433 results about "Hyperbranched polyester" patented technology

The invention relates to the field of matt films, in particular to a BOPP matt film suitable for a direct coating process and a preparation method of the BOPP matt film. The BOPP matt film suitable for the direct coating process comprises an upper surface layer, a middle core layer and a lower surface layer which are sequentially arranged, the upper surface layer is an extinction layer and comprises polypropylene random copolymer, 40-51 wt% of high-density polyethylene, 2-3 wt% of n-alkyl chain modified hyperbranched polyester and 5-8 wt% of maleic anhydride-styrene melt grafted polypropylene random copolymer; the middle core layer comprises homo-polypropylene; and the lower surface layer comprises homo-polypropylene. According to the matt film, the roughness of the matt layer can be improved by optimizing the components of the matt layer, the problem of whitening'hard spots' on the surface of the matt film in a direct coating process is solved, and then the quality of a coated matt film product is improved, so that the appearance quality of products such as laminated paper, paper boxes and labels which are subsequently laminated is ensured.

The invention relates to the technical field of folding screen supporting films, and particularly discloses a double-layer buffering supporting film for a flexible folding display screen and a preparation method of the double-layer buffering supporting film. The double-layer buffer supporting film for the flexible folding display screen sequentially comprises a release film layer, a first adhesive layer, a first stainless steel layer, a second adhesive layer, a second stainless steel layer and a protective film layer from top to bottom, the first adhesive layer and the second adhesive layer are prepared by curing the same pressure-sensitive adhesive composition; the pressure-sensitive adhesive composition is prepared from the following raw materials: acrylate copolymer, hydrogenated rosin glyceride, hyperbranched polyesteramide-dopamine conjugate, acylhydrazone bond modified siloxane, a curing agent and a silane coupling agent; the protective film layer comprises the following raw materials: PET particles, nano silicon dioxide, an ethylene-vinyl acetate copolymer and an antioxidant. The double-layer buffer supporting film has the advantages of being high in supporting rigidity and interlayer peel strength, and serious folds caused by long-term repeated folding of the folding screen can be relieved.

The invention discloses a waterproof anticorrosive coating and a preparation method and application thereof, and relates to the technical field of coatings, and the waterproof anticorrosive coating is prepared from the following raw materials in parts by weight: 30-40 parts of carboxyl-terminated hyperbranched polyester resin, 20-30 parts of carboxyl-terminated functional polyamide, 10-15 parts of hyperbranched polyurethane containing epoxy groups, 15-20 parts of filler, 1-3 parts of (3, 6-diamino acridine-9-yl) boric acid, 1-3 parts of 1, 3, 5-trimethyl-1, 3, 5-trimethyl-1, 3, 5-trimethyl-1, 3, 5-trimethyl-1, 3, 5-trimethyl-1, 3, 5-trimethyl-1, 3, 5-trimethyl-1, 3, 5-trimethyl-1, 3, 5- the component A is prepared from the following components in parts by weight: 3-5 parts of 2, 3, 5-triglycidyl-S-triazinetrione, 1-2 parts of a coupling agent, 0.8-1.2 parts of a flatting agent and 0.6-1.3 parts of a defoaming agent; the carboxyl-terminated functional polyamide comprises a structural unit introduced by the following monomers: N-(4H-1, 2, 4-triazole-4-yl) diphenylamine-4, 4 '-dicarboxylic acid, and 3, 3'-diamino-4, 4 '-difluorodiphenyl sulfone. The coating is good in waterproof and anti-corrosion performance, high in adhesive force with a base material, sufficient in solvent resistance and aging resistance and long in service life.

