typically compounds of the class referred to as N-O-alkyl HALS, with very high selectivity and conversion and without the need for the use of catalysts, in particular metal catalysts.

The invention relates to the technical field of polyurethane foam preparation, and discloses polyurethane foam for a heat insulation strip and a preparation method of the polyurethane foam. The polyurethane foam is prepared from the following raw materials in parts by weight: 40 to 60 parts of polytetrahydrofuran ether glycol, 10 to 15 parts of modified monomer, 1 to 5 parts of ethylenediamine, 1 to 5 parts of hydroxyethyl methylacrylate, 60 to 80 parts of diphenylmethane diisocyanate, 3 to 5 parts of modified filler, 0.3 to 0.5 part of benzophenone and 10 to 15 parts of n-pentane. Double bonds on hydroxyethyl methylacrylate can react with sulfydryl on the surface of the modified filler, then a cross-linked network is formed in the material, the foam structure is more uniform and stable by limiting molecular chain movement and reducing gas diffusion and heat conduction paths, and the closed-cell rate of the foam can be increased by matching with a multi-layer coated hollow structure of the modified filler, so that the thermal conductivity of the foam is improved. And gas diffusion is reduced, so that the long-term stable heat insulation effect is maintained.

The invention discloses printing ink and application thereof, and relates to the technical field of light-cured printing ink. The ink comprises a photoinitiator and an ultraviolet light absorber, the mass fraction of the ultraviolet light absorber is 20%-80% based on 100% of the mass fraction of the photoinitiator, and the light absorption wavelength of the ultraviolet light absorber is 250 nm-360 nm; the ultraviolet light absorber comprises at least one of a benzophenone ultraviolet light absorber, a triazine ultraviolet light absorber and a formamidine ultraviolet light absorber. By selecting the components of the ink, the curing uniformity of the surface layer and the bottom layer of the ink is better, and the stability and durability of the ink layer are favorably improved.

The multilayer polyimide film (10) has a non-thermoplastic polyimide layer (11) and a thermoplastic polyimide layer (12) disposed on at least one surface of the non-thermoplastic polyimide layer (11). A non-thermoplastic polyimide contained in the non-thermoplastic polyimide layer (11) has, as a tetracarboxylic acid dianhydride residue, a tetracarboxylic acid dianhydride residue containing a benzophenone skeleton, and has, as a diamine residue, a diamine residue containing a biphenyl skeleton. Furthermore, in the multilayer polyimide film (10), the content of diamine residues containing a biphenyl skeleton in the non-thermoplastic polyimide is 30-100 mol% with respect to the total diamine residues constituting the non-thermoplastic polyimide.

The invention discloses a self-cleaning bionic anti-drag film based on a sharkskin surface structure and a preparation process of the self-cleaning bionic anti-drag film, and relates to the technical field of bionic anti-drag film preparation. According to the invention, resorcinol bis (2-hydroxyethyl) ether, 3, 3 ', 4, 4'-benzophenone tetracarboxylic dianhydride and the like are used as raw materials to prepare polyol containing an ester bond and an ether bond, the polyol reacts with 4, 4-diisocyanate dicyclohexylmethane to obtain a thermoplastic polyurethane film with high temperature resistance, and the polyol is also used for preparing an antistatic polyurethane coating, so that the antistatic polyurethane coating has high temperature resistance. And quaternary ammonium salt and sulfhydrylated titanium dioxide are introduced, so that the anti-drag layer formed after embossing and curing has antistatic and self-cleaning properties at the same time.

The application discloses an environmentally-friendly soft type yoga mat special silk-screen printing ink and a preparation method thereof, and belongs to the technical field of silk-screen printing inks. The ink comprises the following components in parts by weight: 30-50 parts of main body resin, 5-15 parts of environmentally-friendly pigment, 25-45 parts of environmentally-friendly composite solvent, 1-5 parts of adhesion promoter, 0.5-2 parts of rheological additive, 0.5-2 parts of scratch-resistant additive, and 2-8 parts of environmentally-friendly non-ortho phenyl plasticizer. The ink is extremely environmentally-friendly, meets international export standards, and is free of phthalate plasticizers, benzophenone solvents and heavy metal pigments in the whole process. Instead, the ink uses citric acid ester non-ortho phenyl plasticizers, benzene-free and ketone-free composite solvents and heavy metal-free organic pigments. The VOC content is far lower than the national limit value, the irritating odor is eliminated, and phthalate controlled substances are not detected. The ink meets the EU REACH regulation appendix XVII 51 / 52 and the EN71-3 toy safety standard, and completely solves the problem of limited export of traditional inks.

The invention provides a metal or alloy surface treatment method and a metal or alloy product. The surface treatment method of the metal or the alloy comprises the following steps: forming an organic-inorganic hybrid layer on the surface of an anodic oxide layer on at least one surface of the metal or the alloy; the organic-inorganic hybrid layer is provided with a spatial network structure formed by silicon dioxide, a copolymer of organic oxysilane containing an epoxy group and a benzophenone compound containing a hydroxyl group, and nanocrystallized superfine carbon black. At least one surface of the metal or alloy product is provided with an anodic oxide layer and an organic-inorganic hybrid layer; the organic-inorganic hybrid layer is provided with a spatial network structure formed by silicon dioxide, a copolymer of organic oxysilane containing an epoxy group and a benzophenone compound containing a hydroxyl group, and nanocrystallized superfine carbon black. According to the technical scheme, the organic-inorganic hybrid high-brightness black layer is formed, so that the high-brightness black coating not only has an excellent appearance orange peel effect and excellent xenon lamp aging resistance, but also has extremely high hardness and extremely excellent car washing resistance.

The invention discloses a PVC fireproof plate prepared from oyster shells and a preparation method of the PVC fireproof plate, and relates to the technical field of PVC fireproof materials. The preparation method comprises the following steps: step 1, pretreating the oyster shell powder, and reacting quaternized chitosan with epoxidized soybean oil to obtain enhanced oyster shell powder; 2, the oyster shell powder is pretreated, benzophenone chitosan and epoxidized soybean oil are subjected to a reaction, and anti-ultraviolet oyster shell powder is obtained; and step 3, uniformly mixing the raw material components of the PVC fireproof plate according to the formula proportion, adding the mixture into a conical twin-screw extruder, and carrying out mixing extrusion, mold shaping, traction and cutting to obtain the PVC fireproof plate. The prepared PVC fireproof plate has excellent heat resistance, mechanical properties and ultraviolet resistance.