252 results about "Adipic Dihydrazide" patented technology

The invention relates to a preparation method of injectable natural polysaccharide self-healing hydrogel. The preparation method of the injectable natural polysaccharide self-healing hydrogel comprises the following steps: firstly synthesizing water soluble N-carboxyethyl chitosan by carrying out a Michael addition reaction on acrylic acid and chitosan, carrying out an oxidization reaction on sodium periodate and sodium alginate to obtain oxidized sodium alginate, then carrying out a dehydration condensation reaction on N-carboxyethyl chitosan and oxidized sodium alginate and on adipic dihydrazide and oxidized sodium alginate in a phosphate buffer liquid at the temperature of 37 DEG C, so as to respectively generate invertible imine bond and acylhydrazone bond, and finally preparing injectable natural polysaccharide macromolecular hydrogel with self-healing property. The preparation method of the injectable natural polysaccharide self-healing hydrogel has the advantages that a synthetic process of the injectable self-healing hydrogel is simple and green, reaction conditions are mild, the injectable self-healing hydrogel can form gel in a physiological environment and has self-healing capability, and the injectable self-healing hydrogel has a good application prospect in the fields of drug sustained release and the like.

The invention discloses a preparation method and application of internal-external dual cross-linked core-shell structured acrylic acid emulsion. The method employs a multi-step pre-emulsification and polymerization process for seed emulsion to prepare the acrylic acid emulsion and mainly comprises a first step of preparation of seed monomers, a second step of seed emulsion polymerization, a third step of core emulsion polymerization and a fourth step of shell emulsion polymerization; after polymerization is finished, the pH value of the emulsion is adjusted, and adipic dihydrazide is added so as to obtain the internal-external dual cross-linked core-shell structured acrylic acid emulsion. According to the invention, polymerization stability and minimum film-forming temperature of the core-shell structured acrylic acid emulsion prepared in the invention are greatly improved; the acrylic acid emulsion is applied in the field of water-borne wood paints and can improve the cross-linking degree, density and hardness of a paint film and reduce water absorption and a glass transition temperature of the paint film.

The invention provides an amphiphilic polymer resin with hydrophilicity and hydrophobicity, which is polymerized by methacrylic acid, methyl methacrylate, butyl acrylate, beta-hydroxypropyl methacrylate, acrylamide, diacetone acrylamide and adipic dihydrazide monomers or the like. The amphiphilic polymer resin can be used as main filming material of paint to combine various cell forming materials to prepare the paint with decorativeness, humidity adjustment, permeability, thermal insulation, dew prevention, water and alkali resistance and anti-bacterial property, as one multifunctional intelligent breath paint. The product can overcome the defects of traditional air conditioner as high energy consumption and can avoid paint from dropping off wall caused by leakage and water, thereby prolonging the service life of paint, and the invention has wide application.

The invention discloses a normal temperature self-crosslinking acrylic emulsion and a preparation method thereof. The acrylic emulsion is obtained by radical-initiated polymerization of the following raw materials by weight: 50 to 52 parts of deionized water, 2 to 3 parts of emulsifier RN-30, 12 to 16 parts of butyl acrylate, 22 to 28 parts of methyl methacrylate, 0.5 to 1 part of hydroxyethyl acrylate, 0.3 to 0.6 part of acrylic acid, 0.4 to 0.8 part of vinyltrimethoxy silane, 0.1 to 0.3 part of sodium bicarbonate, 0.2 to 0.4 part of ammonium persulfate, 1 part to 2 parts of diacetone-acryloamide, 0.5 part to 1.5 parts of adipic dihydrazide, 0.1 to 0.14 part of the oxidizing agent tert-butyl hydroperoxide, 0.1 to 0.14 part of the reducing agent rongalite and 0.3 to 0.6 part of ammoniacalliquor. The normal temperature self-crosslinking acrylic emulsion provided in the invention has better water resistance and oil resistance and greatly enhances the problems of after tack at high temperature and embrittlement at low temperature under the condition that the quality of a final product is guaranteed to be no worse than the quality of products of a same kind.

