1304results about "Hybrid capacitor electrolytes" patented technology

The invention relates to the technical field of supercapacitors, and provides a cement-based supercapacitor, a preparation method and application. The cement-based supercapacitor comprises a cement-based electrolyte and two structural electrodes arranged on the two sides of the cement-based electrolyte. The cement-based electrolyte is prepared from cement, alkali, alkali metal salt, water and an additive, wherein the alkali metal salt comprises lithium salt; each structural electrode is composed of foamed nickel loaded with nitrogen-doped reduced graphene oxide. The lithium salt is added to construct an efficient ionic conductive network, so that the ionic conductivity of the cement-based electrolyte is enhanced, and the electrochemical performance is obviously improved. The reduced graphene oxide in the structural electrode is doped with nitrogen to enhance the electrostatic force between ions and the surface of the electrode, so that the electrochemical stability of the surface of the electrode is improved, and self-discharge is effectively inhibited. By improving an electrolyte and a structural electrode material, a cement-based supercapacitor with specific capacitance and mechanical properties is obtained and is combined with a building structure to realize building energy storage.

Disclosed herein are halide-based solid electrolytes with high ionic conductivity for all-solid-state sodium ion batteries. For example, disclosed herein are solid electrolytes comprising: ABCλ-2x-zDx+y, wherein: A is chosen from Li, Na, K, Mg, Ca, Zn, Al, In, Fe, and combinations thereof; B is chosen from Ca, Mg, Zn, In, V, Nb, Ta, Mn, Ti, Zr, Hf, Fe, Co, Ni, Al, Ga, and combinations thereof; C is chosen from F, Cl, Br, I, and combinations thereof; D is chosen from O, S, Se, Te, and combinations thereof; λ is an integer chosen from 4, 5, and 6, such that the solid electrolyte is charge neutral; 0 < x < 1; 0 < z < 2; and 0 < y < 1.

The invention discloses an electrolyte, an electrochemical device comprising the electrolyte and a vehicle. The electrolyte comprises a solvent, a first additive and a second additive, the solvent comprises chain carboxylic ester, and the first additive comprises a sulfonate compound or / and a sulfate compound; the second additive comprises vinylene carbonate or / and fluoroethylene carbonate. According to the electrolyte disclosed by the invention, the chain carboxylic ester solvent, the first additive containing the sulfonate compound or / and the sulfate compound and the second additive containing the vinylene carbonate or / and the fluoroethylene carbonate are matched for use; the rapid charging capability and the high-temperature cycle performance of a lithium iron phosphate system battery with high safety performance can be improved, and the application of lithium iron phosphate in a power battery is further widened.

The present invention relates to a flexible iron aluminate cement-based supercapacitor and a preparation method thereof. The flexible iron aluminate cement-based supercapacitor is assembled with rGO / Ni as the positive electrode, rGO@α-Fe2O3 spindle / Ni as the negative electrode, and polyacrylamide-cement-emulsion-latex powder-water-KOH as the flexible cement-based solid electrolyte. Compared with the prior art, the flexible energy storage cement-based material, as a new type of building material integrating structure / function, realizes the integration of flexible lightweight design and functional technology. Its flexible characteristics can closely fit complex-shaped buildings and have good adaptability to special-shaped curved building structures. At the same time, a non-destructive construction process can also be adopted, and the energy storage function can be imparted to the existing structure by an external pasting method, so that the energy storage function can be imparted without structural reconstruction.

A nanocomposite electrode and a supercapacitor device including said nanocomposite electrode. The nanocomposite electrode includes a mixture of at least one binding compound, at least one conductive additive, and at least one molybdenum doped carbon material coated onto a substrate. The supercapacitor device includes two nanocomposite electrodes disposed facing one another, wherein the substrate of each nanocomposite electrode is coated with the mixture on an inside facing surface and the outer surfaces of the nanocomposite electrodes are not coated with the mixture, and the inside facing surfaces are separated by at least one electrolyte.

