271 results about "Hyperbranched polyester" patented technology

The invention relates to the technical field of folding screen supporting films, and particularly discloses a double-layer buffering supporting film for a flexible folding display screen and a preparation method of the double-layer buffering supporting film. The double-layer buffer supporting film for the flexible folding display screen sequentially comprises a release film layer, a first adhesive layer, a first stainless steel layer, a second adhesive layer, a second stainless steel layer and a protective film layer from top to bottom, the first adhesive layer and the second adhesive layer are prepared by curing the same pressure-sensitive adhesive composition; the pressure-sensitive adhesive composition is prepared from the following raw materials: acrylate copolymer, hydrogenated rosin glyceride, hyperbranched polyesteramide-dopamine conjugate, acylhydrazone bond modified siloxane, a curing agent and a silane coupling agent; the protective film layer comprises the following raw materials: PET particles, nano silicon dioxide, an ethylene-vinyl acetate copolymer and an antioxidant. The double-layer buffer supporting film has the advantages of being high in supporting rigidity and interlayer peel strength, and serious folds caused by long-term repeated folding of the folding screen can be relieved.

The invention discloses a synergistic compound light stabilizer for an automobile coating and a preparation method of the synergistic compound light stabilizer, and belongs to the technical field of coating additives. The light stabilizer comprises the following components in percentage by mass: 30-50% of a hindered amine light stabilizer, 20-40% of an ultraviolet light absorber, 5-15% of surface modified nano cerium dioxide, 5-10% of a hyperbranched polyester anti-migration aid and the balance of a solvent, wherein the ultraviolet light absorber is a mixture of benzotriazole and triazine in a mass ratio of (1: 1)-(1: 3); the particle size of the nano cerium dioxide is 10-50nm, and the surface of the nano cerium dioxide is coated with a silane coupling agent; the preparation method comprises the following steps: modifying the surface of nano cerium dioxide, shearing and dispersing multiple components at a high speed, and adjusting and filtering a solvent; the weather resistance of the automobile coating is remarkably improved and the service life of the automobile coating is remarkably prolonged through the synergistic effect of a plurality of light stabilizing components and the combination of the photocatalytic degradation capability of the nano cerium dioxide and the anti-migration characteristic of the hyperbranched polyester.

The invention provides a low-temperature-impact-resistant food packaging material and a preparation method and application thereof.The low-temperature-impact-resistant food packaging material is prepared from, by mass, 100 parts of polylactic acid, 1-10 parts of modified layered double hydroxide and 5-40 parts of hyperbranched polyester; wherein the modified layered double hydroxide is obtained by treating layered double hydroxide with a composite anionic surfactant and then treating the treated layered double hydroxide with an organic cationic compound with a long alkyl chain; the composite anionic surfactant comprises a first anionic surfactant and a second anionic surfactant; wherein the first anionic surfactant comprises sodium dodecyl sulfate; the second anionic surfactant comprises a sulfonate anionic surfactant containing an amido bond and a catechol structure. Through the formula design, the impact toughness of the material at low temperature can be improved while the mechanical property of polylactic acid is maintained, and the material can be suitable for the field of food packaging.

The invention discloses a bio-based fiber reinforced composite material and a preparation method thereof, and belongs to the technical field of bio-based fiber composite materials. The bio-based fiber reinforced composite material is prepared from the following raw materials in parts by weight: 60 to 80 parts of nylon 6, 10 to 20 parts of bio-based aramid fiber, 5 to 10 parts of modified carbon fiber, 2 to 6 parts of hyperbranched polyester modified zinc oxide and 1 to 3 parts of antioxidant, the bio-based aramid fiber is prepared by reacting 2, 5-furandicarbonyl chloride with two diamine monomers, and the two diamine monomers respectively contain trifluoromethyl and sulfuryl; the modified carbon fiber is obtained by grafting polyamidoamine on the surface of carbon fiber; the hyperbranched polyester terminal group of the hyperbranched polyester modified zinc oxide contains an epoxy group. The modified carbon fiber, the bio-based aramid fiber and the hyperbranched polyester modified zinc oxide are added into the nylon matrix, so that the composite material is endowed with good ultraviolet resistance, comprehensive mechanical properties and durability.

