878 results about "Phosphazene" patented technology

The invention discloses an environment-friendly organic silicon intumescent fireproof coating for a transformer substation or a converter station as well as a preparation method and application of the environment-friendly organic silicon intumescent fireproof coating. The coating comprises the following raw materials in parts by mass: 30-60 parts of organic silicon resin, 30-45 parts of an intumescent flame retardant, 5-10 parts of modified glass powder, 2-20 parts of an inorganic filler, 2-10 parts of an auxiliary agent and 5-25 parts of a curing agent. The intumescent flame retardant takes a phosphazene compound as a gas source and an acid source; the phosphazene compound is prepared by carrying out nucleophilic substitution reaction on phosphonitrilic chloride trimer and melamine or dicyandiamide; the modified glass powder is prepared by mixing a plurality of glass powder with the melting point of 350-700 DEG C and then modifying by adopting a silane coupling agent. According to the invention, the high-temperature resistance of the organic silicon resin coating is improved through formula design, so that the service life of the steel in a high-temperature scene is prolonged, the performance reliability of fire-fighting equipment of a transformer substation or a converter station is improved, and the purpose of high-temperature resistance is achieved.

The invention relates to the technical field of fibers, and discloses an ultrahigh-moisture-absorption anti-static polyester fiber and a preparation method thereof. The preparation method comprises the following steps: carrying out nucleophilic substitution reaction on 1, 2-benzisothiazolin-3-one and methacryloyl chloride to obtain modified benzisothiazolinone; the preparation method comprises the following steps: carrying out nucleophilic substitution reaction on phosphonitrilic chloride trimer and allylamine, and then carrying out nucleophilic substitution reaction on the phosphonitrilic chloride trimer and melamine again to obtain modified cyclophosphazene; the preparation method comprises the following steps: mixing gamma-methacryloxypropyltrimethoxysilane with aluminum zinc oxide for reaction, and mixing the obtained modified aluminum zinc oxide with modified benzisothiazolinone and modified cyclophosphazene for copolymerization in the presence of an initiator to obtain a flame-retardant antibacterial additive; mixing the flame-retardant antibacterial additive, calcium carbonate and polyethylene glycol terephthalate, performing melt spinning, and performing acid treatment to obtain modified polyester fibers; dipping the modified polyester fiber in a finishing liquid containing modified chitosan to obtain the ultrahigh-moisture-absorption anti-static polyester fiber.

The invention provides a low-smoke halogen-free flame-retardant cable material and a preparation method thereof, and belongs to the field of cable materials. The low-smoke halogen-free flame-retardant cable material is prepared from the following chemical components: 32 to 40 parts of nitrile rubber, 22 to 27 parts of natural rubber, 8 to 12 parts of benzoxazole-siloxane copolymer containing phosphate dynamic bonds, 13 to 15 parts of core-shell-sheath three-stage structure flame retardant, 4 to 6 parts of hexaphenoxy cyclotriphosphazene modified carbon nanotubes, 2 to 3 parts of europium-doped mesoporous cerium dioxide and 3 to 4 parts of nano zinc oxide. The composite material is prepared from the following components in parts by weight: 3 to 4 parts of carbon nanotube grafted montmorillonite hybrid, 2 to 3 parts of lubricant, 0.8 to 1.2 parts of cross-linking agent, 0.3 to 0.4 part of accelerant, 0.4 to 0.6 part of dicumyl peroxide and 0.1 to 0.2 part of antioxidant. Unification of high flame retardance, low smoke, excellent mechanical property and processability of the cable material is realized.

The phosphazene covalent organic framework (COF) is a material with high efficiency to improve the removal of iodine from nuclear waste. The COF can be obtained by a solvothermal reaction of hexa(4-formyl-phenoxy)cyclotriphosphazene and 1,3,6,8-tetra(aminophenyl)pyrene. The resulting three-dimensional phosphazene COF has iodine uptakes as high as 9.4 g g−1 due to its 3D framework with higher specific surface areas and interconnected channels.

