3298 results about "Benzaldehyde" patented technology

The invention relates to a preparation method of a benzaldehydes compound and a catalyst for the preparation method. The catalyst is composed of 0.01-90 wt% of metal grains and 10-99.99 wt% of mesoporous carbon carrier; the metal grains are selected from any two of Pd, Au, Ag, Pt, Ru, Rh, Ni, Cu, Fe, Co, Cr, W, Mo, Ti and Ta; the weight ratio of two types of the metal is 1: (0.01-100) and the average grain diameter of the metal grains is 1-100 nm; and the mesoporous carbon carrier is prepared from a heteroatom-doped mesoporous carbon material. The content of heteroatoms in the mesoporous carbon material is 0.01-80 wt%. The catalyst provided by the invention is stable for water, air and heat and has an excellent catalytic activity; particularly, the catalyst has a high selectivity when being used for catalyzing an alcohol oxidation reaction to prepare aldehyde or ketone. The preparation method of the benzaldehydes compound provided by the invention has the advantages of high conversion rate of raw materials and good selectivity of a target product.

The present Invention relates to a preservative composition comprising:

a mixture of two to ten of well characterized fragrance raw materials with a cosmetic function, of which at least two are selected from: allyl caproate, benzyl acetate, benzaldehyde, dihydrolsojasmonate, ethyl phenethylacetal, ethyl cinnamate, ethyl methyl phenyl glycidate, ethyl vanillin, 2-heptylcyclopentanone, geranyl acetate, heliotropine, cis-hex-3-en-1-ol, ethylene brassylate, nonalactone gamma, camphylcyclohexanol, undecalactone gamma, 2-t-butylcyclohexylacetate, pentyl salicylate, 2-phenylethanol and 2-phenylethyl acetate; and are contained in at least 20% by weight of said mixture;

at least one preservative; and a sequestrant.

The new type of styryl radical substituted boron fluoride complexed dipyrrolyl methane fluorescent dyes are prepared through complexing boron fluoride and dipyrrolyl methane fluorescent dye and further reaction with benzaldehyde compound. Partial single styryl radical substituted dyes have absorption spectrum and emission spectrum in near infrared region, while all double styryl radical substituted dyes have absorption spectrum and emission spectrum in near infrared region. When the dye structure has amino radical, it will produce ICT under the excitation of light to raise fluorescent quantum efficiency rapidly. Therefore, the present invention may be used as pH probe in testing pH value and in designing high sensitivity ion probe and sugar probe.

The invention relates to a high-temperature-resistant and high-salinity-resistant water-plugging profile control agent, and a preparation method and application thereof. The water-plugging profile control agent comprises polyacrylamide, a composite crosslinking agent, cyclodextrin, metaphenylene diamine and deoxidant, wherein the composite crosslinking agent consists of aldehyde, phenol and aluminum citrate; the aldehyde is one or the combination of benzaldehyde and paraformaldehyde; and the phenol is one or more of phenol, resorcinol and hydroquinone. The water-plugging profile control agent can resist the temperature of 120 DEG C, can be directly prepared by using water with mineralization degree of 150,000 mg/L, and has high crosslinking performance and long-term stability. The preparation method for the water-plugging profile control agent is simple, convenient to operate, and easy to control, and water-plugging profile control agent has a good plugging effect, and construction can be performed after the water-plugging profile control agent is directly prepared on site.

This invention relates to a process for preparing alditol acetals, such as dibenzylidene sorbitols, monobenzylidene sorbitols, and the like, through the reaction of unsubstituted or substituted benzaldehydes with alditols (such as sorbitol, xylitol, and ribitol) in the presence of a mineral acid and at least one surfactant having at least one pendant group of 6 carbon chains in length. Such a reaction provides a cost-effective, relatively safe procedure that provides excellent high yields of alditol acetal product. Furthermore, such a specific reaction is also the best known procedure for the production of certain compounds which can be easily separated from other formed isomers. Additionally, such a procedure facilitates the production of certain asymmetric alditol acetal compounds and compositions in acceptable yields as well. Such alditol acetals are useful as nucleating and clarifying agents for polyolefin formulations and articles, as one example.