The invention belongs to the technical field of high polymer materials, and particularly relates to a PET decorative film and a preparation method thereof. The preparation method comprises the following steps: synthesizing hydroxyl-terminated hyperbranched polyester by taking pentaerythritol and 2, 2-dimethylolpropionic acid as raw materials, and reacting with polyol glycidyl ether to prepare an epoxy-terminated organic modifier; silver-loaded nano silicon dioxide subjected to surface treatment by an amino silane coupling agent is used as inorganic functional particles; pET resin, an organic modifier and inorganic functional particles are subjected to melt blending and extrusion granulation, and modified PET is prepared; the modified PET is prepared into the film through a two-way stretching process. Epoxy groups of the organic modifier chemically react with amino groups at the tail end of a PET molecular chain and on the surfaces of inorganic particles respectively, a stable organic-inorganic hybrid network is constructed, synergistic improvement of reinforcement, toughening and long-acting antibiosis is achieved, and the technical problems that functional particles are not uniform in dispersion, interface bonding is weak, and antibacterial components are prone to migration are effectively solved.

The low-VOC modified melamine formaldehyde resin is prepared from the following components in parts by weight: 80 to 100 parts of melamine formaldehyde resin, 5 to 10 parts of hydroxyl-terminated hyperbranched polyester, 8 to 15 parts of epoxy-terminated polybutadiene, 1 to 3 parts of fumed silica, 5 to 15 parts of polyvinyl butyral, 0.1 to 0.2 part of a coupling agent, 1 to 3 parts of a catalyst and 2 to 5 parts of a cross-linking agent, the preparation method comprises the following steps: in a stirring state, adding hydroxyl-terminated hyperbranched polyester, epoxy-terminated polybutadiene, a polyvinyl butyral resin solution and coupling agent modified fumed silica into a melamino-formaldehyde resin solution, heating to 50-70 DEG C, and adding a catalyst and a cross-linking agent; the melamine modified resin prepared by the components and the preparation method has the characteristics of low formaldehyde volatilization, high toughness and durability.

The invention discloses a wear-resistant coating and application thereof on a leather surface, and belongs to the technical field of leather finishing. The coating comprises a functionalized polyurethane-acrylate composite emulsion, a photoinitiator, an auxiliary agent and deionized water. Wherein the composite emulsion is prepared from hyperbranched polyester polyol, a dynamic bond chain extender and the like through prepolymerization, fluorine-containing grafting and in-situ sol-gel reaction, a hyperbranched skeleton provides mechanical support, double dynamic bonds endow a self-repairing function, in-situ nano-compounding enhances wear resistance, a diurea hydrogen bond enhances binding force, and a fluorine-containing side chain endows a coating with hydrophobic and stain-resistant performance; and preparing the coating by matching with a gradient curing process. The coating prepared by the invention has high wear resistance, efficient self-repairing property, firm adhesive force, excellent stain resistance and leather adaptation flexibility, and meets the actual requirements of middle and high-end leather finishing.

The invention discloses a multi-layer composite polypropylene color master batch and a preparation method thereof.The multi-layer composite polypropylene color master batch comprises an inner layer, a middle layer and an outer layer, the inner layer is coated with the middle layer, the middle layer is coated with the outer layer, matrix resin, a composite toughening agent and an interface modifier are subjected to melt blending in a double-screw extruder, nano reinforcing filler is added, extrusion granulation is performed, and the multi-layer composite polypropylene color master batch is obtained. Carrier resin, hyperbranched polyesteramide and a toner pre-dispersion body are mixed at a high speed and then uniformly coated on the outer surface of the inner layer through fluidized bed equipment, and a mixture of a weather-proof additive and a lubricant is attached to the outer surface of the middle layer by adopting an electrostatic spraying process to form the outer layer. According to the multi-layer composite color master batch, the matrix resin and the composite toughening agent have a synergistic effect, so that the impact strength of the color master batch is improved, the cavity structure of hyperbranched polyesteramide is coated with the toner, the silane is used for treating the nano filler to reduce agglomeration and chromatic aberration, the outer layer delays aging, the lubricant reduces the extrusion torque, and the multi-layer composite color master batch is adaptive to a high-speed pipe production line.