The invention belongs to the technical field of lithium ion batteries, and provides an electrolyte additive composition, an electrolyte containing the electrolyte additive composition, and a preparation method and application of the electrolyte additive composition. The electrolyte additive composition comprises an aluminum alkoxide compound and a phosphazene compound, the structure of the phosphazene compound is shown as a formula I, and R1-R6 are independently selected from fluorine, alkoxy or phenoxy. The electrolyte containing the additive composition has good thermal stability and flame retardance under high voltage, and the safety of the battery is greatly improved; in addition, the electrolyte additive composition can inhibit hydrolysis of LiPF6, so that generation of HF and side effects caused by HF are reduced. # imgabs0 #

A full-bio-based flame-retardant material and a preparation method therefor. The composition of the full-bio-based flame-retardant material comprises a hexaldehyde bio-based phosphazene monomer, and a castor oil polyamine and / or a furyl diamine, wherein the molar ratio of the total amino groups in the castor oil polyamine and furyl diamine to the aldehyde groups in the hexaldehyde bio-based phosphazene monomer is 1 : (0.8-1.2). The full-bio-based flame-retardant material is a full-bio-based material, and the mechanical and the flame-retardant properties thereof can be adjusted and controlled by adjusting the content of the castor oil polyamine and furyl diamine to adapt to the different requirements of different products for the flame-retardant material. Moreover, the full-bio-based flame-retardant material further has self-repairing, reprocessing and degradability properties.

The invention relates to an anti-yellowing automobile composite film and a preparation method thereof, and belongs to the technical field of high polymer materials. The yellow-resistant automobile composite film is prepared from the following components in parts by weight: 60 to 70 parts of PVC (Polyvinyl Chloride) master batch, 10 to 20 parts of TPU (Thermoplastic Polyurethane) master batch, 1 to 2 parts of plasticizer, 0.5 to 0.8 part of flatting agent, 0.1 to 2 parts of yellowing-resistant modifier and 0.1 to 2 parts of modified flame retardant, sym-triazine cyanuric chloride and a benzotriazole intermediate in the anti-yellowing modifier absorb ultraviolet rays and reduce yellowing of the ultraviolet rays on the composite material, and maleimide groups, maleic anhydride and isocyanurate rings for increasing the crosslinking density cooperate with one another, so that the heat resistance of the material is improved, and the yellowing is reduced; phosphorus and nitrogen main chains of phosphonitrilic chloride trimer in the modified flame retardant have a conjugation effect, so that a protective film is formed, oxygen is isolated, and the phosphonitrilic chloride trimer and nitrogen are synergistically flame-retardant; the anti-yellowing automobile composite film prepared by the invention not only has excellent ultraviolet absorption performance, heat resistance and anti-yellowing effects, but also has a good flame retardant effect.

The invention relates to the technical field of electric wire materials, in particular to a preparation process of a high-strength halogen-free flame-retardant electric wire. According to the preparation method, the polyolefin flame-retardant microspheres are obtained by adding propenylated cyclotriphosphazene, propenylated phosphaphenanthrene, methyl methacrylate, lauroyl peroxide, polyvinyl alcohol and deionized water. The flame-retardant modified boron nitride nanosheet is prepared by the following steps: firstly, preparing a flame-retardant modified boron nitride nanosheet, and then adding hydroxylated boron nitride, gamma-glycidyl ether oxypropyl trimethoxy silane and 9, 10-dihydro-9-oxa-10-phosphaphenanthrene-10-oxide, so as to obtain the flame-retardant modified boron nitride nanosheet. An ethylene-vinyl acetate copolymer, polyolefin flame-retardant microspheres, flame-retardant modified boron nitride nanosheets, an antioxidant and a lubricant are mixed and react, and the high-strength halogen-free flame-retardant protective sleeve is obtained. And wrapping the periphery of the copper core wire with the high-strength halogen-free flame-retardant protective sleeve to obtain a finished product. The finished product prepared by the invention has excellent flame retardant property and high strength, thereby having a wide application prospect in the technical field of electric wire materials.