The invention relates to the field of quantum dot ink, and discloses diffusion plate printing quantum dot ink and a preparation method thereof.The diffusion plate printing quantum dot ink comprises acrylic resin, hyperbranched polyester resin, a quantum dot material, modified boron nitride, a reactive diluent, a photoinitiator, a wetting agent and a defoaming agent; the hyperbranched polyester resin is prepared by reacting hyperbranched polyester acrylate and a sulfydryl-terminated silicon-containing reaction monomer, wherein the hyperbranched polyester acrylate is prepared by reacting pentaerythritol with 2, 2-dimethylolpropionic acid and then carrying out esterification reaction with acrylic acid; the sulfydryl-terminated silicon-containing reaction monomer is prepared by reacting eugenol with 1, 1, 3, 3-tetramethyldisiloxane and then carrying out esterification reaction with 3-mercaptopropionic acid; the modified boron nitride is prepared by modifying a cationic polymer which is prepared by carrying out a Mannich reaction on triethylene tetramine, formaldehyde and acetone and then carrying out a condensation polymerization reaction with formaldehyde. After the ink prepared by the invention is cured, a coating film is high in hardness, adhesive force and heat conductivity coefficient, and good in flexibility, heat resistance and migration barrier property.

The invention discloses a synergistic compound light stabilizer for an automobile coating and a preparation method of the synergistic compound light stabilizer, and belongs to the technical field of coating additives. The light stabilizer comprises the following components in percentage by mass: 30-50% of a hindered amine light stabilizer, 20-40% of an ultraviolet light absorber, 5-15% of surface modified nano cerium dioxide, 5-10% of a hyperbranched polyester anti-migration aid and the balance of a solvent, wherein the ultraviolet light absorber is a mixture of benzotriazole and triazine in a mass ratio of (1: 1)-(1: 3); the particle size of the nano cerium dioxide is 10-50nm, and the surface of the nano cerium dioxide is coated with a silane coupling agent; the preparation method comprises the following steps: modifying the surface of nano cerium dioxide, shearing and dispersing multiple components at a high speed, and adjusting and filtering a solvent; the weather resistance of the automobile coating is remarkably improved and the service life of the automobile coating is remarkably prolonged through the synergistic effect of a plurality of light stabilizing components and the combination of the photocatalytic degradation capability of the nano cerium dioxide and the anti-migration characteristic of the hyperbranched polyester.

The invention belongs to the technical field of modification of ultra-high molecular weight polyethylene, and particularly relates to special resin for a modified ultra-high molecular weight polyethylene lining oil pipe and a preparation method of the special resin. The special resin for the modified ultra-high molecular weight polyethylene lining oil pipe is prepared from the following raw materials in parts by mass: 65 to 80 parts of ultra-high molecular weight polyethylene, 5 to 10 parts of high-density polyethylene, 8 to 12 parts of modified polyaryletherketone, 4 to 7 parts of modified hyperbranched polyester, 0.3 to 2 parts of silicone master batch and 0.1 to 0.5 part of antioxidant. The lining oil pipe prepared from the special resin for the modified ultra-high molecular weight polyethylene lining oil pipe has excellent wear resistance and high temperature resistance, and also has good mechanical properties such as tensile strength and impact strength.

The invention provides a low-temperature-impact-resistant food packaging material and a preparation method and application thereof.The low-temperature-impact-resistant food packaging material is prepared from, by mass, 100 parts of polylactic acid, 1-10 parts of modified layered double hydroxide and 5-40 parts of hyperbranched polyester; wherein the modified layered double hydroxide is obtained by treating layered double hydroxide with a composite anionic surfactant and then treating the treated layered double hydroxide with an organic cationic compound with a long alkyl chain; the composite anionic surfactant comprises a first anionic surfactant and a second anionic surfactant; wherein the first anionic surfactant comprises sodium dodecyl sulfate; the second anionic surfactant comprises a sulfonate anionic surfactant containing an amido bond and a catechol structure. Through the formula design, the impact toughness of the material at low temperature can be improved while the mechanical property of polylactic acid is maintained, and the material can be suitable for the field of food packaging.

