1375 results about "Alkali metal" patented technology

The invention discloses a series of alkali metal borate compounds and alkali metal borate crystals as well as a preparation method and application thereof, and belongs to the technical field of photoelectric functional crystal materials. The chemical general formula of the series of compounds and crystals thereof is A3RE (B3O6) 2, wherein A is K, Rb, Cs or NH4; rE = Sc and Y, the molecular weight is 355.93-744.48, the series of crystals belong to a trigonal system, the space group is P321, the cell parameters a = b = 10.5237 (13)-135237 (13), and # imgabs0 # Z = 3. The series of alkali metal borate compounds are synthesized by adopting a solid-phase reaction method or a hydrothermal method, and the series of crystals grow by adopting a high-temperature melt method or a hydrothermal method or a solution method. The series of materials can be used for manufacturing second harmonic generators, upper and lower frequency converters, optical parametric oscillators, polarizing prisms and the like.

The invention relates to a preparation method and system for an atomic gas chamber for sapphire coating, and the preparation method comprises the steps: S1, placing a cleaned atomic gas chamber on a heating base station of a reaction chamber, and filling the reaction chamber with replacement gas to discharge residual gas in the reaction chamber; s2, filling aluminum source gas into the reaction chamber, and carrying out chemical adsorption on the wall surface of the atomic gas chamber to form a first film layer; s3, filling replacement gas into the reaction chamber to discharge residual aluminum source gas in the reaction chamber; s4, filling oxide gas into the reaction chamber to oxidize the first film layer and convert the first film layer into an aluminum oxide film layer; s5, filling replacement gas into the reaction chamber to discharge residual oxide gas in the reaction chamber; and S6, repeating the steps S2 to S5 to form a preset number of aluminum oxide film layers with a preset thickness on the wall surface of the atomic gas chamber so as to form the atomic gas chamber with the sapphire coating film. The anti-shielding capability of the alkali metal atomic gas chamber can be enhanced, and the electromagnetic wave precision measurement performance of the atomic gas chamber is improved.

A uranium-based phosphor selected from (i) phosphors having formula I or II:where the phosphor having formula I or II is doped with an activator ion including Pr3+, Sm3+, or mixtures thereof, where 0≤a≤1, 0≤b≤1, 0.75≤x≤1.25, 0.75≤y≤1.25, 0.75≤z≤1.25, 2.5≤p≤3.5, 1.75≤q≤2.25, and 3.5≤r≤4.5; (ii) a phosphor having formula I or II, where the phosphor having formula I or II is doped with an activator ion selected from Eu3+, Pr3+, Sm3+, and mixtures thereof; and a counter ion comprising one or more alkali metal ions; and (iii) phosphors having formula IIIwhere the phosphors having formula III are doped with an activator ion selected from: Eu3+, Pr3+, Sm3+, and mixtures thereof, where A is Li, Na, K, Rb, Cs, or a combination thereof.

According to the SERF magnetic field measuring device closed-loop magnetic compensation method based on double-beam detection, Y-axis direction detection light used for decoupling is added on the basis of X-axis direction detection light, decoupling of three-axis magnetic field signals can be achieved, independent measurement and closed-loop control real-time magnetic compensation of a three-axis magnetic field are achieved, support is provided for further improving compensation precision, and the method is suitable for large-scale popularization and application. Comprising the steps that Y-axis direction detection light penetrating through an alkali metal gas chamber in the Y-axis direction, X-axis direction detection light penetrating through the alkali metal gas chamber in the X-axis direction and pumping light penetrating through the alkali metal gas chamber in the Z-axis direction are arranged in the SERF magnetic field measuring device, the X-axis direction detection light is used for detecting the optical rotation angle, and the Y-axis direction detection light is used for three-axis magnetic field decoupling; the pumping light is used for polarizing atoms in the alkali metal gas chamber; adding a Y-axis calibration signal; controlling the Z-axis coil current to compensate the Z-axis magnetic field according to the Py; controlling the X-axis coil current to compensate the X-axis magnetic field according to the Py; and controlling the Y-axis coil current to compensate the Y-axis magnetic field according to the Px.