The invention discloses a single-component water-based polyurethane / acrylate composite resin capable of being cured at room temperature and a preparation method thereof. The preparation method comprises the steps of mixing keto-containing water-based polyurethane resin with keto-containing water-based acrylate resin in a mass ratio of 1:1 and then adding a crosslinking agent adipic dihydrazide accounting for 50% of total keto molar weight, so as to obtain the single-component water-based polyurethane / acrylate composite resin capable of being cured at room temperature. According to the invention, the preparation process of the single-component water-based polyurethane / acrylate composite resin capable of being cured at room temperature is simple, and crosslinking composition and curing are synchronously carried out. The single-component water-based polyurethane / acrylate composite resin capable of being cured at room temperature is stable in property; and by detection according to the HG / T3828-2006 'indoor water-based woodware paint' standard, the water resistance and alcohol resistance of the composite resin are qualified, and the hardness of the composite resin is 2H.

The invention provides an injectable hyaluronic acid-based hydrogel, which is prepared by mixing modified hyaluronic acid, a cross-linking agent and a solvent, wherein the cross-linking agent comprises a repeating unit having a structure represented by a formula (I) and an end group having a structure represented by a formula (II). The modified hyaluronic acid hydrogel provided by the invention has the advantages of mild preparation conditions, simple preparation method, controllable mechanical strength and degradation rate, good application prospect in the field of biomedicine, and high adjustable space, so that hydrogel materials with various different physical and chemical properties are prepared by adjusting the molecular weight of hyaluronic acid, the grafting rate of adipic dihydrazide or 3,3'-dithiobis(hydrazine propionate), the molecular weight of a cross-linking agent and the like according to different requirements,.

The invention relates to a polyacrylic woodware emulsion with a core-shell bi-crosslinking structure and a preparation method thereof. The polyacrylic woodware emulsion is prepared from the following components: methyl methacrylate, butyl methacrylate, methacrylic acid, a crosslinking monomer, butyl acrylate, methacrylic acid-2-hydroxy ethyl, diacetone acrylamide, adipic dihydrazide, an initiator, an emulsifier, and deionized water. Through molecular design of the polyacrylic emulsion with hard core and soft shell, the hard core provides the hardness and mechanical strength of a coating film and improves the stain resistance of a paint film, and the soft shell can improve the film-forming property of coating film, has no need for film-forming assistant, reduces VOC emission, and improves the low temperature resistance of the coating film. By means of the core-shell bi-crosslinking system, the hardness and water resistance of the paint film are improved.

The present invention discloses a preparation method of a cationic organosilicon modified waterborne PUA fabric coating adhesive with a self crosslinking structure, the method is as follows:(1)using polyisocyanate and hydroxyl-terminated polysiloxane for synthesis of an-NCO-group-terminated prepolymer;(2)adding polyether or polyester glycol for reaction;(3)reacting with a cationic hydrophilic chain extender for a period of time, and further reacting with adipic dihydrazide(ADH)to obtain a hydrazine-terminated cationic waterborne polyurethane emulsion;(4)using acrylate monomers and diacetone acrylamide(DAAM)for preparing a hydrazide-group-containing polyacrylate emulsion; and(5)mixing the hydrazine-terminated cationic waterborne polyurethane emulsion and the hydrazide-group-containing polyacrylate emulsion in a certain proportion to obtain the self-crosslinking cationic organosilicon modified waterborne PUA fabric coating adhesive. The self-crosslinking cationic organosilicon modified waterborne PUA fabric coating adhesive avoids the use of a harmful crosslinking agent, has the advantages of being environmental-friendly, high in water pressure resistance, good in mechanical properties, low in cost, and dyeable and the like, and can be used for coating finishing of nylon fabrics.

The invention discloses a wood lacquer water-borne flat self-crosslinking acrylic emulsion and a synthesizing method thereof. The wood lacquer water-borne flat self-crosslinking acrylic emulsion is composed of raw materials of monomers, functional monomers, solvent, neutralizer, buffer agent, initiator, emulsifier and flatting agent, wherein the monomers are composed of, by weight part, 3-12 partsof methacrylic acid, 120-300 parts of methyl methacrylate, 2-20 parts of butyl acrylate, 10-50 parts of styrene and 40-120 parts of ethylhexyl acrylate; the functional monomers are composed of 4-14 parts of diacetone acrylamide, 3-10 parts of adipic dihydrazide and 1-10 parts of vinyl trimethoxysilane; the solvent is 500-800 parts of deionized water; the neutralizer is 2-10 parts of ammonia hydroxide; the buffer agent is 0.2-1 part of sodium bicarbonate; the initiator is composed of 0.5-3 parts of ammonium persulfate, 0.1-2 parts of tert-butyl hydroperoxide and 0.1-2 parts of ascorbic acid; the emulsifier is 0.5-8rts of lauryl sodium sulfate; the flatting agent is 5-35 parts of fumed silica. The wood lacquer water-borne flat self-crosslinking acrylic emulsion has the advantages of excellent transparency, excellent water resistance, excellent alcohol resistance and flatness and can be combined to manufacture water-borne wood lacquers of different glossiness.