The present invention provides a polyester heat-shrinkable film containing recycled materials and a preparation method thereof, belonging to the technical field of polymer synthetic films. The raw materials of the polyester heat-shrinkable film include recycled PET polyester particles, PET polyester chips, and a modified masterbatch; the modified masterbatch is prepared from polyethylene terephthalate-1,4-cyclohexanedimethanol ester, triphenyl phosphite, polyethylene glycol block copolymer, nano-silica, and hyperbranched polyester amine; the polyethylene glycol block copolymer is prepared from polyethylene glycol and γ-valerolactone under the action of a catalyst; the hyperbranched polyester amine is prepared from trimethylolpropane, methyl crotonate, and diethylenetriamine. The product of the present invention has excellent properties such as excellent unidirectional anti-shrinkage performance and low haze.

The invention discloses an MLCC release film base film and a preparation method thereof, and relates to the technical field of release films, the MLCC release film base film comprises a core layer and a functional coating layer arranged on the outer surface of the core layer; the core layer is prepared from the following raw materials: PET (Polyethylene Terephthalate) resin, functional polyester containing triazolyl tetrafluorophenyl, a coupling agent, reinforced fibers, an antioxidant and a lubricant; the functional coating layer is prepared from the following components: hydroxyl-terminated hyperbranched polyester, isocyano ethyl methacrylate, vinyl trimethoxy silane, nano filler, 3, 3 '-diamino-4, 4'-difluorodiphenyl sulfone, 2, 2 '-bis (trifluoromethyl) diaminobiphenyl, a photoinitiator, a catalyst A and a diluent. The base film is low in surface roughness and warping degree, good in high temperature resistance, high in flatness and appropriate in stiffness.

The invention relates to the technical field of concrete admixtures, and discloses a hydration temperature rise inhibitor special for mass concrete and a preparation method of the hydration temperature rise inhibitor. Comprising the following raw materials in parts by weight: 95 to 105 parts of borax, 50 to 60 parts of triethanolamine, 90 to 110 parts of gluconate, 190 to 200 parts of polycarboxylic acid and 95 to 105 parts of carboxyl-terminated hyperbranched polyester. According to the invention, by adopting the admixture to reduce hydration heat and prolong final setting time, the defects of large and concentrated heat release of common concrete and complex process, high cost and poor structural integrity of the traditional construction technology can be overcome, the problem of easy generation of temperature cracks in mass concrete is solved, the construction complexity is reduced, and the construction efficiency is improved. And the cracking phenomenon of mass concrete is improved, and the technical purposes of low cost, high efficiency and high adaptability are achieved.

The invention discloses a biodegradable lamination material and a preparation method thereof. The method comprises the following steps: stirring and mixing PLA (polylactic acid), PBAT (polyethylene terephthalate-co-caprolactone), SiO2-HBPE3 (silicon dioxide grafted hyperbranched polyester) and an auxiliary agent through a high-speed mixer; the preparation method comprises the following steps: uniformly mixing the raw materials, adding the uniformly mixed raw materials into twin-screw extrusion equipment for extrusion, carrying out bracing, traction, cooling and pelletizing processes to prepare PLA coating composite modified particles, treating the modified particles in a vacuum dehumidification box, and finally coating.

The invention belongs to the technical field of polymer materials, and provides LED-moisture dual-curing organic silicon modified hyperbranched polyurethane acrylic resin as well as a preparation method and application thereof. The preparation method comprises the following steps: firstly, taking first polyhydric alcohol and polyatomic acid as raw materials, preparing a hyperbranched polyester prepolymer containing hydroxyl at the tail end through a first reaction, and further performing a second reaction with an isocyanate compound and second polyhydric alcohol to prepare a hyperbranched polyurethane prepolymer containing isocyanate groups at the tail end; the coating further prepared from the organosilicon modified hyperbranched polyurethane acrylic resin not only can be subjected to UV curing, but also can be subjected to LED curing and moisture curing, energy required by curing is low, curing is 100%, environment friendliness is achieved, VOC is zero, the flash point is 95 DEG C or above, the product curing speed is high, the viscosity is low, and the coating can be widely applied to the field of high-temperature curing, high-temperature curing, high-temperature curing, high-temperature curing, high-temperature curing, high-temperature curing, high-temperature curing, high-temperature curing, high-temperature curing, high-temperature curing and high-temperature curing. The paint has the advantages of good flexibility, good film-forming property, strong adhesive force and excellent weather resistance.