The invention relates to a synthesis method of a triazol pyridine ring compound, which mainly solves the technical problems of low yield, high synthesizing cost, poor applicability and the like existing in the traditional synthesis method. The synthesis method comprises the following steps of: (1) making substituted 2-hydrazine-based pyridine react with substituted benzaldehyde, and (2) filtering sediments generated by reaction, dissolving the sediments in a solvent and adding lead tetraacetate, and refluxing to obtain a target product. The target product can be also obtained with a one-pot method by directly carry out the step (2) without separating the sediments. The synthesis method has the advantages of easy obtainment of simple raw materials, simple synthesizing steps, mild reaction condition and higher yield.

A catalyst of synthesizing benzaldehyde and benzyl alcohol by methylbenzene, its manufacturing method and application. The active component is zirconium, or transit metals, alkaline metal, alkaline-earth metals, metals of IIIAíóIVA and VA Group in the Periodic Table. The method comprises solving a zirconium compound or a zirconium compound and a compound of an element as the active component, adding a precipitator; drying, burning, pulverizing to particles. In reactions, a gas containing oxygen is the oxygen source, such as oxygen and air, an organic solution wouldn't be used. The catalyzing reaction is 180-195 degree C, the pressure is 0.8-1.2Mpa. when the conversion rate of methylbenzene is 13.0úÑ, the total selectivity of benzaldehyde and benzyl alcohol is 86.6úÑ. In the method, the catalyst is easy to be separated and could be recyclable, the reaction condition is mild.

The invention relates to a method for preparing 2-bromine-4, 5-dimethoxy benzene propane nitrile, which consists of steps: 3-4-dimethoxy benzaldehyde and bromine are dissolved in acetic acid to be reacted; when solid is precipitated, 2-bromine-4, 5-dimethoxy benzaldehyde crystal is obtained through suction filtration; the crystal and acetonitrile are dissolved in organic solvent; after a catalytic reaction, yellow solid is precipitated, cooled, extracted and dried to get 2-bromine-4, 5-dimethoxy cinnamonitrile solid which is then dissolved in methanol with reducing agent and is reduced to obtain 2-bromine-4, 5-dimethoxy benzene propane nitrile after a reflux reaction; or the obtained 2-bromine-4, 5-dimethoxy cinnamonitrile is reduced with hydrogen under the catalysis of palladium-charcoal to get 2-bromine-4, 5-dimethoxy benzene propane nitrile. The 2-bromine-4, 5-dimethoxy benzene propane nitrile prepared by the invention has high yield coefficient; original raw materials of the preparation method are easy to get; the price is low; the reaction operation is simple; the reaction route is short; and the method is easy for industrialization production.

Provided herein are methods for treating sickle cell disease, comprising administering to a subject 2-hydroxy-6-((2-(1-isopropyl-1H-pyrazol-5-yl)pyridin-3-yl)-methoxy)benzaldehyde (Compound 1), or a polymorph thereof, in certain dosing regimens.

The invention relates to a method for preparing di-dithiocarbamate modified chitosan beads. The method comprises the following steps of: after dissolving 5 g of chitosan in an acetic acid solution at first, solidifying the chitosan in a sodium hydroxide solution to form chitosan beads with the diameter of 2-3 mm, wherein the solidifying time is 8-26 h; and, after carrying out Shiff alkali reaction, etherification, amination and elimination of benzaldehyde of the chitosan beads, grafting carbon disulfide under an alkaline condition to obtain di-dithiocarbamate modified chitosan. Compared with the original chitosan, the chitosan disclosed by the invention as a water treatment agent has stronger adsorption property and can be applied to treatment of heavy metal ions in wastewater, such as electroplating wastewater, battery wastewater, wastewater in mining industries and the like; the adsorption selectivity of the chitosan is increased; furthermore, the chitosan can be recycled for many times; and the purpose of rationally utilizing resources is achieved.

The invention provides a ratio type fluorescent probe for distinguishing lipid droplets with different polarities. A chemical name is (E)-7-(N,N-diethylamino)-3-(3-(4-(diphenylamine)phenyl)acrylyl-2H-benzopyrone; N,N-diethylamino salicylic aldehyde reacts with ethyl acetoacetate to generate 3-acetyl-7-(diethylamino)coumarin; the product reacts with 4-(N,N-Diphenylamino)benzaldehyde (4) to obtain the fluorescent probe. The fluorescent probe has a two-photon property and an aggregation-induced light-emitting property; a whole body of the probe is electrically neutral and can be positioned in thelipid droplets with the different polarities very well. The probe has low toxicity, good optical stability and specific response on the polarities; detection on the polarities of the lipid droletps in organs and living bodies is realized. The invention further provides a synthesis method of the probe; the synthesis method has the advantages of simple steps, convenient for purification and high yield.

