163 results about "Mercaptopropionic acid" patented technology

The invention relates to a hyaluronic acid-polyurethane composite material based on a double dynamic network and a preparation method and application thereof, and the preparation method comprises the following steps: carrying out hydrophobic modification reaction on hyaluronic acid and aminophenylboronic acid to obtain aminophenylboronic acid modified hyaluronic acid; the preparation method comprises the following steps: mixing polytetrahydrofuran ether glycol, polyethylene glycol and isophorone diisocyanate, carrying out a primary reaction, adding trimethylolpropane tri (3-mercaptopropionic acid) ester, carrying out a secondary reaction, adding tannic acid, and carrying out a third reaction to obtain tannic acid-terminated dynamic thionocarbamate polyurethane; and mixing the amino phenylboronic acid modified hyaluronic acid with the tannic acid terminated dynamic thionocarbamate polyurethane for reaction to obtain the hyaluronic acid-polyurethane composite material with the double dynamic networks. Compared with the prior art, by introducing a'thionocarbamate-borate 'double-dynamic network, high toughness, high strength, good self-repairability and repeatable processability in an extreme environment are realized, and the material is particularly suitable for manufacturing and repairing of key components in an LNG ship body and a heat insulation system thereof.

The invention relates to the technical field of waterproof materials, and particularly discloses a high-elasticity waterproof emulsion and a preparation method thereof. The invention discloses a high-elasticity waterproof emulsion. The water-based paint is prepared from the following raw materials in parts by mass: 40 to 60 parts of modified acrylic resin emulsion, 25 to 40 parts of waterborne polyurethane, 3 to 6 parts of hydroxyethyl methylacrylate, 0.5 to 1 part of mercaptopropionic acid, 6 to 8 parts of fluorinated mica sheet, 3 to 6 parts of organic silicon emulsion, 2 to 4 parts of fluorocarbon surfactant, 0.8 to 1.5 parts of adipic dihydrazide, 0.3 to 0.8 part of dynamic cross-linking agent, 3 to 8 parts of compatilizer, 0.5 to 1 part of antioxidant, 0.5 to 1 part of anti-aging agent, 0.5 to 1.5 parts of defoaming agent and 40 to 55 parts of solvent. The modified acrylic resin emulsion is prepared from a monomer comprising diacetone acrylamide. The high-elasticity waterproof emulsion prepared by the invention has relatively good elasticity, waterproof performance and aging resistance.

The invention relates to the technical field of vacuum bag films for aeronautical manufacturing, and discloses an eleven-layer co-extruded film for aeronautical use and a preparation process thereof, and the preparation process specifically comprises the following steps: carrying out grafting modification treatment on polyamide acid by using a monoalkenyl diepoxy composite flexible compound through a carboxyl-epoxy ring-opening reaction to prepare alkenyl functionalized processable polyimide; the preparation method comprises the following steps: carrying out modification treatment on nylon 6 resin by using 3-mercaptopropionic acid through an amino-carboxyl condensation reaction to prepare mercapto functionalized nylon; under the hot melting condition, alkenyl functionalized processable polyimide and sulfydryl functionalized nylon are induced to be subjected to reactive compounding through a free radical initiator, PA-PI alloy master batch is prepared, the master batch serves as a functional modification component of copolymerized polyamide 6 / 66 resin, an eleven-layer co-extrusion film is prepared through an eleven-layer co-extrusion blow molding process, and the eleven-layer co-extrusion film is used as a functional modification component of the copolymerized polyamide 6 / 66 resin. The film product has excellent comprehensive performance and can be used as a high-temperature-resistant vacuum bag film for curing aviation composite materials.