The invention discloses high-viscosity and high-elasticity modified asphalt and an asphalt composition, belongs to the field of asphalt, and solves the technical problem that the existing asphalt material lacks high-viscosity and high-elasticity modified asphalt suitable for diversified climates. The high-viscosity and high-elasticity modified asphalt suitable for diversified climates is prepared from the following raw materials in parts by mass: 100 parts of road petroleum asphalt, 2.5-4 parts of an epoxidized modified styrene-butadiene-styrene block copolymer, 5-10 parts of a hyperbranched polyester modified styrene-isoprene-styrene block copolymer, 5-10 parts of tackifying resin, 1-3 parts of a coupling agent, 1-3 parts of a coupling agent, 1-3 parts of a coupling agent, 1-3 parts of an antioxidant and 1-3 parts of a lubricant. The modified asphalt is prepared from, by weight, 1-2 parts of rubber powder, 1-2 parts of oleamide, 2-3 parts of bagasse fibers and 2-10 parts of other functional auxiliaries. The modified asphalt has the advantages of being high in viscosity and elasticity, suitable for various climates and the like.

The invention provides a polyurethane material for leaking stoppage of a coal mine and a preparation method of the polyurethane material, and belongs to the technical field of polyurethane. The preparation method comprises the following steps: preparing melamine formaldehyde resin balls and ZnAl-LDHs, mixing and reacting the melamine formaldehyde resin balls and the ZnAl-LDHs to prepare LDH-MF composite balls, dipping in an iron salt solution, calcining to prepare composite balls, chloridizing with thionyl chloride, reacting with an ionic liquid and hyperbranched polyester to prepare IL / G composite balls, mixing with polyether polyol and a catalyst, adding into water, adding a foaming agent and silicone oil, heating, stirring and mixing, transferring into a mold, and carrying out extrusion molding to obtain a finished product. And adding diisocyanate, foaming, cooling to room temperature, drying and curing to obtain the polyurethane material for leaking stoppage of the coal mine. The prepared polyurethane material for leaking stoppage of the coal mine has good mechanical property, high temperature resistance and antibacterial property, good flexibility, good antistatic property and obviously improved flame retardance, and has a wide application prospect.

The invention discloses a bio-based fiber reinforced composite material and a preparation method thereof, and belongs to the technical field of bio-based fiber composite materials. The bio-based fiber reinforced composite material is prepared from the following raw materials in parts by weight: 60 to 80 parts of nylon 6, 10 to 20 parts of bio-based aramid fiber, 5 to 10 parts of modified carbon fiber, 2 to 6 parts of hyperbranched polyester modified zinc oxide and 1 to 3 parts of antioxidant, the bio-based aramid fiber is prepared by reacting 2, 5-furandicarbonyl chloride with two diamine monomers, and the two diamine monomers respectively contain trifluoromethyl and sulfuryl; the modified carbon fiber is obtained by grafting polyamidoamine on the surface of carbon fiber; the hyperbranched polyester terminal group of the hyperbranched polyester modified zinc oxide contains an epoxy group. The modified carbon fiber, the bio-based aramid fiber and the hyperbranched polyester modified zinc oxide are added into the nylon matrix, so that the composite material is endowed with good ultraviolet resistance, comprehensive mechanical properties and durability.