The invention relates to a self-calibration atomic wavelength meter. The self-calibration atomic wavelength meter comprises a saturated absorption spectrum light path for locking a detection laser frequency on a cesium atom energy level transition line based on a saturated absorption spectrum; the double-peak spectrum light path scans the frequency of a coupled laser after the frequency of the detection laser is locked by a saturated absorption spectrum, and when the detection laser and the coupled laser jointly act on alkali metal atoms and are subjected to resonance excitation, an electromagnetic induced transparency effect is generated; when the detection laser is detuned, the detection laser and the combined laser jointly act on the alkali metal atoms to generate non-resonance excitation, a double-peak EIT spectrum with Doppler frequency shift is generated, and the wavelength measurement of the current detection laser can be completed based on the linear relation between the double-peak spectrum interval and the detuning amount of the detection laser. In addition, the double-peak spectrum interval is compared with the atomic energy level transition frequency, the difference between the double-peak spectrum interval and the atomic energy level transition frequency serves as an error signal to be fed back to the control end of the detection laser, the frequency of the detection laser is tuned to the reference frequency standard, and calibration of the wavemeter can be achieved.

The invention provides a relaxation time measuring method and system. The relaxation time measuring method comprises the following steps: heating an atomic gas chamber to be measured to a set working temperature, and applying a static magnetic field in a z direction to the atomic gas chamber to be measured; starting the pumping laser light source and the detection laser light source, and performing light path alignment adjustment; the pumping laser light source is used for polarizing alkali metal atoms in the atomic gas chamber to be measured; determining a relaxation time measurement mode according to a relaxation time measurement requirement, triggering a corresponding operation, and collecting a corresponding relaxation signal; the measurement mode comprises at least one of the following modes: an alkali metal electron spin transverse relaxation mode, an alkali metal electron spin longitudinal relaxation mode, an inert gas nucleon spin transverse relaxation mode and an inert gas nucleon spin longitudinal relaxation mode; and fitting the relaxation signal corresponding to the mode to obtain a corresponding relaxation time value. According to the invention, the transverse and longitudinal relaxation time of alkali metal electrons and the transverse and longitudinal relaxation time of inert gas nucleons can be measured on the same machine.

A carbon capture and storage (CCS) material may be synthesized using a wide variety of feedstock from agricultural, forestry, and sanitary wastes. The feedstock is heated under a reaction medium. After adding a solution of an activating alkali metal compound to the feedstock, the feedstock and activating alkali metal compound are heated under flowing gases to form the CCS material. This CCS material may be used and regenerated multiple times, then used as a soil amendment.

The invention discloses a sulfate-series sodium-ion battery positive electrode material with an expanded structure, a preparation method of the sulfate-series sodium-ion battery positive electrode material and a sodium-ion battery. The general formula of the sulfate-series sodium-ion battery positive electrode material is Na < 6-x > L < x > Fe < 5-y > M < y > (SO4) 8, wherein x is more than or equal to 0 and less than or equal to 0.5, y is more than 0 and less than or equal to 0.5, L is an alkali metal element with the same chemical valence as Na, and M is a transition metal element with the same chemical valence as Fe. According to the positive electrode material disclosed by the embodiment of the invention, the sodium ferric sulfate material with an expanded structure is taken as a main phase, and elements with variable radiuses are introduced into sodium sites and iron sites, so that the material further obtains a pore channel structure and defects with proper sizes, a three-dimensional diffusion channel of sodium ions is expanded, and the volume change in an electrochemical cycle process is inhibited; the structural stability of the material is ensured, so that the material shows relatively high gram volume and relatively good rate capability.

Provided is an Fe-containing CHA zeolite having a high proportion of iron ions present at cation sites.　This method for producing Fe-containing CHA zeolite comprises: a first step, in which FAU zeolite is mixed with alkali metal ions and / or alkaline-earth metal ions, hydroxide ions (OH-) and water to prepare a mixture slurry; a second step, in which the mixture slurry is subjected to a hydrothermal treatment to prepare CHA zeolite; a third step, in which the CHA zeolite, an iron salt, and water are mixed together to prepare a mixture liquid; and a fourth step, in which the pH value of the mixture liquid is adjusted to a value less than 2.7.