The invention relates to the technical field of building, chemical engineering and energy heat preservation, and discloses a silicon-based aerogel composite material and a preparation method and application thereof. The invention relates to a light-emitting diode (LED) photo-curing agent, which is prepared from tetraethyl orthosilicate, methyltrimethoxysilane, allyltriethoxysilane, pentaerythritol tetra (3-mercaptopropionate), N-(3-(triethoxysilyl) propyl) furfuryl amine, N-(3-(triethoxysilyl) propyl) maleimide, a photoacid generator and a photoinitiator. The composite material has a three-dimensional porous silicon dioxide network skeleton and a polymer interpenetrating network, the three-dimensional porous silicon dioxide network skeleton is formed by copolymerization of tetraethyl orthosilicate and methyltrimethoxysilane, and the polymer interpenetrating network is formed by reaction of pentaerythritol tetra (3-mercaptopropionate) and allyltriethoxysilane. The preparation method comprises the steps of sol preparation, light curing, solvent replacement, surface hydrophobic modification and normal-pressure drying. The material shows excellent thermal insulation and mechanical properties in the fields of building heat insulation, pipeline heat preservation and cryogenic heat insulation.

The invention belongs to the field of intelligent materials, and discloses a nematic phase liquid crystal elastomer fiber and a method for optimizing the thermal shrinkage performance of the nematic phase liquid crystal elastomer fiber. According to the method, the mass ratio of a cross-linking agent pentaerythritol tetra (3-mercaptopropionate) (PETMP) to a chain extender 2, 2 '-[1, 2-ethanediyl bis (oxygen)] bis (ethanethiol) (EDDET) in an LCE spinning solution is accurately controlled through a wet spinning technology, and drafting and heat treatment processes are combined, so that the LCE fiber with adjustable and controllable heat shrinkage performance and mechanical performance is prepared. The invention aims to overcome the limitations of low response speed, low shrinkage rate, insufficient environmental stability and the like of the existing LCE fiber. The reversible thermal shrinkage rate of the fiber can reach up to 35%, the maximum shrinkage deformation can be completed within 2 seconds at the soonest at the temperature of 80 DEG C, and the maximum tensile strength can reach 170 MPa. And the catalyst has excellent oxidation stability (the mass retention rate is about 97%), and can maintain efficient thermal response in a water environment. And a new way is provided for development of high-performance intelligent materials.

The invention relates to the field of inorganic material preparation, and particularly discloses pseudo-boehmite and a preparation method thereof. A preparation method of pseudo-boehmite comprises the following steps: (1) mixing an aluminum salt solution and an aluminate solution, adding a crystal form regulating agent, and stirring for reaction to obtain a sol system; the crystal form regulating agent is ZnS quantum dots modified by thiohydracrylic acid; (2) adding a pore diameter guiding agent into the sol system, and aging for 6-8 hours; the pore diameter guiding agent is a compound of a polyethylene glycol-polypropylene glycol-polyethylene glycol triblock copolymer and sodium citrate; and (3) carrying out solid-liquid separation on the aged sol system, and washing and drying the obtained solid to obtain the pseudo-boehmite. The proportion of 5-10nm pores of the pseudo-boehmite prepared by the preparation method disclosed by the invention reaches 90% or above, so that the pore distribution requirement of a fine catalytic reaction on the pseudo-boehmite can be met, and the efficient catalytic reaction is favorably realized.

The invention discloses a self-repairing composite floor for a clean room and a preparation method of the self-repairing composite floor, and the preparation method comprises the following steps: carrying out amination treatment on nano silicon dioxide and carbon quantum dots by using a silane coupling agent, and sulfonating polyethersulfone ketone by using concentrated sulfuric acid; the preparation method comprises the following steps: carrying out curing treatment on epoxy resin, an amine curing agent, N-hydroxyethyl maleimide and tetrakis (3-mercaptopropionic acid) pentaerythritol ester to obtain epoxy-mercaptan resin; the preparation method comprises the following steps: carrying out prepolymerization reaction on vacuum dehydrated polyester polyol, tetrahydroxyethyl ethylenediamine, furanpropanol, diisocyanate, a catalyst, 2, 2 '-thiodiethanol and hydroxyl silicone oil to obtain a star-shaped polyurethane prepolymer, adding epoxy-thiol resin, glyceryl borate, sulfonated polyethersulfone ketone, aminated silicon dioxide, aminated carbon quantum dots and an auxiliary agent, carrying out ultrasonic treatment, and carrying out drying to obtain the star-shaped polyurethane resin. The self-repairing coating material is obtained; and coating the self-repairing coating material on the surface of a base plate, and performing hot-pressing curing molding to obtain the self-repairing composite floor for the clean room.