The application provides a cement-based zinc ion hybrid capacitor, a preparation method thereof and application of the capacitor in an energy storage device. The cement-based zinc ion hybrid capacitor comprises an active carbon positive electrode, a zinc foil negative electrode and a composite air-entraining mortar interlayer arranged between the two electrodes. The active carbon positive electrode is active carbon loaded on a carrier with good conductivity, and the carrier is any one of carbon-based materials such as carbon felt, carbon fiber and graphite plate or any one of foils, meshes and foams of metals such as stainless steel, copper, titanium and nickel and alloys thereof. The composite air-entraining mortar interlayer between the two electrodes is immersed in an electrolyte under negative pressure. The composite air-entraining mortar has interconnected pores, and ions are transmitted through the electrolyte in the pores and participate in electrode reactions. The application mainly provides a porous cement-based solid electrolyte based on a composite air-entraining technology and a structural electrochemical energy storage device, and the structural energy storage device can simultaneously have good energy storage characteristics and mechanical properties.

The invention relates to the technical field of supercapacitors, in particular to an alkali-activated solid-waste-based supercapacitor and a preparation method thereof.The preparation method comprises the steps that industrial solid waste and fiber forestry and agricultural residues are subjected to co-pyrolysis to form organic-inorganic composite solid waste gelling powder, an alkali activator and a functional additive are added to prepare alkali-activated slurry, and the alkali-activated slurry is prepared; pouring, molding and curing to obtain an alkali-activated solid waste-based electrolyte substrate; the method comprises the following steps: performing high-temperature pyrolysis, activation and the like on granular agricultural and forestry wastes to prepare a carbon-based composite conductive material, and preparing a biochar electrode plate; the preparation method comprises the following steps: taking PVDF as a raw material, bonding and curing the PVDF and the raw material, immersing the PVDF and the raw material into a KOH solution containing a PVA thickener, inserting a glass fiber diaphragm, and regulating and controlling the use amount of PVDF and other binders and a solvent system to optimize slurry viscosity and film forming uniformity so as to obtain an electrode film with mechanical flexibility and interface adhesive force; the composite electrode forms a stable composite interface in the process of being in contact with an alkali-activated electrolyte interface, and the phenomena of interface aging and capacitance attenuation caused by mismatching between the electrode and the electrolyte in a traditional cement-based system are effectively avoided.

The invention relates to the technical field of polymer photoelectric materials, in particular to a preparation method of a supramolecular gel electrolyte. The method comprises the following steps: esterifying tetraphenylethylene alcohol and methacryloyl chloride to form tetraphenylethylene methacrylate, and performing staged linear heating polymerization on the tetraphenylethylene methacrylate, 3-(methacrylamido) propyl dimethyl 3-thiopropyl ammonium oxide inner salt, acrylic acid, tetraphenylethylene methacrylate and 4-vinylpyridine under the action of ammonium persulfate to obtain a tetraphenylethylene copolymer. And finally, soaking in a lithium chloride aqueous solution to obtain the supramolecular hydrogel electrolyte. The hydrogel obtained by the invention has high mechanical strength and high ionic conductivity, and is suitable for energy storage devices such as flexible supercapacitors and the like.

The invention relates to a super-flexible supercapacitor with a multi-layer seamless interlocking interface and a preparation method of the super-flexible supercapacitor. The super-flexible supercapacitor takes a carbon nanotube or a composite film thereof as an electrode; and polyanion gel (polyacrylamide / polyacrylic acid / poly (3-sulfonic acid propyl methyl acrylic acid potassium salt) and polycation gel (polyacrylamide / polyacrylic acid / poly (methacryloyloxyethyl trimethyl ammonium chloride) are used as the double-layer heterogeneous electrolyte. A covalent connection electrode / electrolyte interface is constructed through anchoring interface polymerization, and double-layer gel electrolyte with electrostatic attraction and mutual entanglement is constructed through in-situ polymerization, so that the super-flexible supercapacitor with a multi-layer seamless interlocking interface is realized. Compared with the prior art, the super capacitor has super-strong interface toughness and interface adhesion, can resist mechanical deformation including bending, folding, twisting, winding, extruding, knotting and the like, the capacity retention ratio is greater than 95% after the super capacitor is folded for hundreds of thousands of times, and the capacity retention ratio is greater than 89% after the super capacitor is circularly charged and discharged for hundreds of thousands of times.