The invention relates to high-strength corrosion-resistant PA66 and a preparation method and application thereof, and belongs to the technical field of high polymer materials, the high-strength corrosion-resistant PA66 comprises the following raw materials: 55-65 parts of a PA66 base material, 20-25 parts of multifunctional modified glass fibers, 0.5-1.5 parts of an antioxidant, 1-2 parts of a lubricant, 0.1-0.5 part of a coupling agent and 2-4 parts of a flexibilizer; according to the technical scheme, the silane modified glass fiber is obtained by combining the nano material with the glass fiber and then grafting the silane coupling agent; combining the silane modified glass fiber, diamine and fluorinated dianhydride to obtain an anhydride-terminated compound; combining the anhydride-terminated compound with amphiphilic hyperbranched polyester to obtain the multifunctional modified glass fiber; mixing the PA66 base material, the multifunctional modified glass fiber, an antioxidant, a lubricant, a coupling agent and a flexibilizer, and performing extrusion granulation to obtain the high-strength corrosion-resistant PA66. The corrosion resistance, the thermal stability and the mechanical property of the PA66 are integrally improved.

The invention relates to the technical field of modified polypropylene composite materials, in particular to a polypropylene composite material for thin-wall injection molding and a preparation method thereof.The polypropylene composite material is prepared from 70-85 parts of polypropylene, 1-15 parts of toughened branched resin, 3-5 parts of maleic acid copolymer, 5-10 parts of inorganic filler, 0.1-0.5 part of antioxidant and 0.1-0.5 part of light stabilizer; the toughened branched resin comprises carboxyl-terminated hyperbranched polyester and methoxyl polyethylene glycol, and the mass ratio of the carboxyl-terminated hyperbranched polyester to the methoxyl polyethylene glycol is 1: (2-4). According to the invention, impact energy is dispersed by toughening a branched structure in the branched resin, the energy absorption capacity is enhanced by an mPEG flexible chain, the impact toughness of the polypropylene composite material is remarkably improved through the synergistic effect of the two, and meanwhile, the tensile strength is maintained. The inorganic filler is matched to enhance the rigidity of the polypropylene composite material, so that the balance of toughness and rigidity is realized.

The invention belongs to the technical field of high polymer material preparation, and provides a low-melting-point toughened copolyester chip and a preparation method thereof. The preparation method comprises the following steps: firstly, preparing hyperbranched polyester of which the surface is rich in carboxyl-terminated functional groups through core growth of polybasic acid alcohol and end group functionalization reaction of anhydride; the other chain extender is a linear chain extender which has a long flexible chain segment and two tail ends of which are also functionalized by carboxyl groups, and is obtained by carrying out end group esterification reaction on polyether glycol; then, in the synthesis process of the main polyester, carrying out multi-stage melt polycondensation on an aromatic dibasic acid component and a polyol component under the action of a composite catalyst system, introducing the hyperbranched polyester and a chain extender into a reaction system in the form of slurry, and covalently bonding a functional additive to a copolyester main chain through a polycondensation process, so as to obtain the hyperbranched polyester. An integrated network reinforced structure is formed, so that the copolyester chip has the characteristics of low melting point and excellent toughness.

Disclosed in the present invention are an acrylic polyurethane finish coat having a high solid content and super weather resistance and a preparation method therefor. The finish coat consists of a component A and a component B, the mass ratio of the component A to the component B being 20:(2-5). The component A comprises the following components in parts by mass: 30-45 parts of acrylic resin, 2-10 parts of a modified resin, 2-10 parts of a hyperbranched polyester polyol, 25-40 parts of a pigment and filler, 0-1.5 parts of a thixotropic agent, 0.1-10 parts of a dispersing agent, 0.1-0.5 part of a defoaming agent, 0.01-1 part of a drier and 1-10 parts of a mixed solvent. The component B comprises the following components in parts by mass: 70-95 parts of an aliphatic isocyanate polymer, 2-15 parts of xylene and 2-15 parts of propylene glycol methyl ether acetate. The coat of the present invention exhibits excellent weather resistance, which is comparable to that of super-weather-resistant finish coats fluorocarbon finish coats and polysiloxane finish coats, and has high mechanical strength and an anti-corrosion property, and is thus particularly suitable for surface coating of steel structures in the environment of South China Sea.