This application relates to the field of polyurethane adhesive technology, and provides a thermally conductive polyurethane structural adhesive and its preparation and application methods. The thermally conductive polyurethane structural adhesive includes a first component and a second component. The first component includes a modified bio-based polyol, a polythiol, a thermally conductive filler, a first dehydrating agent, a thixotropic agent, a first catalyst, and a second catalyst. The second component includes an epoxy resin, a diisocyanate, a polyisocyanate, a thermally conductive filler, a coupling agent, a second dehydrating agent, a dispersant, and a retarder. The modified bio-based polyol is selected from at least one of modified castor oil polyol, modified oil polyol, and modified cashew nut shell oil polyol. The polythiol is selected from at least one of trimethylolpropane tris(3-mercaptopropionate), pentaerythritol tetra(3-mercaptopropionate), butanediol mercaptopropionate, and polythiol. This configuration allows the thermally conductive polyurethane structural adhesive to have a longer open time and to rapidly cure at room temperature in a short time, resulting in high initial strength.

The invention discloses yellowing-resistant light-cured organic silicon resin and a preparation method thereof, and belongs to the technical field of light-cured resin. The resin is prepared from the following raw materials in parts by weight: 80 to 100 parts of vinyl-terminated polysiloxane, 15 to 25 parts of trimethylolpropane tri (3-mercaptopropionate), 1 to 3 parts of yellowing-resistant aid, 2 to 4 parts of photoinitiator and 0.5 to 1 part of flatting agent. When the resin is prepared, the raw materials are uniformly mixed under a dark condition, and the resin is obtained after vacuum defoaming. Wherein the yellowing-resistant auxiliary agent is a benzotriazole ultraviolet light absorber and is synthesized through a multi-step reaction, the structure simultaneously contains a benzotriazole ring and anthryl, and the benzotriazole ring and the anthryl have a synergistic effect so that ultraviolet rays can be efficiently absorbed and yellowing can be inhibited. The obtained resin has excellent yellowing resistance and high curing speed, and is suitable for the fields of coatings, printing ink, adhesives, electronic packaging and the like.

The invention provides a preparation method of a magnetic recoverable catalyst and a method for synthesizing 3-mercaptopropionic acid, and mainly solves the problem that a large amount of acid and alkali solutions are needed in the existing acrylonitrile-sodium hydrosulfide and acrylic acid-thiourea process routes. The thiohydracrylic acid synthesis catalyst is prepared. The use conditions of the catalyst are as follows: the temperature is 30-80 DEG C, the reaction pressure is 0.5-3 MPa, the mass ratio of the acrylic acid to the solvent is 0.1-5, and the mass ratio of the acrylic acid to the catalyst is 0.2-20. Compared with the prior art, the catalyst disclosed by the invention is used as a synthetic catalyst for preparing thiohydracrylic acid through reaction of acrylic acid and hydrogen sulfide, a solid catalyst and a liquid reaction system can be completely separated by adopting simple methods such as filtration, centrifugation or magnetic separation, and a complicated pickling step is not needed; and the problem that a homogeneous catalyst is difficult to rectify after salification in the use process is avoided.

The invention discloses a rapid bacterium detection and counting method based on thiohydracrylic acid quantum dot fluorescence labeling, and the labeling method comprises the following steps: carrying out water-soluble modification on oil-phase quantum dots to obtain water-soluble quantum dot solids, uniformly dispersing the water-soluble quantum dot solids in water, and adjusting the pH value to 12-13 to obtain a water-phase quantum dot solution, the method for water-soluble modification of the oil-phase quantum dots comprises the following steps: dissolving solid oil-phase quantum dots in toluene, uniformly dispersing to obtain a quantum dot solution, adding thiohydracrylic acid into the quantum dot solution, carrying out oscillation reaction, standing, and drying precipitates obtained by centrifugation after precipitates are generated to obtain water-soluble quantum dot solids; and adding the aqueous-phase quantum dot solution into the bacterial liquid, and standing for reaction to finish marking. The bacteria marked by the solid oil phase quantum dots can be quickly imaged through a fluorescence microscope, and counting and morphological analysis of the bacteria can be quickly completed in combination with image analysis software capable of automatically identifying and counting the bacteria.