The invention relates to the field of cables, and discloses a modified polyvinyl chloride composite material for cables and a preparation method thereof.The composite material comprises low-density polyethylene, polyvinyl chloride, ethylene-vinyl acetate copolymer, nitrile rubber, modified graphene oxide, modified nano calcium carbonate and auxiliaries; the modified graphene oxide is prepared by reacting acylating chlorination of graphene oxide with an anti-aging derivative, the anti-aging derivative is prepared by reducing a benzoxazole-containing intermediate generated by a reaction of 2-amino-4-bromophenol and 4-cyanobenzaldehyde to obtain an aminated benzoxazole-containing intermediate, then the aminated benzoxazole-containing intermediate reacts with p-phenylenediamine, and then the product reacts with 3-(3, 4-dichlorophenyl)-1, 2, 3-triazole-3-one to obtain the anti-aging graphene oxide. 2, 5-di-tert-butyl-4-hydroxyphenyl) propionyl chloride is subjected to a reaction to prepare the product. And the modified nano calcium carbonate is prepared by reacting phosphonitrilic chloride trimer with an amino silane coupling agent and 2-amino benzoxazole-5-borate and then grafting on the surface of the nano calcium carbonate. The composite material prepared by the invention has excellent flame retardance, heat resistance and long-acting oxidation resistance.

The invention discloses a high-performance fluororubber sealing material and a preparation method thereof, and relates to the technical field of fluororubber. The high-performance fluororubber sealing material comprises the following components in parts by weight: 100 parts of raw fluororubber, 20-35 parts of modified fluororubber, 4-8 parts of maleic anhydride grafted ethylene propylene diene monomer, 20-35 parts of a reinforcing agent, 2.5-3.5 parts of a vulcanizing agent and 4-8 parts of an auxiliary agent. Wherein the modified fluororubber is prepared by reacting amino-containing perfluoropolyether, amino-terminated cyclotriphosphazene and epoxy-terminated liquid fluororubber; the reinforcing agent is obtained by uniformly mixing polydopamine coated silicon dioxide and carbon black and then modifying the mixture with (3, 3, 3-trifluoropropyl) methyldimethoxysilane. By combining the modified fluororubber, the maleic anhydride grafted ethylene propylene diene monomer and the reinforcing agent, the processability, the mechanical property, the high temperature resistance and other properties of the fluororubber are effectively enhanced synergistically.

The invention relates to a perfluoro wide-temperature electrolyte for a lithium battery and application thereof, the wide-temperature electrolyte comprises a lithium salt, an additive and a plurality of perfluoro mixed solvents, the electrolyte capable of stably working in a wide temperature range (-80-80 DEG C) is successfully constructed, and the excellent electrochemical performance of the lithium battery at the wide temperature is realized. The electrolyte additive disclosed by the invention mainly comprises one or more of hexafluoroisopropoxy cyclotriphosphazene, 3-(2, 2, 2-trifluoroethoxy) propionitrile, 3-(2, 2, 2-trifluoroethoxy) butyronitrile, 3, 4-fluoroethylene sulfate and 4-trifluoromethyl-ethylene sulfate, and the fluorine-containing additive is good in flame retardant effect, moderate in viscosity, good in system compatibility, good in corrosion resistance and good in corrosion resistance. And a protective film can be formed on the surface of the positive electrode of the lithium battery, so that the high-pressure and high-temperature cycle performance of the battery is improved, the electrochemical performance of the battery is not influenced at all, the self-extinguishing time of the electrolyte is obviously shortened, the flame retardant property and the conductivity are excellent, the overcharge resistance of the lithium ion battery is also obviously improved, and the safety performance of the battery is improved.

The invention relates to the field of PVC cable materials, and particularly discloses a high-temperature-resistant flame-retardant PVC cable material and a preparation method thereof. The high-temperature-resistant flame-retardant PVC cable material comprises the following components in parts by mass: 90-120 parts of PVC resin, 30-60 parts of polyphenylene sulfide, 20-40 parts of a composite flame retardant, 5-15 parts of a flexibilizer, 1-5 parts of an antioxidant, 1-3 parts of an ultraviolet light absorber, 1-10 parts of a lubricant and 1-10 parts of a compatilizer. The composite flame retardant is obtained by surface modification of phosphonitrilic chloride trimer intercalated montmorillonite. The high-temperature-resistant flame-retardant PVC cable material has the advantages of excellent flame retardance, good high-temperature resistance and high toughness and mechanical strength.