The invention provides a degradable modified polyester fiber as well as a preparation method and application thereof, and belongs to the field of textile fibers. The degradable modified polyester fiber provided by the invention is prepared from the following components in parts by weight: 80 to 110 parts of PBAT (poly (butylene adipate-co-terephthalate)), 1 to 35 parts of natural plant fiber, 0.1 to 20 parts of hyperbranched polyester grafted carbon nanotube, 0.1 to 20 parts of nano-silver-titanium dioxide compound and 0.1 to 20 parts of plant essential oil microcapsule, the degradable modified polyester fiber is prepared from the components through melt blending and spinning, so that the toughness is enhanced while the mechanical property is improved, the components can be uniformly dispersed, the interfacial compatibility is improved, and the polyester fiber is endowed with antistatic property and antibacterial property. The application of the modified polyester fiber in textiles can solve the problems that waste textiles are difficult to degrade, the textiles are poor in flexibility and comfort and the like.

The invention discloses a low-residue lithium battery positive electrode tab film adhesive material and a preparation method thereof, and belongs to the technical field of lithium battery auxiliary materials. The preparation method comprises the steps of copolymer synthesis, premixing, filler dispersion, crosslinking system introduction and defoaming, and coating and packaging, the copolymer is prepared by norbornene, hexafluorobutyl acrylate and maleic anhydride free radical copolymerization, and fluorinated hyperbranched polyester is subjected to ester exchange and epoxy ring opening one-step functionalization. Aiming at the problems of high high-temperature residue, weak interface adhesion and poor electrolyte resistance of the existing adhesive, the invention designs that a fluorine-containing copolymer with high thermal stability and high reaction activity is taken as a main body and is matched with a reactive compatibilizer to construct a strong chemical bonding interface, and a hyperbranched stabilizer with double functions of physical binding and chemical chelation is introduced, so that the adhesive is prepared. The tab adhesive film bonding material with ultralow residue, ultrahigh peel strength and excellent electrolyte resistance is successfully prepared, and the long-term reliable sealing requirement of a high-energy-density lithium battery can be met.

The invention relates to the technical field of western-style clothes processing, in particular to an anti-wrinkle western-style clothes fabric and a processing technology thereof.The anti-wrinkle western-style clothes fabric is prepared by finishing base cloth through finishing liquid, the base cloth is wool blended fabric, and the wool blended fabric comprises wool, polyester fibers, lyocell fibers, spandex and conductive fibers; the finishing liquid is prepared from the following raw materials in parts by weight: 1 to 4 parts of polyoxyethylene sorbitan monooleate, 0.1 to 1 part of cocamidopropyl betaine, 2 to 6 parts of a fiber protecting agent, 80 to 120 parts of carboxyl-terminated hyperbranched polyester, 40 to 60 parts of butanetetracarboxylic acid, 30 to 50 parts of poloxamer, 0.1 to 2 parts of a silane coupling agent, 2 to 4 parts of an aziridine cross-linking agent and 900 to 1100 parts of water; the fabric has the advantage that the crease resistance of the business suit fabric is improved.

The invention discloses high-strength plastic particles as well as a preparation method and application thereof, and belongs to the technical field of high polymer material modification. The plastic particle is prepared from high-density polyethylene, hyperbranched polyesteramine containing a diurea group, a layered double metal hydroxide-polypyrrole nano hybrid, a maleic anhydride grafted ethylene-octylene copolymer, an antioxidant and calcium stearate. Wherein the hyperbranched polyesteramine containing the diurea group is prepared by reacting pentaerythritol with citric acid to generate a citrate framework and then reacting with diphenylmethane diisocyanate and 1, 4-butanediol; the layered double hydroxide-polypyrrole nano hybrid is prepared by carrying out in-situ polymerization and coating on magnesium-aluminum layered double hydroxides through a pyrrole monomer. According to the plastic particle, the tensile strength, the heat resistance and the flame retardance are remarkably improved through synergistic enhancement of the hyperbranched polyesteramine and the nano hybrid, and the plastic particle can be applied to the fields of automobile bumpers, high-voltage cable sheaths, weather-proof plates for buildings and the like.

The invention relates to the technical field of fiber reinforced resin-based composite materials, and discloses a basalt fiber epoxy resin composite material as well as a preparation method and application thereof. Comprising the following steps: carrying out oxygen plasma treatment and dopamine bionic liquid deposition treatment on basalt fibers, dipping the basalt fibers in a mixed coupling agent solution, and coating the basalt fibers with nano TiO2 sol to obtain nano roughened basalt fibers; mixing bisphenol A epoxy resin, hydrogenated bisphenol A epoxy resin, hyperbranched polyesteramine and ionic liquid modified boron nitride nanosheets to obtain resin A; mixing an epoxy curing agent with a curing accelerator to obtain resin B; and mixing the resin A and the resin B to obtain a mixed material, and infiltrating the nano roughened basalt fibers in the mixed material to obtain the basalt fiber epoxy resin composite material. After the basalt fiber is subjected to bionic multi-stage interface treatment, the basalt fiber is matched with the modified epoxy resin, so that the interface strength, the mechanical property and the weather resistance of the composite material are remarkably improved, and the composite material has a relatively good application scene.