The invention belongs to the technical field of supercapacitors, and particularly relates to a preparation method of a cement-based supercapacitor based on static pressure forming. By applying uniform static pressure, the physical compaction and optimization of the high-carbon-content slurry are realized, and the conductive network connectivity and pore structure optimization of the carbon cement matrix electrode are ensured. The final electrode material shows excellent energy storage performance and mechanical strength, and the capacitive performance and the mechanical performance are both considered. After the electrode is treated by the method, when the forming pressure is 4 MPa, the area specific capacitance can reach 817.3 mF / cm < 2 >, and the mechanical strength of the electrode after being cured for 28 days is 12.7 MPa. Compared with a traditional process, the electrochemical performance and the mechanical performance of the cement-based supercapacitor are remarkably balanced, and the actual application requirement of building-energy storage function integration is met.

The invention discloses an electrolyte based on a fluorine-containing polynitrile compound and a high-voltage supercapacitor, and belongs to the field of energy storage materials. The electrolyte comprises a fluorine-containing polynitrile compound, an organic solvent and electrolyte salt; the structure of the fluorine polynitrile compound is as follows: Fm-A-(CN) n, wherein A is C1-C10 alkyl, C6-C14 aryl or a heteroatom-containing linking group, m is greater than or equal to 1, and n is greater than or equal to 2. By introducing the Fm-A-(CN) n structure compound and utilizing the synergistic effect of fluorine atoms and cyano groups, a stable interfacial film is formed on the surface of an electrode, so that the working voltage of the electrolyte is increased to 3-3.2 V. The capacitance decay rate of the electrolyte in the range of 60-80 DEG C is lt; the method is suitable for the fields of vehicle-mounted energy storage, power grid frequency modulation and the like.

The present disclosure relates to organic electrolyte solutions including organic electrolytes (e.g., aromatic imides, ferrocenes, spiro fused compounds, or cyclopropenium compounds), and redox flow batteries and systems including the same.

The invention provides a design and application of a power type electrolyte of a double-electric-layer capacitor, and the electrolyte comprises an organic solvent, an electrolyte salt and an additive. Wherein the additive has a general formula structure as shown in Figure 1: the additive has a strong electronegativity part and a strong electropositivity part, a proper chain length is adjusted between the two parts, so that the whole molecular size of the additive can be matched with the micropore diameter of the activated carbon, adsorption and desorption are facilitated, bond breaking is easy, and when part of pseudocapacitance is contributed through oxidation bond breaking, the performance of the additive is improved. According to the present invention, the positive electrode and the negative electrode can be preferentially adsorbed to the positive electrode and the negative electrode so as to form the regulation and the low polarity and high density interface, such that the ion association of the salt ions at the double electrode layer is reduced, the reduction of the liquid phase transmission internal resistance is achieved, the excellent power performance is further represented, and the capacity retention rate in the 125A large-rate cycle (the conventional current is 25A) is increased to 90.1% from 76.3%. In addition, the silicon-containing part formed by broken bonds can also synergistically remove HF generated by hydrolysis of salt anions BF4 <-> in the electrolyte, passivate Al foil and reduce the contact internal resistance of the aluminum conducting bar. The configuration of the additive introduced into the electrolyte is shown in the specification.

The invention relates to an integrated Schottky contact power generation-energy storage hydrogel device and a preparation method thereof, PVA hydrogel is adopted as a base material, and conductive PVA coated PPy hydrogel is prepared through an in-situ polymerization reaction of ferric chloride and pyrrole. Meanwhile, PVA is used as a base material, phosphoric acid is introduced to prepare PVA gel electrolyte, and an integrated self-power-generation-energy-storage device based on the Schottky contact principle is constructed. According to the Schottky contact principle, the device can efficiently convert mechanical energy into electric energy, and storage and release of the electric energy are achieved. The electrical characteristics of the device can be optimized according to the external environment through the adjustability of the hydrogel, so that more efficient energy conversion and storage are realized. The self power generation and energy storage characteristics of the device show excellent voltage output and stable current response, and the device has wide application prospects in the fields of wearable equipment, sensors, environment energy collection and the like.