The invention relates to the technical field of fibers, and discloses a high-elasticity polyurethane flame-retardant fiber, a preparation method and application of the high-elasticity polyurethane flame-retardant fiber to a telescopic electric wire. The preparation method comprises the following steps: by using 1, 1, 3, 3-tetramethyldisiloxane as a bridging agent through hydrosilylation reaction, connecting allyl modified DOPO with allyl phenoxy cyclotriphosphazene to prepare a flame retardant with three flame-retardant elements of phosphorus, nitrogen and silicon at the same time; the preparation method comprises the following steps: preparing a polyurethane urea solution by a method of adding 4, 4-diphenylmethane diisocyanate in batches, introducing a flame retardant, mixing the polyurethane urea solution with an antioxidant, a dyeing assistant and a delustering agent, and carrying out dry spinning to obtain the high-elasticity polyurethane flame-retardant fiber. The polyurethane fiber has excellent flame retardant property and heat resistance, and good mechanical property and resilience, and can be applied to telescopic electric wires.

The invention relates to the technical field of refractory materials, in particular to a waste magnesia-calcium brick-containing refractory material and a preparation method thereof, and the waste magnesia-calcium brick-containing refractory material comprises the following components: composite aggregate, calcium aluminate cement, urea resin-aluminum dihydrogen phosphate, active alpha-Al2O3 micro powder, silica micro powder and sodium tripolyphosphate. In the room-temperature spraying maintenance and low-temperature working stage, hydration of free CaO in the waste magnesia-calcium bricks and erosion of OH <-> are prevented through the hydrophobic effect of fluorinated polyphosphazene and modified zirconium oxide sol, and the compatibility and wettability of the composite aggregate and cement paste are improved through carboxylic acid groups of carboxyethyl silanetriol and polyethylene glycol monomethyl ether. According to the present invention, with the temperature rising, the aluminum dihydrogen phosphate forms the viscous liquid phase to wrap the aggregate so as to provide the temporary protection, the temperature continues to rise, the zirconium oxide and the nanometer Al2O3 react with the CaO and the MgO to generate the CaZrO3 and the MgAl2O3, the aluminum dihydrogen phosphate reacts with the nanometer Al2O3 in the system to generate the AlPO4, and the CaZrO3, the MgAl2O3 and the AlPO4 form the multi-phase fire-resistant structure so as to further improve the fire resistance of the fire-resistant material;

The invention discloses flame-retardant recyclable compressible biodegradable cellulose aerogel and a preparation method and application thereof.The preparation method comprises the following steps that 1, phosphorus / nitrogen-containing bridged organosiloxane and tetraethyl orthosilicate are added into bacterial cellulose dispersion liquid and stirred to be uniform, and a milk white dispersion solution is prepared; (2) heating, curing, pre-freezing and freeze-drying the milky white dispersion solution to obtain the flame-retardant recyclable compressible biodegradable cellulose aerogel, and the phosphorus / nitrogen-containing bridged organosiloxane is prepared by carrying out a reaction on phosphonitrilic chloride trimer and 3-aminopropyltriethoxysilane. The prepared cellulose aerogel is excellent in flame retardance, heat insulation and cyclic compression performance, and has a feasible application prospect in the aspect of radiation refrigeration.

The invention relates to the technical field of electric power facilities, in particular to a high-strength flame-retardant fireproof cable and a preparation method thereof. The phosphonitrile flame retardant is prepared by adding phosphonitrilic chloride trimer, phenylphosphonic acid, triethylamine and melamine. Then, 9, 10-dihydro-9-oxa-10-phosphaphenanthrene-10-oxide, the modified carbon nanotubes and the flame-retardant modified halloysite nanotubes are used as main raw materials, and the flame-retardant filler is prepared. The preparation method comprises the following steps: mixing polyolefin, a phosphazene flame retardant, a flame-retardant filler, talcum powder, gum and stearic acid, fully stirring and melting to obtain a sizing material, and carrying out crosslinking, granulation and molding on the sizing material to obtain the cable protection sleeve. And wrapping the outermost layer of the cable with the cable protection sleeve to obtain a finished cable. The finished cable prepared by the invention has good flame retardance and mechanical strength, so that the cable has a wide application prospect in the technical field of electric power facilities.