The invention belongs to the technical field of high polymer materials, and particularly relates to a PET decorative film and a preparation method thereof. The preparation method comprises the following steps: synthesizing hydroxyl-terminated hyperbranched polyester by taking pentaerythritol and 2, 2-dimethylolpropionic acid as raw materials, and reacting with polyol glycidyl ether to prepare an epoxy-terminated organic modifier; silver-loaded nano silicon dioxide subjected to surface treatment by an amino silane coupling agent is used as inorganic functional particles; pET resin, an organic modifier and inorganic functional particles are subjected to melt blending and extrusion granulation, and modified PET is prepared; the modified PET is prepared into the film through a two-way stretching process. Epoxy groups of the organic modifier chemically react with amino groups at the tail end of a PET molecular chain and on the surfaces of inorganic particles respectively, a stable organic-inorganic hybrid network is constructed, synergistic improvement of reinforcement, toughening and long-acting antibiosis is achieved, and the technical problems that functional particles are not uniform in dispersion, interface bonding is weak, and antibacterial components are prone to migration are effectively solved.

The low-VOC modified melamine formaldehyde resin is prepared from the following components in parts by weight: 80 to 100 parts of melamine formaldehyde resin, 5 to 10 parts of hydroxyl-terminated hyperbranched polyester, 8 to 15 parts of epoxy-terminated polybutadiene, 1 to 3 parts of fumed silica, 5 to 15 parts of polyvinyl butyral, 0.1 to 0.2 part of a coupling agent, 1 to 3 parts of a catalyst and 2 to 5 parts of a cross-linking agent, the preparation method comprises the following steps: in a stirring state, adding hydroxyl-terminated hyperbranched polyester, epoxy-terminated polybutadiene, a polyvinyl butyral resin solution and coupling agent modified fumed silica into a melamino-formaldehyde resin solution, heating to 50-70 DEG C, and adding a catalyst and a cross-linking agent; the melamine modified resin prepared by the components and the preparation method has the characteristics of low formaldehyde volatilization, high toughness and durability.

The invention discloses a wear-resistant coating and application thereof on a leather surface, and belongs to the technical field of leather finishing. The coating comprises a functionalized polyurethane-acrylate composite emulsion, a photoinitiator, an auxiliary agent and deionized water. Wherein the composite emulsion is prepared from hyperbranched polyester polyol, a dynamic bond chain extender and the like through prepolymerization, fluorine-containing grafting and in-situ sol-gel reaction, a hyperbranched skeleton provides mechanical support, double dynamic bonds endow a self-repairing function, in-situ nano-compounding enhances wear resistance, a diurea hydrogen bond enhances binding force, and a fluorine-containing side chain endows a coating with hydrophobic and stain-resistant performance; and preparing the coating by matching with a gradient curing process. The coating prepared by the invention has high wear resistance, efficient self-repairing property, firm adhesive force, excellent stain resistance and leather adaptation flexibility, and meets the actual requirements of middle and high-end leather finishing.

The invention relates to the technical field of polyvinyl chloride, in particular to an anti-aging polyvinyl chloride sheet and a preparation method thereof.The anti-aging polyvinyl chloride sheet is characterized in that one of an organic tin stabilizer and a liquid calcium-zinc stabilizer is introduced into a polyvinyl chloride base material to serve as a stabilizer, the processability of the polyvinyl chloride base material is improved by selecting an ACR auxiliary agent, and ethylene bis stearamide serves as an anti-sticking agent; one or more of oxidized polyethlene wax, polyol ester and stearate are used as a lubricant; 2-carboxyethyl phenyl phosphinic acid and 1, 1, 1-trimethylolpropane are used as raw materials to synthesize hyperbranched polyester, then a hydroxyl-containing s-triazine ultraviolet absorbent is grafted, and the modified hyperbranched polyester plasticizer is obtained and used for plastifying sheets. The preparation method comprises the following steps: selecting hydrotalcite-like compound as a filler, selecting carboxylated silsesquioxane as a modifier through a stripping recombination method to obtain carboxylated hydrotalcite-like compound, and then grafting a hydroxyl-containing s-triazine ultraviolet absorbent, thereby greatly enhancing the flame retardance, fire resistance and weather resistance of the sheet and enhancing the use safety of the sheet.