The invention provides bio-based hyperbranched unsaturated polyester, a UV curing coating and application of the bio-based hyperbranched unsaturated polyester and the UV curing coating. The bio-based hyperbranched unsaturated polyester is obtained through polycondensation of preparation raw materials including bio-based hydroxyl-terminated hyperbranched polyester, unsaturated binary acid and / or anhydride thereof and maleic acid modified polyolefin. The preparation raw materials of the UV curing coating comprise the following components in parts by weight: 20-60 parts of bio-based hyperbranched unsaturated polyester, 20-80 parts of an active diluent monomer and 2-7 parts of a photoinitiator. The hyperbranched unsaturated polyester disclosed by the invention is high in reaction activity, low in viscosity and low in shrinkage rate; the UV coating prepared from the resin is low in viscosity and can be coated in a roller coating mode, a cured coating is compact, MEK wiping resistance reaches more than 1000 times, glossiness attenuation is lower than 10% after UVB illumination is adopted for 1600 h, haze is lower than 1%, hardness and abrasion resistance are excellent, adhesive force to multiple base materials is good, and the UV coating is very suitable for being applied to optical films.

The invention relates to a hydroxyl-terminated hyperbranched polyester modified hindered phenol composite material and a butyl rubber damping material prepared from the hydroxyl-terminated hyperbranched polyester modified hindered phenol composite material. The hydroxyl-terminated hyperbranched polyester modified hindered phenol composite material is introduced into a butyl rubber system as a functional additive, on one hand, hydrogen-bond interaction can be formed between the hindered phenol composite material and a polar side group in a rubber matrix, when external stress or vibration is applied, hydrogen bonds in the material are weakened or broken, and new hydrogen bonds are continuously formed, so that the service life of the material is prolonged; in the process, a large amount of energy of a system is consumed, mechanical energy is converted into internal energy, and the damping performance of the composite material is improved; on the other hand, the glass transition temperature of the rubber material can be changed, so that the effect that the optimal damping use temperature range is adjustable is achieved, and the problem that use conditions are limited due to the fact that the glass transition temperature of butyl rubber is low is solved; and meanwhile, the wider damping temperature range and the better stripping performance also conform to the diversification and functionalization development trend of the current non-vulcanized rubber damping material.

The present application relates to the technical field of discontinuous reinforced short fibers, in particular to a high-performance composite short fiber and a preparation method thereof.The present application overcomes the contradiction between the hygroscopicity and mechanical properties of the composite short fiber and the problem of poor skin-core interface compatibility.By reacting acidified carbon nanotubes with hydroxyl-terminated hyperbranched polyester, and then melt extruding with PET chips, a high-strength core layer master batch is obtained;high-density polyethylene, a hydrophilic agent, hydrophilic modified MOF particles and E-GMA copolymer are mixed and extruded to obtain a skin layer PE master batch with long-term hydrophilicity;the skin and core layer master batches are spun into a skin-core structure, and after ring blowing cooling, two-bath drafting, heat setting, mechanical crimping and cutting, a composite fiber is obtained.The prepared PE / PET bicomponent composite short fiber not only has excellent tensile strength, but also has persistent and stable moisture absorption and sweat releasing functions.

The application discloses a wear-resistant coating and application thereof to a leather surface, and belongs to the technical field of leather finishing. The coating comprises a functional polyurethane-acrylate composite emulsion, a photoinitiator, an additive and deionized water. The composite emulsion is prepared through pre-polymerization, fluorine-containing grafting and in-situ sol-gel reaction of hyperbranched polyester polyol, dynamic bond chain extender and the like. The hyperbranched skeleton provides mechanical support, the double dynamic bonds endow the coating with self-repairing function, in-situ nano-composite enhances wear resistance, the double urea hydrogen bonds strengthen the bonding force, and the fluorine-containing side chains endow the coating with hydrophobic and stain-resistant properties. The coating is prepared by matching a gradient curing process. The coating prepared by the application has high wear resistance, efficient self-repairing property, firm adhesion, excellent stain resistance and leather-adaptive flexibility, and meets the actual needs of medium and high-end leather finishing.