The invention relates to the technical field of epoxy splicing adhesives, in particular to a high-performance prefabricated part epoxy splicing adhesive and a preparation method thereof.The epoxy splicing adhesive comprises a component A and a component B. The component A is prepared from 3%-8% of polyether polyol, 2%-4% of hydrophobic fumed silica, 0.1%-1% of a silane coupling agent, 0.01%-0.5% of a defoaming agent, 50%-75% of modified quartz sand, 1%-5% of color paste and the balance epoxy resin; the modified quartz sand is prepared by grafting an amino silane coupling agent on the surface of quartz sand, then reacting with polychlorophosphazene, and then reacting with glycidol; the component B comprises the following components in percentage by weight: 0.2-4% of color paste, 1-5% of hydrophobic fumed silica, 0.1-1% of an amino silane coupling agent, 10-25% of 0.5 mm quartz sand, 40-60% of 0.1 mm quartz sand and the balance of a modified amine curing agent; the preparation method has the advantage that the mechanical strength and the bonding strength of the epoxy splicing adhesive are improved.

The invention relates to a low-gloss fluoride-free flame-retardant PC / ABS (polycarbonate / acrylonitrile-butadiene-styrene) resin composition as well as a preparation method and application thereof. The resin composition is prepared from the following components in parts by weight: 70 to 90 parts of PC (Polycarbonate) resin, 5 to 10 parts of ABS (Acrylonitrile Butadiene Styrene) resin, 8 to 12 parts of phosphazene flame retardant, 2 to 5 parts of flexibilizer, 3 to 6 parts of crosslinking master batch, 1 to 3 parts of UHMWPE (Ultra High Molecular Weight Polyethylene) and 0.5 to 1.5 parts of auxiliary agent. The preparation method comprises the following steps: stirring and fully mixing the raw materials in a high-speed mixer, and carrying out material melting, mixing, homogenizing, bracing, cooling and pelletizing under the conveying, shearing and mixing of screws by a twin-screw extruder to obtain the low-gloss fluoride-free flame-retardant PC / ABS resin composition. The resin composition not only has excellent flame retardant property, but also has excellent mechanical properties and ultralow glossiness, can meet the environmental protection requirements of PFAS prohibited instructions, and is suitable for being applied to the fields of electric tools, rear shells of televisions, OA (office equipment), new energy batteries, electronics and electrical appliances, household appliances and the like.

The invention discloses a lithium carbon fluoride battery electrolyte and a lithium carbon fluoride battery. In order to improve the long-time shelving safety performance and power discharge performance of a lithium carbon fluoride battery in a high-temperature environment and further improve the application prospect of the lithium carbon fluoride battery, the technical scheme adopted by the invention is as follows: the lithium carbon fluoride battery electrolyte is provided and comprises an organic solvent, electrolyte salt and an additive, wherein the electrolyte is a mixture of any one of lithium tetrafluoroborate, lithium bis (trifluoromethylsulfonyl) imide, lithium bis (fluorosulfonyl) imide and lithium trifluoromethanesulfonate and lithium difluorophosphate, and the additive comprises a silane additive, an anhydride additive and a phosphazene additive in a mass ratio of (1-5): (0.5-1): (3-10). According to the electrolyte system disclosed by the invention, the high-low temperature discharge capacity and the large-current pulse discharge capacity of the lithium carbon fluoride battery are obviously improved, and meanwhile, the high-temperature shelving safety performance is also obviously improved.