The invention discloses a preparation method of a double self cross-linking elastic emulsion. The method combines two post cross-linking modes: (1) adding multivalent metal ion compounds to carry out cross-linking reactions; (2) adding diacetone acrylamide into emulsion so as to make diacetone acrylamide participate in the emulsion copolymerization reactions during the emulsion polymerization process so as to introduce keto-carbonyl groups into the chains of copolymer, and then adding binary caprylic hydrazide such as adipic dihydrazide into the emulsion so as to obtain the self cross-linking elastic emulsion. A diacetone-acrylamide and binary caprylic hydrazide cross-linking system and a carboxylic acid and multivalent metal salt cross-linking system are both simultaneously induced into an acrylate emulsion polymerization system to replace an elastic emulsion system formed trough a single reactive cross-linking agent; thus the polymerization property and storage stability of emulsion are improved, the waterproof property, contamination resistant property, after-tack property, and elastic elongation rate of the surface of a coating coated by the elastic emulsion are all improved; and the coating product which adopts the two room temperature self cross-linking systems, has a good adhesive force and elasticity, and has a very good surface waterproof property.

The invention discloses a single-component water-based adhesive for an evaporative cooling wet curtain and a preparation method thereof. The method comprises the following steps of: firstly preparing kettle bottom liquid and adding into a polymerization reaction kettle; then respectively preparing nuclear layer pre-emulsion, transition layer pre-emulsion and shell layer pre-emulsion; removing possibly-caused free formaldehyde through carrying out nuclear layer-transition layer-shell layer gradient emulsion polymerization, by adopting an environmentally-friendly and highly-efficient reactive emulsifier and through replacing hydroxymethyl acrylamide with a novel self-crosslinking monomer and replacing sodium formaldehyde sulphoxylate with a macromolecule polymerization type reducing agent; and introducing carbamido or nitrogen heterocycle into an acrylate structure to provide a higher intermolecular hydrogen bond and an intermolecular acting force and improve the wet adhesive force and the scrub resistance of an adhesive layer. The invention has the beneficial effects that the adhesive force and the water resistance of the adhesive layer are ensured through ion crosslinking and in cooperation with diacetone acrylamide / adipic dihydrazide crosslinking; and by adopting an adjusting agent with the super-strong defoaming and wetting functions, the adhesive is ensured to satisfy higher coating rate in the gluing process and not to generate tiny bubble residues.

The invention relates to a self-crosslinking polyurethane-acrylate composite emulsion and a preparation method thereof. The self-crosslinking polyurethane-acrylate composite emulsion is prepared from polyester polyol, isophorone diisocyanate, diacetone acrylamide, reactive diluent, a hydrophilic chain extender, trimethylolpropane, dihydric alcohol, dibutyltin dilaurate, a neutralizer, water, ethylenediamine, adipic dihydrazide, an initiating agent and an initiating agent diluting solvent. The self-crosslinking polyurethane-acrylate composite emulsion has the advantages that the problem that water resistance is lowered due to addition of an emulsifying agent is avoided, pollution caused by an organic solvent and tediousness of the process of extracting the organic solvent in later period are avoided, and the hardness and resistance of an adhesive film can be improved.