The invention belongs to the technical field of high polymer materials, and particularly discloses glycidyl ester type epoxy resin and a preparation method thereof, the preparation method comprises the following steps: (1) melting polymerized rosin, adding a first catalyst, maleic anhydride, methacrylic acid and hydroxyl-terminated hyperbranched polyester, and reacting to obtain a precursor; and (2) adding bisphenol A epoxy resin and a second catalyst into the precursor, and reacting to obtain the glycidyl ester type epoxy resin. According to the invention, maleic anhydride, methacrylic acid, hydroxyl-terminated hyperbranched polyester and bisphenol A epoxy resin are combined; the three-dimensional synergistic enhancement of rigidity-flexibility-branching is realized, the proportion of rigid and flexible chain segments in a molecular structure is effectively coordinated, reaction active sites and crosslinking density are effectively improved, more reaction active sites and reaction activity are provided, and the mechanical property of a product is effectively improved.

The application discloses a PET composition, which comprises the following components in parts by weight: PET 51-61 parts; PETG 5-15 parts; carboxyl-terminated hyperbranched polyester 1-5 parts; glass fiber 25-35 parts; nucleating agent 0.2-0.8 parts. By adding specific amounts of PETG, hyperbranched polyester and nucleating agent, the screw column torque performance of the PET composition can be significantly improved, and the high screw column torque is obtained, so that the PET composition is suitable for preparing household appliances, electronic appliances and other products requiring screw installation.

The invention discloses rapid ultraviolet curing conductive silver paste for LTCC (Low Temperature Co-Fired Ceramic) and a preparation method of the rapid ultraviolet curing conductive silver paste. The rapid ultraviolet curing conductive silver paste comprises the following materials in parts by weight: 10-25 parts of prepolymer; 1-5 parts of a plasticizer; 60 to 85 parts of silver powder; 3-8 parts of glass powder; 0.5 to 2 parts of a photoinitiator; wherein the prepolymer is hyperbranched polyester acrylate, the branching degree of the hyperbranched polyester acrylate is 0.5-0.7, the hyperbranched polyester acrylate has a sea urchin-shaped structure, and the number-average molecular weight of the hyperbranched polyester acrylate is 16000-22000. The specific hyperbranched polyester acrylate is selected as a prepolymer and compounded with other components in a system according to a specific proportion, the prepared silver paste can be rapidly cured at room temperature under ultraviolet light and can be cured within 5 seconds, the viscosity of the paste is low, powder (silver powder and glass powder) is uniformly dispersed, printing processing is easy, the prepared silver paste is low in resistivity, and the silver paste has good application prospects. And the conductivity is good.

The present application relates to a kind of good antibacterial shape retention textile fabric.The textile fabric is spun from modified cotton fiber and auxiliary fiber;The modified cotton fiber is obtained by two-step modification of surface coating modification and surface quaternization modification, the surface coating modification realizes the grafting of hyperbranched polyether chain segment and siloxane chain segment on the surface of cotton fiber by chemical bond chain, the toughening characteristics of hyperbranched polyether chain segment is used to improve the toughness of cotton fiber, improve the appearance flatness of the obtained fabric, while overcome the characteristics of fabric prone to damp due to the introduction of hyperbranched polyether, finally after surface quaternization modification, quaternary ammonium salt structure is introduced into hyperbranched polyester chain segment, and then antibacterial properties are given to cotton fiber;Therefore, the textile fabric obtained by the present application has good antibacterial properties and wash fastness.

The invention discloses a battery shell outer layer composite material, a battery shell outer layer and a preparation method of the battery shell outer layer, and belongs to the technical field of battery shell outer layer composite materials. The matrix resin comprises the following preparation raw materials: 5-18% of modified hydroxyl-terminated hyperbranched polyester, 2-6% of hydrophobic modified silica sol, 2-10% of a lubricant, 2-8% of a heat conduction phase, 0.5-3% of a composite anti-aging agent and the balance of co-polypropylene; the modified hydroxyl-terminated hyperbranched polyester is hydroxyl-terminated hyperbranched polyester treated by a vulcanized maleimide derivative. According to the matrix resin disclosed by the invention, co-polypropylene is taken as a matrix, vulcanized maleimide derivative modified hydroxyl-terminated hyperbranched polyester and modified silica sol are introduced to construct a compatible system, a filler system is further optimized, and finally, the outer-layer composite material of the battery shell is prepared. The composite material for the outer layer of the battery shell is excellent in mechanical property and weather resistance.