A compound (8) represented by the formula: (8)

wherein R₁ represents a 6- to 14-membered aromatic hydrocarbon ring group which may have a substituent; and n represents 0 to 2, can be produced with good efficiency by reacting a compound (3) represented by the formula: (3)

wherein R₁ and n are as defined above; and Q represents a single bond or —CH(Y)— where Y represents a hydrogen atom or a C1-6 alkyl group] with 3-methoxy-4-(4-methyl-1H-imidazol-1-yl)benzaldehyde in the presence of a base.

Compounds represented by the following structure (I) are disclosed:

as are methods for making such compounds, wherein said methods comprise reacting a diacyldiketopiperazine with a first aldehyde to produce an intermediate compound; and reacting the intermediate compound with a second aldehyde to produce the class of compounds with the generic structure, where the first aldehyde and the second aldehydes are selected from the group consisting of an oxazolecarboxaldeyhyde, imidazolecarboxaldehyde, a benzaldehyde, imidazolecarboxaldehyde derivatives, and benzaldehyde derivatives, thereby forming the above compound wherein R₁, R₁′, R₁″, R₂, R₃, R₄, R₅, and R₆, X₁ and X₂, Y, Z, Z₁, Z₂, Z₃, and Z₄ may each be separately defined in a manner consistent with the accompanying description. Compositions and methods for treating vascular proliferation are also disclosed.

The invention relates to a preparation method and application of a formaldehyde fluorescent probe, and belongs to the technical field of analytical chemistry. The formaldehyde fluorescent probe is a ratio-type fluorescent probe with double emission bands. The excitation wavelength is 318 nm; and the fluorescence peak at 359nm decreases gradually with the increasing of the concentration of formaldehyde, and at the same time a new emission band is produced at 451 nm and the fluorescence peak gradually increases. The formaldehyde fluorescent probe can resist the interference of acetaldehyde, glyoxal, methylglyoxal, benzaldehyde, alanine, glycine, serine, arginine, cysteine, glutathione and glucose, has high detection accuracy, high sensitivity and strong anti-interference capability. In addition, the formaldehyde fluorescent probe of the invention can detect the formaldehyde in a biological sample (cell environment), realizes formaldehyde fluorescence imaging in living cell level, and has potential practical application value. The synthesis of the formaldehyde fluorescent probe only needs a one-step reaction, which is simple and high in yield.

The invention discloses new semi-bright lead-free chemical tinning liquid and a using method thereof. A semi-bright silver tin-copper alloy chemical plating layer is obtained on copper and copper alloy matrix. In the chemical plating liquid, tin sulfate is used as a main salt, thiourea is used as a main complexing agent, citric acid is used as an auxiliary complexing agent, sodium hypophosphite is used as a reducing agent, ethylene diamine tetraacetic acid is used as an antioxidant, sulfuric acid is used as a stabilizing agent, gelatin is used as a leveling agent, and benzaldehyde is used as an auxiliary brightening agent. The pH value of the plating liquid is 0.8 to 2.0, the temperature of the plating liquid is between 80 and 90 DEG C, the carrying capacity of the plating liquid is 0.8 to 1.5dm2/L, and the mechanical stirring speed is 50 to 100 rpm. The continuous self-catalytic deposition of tin is implemented on the copper and copper alloy matrix, plating layers of different thicknesses can be obtained by controlling the chemical plating time, and the deposition speed is high; crystalline grains are obviously refined, the surface flatness of the plating layer is improved, and the plating surface area is large; the plating layer and the matrix are combined firmly; and after passivating treatment, the change resistance of the plating layer is high. The technology has broad application prospect in products such as deep hole pieces, blind hole pieces, small-sized electronic parts and components which are difficult to process, printed circuit boards (PCB) and the like.