The invention discloses a wood-plastic composite material for a laboratory fume hood and a preparation method thereof, and relates to the technical field of composite materials, and the wood-plastic composite material is prepared from the following raw materials in parts by weight: 30-40 parts of plant fiber powder, 40-50 parts of functional polycondensate, 20-30 parts of PBT resin, 10-20 parts of aromatic hyperbranched polyester, 1-2 parts of a coupling agent, 0.3-0.8 part of an antioxidant, 0.8-1.5 parts of a lubricant, and 1-2 parts of 2, 2, 4-trimethyl-1, 3-pentanediol monoisobutyrate. 1-2 parts of 2, 7-anthraquinone disulfonic acid and 1-3 parts of a catalyst A; the functional polycondensate comprises structural units introduced by the following monomers: 4, 6-hydroxy-2-cyanobenzothiazole, 2, 2-bis [4-(4-aminophenoxy) phenyl]-1, 1, 1, 3, 3, 3-hexafluoropropane and dimethyl biphenyl diisocyanate. The composite material is high in mechanical strength, sufficient in toughness and excellent in flame retardance and aging resistance.

The invention belongs to the technical field of melt-blown non-woven fabrics, and relates to a preparation method of a hydrophilic polyester melt-blown non-woven fabric, which comprises the following steps: raw material drying, melt spinning, hot air traction, and roller receiving molding. The raw materials contain 8-10wt% of coated modified inorganic nano functional powder, and the base material of the raw materials is polyester; the coating modified inorganic nano functional powder comprises coupling agent modified inorganic nano powder and hydrophilic hyperbranched polyester coating the surface of the coupling agent modified inorganic nano powder, the coupling agent modified inorganic nano powder contains amino or epoxy groups, and the hydrophilic hyperbranched polyester contains sulfonic acid groups; and the D50 particle size of the coated modified inorganic nano functional powder is 80-150 nm. The coating modified inorganic nano functional powder is coated with the hydrophilic hyperbranched polyester, so that the melt index of the polyester base material is increased, the flowability of the polyester base material is improved, and the hydrophilicity and moisture conductivity of the polyester melt-blown non-woven fabric are enhanced.

The invention belongs to the technical field of coatings, and particularly relates to a high-flash-point phenolic anticorrosive coating as well as a preparation method and application thereof. The high-flash-point phenolic anticorrosive paint is prepared from the following raw materials in parts by mass: 40 to 70 parts of xylene phenolic resin, 30 to 60 parts of hyperbranched polyester modified phenolic resin, 10 to 15 parts of silicone acrylic emulsion, 5 to 10 parts of modified glass fiber, 5 to 10 parts of pigment, 3 to 8 parts of solvent, 3 to 8 parts of light stabilizer-beta-cyclodextrin inclusion compound and 1 to 3 parts of drier. A coating layer obtained by the phenolic anticorrosive paint provided by the invention has good adhesive force, flexibility, long-term salt fog resistance, weather resistance and heat and humidity resistance.

The invention discloses a photoaging-resistant thermoplastic polyolefin waterproof coiled material which comprises the following raw materials: basic resin, the material proportion of the basic resin is about 65-75%, and the basic resin comprises high-crystallinity polypropylene, metallocene polyethylene and a cyclic olefin copolymer; the material proportion of the composite stabilizing material and the composite stabilizing agent is about 4-6%, and the composite stabilizing agent comprises a nano cerium oxide coated ultraviolet light absorber, a high molecular weight hindered amine light stabilizer, a novel benzotriazole / triazine hybrid stabilizing agent and a composite antioxidant; the material proportion of the functional filler is about 18-22%, and the functional filler comprises silane coupling agent modified nano kaolin, titanate treated calcium carbonate and graphene modified glass beads; and the material proportion of the special auxiliary agent is about 3-5%, and the special auxiliary agent comprises a hyperbranched polyester plasticizer, a phosphorus-nitrogen intumescent flame retardant and a fluorine surfactant. Compared with the prior art, the invention has the advantages of strong weatherability, high tensile strength and fracture resistance.