The invention discloses a light high-strength corrosion-resistant composite insulated electric pole and a preparation method thereof, and belongs to the technical field of power transmission facilities. The electric pole is of a conical hollow structure, and an inner tough layer, a structural layer and an outer protective layer are sequentially compounded on a wall layer from inside to outside. The inner tough layer is made of a hyperbranched polyester modified epoxy vinyl ester-glass fiber composite material, so that the electric pole is endowed with excellent bending resilience performance; the structural layer is made of S glass fiber and T700 carbon fiber hybrid reinforced epoxy resin, so that high strength and rigidity are ensured; the outer protective layer is a fluorinated polyurethane / boron nitride composite coating, and provides long-acting weather resistance, corrosion resistance and insulation protection. According to the invention, through collaborative design of multi-layer materials and an integrated forming process, light weight, high mechanical strength, excellent insulativity and recoverability after bending of the electric pole are realized, and the electric pole is suitable for electric power line construction in a harsh environment.

The present application relates to the field of rubber, in particular to a kind of flame-retardant neoprene and preparation method thereof.The present application first prepares the raw material of flame-retardant neoprene, mixes and masticates the raw material under certain conditions to obtain mixed rubber, and finally vulcanizes the mixed rubber to prepare a kind of flame-retardant neoprene;Its characteristics lie in that the composition of flame-retardant agent in the raw material of flame-retardant neoprene is the mixture of nano zinc oxide and nano magnesium oxide modified by silane coupling agent grafted onto hyperbranched polyester structure, which can improve the dispersibility of nano structure on one hand, prevent the occurrence of agglomeration phenomenon, and at the same time, the reaction efficiency can be improved by grafting the reactants together;On the other hand, the phosphorus-containing group and nitrogen-containing group of urea and phosphoric acid are grafted onto the hyperbranched polyester structure, so that the groups of hyperbranched polyester are rich in flame-retardant elements nitrogen and phosphorus, thereby significantly improving the flame-retardant performance of neoprene.

The invention discloses an automobile ornament softwood surface coating, a preparation method and application, and relates to the technical field of automobile coatings, the automobile ornament softwood surface coating comprises the following specific components: a primer, a brush-off layer, a seal paint and a finish paint. Aiming at the structural defects and practical application requirements of the cork material, a multifunctional synergistic system of primer, brush-off layer, seal paint and finish paint is constructed; the nano flake mica and the nano montmorillonite form a labyrinth type water-blocking structure in the primer, the hyperbranched polyester and the nano cellulose construct a stable color wiping and developing system, and the organic silicon sealing layer is compounded with the hollow microbeads and the nano zinc oxide to realize light-weight heat insulation protection. And nano aluminum oxide and fluorine modified wax powder in the finish paint jointly enhance the wear resistance and scratch resistance of the surface, so that the overall weather resistance, adhesive force, damp heat resistance, aging resistance and mechanical stability of the cork are effectively improved on the premise of not sacrificing the natural touch of the cork. And a complete set of technical support and an industrialization foundation are provided for large-scale application of the cork material in automobile high-end ornaments.

The invention discloses a maleic anhydride functional modified polyolefin resin composition as well as a preparation method and application thereof, and relates to the technical field of high polymer materials. Comprising the following steps: mixing maleic anhydride modified polypropylene, polylactic acid and dicumyl peroxide, banburying, adding modified silicon dioxide, a synergist, epoxidized soybean oil and hydroxyl-terminated hyperbranched polyester, carrying out melt blending, and carrying out water-cooling tabletting and crushing treatment to obtain the maleic anhydride functionalized modified polyolefin resin composition. By introducing maleic anhydride modified polypropylene prepared from polypropylene, maleic anhydride and other components, the adhesive force, impact resistance and flame retardance of the polyolefin resin composition can be effectively improved; and the flame retardance, the corrosion resistance, the impact resistance and the heat resistance of the polyolefin resin composition are further improved due to the introduction of the synergist, the modified silicon dioxide and other components. Therefore, the method has a wider application prospect.