The present disclosure relates to organic electrolyte solutions including organic electrolytes (e.g., aromatic imides, ferrocenes, spiro fused compounds, or cyclopropenium compounds), and redox flow batteries and systems including the same.

A power storage device (10) comprises: a positive electrode (21) in which a positive electrode active material layer (21b) is formed on a first surface (21a1) of a positive electrode collector (21a); and a sealing part (24) that is adhered to the first surface (21a1) of the positive electrode (21). The sealing part (24) is formed from an acid-modified polyolefin resin. The positive electrode (21) comprises a carbon coating layer (M) that is provided at the portion of the first surface (21a1) of the positive electrode collector (21a) to which the sealing part (24) is adhered. The carbon coating layer (M) includes carbon particles and a coating layer binding agent. For the coating layer binding agent, the intensity ratio (PCOO / PCH) of a peak (PCOO) that represents a COO structure to a peak (PCH) that represents a CH structure on an IR absorption spectrum, as measured by infrared spectrophotometer, is 0.5-3.3.

A polymer that includes repeating units having a structure which is at least one selected from the group including of formula (1) and formula (2). Further, a method of forming the polymer is described. The polymer is used in a supercapacitor, which includes first and second electrodes and an electrolyte which includes the polymer.

This synthetic stone can be used as electrical energy storage which acts like a supercapacitor and invention also discloses a preparation method thereof. According to this invention, geopolymer (11) and cement (12) are being taken as materials for an electrolyte. A supercapacitor of the present invention comprises a geopolymer (11) and cement matrix (1) and a positive and negative steel electrode (2, 3), whereby the steel electrodes (2, 3) are arranged in the matrix (1), and the matrix (1) is prepared from conductive mortar. The conductive mortar (1) comprises fly ash, cement (12), gravel and sand, alkali activator (KOH and SiO2) (13), and some additives (14) of synthetic stone compounds such as poly carboxylate ether, retarder, lignosulfonate, ethylene-vinyl acetate, hydroxypropyl methyl cellulose, pigment and carbon black. This supercapacitor synthetic stone is simple in structure and is based on a particular formulation.

Provided is a secondary battery having high capacity and little deterioration. Provided is a novel power storage device. The secondary battery includes a positive electrode and a negative electrode, the negative electrode including a first active material, a second active material, and a graphene compound, at least a part of a surface of the first active material including a region covered with the second active material, the surface of the second active material and at least a part of the surface of the first active material include a region covered with a graphene compound, the first active material contains graphite, the second active material contains silicon, and the capacity of the positive electrode is 50% or more but less than 100% of the capacity of the negative electrode.

Rapid development of wearable portable devices urgently requires high performance flexible supercapacitors and batteries. As a core component of a flexible energy storage device, hydrogel electrolyte has aroused wide attention. According to the invention, the PBAx composite hydrogel (x represents the PVA content, and the values are 0, 0.5, 1 and 1.5) is prepared through chain crosslinking of sodium polyacrylate (PANa), polyvinyl alcohol (PVA) and bacterial cellulose (BC). The PVA component can effectively regulate and control intramolecular crosslinking among PANa molecular chains through hydrogen-bond interaction, so that the optimized PBA0.5 hydrogel forms a porous structure, the structure shows remarkably enhanced water holding capacity and mechanical strength, and the ultimate compressive strength reaches 258.4 kPa. By utilizing the ionic conductivity characteristic of 4.607 S m <-1 > of the material, the specific capacity of a basic zinc battery assembled by the material reaches 171.3 mAh g <-1 >, and the material shows excellent rate capability. The hydrogel electrolyte can effectively protect the zinc negative electrode and guarantee the cycling stability of the battery. In addition, due to the excellent anti-freezing performance of the PBA0.5 hydrogel, the specific capacity of the battery in a low-temperature environment of-40 DEG C can still be kept at 83.1 mAh g <-1 >.