The present invention relates to preparation method of aflatoxin immuno-affinity column, including steps of: preparation of hydrazine antibody: employing sodium periodate oxidating unconjugated active area Fc hydroxoy of antibody to aldehyde group, and reacting with adipic dihydrazide to gain hydrazine antibody; preparation of aldehyde solid substrate: oxidating solid substrate containing continued diol structure by sodium periodate to gain aldehyde solid substrate; coupling of antibody and solid substrate: mixing hydrazine antibody and aldehyde solid substrate, adding sodium borohydride to seal unreacted aldehyde group on solid substrate after oscillating reaction to gain coupling antibody solid substrate; column packed. The present invention couples the unconjugated active area Fc end of antibody to solid substrate to remain activity of antibody better; hydrazide derived on antibody instead of solid substrate to avoid nonspecific adsorption of hydrazide group; the combined affinity column not introducing new groups ( such as carboxyl, amido and so on) except coupling antibody to avoid nonspecific adsorption from them.

A coating for application to the surface of an interior building product comprises: a resin formulation such as a melamine formaldehyde resin characterized by its ability to strengthen the interior building product when applied as a coating to the building product; and an aldehyde scavenger selected from the group consisting of; tetraethylene pentamine, propionamide, caprolactam, ammonium hydroxide, sodium bisulfate, sodium metabisulfite, ammonium primary phosphate, ammonium secondary phosphate, a combination of ammonium primary phosphate and ammonium secondary phosphate, a combination of ammonium primary phosphate, ammonium secondary phosphate and a sulfite, a polyvinyl alcohol; adipic dihydrazide and a combination of a polyvinyl alcohol and adipic dihydrazide.

The invention discloses an ecological diatom coating and a preparation method thereof. Adipic dihydrazide prepared from diatomite, titanium dioxide, polyacrylate emulsion, antibacterial agent BIT and tourmaline loaded nano titanium dioxide through stirring is taken as a formaldehyde catching agent, the tourmaline loaded nano titanium dioxide is taken as an air cleaning catalyst, polyacrylic acid is taken as a thickener, and sodium polyacrylate is taken as a dispersing agent. The diatom ooze decorative wall material has the main functional material diatomite which has a porous structure, thus being capable of regulating the indoor temperature and humidity. The preparation method is simple and easy to carry out. The formula adopts the polyacrylate emulsion, and the glass transition temperature is 10-14 DEG C, so that film-forming agent is not needed, the ecological diatom coating does not volatilize toxic gases and is more environment-friendly; furthermore, the formula adopts the thickener, so that both the thickening capacity and dispersing capacity of the coating are improved; the step of dissolving in advance is saved in preparation, so that the preparation steps are simplified, the production cost of enterprises is lowered, therefore, the coating is an ideal ecological diatom coating.

The invention discloses a modified polymer cement-based waterproof material. The modified polymer cement-based waterproof material comprises a liquid material and a powder material which are combined in application; the liquid material comprises the following components in percentage by weight of 97-98% of modified acrylate emulsion A, 0.2-0.4% of dispersing agent, 0.3-0.6% of organic silicone defoaming agent, 1-2% of plasticizer and 0.3-0.5% of preservative, the powder material comprises 50-55% of PII52.5 cement, 20-30% of 200-mesh fine sand or quartz powder, 16-20% of 400-mesh heavy calcium carbonate and 5-10% of polyvinyl alcohol-adipic dihydrazide composite powder, wherein the modified acrylate emulsion A is modified by diacetone-acryloamide accounting for 5-8% of the total weight of a monomer in a synthesis later period of acrylate emulsion A, and solid content of the emulsion after modification is 54-56%. The modified polymer cement-base waterproof material can meet national standards, constructability of a waterproof material is improved, structural strength, water resistance and weather resistance of a composite material after moulding are also greatly improved, and the modified polymer cement-base waterproof material is also superior in slag resistance.

The invention relates to the preparation of a growth factor porous micro-sphere compound system coated by an injectable hydrogel. The preparation is characterized by comprising a first component, namely HA-ADH sol obtained by cross-linking of hyaluronic acid (HA) and adipic dihydrazide (ADH), and polylactic acid (PLLA) porous micro-spheres which are carried with growth factors and loaded in the first component. The compound system is capable of degrading and slowly releasing the growth factors under physiological conditions, so that the slow releasing of the growth factors in a body is realized, and the problems that the growth factors are released too fast and an action period is too short are solved, thereby reaching the effect of neural restoration.