The invention discloses a composition for relieving, repairing and promoting skin regeneration as well as a preparation method and application of the composition. The composition is prepared from the following raw materials in parts by weight: 0.1 to 5 parts of mandelic acid, 0.5 to 10 parts of a cynanchum atratum extract, 1 to 8 parts of a xylitol compound, 0.5 to 15 parts of regenerated silicon, 1 to 10 parts of a starfish regeneration repair factor, 0.3 to 1.5 parts of trimethylolpropane tri (3-mercaptopropionic acid) ester, 0.05 to 0.5 part of calcium chloride, 0.1 to 1 part of an additive, 0.2 to 2 parts of chitosan-polycaprolactone, 0.2 to 1 part of a pH regulator and 5 to 15 parts of a solvent. 0.3 to 0.8 part of an antioxidant and 3 to 10 parts of a humectant; the additive is hyaluronic acid or formylated hyaluronic acid. Through a multi-channel synergistic effect, the effects of relieving, repairing and promoting skin regeneration are improved.

The invention relates to the technical field of high polymer materials, and particularly discloses a high-strength polyurethane adhesive as well as a preparation method and application thereof. The adhesive is prepared by compounding a double-bond-terminated polyurethane prepolymer monomer and a multi-sulfydryl cross-linking agent. And the prepolymer monomer is synthesized by reacting 4, 4-diisocyanate dicyclohexylmethane and hydroxyethyl (meth) acrylate according to a molar ratio of 1: 2. The polythiol cross-linking agent is tetrakis (3-mercaptopropionic acid) pentaerythritol ester or tetrakis (2-mercaptoacetic acid) pentaerythritol ester. When in use, the two components are mixed and then coated on a base material, and the mixture is cured at 30-100 DEG C for 0.5-5 hours. The adhesive disclosed by the invention forms a compact network through multiple crosslinking mechanisms such as sulfydryl-alkene Michael addition, so that the adhesive has extremely high shear strength (up to more than 30MPa) and excellent heat resistance and aging resistance on metal, glass, glass fiber plates and the like.

The invention discloses a carbon nanotube / cadmium selenide quantum dot heterojunction photoelectric catalyst as well as a preparation method and application thereof. The method comprises the following steps: activating single-wall and / or multi-wall carbon nanotubes by aqua regia at room temperature, dispersing the single-wall and / or multi-wall carbon nanotubes in an aqueous solution containing CdCl2. 5H2O, adding a Na2SeSO3 selenium source and 3-mercaptopropionic acid, and reacting at 110-150 DEG C, so that CdSe quantum dots with the particle size of 1-5 nm are subjected to in-situ nucleation growth on the surfaces and / or the interiors of the carbon nanotubes and form a heterojunction interface. The obtained catalyst and Nafion are prepared into ink drops, the ink drops are coated on conductive glass to construct a photocathode, in an H-type electrolytic tank with a light path, a high-purity CO2 saturated bicarbonate aqueous solution is used as an electrolyte, Ag / AgCl is used as a reference electrode, and under irradiation of an LED light source with the maximum wavelength being 450 nm and bias voltage ranging from-0.1 V (vs. RHE) to-1.0 V (vs. RHE), CO is generated through water-phase photoelectrocatalysis CO2 reduction. The photoelectrocatalyst has the characteristics of simple synthesis method and excellent photoelectrocatalytic reduction effect of carbon dioxide.

The application discloses a preparation method of nano copper powder and belongs to the technical field of nano copper powder preparation. The method comprises the following steps: S1, preparing a mercaptopropionic acid-ethanol solution; S2, preparing surface carboxylated quantum dots; S3, preparing an enzyme solution; S4, preparing an enzyme solution in which surface carboxyl groups are converted into active esters; S5, preparing a surface carboxylated quantum dot solution; S6, preparing a quantum dot-biomolecule mixture; S7, preparing a copper salt solution and adjusting the pH to 5-6; and S8, preparing nano copper powder. In the method, copper ions in the copper salt solution are reduced into copper atoms by the quantum dot-biomolecule mixture to prepare the nano copper powder. The prepared nano copper powder can accurately control the nucleation rate and quantity of the nano copper powder, and has low preparation cost and high preparation efficiency.