An MCF includes a plurality of cores each extending in a direction along a central axis and a cladding covering each of the plurality of cores. The cladding includes a low refractive index barrier. The low refractive index barrier includes an alkali metal element. A relative refractive index of the low refractive index barrier is lower than an average value of a relative refractive indices of the cladding overall. The core interval is set such that a total sum of the power coupling coefficients between a specific core among the plurality of cores and each of all remaining cores is 2.3×10−4 / km or less.

The invention discloses a low-dimensional organic-alkali metal-copper (I) halide supramolecular scintillator based on crown ether assisted self-assembly, a synthesis method thereof and application of the low-dimensional organic-alkali metal-copper (I) halide supramolecular scintillator in single crystal X-ray imaging. A series of supramolecular scintillators are successfully synthesized by adopting a supramolecular coordination strategy of crown ether (L) and alkali metal ions (M) and a saturated solution volatilization method. By optimizing the crown ether coordination mode, controllable preparation of large-size single crystals is achieved, the optical and X-ray imaging performance of the large-size single crystals is improved, a new thought is provided for research and development of novel high-performance X-ray scintillators, and the application potential of the supramolecular scintillators in the field of high-resolution single crystal X-ray imaging is expanded.

The invention discloses a rapid enrichment-atomic absorption spectrum analysis method for low-content gold in gold ore, and relates to the technical field of gold ore analysis and detection.The rapid enrichment-atomic absorption spectrum analysis method comprises the following steps that an ore sample and a solid composite additive are mixed and roasted at the low temperature of 500-650 DEG C, and the additive contains alkali metal carbonate and zinc oxide; sulfur fixation, catalytic oxidation of organic carbon and stabilization of volatile elements can be synchronously realized; the method comprises the following steps: roasting gold-loaded activated carbon, dissolving the gold-loaded activated carbon in aqua regia to obtain a to-be-enriched solution, enabling the solution to pass through an adsorption column filled with modified activated carbon, pretreating the activated carbon with a 1-10% ammonium citrate solution to improve the selective adsorption capacity of the activated carbon on gold chloride complex ions, ashing the gold-loaded activated carbon, dissolving residues, fixing the volume, and measuring by using an atomic absorption spectrometry. According to the rapid enrichment-atomic absorption spectrum analysis method for the low-content gold in the gold ore, through cooperation of low-temperature roasting of the composite additive and selective adsorption of the modified activated carbon, the decomposition efficiency and enrichment selectivity of the ore difficult to treat are improved.

Provided is a silicon-based negative electrode active material, including M2Si2O5 and M2SiO3, where M includes one or more alkali metal elements; in an XRD pattern of the silicon-based negative electrode active material, a diffraction angle 2θ has a first diffraction peak ranging from 24° to 25°, and a half-peak width of the first diffraction peak is βA; the diffraction angle 2θ has a second diffraction peak ranging from 26° to 27°, and a half-peak width of the second diffraction peak is βB; and the silicon-based negative electrode active material satisfies 1.0≤βA / βB≤2.5.

The present invention discloses a ZIF / SPEEK composite diaphragm for a flow battery and a preparation method thereof. The composite diaphragm uses an alkali metal ion type sulfonated polyether ether ketone as a base film, and the sulfonation degree is 60% to 70%. The filler includes ZIF-8-X and ZIF-90-X. The ZIF-8-X material is ZIF-8-SO3H, ZIF-8-COOH or ZIF-8-OH, and the ZIF-90-X material is ZIF-90-SO3H, ZIF-90-COOH or ZIF-90-OH. The total doping amount of ZIF-8-X and ZIF-90-X is 1 to 5%. The present invention has excellent ion selectivity and ion conductivity, good chemical stability and mechanical properties, is applicable to various flow battery systems, and has good battery performance.