The invention discloses a production method for natural benzaldehyde, comprising the following steps: putting cinnamyl aldehyde and an alkaline aqueous solution into a reactor, causing the cinnamyl aldehyde and the alkaline aqueous solution to be subject to anti-aldolisation, carrying out sectional type temperature control and cooling on natural benzaldehyde-containing steam generated by the reaction through a tertiary condensation system, and then collecting products in a product receiver. In the production method for the natural benzaldehyde, the tertiary condensation system is adopted to substitute for the single condensation device in the prior art, thereby improving the production efficiency, reducing the energy consumption and overcoming the defects of the existing production methodfor the natural benzaldehyde on the premise of ensuring the natural degree and pure smell of the nature benzaldehyde.

An acetal compound may be formed by the method of reacting a substitiuted or unsubstituted benzaldehyde, a polyhydric alcohol, and an at least one acid catalyst at ambient temperatures, in a homogenous reaction media in the presence of at least one water miscible organic solvent. The molar ratio of the acid catalyst to the benzaldehyde may be less than about 0.6 to 1, respectively, of acid catalyst to benzaldehyde.

The invention belongs to the technical fields of material preparation and photocatalysis, and discloses a phenyl ring modified graphite-like carbon nitride photocatalyst, and a preparation method and an application thereof. The method comprises the following steps: 1, dissolving nitrogen-containing organic micro-molecules and a phenyl ring-containing compound in a solvent, and evaporating the obtained solution until the solution is dry in order to obtain a mixed precursor; and 2, roasting the mixed precursor to obtain the phenyl ring modified graphite-like carbon nitride photocatalyst, wherein the nitrogen-containing organic micro-molecules are one or more of urea and melamine; and the phenyl ring-containing compound is one or more of trimesic acid, phenol, benzoic acid and benzaldehyde. The electron structure of the photocatalyst is changed by phenyl ring modification, so the pi electron delocalization of graphite-like carbon nitride is excited, the absorption of visible lights is improved, compounding of photon-generated carriers is inhibited, and the photocatalytic hydrogen production performance is improved. The method has the advantages of simple preparation, no expensive device and good practical application prospect.

The present invention is directed to methods and compositions for use to control parasitic mites of honey bees, particularly Varroa mites. In one aspect, the invention is directed to control of parasitic mites of honey bees wherein the active ingredient is a miticidally effective amount of a selected ketone or 1-heptanol, ethyl butyrate, benzaldehyde, heptaldehyde, or d-limonene. In a second aspect, the invention is directed to control of parasitic mites of honey bees wherein the active ingredient is an effective attractant amount of 2-heptanone. The attracted mites are then trapped or otherwise removed from the locus of the bees. The present invention is also directed to methods and compositions which include 2-heptanone to control hive invading pests of honey bees.

The invention provides a method for preparing bromhexine hydrochloride, which comprises the steps as follows: (1) 2-amino-3,5-dibromo benzaldehyde and reducing agents are in a reduction reaction to generate 2-amino-3,5-dibromo benzyl alcohol; (2) 2-amino-3, 5-dibromo benzyl alcohol that is obtained in the step (1) reacts with chlorinating agents to generate 2, 4-bromine-6-chloride methylaniline; and (3) 2,4-bromine-6-chloride methylaniline obtained in the step (2) and N-methylcyclohexylamine are in an amination reaction, and then 2, 4-bromine-6-chloride methylaniline and HCl salification agents are in a salification reaction, so that bromhexine hydrochloride is obtained. The preparation method adopts multiple advanced technologies, is easy to get starting materials, and has the advantages of stable property of intermediates, extremely low environment pollution, high yield coefficient of products and high purity.

The invention discloses a polyurethane foam fire retardant obtained by reacting 9, 10-dihydro-9-oxa-10-phosphaphenanthrene-10-oxide, aniline and benzaldehyde. The structural formula of the polyurethane foam fire retardant is represented by a formula in the patent specification. According to the preparation method of 9, 10-dihydro-9-oxa-10-phosphaphenanthrene-10-oxide-4-[(aniline)methyl]benzene, aniline and benzaldehyde are introduced into the 9, 10-dihydro-9-oxa-10-phosphaphenanthrene-10-oxide (DOPO) fire retardant structure by Mannich reaction, so that the cost of the fire retardant is reduced; synthesized 9, 10-dihydro-9-oxa-10-phosphaphenanthrene-10-oxide-4-[(aniline)methyl]benzene is used as a fire-retardant rigid polyurethane foam, and possesses relatively high fire retardant; and the oxygen index can reach 24 to 26%. The polyurethane foam fire retardant possesses a promising application prospect in buildings, insulation, and specific occasions.