The invention relates to a room-temperature self-crosslinking wood lacquer emulsion which is characterized by being prepared from the following components: methyl methacrylate, styrene, butyl acrylate, diacetone-acryloamide, glycidyl methacrylate, methacrylic acid, polycarbodiimide resin, adipic dihydrazide, an emulsifier, an initiator, a neutralizer, a molecular weight regulator and deionized water. The preparation method comprises the following steps: adding 10-50% of emulsifier aqueous solution into a reaction kettle, stirring and raising the temperature; in an emulsifying kettle, sequentially adding monomer materials into the residual emulsifier aqueous solution in a high speed disperse state and stirring; then, adding 5% of monomer pre-emulsion into the reaction kettle, adding an initiator solution, and starting to add the residual emulsion and initiator solution dropwise when the temperature of the reaction kettle reaches 80 DEG C, and then starting cooling the reaction kettle; and adding the neutralizer, adipic dihydrazide and polycarbodiimide resin into the reaction kettle, stirring for 30-40 minutes and filtering and packaging. According to the room-temperature self-crosslinking wood lacquer emulsion provided by the invention, cross-linking reaction of diacetone-acryloamide and adipic dihydrazide, polycarbodiimide resin and methacrylic acid is adopted, and the double crosslinking reaction is of great benefit to enhancing the adhesive property of a film.

The invention discloses an elastic emulsion paint which is prepared from raw materials of deionized water, adipic dihydrazide, hydroxyethylcellulose, propanediol, 215 titanium dioxide, wollastonite powder, kaolin, 800 coarse whiting, waterborne fluorocarbon resin, styrene-acrylic emulsion, elastic emulsion, and the like in dispersive mixing way. With good expansion rate, the elastic emulsion of the invention can be painted in brushing, rolling and spraying way, is provided with breakthrough in stain resistance and hydrophobic property and has the advantages of waterproof and breathable performance, strong anti-pollution performance, alkali and acid resistance and lasting weather resistance.

The invention discloses an antibacterial and anti-fouling modified adhesive. The adhesive is prepared from raw materials including polyurethane, methyl methacrylate, butyl acrylate, methacrylic acid, benzoyl peroxide, potassium persulfate, polyvinyl alcohol, diacetone acrylamide, adipic dihydrazide, dibutyl phthalate, tributyl citrate, tartaric acid, sodium bicarbonate, an antibacterial modifier, an anti-fouling enhancer and deionized water. The invention further provides a preparation method of the antibacterial and anti-fouling modified adhesive. The prepared modified adhesive is applied to textile processing and has excellent antibacterial and anti-fouling performance.

The invention relates to the technical field of acrylic emulsions, and particularly relates to a self-crosslinking acrylic emulsion and a preparation method thereof. The self-crosslinking acrylic emulsion is prepared from the following raw materials in parts by weight: a component A, namely 130-150 parts of crylic acid solid resin, 350-450 parts of water and 40-60 parts of ammonium hydroxide or monoethanolamine or triethanolamine, a component B, namely 5-12 parts of an emulsifier and 15-25 parts of water, a component C, namely 1-3 parts of persulfate and 5-12 parts of water, a component D 1, namely 85-95 parts of methyl methacrylate and 70-80 parts of ethyl acrylate, a component D 2, namely 85-95 parts of methyl methacrylate and 70-80 parts of ethyl acrylate, a component E, namely 0.8-1.5 parts of persulfate and 5-15 parts of water, a component F, namely 5-12 parts of diacetone-acryloamide and 25-35 parts of water, and a component G, namely 2-5 parts of adipic dihydrazide and 25-35 parts of water. The self-crosslinking acrylic emulsion does not contain a toxic solvent, so that the VOC content is low; and the self-crosslinking acrylic emulsion does not contain TDI and various heavy metals, so that the self-crosslinking acrylic emulsion is environment-friendly and safe, has the advantages of relatively good levelling property and film surface smoothness, shows a bright effect after forming a film, and is free of a white scar or dusting when rubbed and kneaded.