The application discloses a preparation method of a semi-interpenetrating network hydrogel based on an amino-succinimide ring-opening reaction, which comprises the following steps: firstly, a hydrophilic compound containing amino groups, such as trishydroxymethylaminomethane, is used to modify polysuccinimide to obtain water-soluble polysuccinimide polymer; N-vinylcaprolactam and 3-mercaptopropionic acid are reacted to obtain poly-N-vinylcaprolactam polymer with terminal carboxyl groups; and the polymer is used to graft hydroxypropyl methyl cellulose to obtain macromolecular hydroxypropyl methyl cellulose derivative. The water-soluble polysuccinimide, the polymer containing amino groups and the hydroxypropyl methyl cellulose derivative are dissolved in water, and the amino-succinimide ring-opening reaction is utilized to obtain the hydrogel; the hydrogel is soaked in water to remove uncrosslinked components; and after drying, the semi-interpenetrating network hydrogel is obtained. The preparation process is simple, the conditions are mild, and the reaction speed is fast; and the prepared hydrogel has pH / temperature sensitivity and can be used in many fields such as tissue engineering, drug release, water treatment and the like.

The application relates to the field of biological medicine, and discloses an active oxygen response thione aldehyde linker as well as a preparation method and application thereof. The thione aldehyde linker structure is a thione aldehyde structure with a p-hydroxyphenyl as a center. The thione aldehyde carbon atom is connected with two -CH2CH2COOH groups through a sulfur atom. The preparation method of the active oxygen response thione aldehyde linker comprises the following steps: dissolving 3-mercapto propionic acid and p-hydroxybenzaldehyde in ethyl acetate, adding trifluoroacetic acid as a catalyst, stirring and reacting at room temperature, and after the reaction is completed, the thione aldehyde linker is obtained through separation and purification. The thione aldehyde linker can respond to the increased ROS level in a tumor microenvironment, is broken under a high ROS condition, and thus realizes the release of a drug molecule connected therewith, which is beneficial to realizing the specific release of the drug at a tumor site.

The invention discloses a silver sulfide quantum dot loaded composite photocatalyst as well as a preparation method and application thereof, and belongs to the technical field of greenhouse gas treatment. According to the invention, different amounts of AgNO3 and 3-mercaptopropionic acid are added on the surface of CuInS2 to introduce Ag2S quantum dots in situ, so that the separation and transfer capabilities of photo-generated charges are enhanced; the composite catalyst can construct carbon dioxide reaction active sites on the premise of maintaining the unique structure and electronic characteristics of the ternary chalcogenide, improves the carbon dioxide photoreduction reaction activity, and can maintain good stability.

The invention discloses a method for preparing high-energy-density fuel from ketone and phenol. The method comprises the following specific steps: step 1, under a solvent-free condition, ketone (cyclohexanone or 3, 3, 5-trimethyl cyclohexanone) and phenol are subjected to an alkylation reaction under the catalytic action of an acidic catalyst and a cocatalyst 3-mercaptopropionic acid to generate a bisphenol product; and 2, carrying out hydrodeoxygenation (HDO) reaction on the bisphenol product serving as a high-energy-density fuel precursor under the co-catalysis of Metal / C or nonmetal RaneyNi and a solid acid catalyst to obtain the high-energy-density fuel. According to the method, green renewable raw materials are taken as starting points, high-selectivity synthesis of the target product is realized through a few-step and easy-to-operate reaction path, and the method has both environmental protection property and high efficiency; the density of the prepared high-energy-density fuel is greater than 0.90 / cm < 3 >, the calorific value is greater than 40J / L, and the performance is comparable with that of a petroleum-based high-energy-density fuel.