A heating circuit for an energy storage device having a core with an electrolyte, inputs, a capacitance across the electrolyte and the core, and internal surface capacitance between inputs which can store electric field energy between internal electrodes of the energy storage device that are coupled to the inputs, including: a power source coupled to one of the inputs, wherein the power source provides positive and negative input currents to the input, the positive input current flows in to one of the inputs and the negative input current flows out another of the inputs; and a controller for controlling the power source to provide alternating between the positive and negative input currents to the input at a frequency sufficient to effectively short the internal surface capacitance of the energy storage device to generate heat and raise a temperature of the electrolyte.

The invention provides an anisotropic ion transmission supercapacitor based on topological insulator electrolyte. Relates to the technical field of energy storage devices, and comprises an electrolyte module, the electrolyte module comprises an electrolyte, the electrolyte is a network formed by Bi2Se3 nanowires, and the Bi2Se3 nanowires form an anisotropic ion transport channel through a surface modification method of sodium dodecyl benzene sulfonate and vertical orientation arrangement. According to the anisotropic ion transmission supercapacitor based on the topological insulator electrolyte, an electrolyte module with anisotropic ion transmission characteristics is formed by adopting a network formed by topological insulator electrolyte Bi2Se3 nanowires and a surface modification technology. The electrode performance of the electrode module is enhanced through a vertical heterojunction structure, laser reduction, plasma etching and other processes, and therefore the excellent performance of the solid-state supercapacitor in the aspects of high energy density, low-temperature stability and structural stability is achieved.

A method of processing a battery including an electrode including pores filled with a gas involves applying a formation current to the battery, the formation current comprising at least one frequency attribute, the at least one frequency attribute based on an assessed dielectric attribute associated with wetting the pores with electrolyte. A method of processing a battery including a battery comprising an electrode involves applying a formation current to the battery comprising at least one frequency attribute, the at least one frequency attribute based on an assessed dielectric attribute associated with forming a solid electrolyte interphase (SEI) layer on the electrode.

The invention relates to the technical field of electronic component manufacturing, solves the technical problem that interface contact resistance bounces and rises due to thermal stress mismatch, and particularly relates to an electronic component preparation parameter optimization method and system. Generating a gradient layer of which the thermal expansion coefficient continuously changes; and calculating a target thermal expansion coefficient for eliminating the interface thermal stress and an actual thermal expansion coefficient of the in-situ monitoring gradient layer based on the metal and ceramic concentration distribution function. According to the method, component continuous transition is achieved through metal / ceramic precursor dynamic flow control, continuous gradual change from metal to ceramic components is achieved, the coefficient of thermal expansion is in smooth transition in the thickness direction, and internal stress accumulation caused by material expansion difference is blocked from the source; and dynamic deposition regulation is combined to ensure that the thermal expansion gradient at any position is lower than a critical threshold value, and stripping or cracking caused by stress concentration in thermal circulation is avoided.

The invention provides a high-voltage-resistant electrolyte and a supercapacitor, the electrolyte comprises a mixed electrolyte salt, a mixed organic solvent and an additive, the additive is a mixed additive of a sulfur-containing additive and a functional additive, the functional additive containing cyano and nitrogen-rich pyrazine ring is introduced into the electrolyte, the functional additive can be oxidized preferentially at a positive electrode interface, and the positive electrode interface can be oxidized preferentially at a negative electrode interface. A stable and compact positive electrode electrolyte interface film (CEI) is constructed, and continuous decomposition of the electrolyte under high voltage is inhibited; and corrosive HF acid can be removed, transition metal ions are complexed, the catalytic chain reaction is cut off, and the structure degradation and capacity fading of the positive electrode material are relieved. By adopting the high-voltage-resistant electrolyte disclosed by the invention, the cycling stability and safety of the supercapacitor under high cut-off voltage can be remarkably improved, and the key technical problems of electrolyte decomposition, performance degradation of a positive electrode material and the like when the traditional electrolyte is applied at high voltage are effectively solved.