The invention discloses a preparation method of low-volatile-matter side hydrogen-containing silicone oil, and belongs to the technical field of silicone oil production. The preparation method of the hydrogen-containing silicone oil comprises the following steps: (1) adding a hydroxyl-terminated polydimethylsiloxane oligomer (linear body) and a phosphonitrile chloride composite catalyst into a reaction kettle, stirring, vacuumizing, and heating for reaction; (2) detecting the viscosity on line, when the viscosity reaches the specified viscosity, recovering the normal pressure, adding the high-hydrogen silicone oil, hexamethyldisiloxane and phosphonitrile chloride composite catalyst, and reacting at low temperature; and (3) adding a terminator to finish the reaction, and filtering to obtain the hydrogen-containing silicone oil. The hydrogen-containing silicone oil is prepared by adopting the linear body, the high-hydrogen-content silicone oil and the high-catalytic-activity phosphonitrile chloride as raw materials, no obvious cyclosiloxane is generated in the reaction process, the content of low-boiling-point substances is extremely low, the cost of the raw materials is reduced, the problem that a large amount of solid waste is generated in a neutralization reaction in a traditional acid equilibrium catalysis process is solved, and environmental pollution is reduced.

The invention relates to a flame-retardant sodium ion electrolyte as well as a preparation method and application thereof, and belongs to the technical field of electrolytes. The flame-retardant sodium ion electrolyte comprises the following components in percentage by mass: 13-15% of sodium salt, 3-10% of a first additive, 1-3% of a second additive and the balance of an organic solvent, and the first additive is pentafluorobenzene dimethyl silicon diethylamine. According to the flame-retardant sodium-ion electrolyte provided by the invention, the specific first additive is selected, and the effect of the flame-retardant sodium-ion electrolyte is comprehensively superior to that of traditional phosphazene and phosphite flame-retardant additives when the flame-retardant sodium-ion electrolyte is used in a sodium-ion battery; according to the present invention, the lithium ion battery electrolyte has the flame retardation effect, the NaF component-rich SEI film can be formed on the negative electrode side so as to easily provide the electrochemical performance, and the Si-N bond in the structure can remove hydrogen fluoride (HF) and phosphorus pentafluoride (PF5), such that the impurities in the electrolyte can be removed, the cycle performance and the stability of the battery can be improved, and the high application value can be provided.

The invention relates to the technical field of high polymer materials, and particularly discloses a nuclear-grade cable for spent fuel aftertreatment and a preparation method of the nuclear-grade cable. Comprising the following steps: S1, taking hydroxyl-containing cyclotriphosphazene, tetra (4-hydroxybenzene) ethylene, oleic acid acyl chloride, guar gum hydroxypropyl trimethyl ammonium chloride, triethylamine and a mixed solvent, cooling, dropwise adding triethylamine in a nitrogen atmosphere, dropwise adding a phenoxyphosphoryl dichloride solution, stirring for reaction, filtering, and performing rotary evaporation to obtain a composite flame retardant; s2, polyethylene, aluminum hydroxide, a composite flame retardant and an anti-radiation agent are added into an internal mixer for mixing, a cross-linking agent is added, uniform mixing, extrusion and granulation are performed, and a cable material is obtained; the cable material is used for preparing an outer sheath layer of a nuclear-grade cable. S3, twisting a plurality of copper metal monofilaments to form a conductor, wrapping the conductor with an insulating layer, and wrapping the conductor with a polyimide film to form a wire core; a plurality of wire cores are twisted to form a cable core; a non-woven fabric wrapping tape layer and an outer sheath layer are wrapped outside the cable core; and obtaining the nuclear-grade cable.

The invention discloses an indoor flame-retardant insulated flexible wire and a preparation method thereof, belongs to the technical field of flexible wires, and is used for solving the technical problem that the insulating property and flame-retardant property of an indoor flexible wire in the prior art need to be further improved. The cable comprises a wire layer formed by twisting a plurality of copper wires, an insulating layer and an outer sheath layer, a modified aminating agent taking a siloxane chain segment as a main body is prepared, polyvinyl chloride is aminated and hybridized with a space chain segment of the polyvinyl chloride at the same time, after phosphorus-hydrogen addition and surface modification, the hybridized polyvinyl chloride is obtained, and through sodium hypophosphite and 1, 2, 4-trimethyl-1, 3-pentanediol, the flame retardant is added to the polyvinyl chloride, so that the cable is formed. The preparation method comprises the following steps: carrying out phosphorus-hydrogen addition on 2, 3-dihydroxystyrene to obtain a modified cross-linking agent, forming a spherical structure by the modified cross-linking agent and phosphonitrilic chloride trimer under triethylamine and ultrasonic conditions, carrying out surface modification to obtain flame-retardant microspheres, and carrying out melt extrusion on the modified cross-linking agent and phosphonitrilic chloride trimer as main materials and auxiliary materials of an outer sheath layer to finally prepare the flame-retardant insulated flexible wire.