The invention discloses a reaction type VOCs absorbent. The reaction type VOCs absorbent comprises the following components by mass percent: 92% to 97% of water, 0.2% to 1% of a surfactant, 0.5% to 1% of inorganic salt and 0.2% to 1% of an organic matter decomposing agent, wherein the surfactant is at least one in castor oil sodium sulfonate, sodium sulpho methyl stearate, Tween 20, Tween 80, alkyl glycoside, sodium citrate and sodium dodecyl benzene sulfonate; inorganic salt is at least one in sodium carbonate, potassium carbonate, sodium metasilicate, sodium chloride, potassium chloride and ammonium chloride; and the organic matter decomposing agent is at least one in cysteine hydrochloride, arginine, lysine, histidine, 2-imidazolidone, acethydrazide and adipic dihydrazide. The reaction type VOCs absorbent has the advantages that multiple components in VOCs can be treated at the same time, the removing efficiency for volatile organic matters is high, the organic matter decomposing agent in the components of the absorbent can degrade organic exhaust gas into CO2 and water or other micromolecules, the raw materials are wide in source, the cost is low, and follow-up treatment is simple.

The present invention discloses heparin or heparin salt modified graphene oxide and a preparation method and application thereof, the modified graphene oxide can be used as a drug, particularly an anti-cancer drug carrier material. By use of pH sensitive principle, adipic dihydrazide is used as a linker molecule, or by use of redox principle, cystamine is used as a linker molecule, heparin is used for chemically modifying graphene oxide, and the heparin has the advantages of increase of water solubility and anti-cancer drug tumor synergistic effect of graphene oxide, and solves the problems of poor water solubility and easy aggregation and the like of the graphene oxide.

The invention discloses waterborne wood lacquer which consists of component A and component B, wherein, component A is obtained by dispersing and mixing deionized water, adipic dihydrazide, droxyethylcellulose, 215 titanium white powder, wollastonite powder, kaolin, 800-mesh heavy calcium carbonate and other raw materials; component B is prepared by dispersing and mixing water-based fluorocarbon resin, water-soluble acrylic resin, film-forming assistant and other raw materials. During use, component A and component B are mixed by the weight ratio of 1:1, and brush coating, roll coating and spray coating with the lacquer can be conducted after an appropriate amount of water is added to be stirred evenly. The waterborne wood lacquer of the invention is waterproof and permeable, has good weather and water resistant, strong adhesion force, and has excellent performance in particular in lustrousness and hydrophobicity.

The invention provides an acrylate emulsion for building interior wall paint and a preparation method thereof, and paint, and belongs to the technical field of building paint. The emulsion is preparedfrom the following raw materials, by weight: 6-20 parts of butyl acrylate, 15.5-26 parts of styrene, 6-20 parts of 2-ethylhexyl acrylate, 0.11-0.55 part of a self-crosslinking monomer, 0.15-1.3 partsof acrylamide, 0.2-3 parts of a carboxyl monomer, 0.015-0.12 part of a silane coupling agent, 0.21-0.81 part of a reactive anionic emulsifier, 0.21-0.81 part of a reactive non-ionic emulsifier, 0.1-2parts of polyethyleneimine, 0.1-0.2 part of adipic dihydrazide, 0.12-0.45 part of persulfate, 0.2-2 parts of ammonia water, and 30-60 parts of water. The emulsion is mainly used for building interiorwall paint; the emulsion can have low MFFT without adding a film forming auxiliary; and the paint prepared by the emulsion can have excellent scrubbing resistance and freeze-thaw stability, and is low in VOC content and excellent in environmental protection.

The invention provides aqueous plastic-plastic compounding glue water for soft packaging, and relates to compounding glue water. The compounding glue water is prepared from the following ingredients in parts by weight: 20 to 30 parts of acrylic ester monomers, 1 to 5 parts of acrylic acid or methacrylic acid, 2 to 4 parts of alkyl methacrylate esters, 10 to 20 parts of styrene or acrylonitrile, 1 to 2 parts of acrylic acid hydroxyl esters, 0.2 to 1 part of N-Methylol acrylamide or diacetone-acryloamide, 1 to 5 parts of adipic dihydrazide, 0.4 to 0.8 part of itaconic acid, ethylene dimethacrylate or diallyl maleate, 0.3 to 1 part of emulsifying agents, 0.2 to 0.8 part of initiating agents, 0.1 to 0.3 part of buffering agents and 0.3 to 1 part of wetting agents. According to the material structure matching, the dry glue coating quantity per square meter can be controlled to be 0.5 to 2g, and the requirements can be met, for example, thin BOPP / CPP only needs 0.5 kg of dry glue, and the transparency and the firmness degree can reach the requirements; the cost of glue water used in per square meter is as low as 0.02 Yuan RMB; the product can be used on an original dry type compounding machine; the addition of equipment investment is not needed.