The application discloses an ionic liquid functionalized eggshell membrane protein material and a preparation method and application thereof, and belongs to the technical field of biological piezoelectric materials. The eggshell membrane is pretreated and then grinded into powder; the eggshell membrane powder is treated with a NaOH solution and then cleaned to neutral; the eggshell membrane powder is dissolved in an aqueous solution of 3-mercaptopropionic acid and acetic acid to react, the pH is adjusted to an isoelectric point, and a precipitate is collected and dried to obtain soluble eggshell membrane; the soluble eggshell membrane is added into ionic liquid and fully stirred and dissolved to obtain an eggshell membrane protein solution; dialysis and freeze-drying are performed to obtain ionic liquid functionalized eggshell membrane protein; and the ionic liquid functionalized eggshell membrane protein is redissolved in an aqueous solution, subjected to static defoaming, dried, and immersed in anhydrous ethanol for cross-linking to obtain an ionic liquid functionalized eggshell membrane protein film. The eggshell membrane protein film prepared by the application has good mechanical properties, high thermal stability and piezoelectricity, and the degradable protein material can be applied to the fields of biological tissue engineering, intelligent sensing and energy collection.

The application discloses a preparation method of 3-methyl mercaptopropionate, and belongs to the technical field of pesticide intermediate preparation. The application takes di-tert-butyl disulfide and methyl acrylate as raw materials, generates 3-tert-butyl mercaptopropionate under the action of lithium borohydride, then generates 3-methyl mercaptopropionate and 5-tert-butyl-1,3-dimethoxybenzene under the action of tri (pentafluorophenyl) boron while isobutene is removed and isobutene reacts with m-dimethoxybenzene, and 3-methyl mercaptopropionate is obtained after rectification. In the method, the route is good in operability, low in three wastes and cost, and provides a reference for the preparation of the compound.

The present application relates to the field of nanomaterials and analytical detection technology, in particular to a reagent for rapid detection of aureomycin and a rapid detection method of aureomycin. After adding 3-mercaptopropionic acid modified AgInS2 quantum dots to aureomycin, the fluorescence intensity and color of AgInS2 QDs change due to electrostatic interaction and band gap transition, thereby constructing a fluorescence colorimetric sensor to realize the ultra-sensitive detection of aureomycin. In order to realize the on-site detection of aureomycin, a portable device equipped with a smartphone and integrated with the AgInS2 QDs sensor is also designed. The cloud server data analysis system based on machine learning algorithm is integrated into the smartphone, which is convenient for color data collection, correction, interpretation and display. The present application utilizes the function of modern smartphones to capture and process fluorescence color signals, thereby providing a user-friendly on-site detection solution for aureomycin detection.

The invention discloses an oiling agent with high film-forming property and antistatic property for a dry-jet wet spinning precursor and a preparation method of the oiling agent, and belongs to the technical field of carbon fiber precursor oiling agents. The preparation method comprises the following steps: performing HF etching and ultrasonic stripping on a Ti3C2 precursor to prepare single-layer Ti3C2Tm, and compounding the single-layer Ti3C2Tm with fluorinated ionic liquid to form an antistatic nanosheet; the preparation method comprises the following steps: modifying chitosan with 3-mercaptopropionic acid to obtain thiolated chitosan; synthesizing a siloxane-polyurethane block compound from the epoxy modified silicone oil and the polyurethane prepolymer under the action of a catalyst; mixing the antistatic nanosheets, an emulsifier and water to form a first emulsion; emulsifying sulfhydrylated chitosan and a block compound to prepare a second emulsion; and mixing the two emulsions to obtain a finished product. Through the collaborative innovation design of the antistatic nanosheets, the thiolated chitosan and the siloxane-polyurethane block, the problems that a traditional oiling agent is poor in film-forming property, unstable in antistatic property and prone to failure at high temperature are solved, and a key technical support is provided for preparation of high-performance carbon fiber precursors.