The invention belongs to the field of alkali metal batteries, and discloses an alkali metal alloy powder material and a preparation method, application and a product thereof, the alkali metal alloy powder material is alloy powder formed by an alkali metal element and at least one non-alkali metal element, the particle size is 1-100 microns, the atomic ratio of all elements in any single powder is highly consistent with the feeding ratio of raw materials, and the atomic ratio of all the elements in the powder is 1-100 microns. The high reducibility similar to alkali metal is maintained, the electronic conductivity is larger than 0.01 mS / cm, the average chemical valence state is smaller than 0.5 valence, and the electrochemical potential relative to metal lithium or metal sodium is 0-2 V. The preparation method comprises the following steps: heating and melting an alkali metal raw material to form an alkali metal melt, introducing a non-alkali metal raw material into the alkali metal melt, cooling to obtain an alkali metal alloy ingot, and physically grinding the alkali metal alloy ingot in a protective atmosphere to obtain powder with uniform components. The invention aims to provide a high-activity alkali metal alloy material in a powder form so as to fill the blank of the industry.

The invention discloses an intelligent prediction method and system for the alkali metal slagging tendency of a biomass gas coupled coal-fired boiler, and relates to the field of slagging tendency prediction.The intelligent prediction method comprises the steps that flue gas temperature data of a target area of a convection heating surface of the boiler is obtained, and the ash content melting characteristic temperature and alkali metal element content data of mixed fuel entering the boiler are obtained; performing physically constrained ash temperature-liquid phase yield adaptive correlation calculation, calculating coupling adhesion force, generating equivalent adhesion strength distribution of particle surfaces, counting particle turbulence collision physical parameters based on the equivalent adhesion strength distribution of the particle surfaces, and judging effective collision adhesion efficiency based on energy competition. The method comprises the following steps: calculating the agglomeration growth rate of ash particles in a flow field, outputting the spatial growth configuration of ash particle aggregates, carrying out macroscopic mechanical characteristic analysis and bridging stability judgment on an accumulation body at the throat part of the dry bottom hopper according to the spatial growth configuration of the ash particle aggregates, and outputting the blockage risk level of the dry bottom hopper, thereby effectively solving the blockage problem of the dry bottom hopper.

The invention discloses a preparation method of polyether-ether-ketone. The preparation method of the polyether-ether-ketone comprises the step of preparing the polyether-ether-ketone in the presence of carbonate and / or bicarbonate of alkali metal, wherein the D90 of the carbonate and / or bicarbonate of the alkali metal is less than 45 [mu] m. Under the condition of reduced pressure operation, when carbonate and / or bicarbonate of alkali metal with D90 smaller than 45 microns are / is used for preparing polyether-ether-ketone, polyether-ether-ketone with properties (such as color, mechanical property and the like) equivalent to those of a conventional process can be obtained, and the gel content is lower.

To provide a method for producing recycled positive electrode active material that can inhibit deterioration of a positive electrode active material due to hot carbon dioxide.SOLUTION: A method for producing a recycled positive electrode active material includes the following steps: (1) mixing a positive electrode mix containing a positive electrode active material and a carbon-containing material with an activation treatment agent containing one or more alkali metal compounds to obtain a mixture; (2) carrying the mixture into a continuous furnace and heating the mixture by supplying air in a direction opposite to the advancing direction of the mixture to obtain a heated mixture; and (3) recovering the heated positive electrode active material from the heated mixture.SELECTED DRAWING: None

The invention provides an anion-doped perovskite type titanate material and a preparation method and application thereof, the structural formula of the anion-doped perovskite type titanate material is AxByTiOzN1-z, A is an alkali metal element, B is a rare earth element, N is an anion element, 0 lt; x is less than or equal to 1, 0lt; y < = 1, 0lt; z < = 4. The prepared anion-doped perovskite type titanate material is applied to a negative electrode of a lithium ion battery, and compared with a traditional perovskite type titanate material, the anion-doped perovskite type titanate material has better fast charging performance and power characteristics, ultra-long cycle life and excellent safety.