The invention discloses a preparation method of an anti-corrosion film layer on the surface of an electrical material aluminum alloy. The preparation method sequentially comprises the following steps of degreasing, alkali corrosion, neutralization decontamination, anodic oxidation, hole sealing, water washing and drying. An anodic oxidation solution used in the anodic oxidation step is a mixed compound solution and comprises hyperbranched polyester, sodium tannate and sulfuric acid, the concentration of the hyperbranched polyester is 2-2.8 g / L, the concentration of the sodium tannate is 0.021-0.029 mol / L, the concentration of the sulfuric acid is 0.05-0.07 mol / L, the sodium tannate and the hyperbranched polyester are added into the anodic oxidation solution, and the sodium tannate and the hyperbranched polyester are added into the anodic oxidation solution. And through the synergistic effect of the two components, the deposition mode and compactness of an anodic oxide film are improved, so that an anti-corrosion film layer formed on the surface of the electrical material aluminum alloy has excellent corrosion resistance and adhesive force.

The invention discloses a multi-layer composite polypropylene color master batch and a preparation method thereof.The multi-layer composite polypropylene color master batch comprises an inner layer, a middle layer and an outer layer, the inner layer is coated with the middle layer, the middle layer is coated with the outer layer, matrix resin, a composite toughening agent and an interface modifier are subjected to melt blending in a double-screw extruder, nano reinforcing filler is added, extrusion granulation is performed, and the multi-layer composite polypropylene color master batch is obtained. Carrier resin, hyperbranched polyesteramide and a toner pre-dispersion body are mixed at a high speed and then uniformly coated on the outer surface of the inner layer through fluidized bed equipment, and a mixture of a weather-proof additive and a lubricant is attached to the outer surface of the middle layer by adopting an electrostatic spraying process to form the outer layer. According to the multi-layer composite color master batch, the matrix resin and the composite toughening agent have a synergistic effect, so that the impact strength of the color master batch is improved, the cavity structure of hyperbranched polyesteramide is coated with the toner, the silane is used for treating the nano filler to reduce agglomeration and chromatic aberration, the outer layer delays aging, the lubricant reduces the extrusion torque, and the multi-layer composite color master batch is adaptive to a high-speed pipe production line.

The invention discloses a preparation method and application of a degradable flocculating agent for sludge, and belongs to the technical field of sludge treatment.The preparation method of the flocculating agent comprises the following steps that acrylamide, chlorin grafted itaconic acid hyperbranched polyester, a polyaspartic acid derivative and a cationic monomer are added into a solvent, an initiator is added in the nitrogen atmosphere, stirring is carried out, and the flocculating agent is obtained. And after the reaction is finished, cooling to room temperature, precipitating the reaction product by using absolute ethyl alcohol, filtering the precipitated product, washing by using absolute ethyl alcohol, and drying to obtain the degradable flocculating agent for sludge. The chlorin grafted itaconic acid hyperbranched polyester and the polyaspartic acid derivative are introduced to optimize the flocculation performance of traditional cationic polyacrylamide, sludge can be deeply dewatered, the turbidity and COD content of dewatered filtrate are low, and good biodegradability is achieved.