The present application relates to the field of polymer composite materials, and more specifically, it relates to a fluorine-free flame retardant PC material and a preparation method thereof, which is composed of the following raw materials in weight percentage: 10-15% silicon PC, 0.1-1% anti-aging agent, 2-6% fluorine-free flame retardant, and the balance is PC; the fluorine-free flame retardant is composed of at least three of polydiphenyloxyphosphazene, tetraphenyl bisphenol A diphosphate, polydimethylsiloxane, and methacrylate-based phenyl polymer complex. When polydiphenyloxyphosphazene, tetraphenyl bisphenol A diphosphate, polydimethylsiloxane, and methacrylate-based phenyl polymer complex are compounded, a synergistic effect is achieved, and the silicon PC is combined to make the prepared PC material have better flame retardant properties, light transmittance, anti-aging properties, and physical properties.

The invention discloses organosilicone cyclophosphazene modified epoxy resin and a preparation method thereof, belongs to the field of flame-retardant materials, and particularly relates to a preparation method of an organosilicone cyclophosphazene flame retardant and a preparation method of the organosilicone cyclophosphazene modified epoxy resin. The invention aims to research and develop a synergistic composite flame retardant of three elements of N, P and Si by optimizing the structure of the flame retardant and solve the problem of low flame retardant efficiency of the flame retardant. The preparation method comprises the following steps: taking hexachlorotripolyphosphazene, p-hydroxybenzaldehyde, p-aminobenzoic acid, DOPO and triphenylsilanol as raw materials, and carrying out substitution, dehydration condensation, addition and esterification to obtain the organic silicon cyclophosphazene flame retardant. The modified epoxy resin is obtained by taking m-phenylenediamine as a curing agent and adding organosilicone cyclophosphazene flame retardants in different proportions. The organosilicone cyclophosphazene modified epoxy resin provided by the invention reaches the standard of a flame-retardant material, and the limit oxygen index is up to 31.6%, which passes a UL-94 test.

The invention relates to the technical field of plastic materials, in particular to a transparent flame-retardant polymethyl methacrylate composite material and a preparation method thereof. The transparent flame-retardant polymethyl methacrylate composite material is prepared from the following raw materials in parts by weight: 75 to 82 parts of polymethyl methacrylate, 15 to 20 parts of acrylate rubber grafted methyl ester acrylate, 15 to 18 parts of a flame retardant, 4 to 7 parts of a toughening agent, 1 to 1.5 parts of a coupling agent, 0.3 to 0.5 part of an antioxidant and 0.3 to 0.5 part of a lubricating agent, the flame retardant is prepared by mixing modified hexaphenoxy cyclotriphosphazene and modified hexa (4-aminophenoxy) cyclotriphosphazene. The transparent flame-retardant polymethyl methacrylate composite material prepared by the invention has multiple advantages, is suitable for the field of electronic and electric appliances requiring high flame retardance, good transparency and excellent mechanical properties, and has relatively high application value and market potential.