The present application provides a kind of for the preparation of C 3+ The application discloses a catalyst for olefin, a preparation method and application, the catalyst is supported by a molecular sieve, and the molecular sieve is MFI molecular sieve or SBA-16 molecular sieve, and the catalyst is loaded with multi-metal, and the multi-metal includes metal tungsten, transition metal and alkali metal. The catalyst is used for providing Lewis acid sites by introducing metal tungsten into MFI molecular sieve or SBA-16 molecular sieve by one-step process, and further selectively introducing transition metal and alkali metal. By selectively coupling hydrogenation-dehydrogenation sites, C-C coupling sites and alkali metal sites in the same multifunctional catalyst, the synergies between the molecular sieve carrier and the multi-metal are realized. The catalyst realizes high-efficiency ethanol-to-C 3+ Olefins conversion in ethanol, with acetaldehyde as the reaction intermediate, and has the advantages of high C 5+ Olefins selectivity.

A method of obtaining a purified rare earth metal deposit from a rare earth metal halide salt, by: (i) producing a rare earth metal borohydride salt by the following reaction:n·ABH4+m·(RE)X3→RE(BH4)3+n·AXwherein the variables are defined as follows: A is an alkali metal cation; RE represents one or more rare earth metal cations; X represents a halide selected from chloride, bromide, and iodide; n is the molar amount of ABH4; and m is the molar amount of (RE)X3; wherein the ratio of n:m is 3:1 to 5:1; (ii) mixing RE(BH4)3 and AX with a halogen-free organic solvent to form a solution containing the RE(BH4)3 salt dissolved therein and with AX undissolved and precipitated; and (iii) contacting the solution from step (ii) with an anode and cathode in electrical communication, and electrically charging the anode and cathode to electroplate the rare earth metal onto the cathode.

A compound, and a preparation method therefor and the use thereof. The compound has a structure as represented by formula (I). In formula (I), R1 is selected from H and a substituted or unsubstituted C1-C6 alkyl; R2, R3, R4 and R5 are each independently selected from H, a substituted or unsubstituted C1-C6 alkyl and a substituted or unsubstituted C6-C12 aryl; R6 is selected from a substituted or unsubstituted C1-C4 alkylene; and M is selected from H or an alkali metal. The compound can be used as a viscosity reducer applied to thickened oil exploitation, and has the effects of strong high-temperature resistance and a good viscosity reduction effect.

The invention discloses a preparation method and application of a graphene oxide permeable membrane suitable for a concentrated salt brine system, and relates to the technical field of organic matter removal and desalinization. According to the method, polyether sulfone serves as a basement membrane, carboxylated graphene oxide and sodium alginate are subjected to cross-linking construction, and a graphene oxide / sodium alginate composite membrane is prepared; and then the graphene oxide permeable membrane is immersed in an alkali metal Sr < 2 + > solution and transition metal Fe < 2 + > and Fe < 3 + > solutions in sequence, and the graphene oxide permeable membrane is prepared. The prepared permeable membrane material can realize efficient interception of various soluble organic matters in a salt lake brine system, shows excellent desalting performance, and has a good application prospect in the field of salt lake brine treatment.

The invention discloses a double-perovskite thin film material, a preparation method thereof and a double-perovskite solar cell, and relates to the technical field of perovskite materials. The double perovskite thin film material comprises A2BCX6 type double perovskite, A is an alkali metal cation, B is a monovalent metal cation, C is a trivalent metal cation, and X is a halogen anion; the additive is a compound comprising a benzene ring and at least two sulfydryl substituted at different positions of the benzene ring. According to the embodiment, the composite center of the interior and interface of the double-perovskite thin film material can be reduced, the nucleation density in the preparation process of the double-perovskite thin film is reduced, the double-perovskite film layer has high crystallinity and larger grain size, the grain boundary in the film layer is reduced, the grain boundary defect is passivated, and the performance of the double-perovskite thin film is improved. And the photoelectric conversion efficiency of the solar cell containing the double perovskite thin film material can be improved.