The invention discloses ketone-hydrazine crosslinking aqueous acrylic resin with a film-forming-assisting function and a preparation method and application thereof. The preparation method comprises the steps of: dissolving an acrylic monomer, diacetone-acryloamide and an initiator in a solvent, then adding 20-50% of the mixture into a reaction kettle, and raising the temperature to 60-90 DEG C; dropwise adding the residual monomer and initiator into the reaction kettle within 3-5 hours, and performing an insulating reaction for 1.5-3.0 hours after dropwise adding; reducing the temperature to below 80 DEG C, adding a neutralizer to neutralize for 10-30 minutes, and adding water to disperse; and after dispersing and stabilizing, distilling to remove the solvent, and adding adipic dihydrazide to obtain the ketone-hydrazine crosslinking aqueous acrylic resin. The ketone-hydrazine crosslinking aqueous acrylic resin has an excellent film-forming-assisting function and can replace a small molecular coalescing agent to assist high Tg-polyacrylate emulsion to form a film. The content of volatile organic compounds of a prepared aqueous wood coating is lower than 50g / L, and the coating has an excellent chemical-resistant property.

The invention relates to a preparation method of a crosslinked polymer cement waterproof coating, which comprises the following steps: (a) mixing diacetone acrylamide with other polymerizable acrylic monomers and adding a surfactant for pre-emulsification; taking a part of pre-emulsified monomers, increasing the temperature to 60-90 DEG C, adding an initiator for polymerization reaction and then adding the left pre-emulsified monomers and an initiator within 0.2-1 hour for polymerization reaction at the temperature of 60-90 DEG C to obtain polymer emulsion; (b), adding an alkali agent and adipic dihydrazide into the polymer emulsion in the step (a); and (c), uniformly agitating the neutralized and activated polymer emulsion and a mixed filler during the construction to obtain the crosslinked polymer cement waterproof coating. The preparation method is simple, is low in cost and is suitable for industrial production; and the crosslinked polymer cement waterproof coating prepared by the method has a cement water reducing effect, can improve the cement strength and can be formed at the room temperature.

The invention discloses a high performance modified polyurethane coating. The coating comprises isophorone diisocyanate, polytetramethylene ether glycol, alkynyl group-containing polyol, phenylboronic acid, trimethylol propane, N,N-dimethylbenzylamine, cerium hydroxide, acidified carbon nanotubes, organic modified montmorillonite, 2,3-dibromo tripropylborate, triethylamine, 3,3'-diamino-4,4'-dihydroxydiphenylsulphone, 1-sulfolane-3-ethoxycarbonyl-5-hydroxypyrazole, 1,4-bis(dimethylhydroxysily)benzene, a leveling agent, methylsilicone oil, a wetting agent, benzoic acid, propylene glycol, dihydroxyacetone, adipic dihydrazide, liquid styrene butadiene rubber, liquid nitrile butadiene rubber and water. The high performance modified polyurethane coating has the advantages of excellent flame retardation performance, high strength, good heat stability, strong adhesion to a substrate, and long service life.

The invention provides a water white resistant particle crosslinking type water-in-water multicolor paint which is a water-based paint prepared by mixing a dispersing phase, a protecting adhesive aqueous solution and a continuous phase, wherein a crosslinking agent is a combination body of water-based isocyanate and hydrazine hydrate, or water-based isocyanate and adipic dihydrazide, or water-based isocyanate, hydrazine hydrate and adipic dihydrazide; a neutralizer is one or two of diethanol amine and triethanolamine. According to the water white resistant particle crosslinking type water-in-water multicolor paint provided by the invention, by the use of the neutralizer containing functionality hydroxyl in the dispersing phase and the continuous phase, the application of the hydroxyl at the grafted end of a neutralizing reaction emulsion molecular chain and the application of the hydroxyl in the neutralizer and isocyanato in the crosslinking agent, the isocyanato in the crosslinking agent and amino acid react with each other to generate polyurethane and polyurea, so that the dispersing phase and continuous phase meshed crosslinking density is increased, the molecular structures of polyurethane and polyurea materials are introduced, and a three-dimensional meshed structure crosslinking technology and high water resistance, toughness, weather resistance and strength of polyurethane or polyurea are used.