The invention relates to the field of fabrics, in particular to a breathable composite fabric and a preparation process thereof.The breathable composite fabric is characterized in that base cloth and a reinforcing layer are subjected to composite crocheting through polyester fibers to obtain a fabric body, and then the fabric body is transferred to protective finishing liquid to be subjected to padding treatment; bamboo charcoal fibers and cotton fibers are blended to serve as warps, the cotton fibers serve as wefts, and the warps and the wefts are interwoven to form base cloth; bamboo charcoal fibers are selected as warps, polyester fibers are selected as wefts, and the warps and the wefts are interwoven to form a reinforcing layer; the preparation method comprises the following steps: modifying chitosan with acrylic acid to obtain soluble N-carboxyethyl chitosan; the preparation method comprises the following steps: quantitatively modifying vanillin methacrylate by gelatin, modifying the gelatin by dopamine, and then grafting hexaborophosphazene; the preparation method comprises the following steps: by taking zinc acetate as a zinc source and cellulose nanocrystals as a template, carrying out in-situ polymerization-precipitation to obtain composite cellulose nanocrystals, carrying out dopamine polymerization to obtain polydopamine-coated composite cellulose nanocrystals, and then grafting hexaborophosphazene to obtain the modified cellulose nanocrystals.

The invention provides a method for preparing a nitrogen, phosphorus and sulfur tri-doped hollow carbon nanocage material derived from a covalent triazine polymer. The method comprises the following steps: by taking zinc nitrate hexahydrate and 2-methylimidazole as reactants and methanol as a solvent, stirring at room temperature to synthesize ZIF-8; the preparation method comprises the following steps: by taking phosphonitrilic chloride trimer and bisphenol S as monomers and ZIF-8 as a template agent, carrying out polymerization under the induction of an N, N-diisopropylethylamine initiator so as to generate ZIF-8 (at) PZS; and performing high-temperature pyrolysis to synthesize the nitrogen, phosphorus and sulfur triple-doped hollow carbon nanocage material. The invention also discusses the application of the nitrogen, phosphorus and sulfur tri-doped hollow carbon nanocage material in an air electrode material of a zinc-air battery. Meanwhile, the conductivity and the oxygen reduction reaction electro-catalytic performance of the obtained carbon material are remarkably improved through the nitrogen, phosphorus and sulfur doped synergistic effect, the half-wave potential of the carbon material reaches up to 0.85 V vs. RHE, and the limiting current density can reach 5.19 mA cm. A zinc-air battery assembled by using the material as an air electrode shows high peak power density of 194 mW cm.

The invention discloses a modified polypropylene HPPM square electric power corrugated pipe, belongs to the technical field of corrugated pipes, and aims to solve the problem that the polypropylene square electric power corrugated pipe cannot have toughness and excellent mechanical performance when being prepared in the prior art. The adopted nucleating agent has the technical problems of low nucleating efficiency and complex preparation process; the composite material comprises block co-polypropylene, a modified nucleating agent, alkaline glass fibers and related auxiliaries, maleimide, propylene and allyl cinnamate serve as monomers, the block co-polypropylene with high mechanical performance and high toughness is prepared, ethylene diamine and hexachlorocyclotriphosphazene are subjected to nucleophilic substitution, and the composite material is obtained. The preparation method comprises the following steps: preparing polydiamino-containing polyamine phosphazene by using a one-step method, reacting the polyamine phosphazene with phthalic anhydride to obtain a modified nucleating agent with a large number of amide carboxylic acid nucleation centers, and has the advantages of high nucleation efficiency and simplified preparation process.

The invention relates to an aliphatic copolyester elastomer and a preparation method thereof, and belongs to the field of high polymer materials. The elastomer is prepared through a series ring-opening copolymerization reaction of epoxide and cyclic anhydride, and the method comprises the following steps: under the action of a metal-free catalyst (a phosphazene ligand P1-tert-octyl / triethyl boron system) and an initiator (terephthalyl alcohol), carrying out a series ring-opening copolymerization reaction on epoxide and cyclic anhydride, the preparation method comprises the following steps: reacting epoxide (such as epoxypropane and allyl glycidyl ether) with aliphatic anhydride (such as glutaric anhydride) in a xylene solvent to generate a polyester prepolymer retaining an active end; adding a second group of epoxide (such as cyclohexene oxide) and anhydride (such as tetrahydrophthalic anhydride and norbornene dianhydride), continuously reacting to form a block copolymer, and then crosslinking. The material performance can be regulated by changing the monomer combination, the atom economy is high, and the raw materials can be produced on a large scale. The process is simple and environment-friendly, and a new choice is provided for application of the degradable elastomer in the fields of medical treatment, environmental protection and the like.