The invention relates to a water-repellent polyester fiber and a preparation method thereof. The preparation method comprises the following steps: firstly, carrying out dehydration reaction on hydroxyl-terminated hyperbranched polyester and asymmetric alcoholic hydroxyl single-terminated polydimethylsiloxane to obtain siloxane-terminated hyperbranched polyester; then, polyethylene glycol terephthalate I, siloxane-terminated hyperbranched polyester and dimethyl vinyl siloxy polyhedral oligomeric silsesquioxane are subjected to melt blending to prepare a water-repellent polyester functional master batch, polyethylene glycol terephthalate II and the water-repellent polyester functional master batch are blended, and melt spinning is performed; and finally, coating the surface of the fiber obtained by melt spinning with tri-tert-butoxyvinyl silane, and inducing a grafting reaction through ultraviolet radiation to prepare the water-repellent polyester fiber. The number-average molecular weight of the polyethylene glycol terephthalate I and the polyethylene glycol terephthalate II is in the range of 20000-30000 g / mol; and the contact angle of the water-repellent polyester fiber is greater than 145 degrees. The method is simple; and the prepared product has good mechanical properties and water repellency.

The invention relates to high-strength corrosion-resistant PA66 and a preparation method and application thereof, and belongs to the technical field of high polymer materials, the high-strength corrosion-resistant PA66 comprises the following raw materials: 55-65 parts of a PA66 base material, 20-25 parts of multifunctional modified glass fibers, 0.5-1.5 parts of an antioxidant, 1-2 parts of a lubricant, 0.1-0.5 part of a coupling agent and 2-4 parts of a flexibilizer; according to the technical scheme, the silane modified glass fiber is obtained by combining the nano material with the glass fiber and then grafting the silane coupling agent; combining the silane modified glass fiber, diamine and fluorinated dianhydride to obtain an anhydride-terminated compound; combining the anhydride-terminated compound with amphiphilic hyperbranched polyester to obtain the multifunctional modified glass fiber; mixing the PA66 base material, the multifunctional modified glass fiber, an antioxidant, a lubricant, a coupling agent and a flexibilizer, and performing extrusion granulation to obtain the high-strength corrosion-resistant PA66. The corrosion resistance, the thermal stability and the mechanical property of the PA66 are integrally improved.

The invention relates to the technical field of modified polypropylene composite materials, in particular to a polypropylene composite material for thin-wall injection molding and a preparation method thereof.The polypropylene composite material is prepared from 70-85 parts of polypropylene, 1-15 parts of toughened branched resin, 3-5 parts of maleic acid copolymer, 5-10 parts of inorganic filler, 0.1-0.5 part of antioxidant and 0.1-0.5 part of light stabilizer; the toughened branched resin comprises carboxyl-terminated hyperbranched polyester and methoxyl polyethylene glycol, and the mass ratio of the carboxyl-terminated hyperbranched polyester to the methoxyl polyethylene glycol is 1: (2-4). According to the invention, impact energy is dispersed by toughening a branched structure in the branched resin, the energy absorption capacity is enhanced by an mPEG flexible chain, the impact toughness of the polypropylene composite material is remarkably improved through the synergistic effect of the two, and meanwhile, the tensile strength is maintained. The inorganic filler is matched to enhance the rigidity of the polypropylene composite material, so that the balance of toughness and rigidity is realized.

The invention belongs to the technical field of high polymer material preparation, and provides a low-melting-point toughened copolyester chip and a preparation method thereof. The preparation method comprises the following steps: firstly, preparing hyperbranched polyester of which the surface is rich in carboxyl-terminated functional groups through core growth of polybasic acid alcohol and end group functionalization reaction of anhydride; the other chain extender is a linear chain extender which has a long flexible chain segment and two tail ends of which are also functionalized by carboxyl groups, and is obtained by carrying out end group esterification reaction on polyether glycol; then, in the synthesis process of the main polyester, carrying out multi-stage melt polycondensation on an aromatic dibasic acid component and a polyol component under the action of a composite catalyst system, introducing the hyperbranched polyester and a chain extender into a reaction system in the form of slurry, and covalently bonding a functional additive to a copolyester main chain through a polycondensation process, so as to obtain the hyperbranched polyester. An integrated network reinforced structure is formed, so that the copolyester chip has the characteristics of low melting point and excellent toughness.