A zinc (Zn) ion hybrid supercapacitor (ZIHSC) in the form of an electrochemical cell includes a Zn nanosheets electrodeposited metal substrate (Zn ED-MS) as an anode, and a jute activated carbon coated conductive carbon substrate (the JAC-CCS) as a cathode, an electrolyte including an aqueous solution of Zn salt at a concentration of 0.05 to 5 molars (M), and a membrane as a separator.

A gel electrolyte is configured for use in an energy storage device, and the electrolyte includes phosphoric acid and nonionic surfactant. The molar ratio of phosphoric acid (PA) to nonionic surfactant is 50 to 120.

The invention discloses a high-toughness double-network hydrogel electrolyte as well as a preparation method and application thereof. The preparation method comprises the following steps: dissolving carrageenan in deionized water, magnetically stirring and heating until the carrageenan is completely dissolved, cooling, and adding a ZnSO4 solution for pre-crosslinking to form a carrageen-Zn < 2 + > solution; dissolving AM and a cross-linking agent in water to form an AM monomer solution; mixing with a carrageen-Zn < 2 + > solution, adding glycerol as a plasticizer, and uniformly stirring for plasticizing; and adding a photoinitiator, carrying out ultraviolet radiation to form a PAM chemical cross-linked network so as to obtain double-network hydrogel, and soaking the double-network hydrogel in a mixed solution of ZnSO4 and boric acid to strengthen the cross-linked network, thereby obtaining the hydrogel. The high-toughness double-network hydrogel electrolyte is stable in structure, excellent in conductivity, high in mechanical strength and good in flexibility, dendritic crystal growth can be inhibited, the ion migration efficiency and the interface stability can be improved, and the high-toughness double-network hydrogel electrolyte has wide prospects when being used for flexible electronic devices, new energy systems and other energy storage devices.

The invention relates to a ceramic capacitor dielectric material and a preparation method and application thereof, and belongs to the field of ceramic capacitor dielectric materials. The problems that an X7R / X8R type ceramic capacitor material cannot meet the high-temperature application requirement, loss is high, and stability is insufficient are solved. The invention provides a dielectric material for a ceramic capacitor. The dielectric material is prepared from the following components in percentage by weight: 96.5 percent of BaTiO3, 3.5 percent of CaZrO3, 1.26 percent of NiO: Nb2O5 and 0.3 to 0.5 percent of MnCO3. According to the ceramic capacitor dielectric material, the capacitance change rate delta C / C25 DEG C is smaller than or equal to + / -15% within the range of-55 DEG C to 200 DEG C, and the X9R standard is met; the dielectric constant is as high as 4265, and the dielectric loss is as low as 0.012; the step-by-step pre-sintering and gradient sintering process inhibits abnormal growth of crystal grains, the density is improved, and the repeatability is high; the method does not need complex equipment and is suitable for industrial production.

The invention discloses a carbon-based aqueous zinc ion supercapacitor and a preparation method thereof, and belongs to the technical field of zinc ion supercapacitors. The capacitor comprises a positive electrode, a negative electrode, a multi-element electrolyte and a porous diaphragm, the anode is an activated carbon composite material; the negative electrode is a rolled zinc foil; the multi-element electrolyte is a mixed system aqueous solution formed by dissolving zinc trifluoromethanesulfonate, zinc sulfate, zinc chloride, zinc perchlorate and an electrolyte additive in deionized water; and the porous diaphragm is glass fiber. The preparation method comprises the following steps: uniformly mixing the activated carbon composite material, the conductive black and the binder in proportion, adding the organic solvent, grinding into slurry, coating the slurry on the carbon paper, performing vacuum drying to obtain the positive electrode plate, and assembling the positive electrode plate with the multi-element electrolyte, the negative electrode and the porous diaphragm. The raw material cost and the energy consumption are low, the operability is greatly improved, and the repeatability is good.