The invention relates to the technical field of copper foils, in particular to a carrier copper foil and a preparation method and application thereof. The copper foil comprises a copper foil layer, a stripping layer and a carrier layer; and the stripping layer comprises rare earth oxide nanoparticles and silver nanowires which are distributed in an interlaced manner. Silver nanowires, ethyl alcohol and isopropyl alcohol are mixed, then thiohydracrylic acid, an activating agent and a stabilizing agent are added, mixing is conducted, and suspension liquid containing the silver nanowires and the thiohydracrylic acid is obtained; mixing rare earth oxide, polyvinylpyrrolidone and ethanol, centrifuging, collecting supernate, mixing with an amino-containing silane coupling agent and ethanol, mixing with a suspension containing silver nanowires and thiohydracrylic acid to obtain a stripping layer mixed solution, coating the surface of the carrier layer with the stripping layer mixed solution, and drying to form the stripping layer to obtain the carrier layer attached with the stripping layer; and carrying out electro-deposition on the carrier layer attached with the stripping layer to obtain the carrier copper foil. According to the prepared carrier copper foil, the copper foil layer is thin and can be completely stripped from the surface of the carrier layer.

The invention provides an interdigital electrode based on MPA and APTES synergistic modification and a preparation method and application thereof. The interdigital electrode based on MPA and APTES synergistic modification comprises an interdigital electrode substrate, a modification layer and a quantum dot layer which are sequentially stacked; and the modification layer is prepared from mercaptopropionic acid and 3-aminopropyl triethoxy silane. According to the interdigital electrode provided by the invention, the quantum dot layer can be firmly fixed through the synergistic effect of MPA and APTES, and the interface impedance is remarkably reduced.

This invention relates to a thiazole hydroxyphenyl dithiopropionic acid-based zirconium ion fluorescent probe and its preparation method. The preparation method involves a condensation reaction between ethyl 2-(3-aldehyde-4-hydroxyphenyl)-4-methylthiazole-5-carboxylate and mercaptopropionic acid to obtain a thiazole hydroxyphenyl dithiopropionic acid-based Zr ion fluorescent probe. 4+ Fluorescent probe. This invention provides a simple preparation and detection method for a thiazole hydroxyphenyl dithiopropionic acid-based fluorescent probe. It exhibits strong specificity, a wide pH range, and produces blue fluorescence upon binding with zirconium ions, allowing direct detection under ultraviolet light. This method can be applied to natural environments and areas contaminated with transition metals such as mines and chemical plants. 4+ Its convenient and efficient detection capabilities have significant practical application and expansion value.

The invention relates to a self-repairing flexible electronic material based on a non-covalent bond network and a preparation method and application thereof, and the preparation method comprises the following steps: mixing an organic silicon elastomer of a metal coordination bond, a functionalized carbon nanotube, zinc oxide and a peroxide vulcanizing agent, and carrying out a reaction to obtain the self-repairing flexible electronic material, the preparation method of the organosilicone elastomer with the metal coordination bonds comprises the following steps: firstly, mixing polysilicone rubber, thiohydracrylic acid and a photoinitiator, carrying out an ultraviolet irradiation reaction, then mixing a prepolymer, a coordination agent and a metal ion solution, and carrying out a reaction, so as to obtain the organosilicone elastomer with the metal coordination bonds, the preparation method of the functionalized carbon nanotube comprises the following steps: mixing the carbon nanotube and a silane coupling agent, and reacting to obtain the functionalized carbon nanotube. Compared with the prior art, the elastomer material disclosed by the invention can be widely applied to the fields of electronic skin, flexible sensors, intelligent wearable equipment and the like, and is particularly suitable for application scenes needing long-term reliability and environmental adaptability.

The invention relates to the technical field of micro-plastics, in particular to a novel micro-plastic composite adsorption material and a preparation method thereof. Comprising the following raw materials in parts by weight: 20-50 parts of modified sodium alginate, 8-12 parts of modified nanofibers, 3-8 parts of a graphene-based compound, 2-4 parts of modified charcoal, 2-6 parts of a plasticizer, 1-3 parts of a cross-linking agent, 0.5-1 part of an antioxidant and 0.5-1 part of L-2-amino-3-mercaptopropionic acid. The graphene-based compound is prepared by modifying the surface of graphene gel with Ag3PO4. A plurality of composite materials show the properties of rapidness, high efficiency and strong selectivity, and have excellent adsorption rate which is far higher than that of a traditional adsorption material.