An atomic oscillator of the present disclosure includes: a gas cell in which an alkali metal atom is encapsulated; a light generating unit emitting emission light onto the gas cell; a light detecting unit detecting transmitted light passed through the gas cell; and a control device determining a resonance frequency of the emission light based on a light amount of the detected transmitted light. The control device stores correspondence information in which a feature value of a transmitted light spectrum is associated with a state of the emission light, performs estimation processing to extract the feature value of the transmitted light spectrum from the detected transmitted light and estimate the state of the emission light corresponding to the extracted feature value of the transmitted light spectrum based on the correspondence information, and controls an emission state of the emission light based on the estimated state of the emission light.

The invention relates to an alkali metal gas chamber anti-relaxation self-assembly molecular coating adsorption energy quantification method, which finally realizes the physical quantification of the anti-relaxation coating adsorption energy by establishing a contact angle and surface topography collaborative characterization model and combining an adsorption-desorption dynamic formula, and is characterized by comprising the following steps: 1) establishing a contact angle and surface topography collaborative characterization model; depositing organosilane on a gas chamber glass substrate by adopting a liquid phase self-assembly method to form an anti-relaxation coating sample; step 2, selecting a plurality of measuring points on the anti-relaxation coating sample, dropping a 1 [mu] L ultrapure water liquid drop on each measuring point, determining a polarization retention angle of each measuring point according to the liquid drop height and the liquid drop substrate radius obtained by a contact angle measuring instrument, and scanning a local area of the corresponding measuring point by using an atomic force microscope (AFM), extracting an arithmetic mean value Ra of the surface roughness parameter and a root-mean-square value Rq of the surface roughness parameter as quantitative indexes of the polarization maintaining cross section; and step 3, taking free energy formed by the molecular layer of the coating as coating adsorption energy delta G.

The invention relates to a boiler operation parameter optimization method and system for multi-fuel combustion of multiple solid wastes, and the method comprises the following steps: (1) multi-source data collection: obtaining the heat value, the water content, the chlorine-sulfur ratio and the heavy metal content of the solid wastes in real time through a spectrum analyzer, a visual recognition system and an online sensor; (2) intelligent compatibility optimization: calculating a solid waste mixing ratio by adopting a genetic algorithm based on calorific value balance and pollutant inhibition targets, and controlling a Cl / S molar ratio to be 1.2-1.8 and the alkali metal content to be 1t; 50%; (3) pretreatment and drying: the water content gt; and carrying out microwave-steam combined drying on 25% of solid waste, and dynamically adjusting microwave power, steam injection time and the like. The method has the advantages that through the technical integration of multi-source data fusion, intelligent algorithm optimization and digital twinborn verification, a solid waste co-combustion full-process optimization system is constructed, and ultralow emission of pollutants and safe and economical operation are achieved while the energy utilization rate is increased.

The invention belongs to the technical field of fuel analysis, and particularly discloses a spectrum detection device and method for reaction activity and alkali metal content of multi-element fuel, the spectrum detection device comprises a sample unit, an LIBS detection unit and an NIRS detection unit, the sample unit is used for placing the multi-element fuel to be detected; the LIBS detection unit is used for carrying out LIBS detection on the to-be-detected multi-element fuel so as to detect the element content of the to-be-detected multi-element fuel; the NIRS detection unit is used for performing NIRS detection on the to-be-detected multi-element fuel at the pulse interval of LIBS detection so as to detect the functional group content of the to-be-detected multi-element fuel and further obtain the reaction activity and the alkali metal content of the to-be-detected multi-element fuel. According to the method, the LIBS and the NIRS are combined, so that unstable factors of NIRS measurement can be reduced, and the types of functional groups are corrected by utilizing the element contents, so that quick and synchronous detection of bimodal spectral information is realized.

To provide a detector capable of detecting vacuum leaks at low cost.SOLUTION: A vacuum leak detector (10) is provided, comprising an alkali metal body (12) disposed inside a vacuum vessel (20) that designed to generate heat from reaction with the insulating gas (30) contained in the atmosphere outside the vacuum vessel, and a temperature measurement device (11) capable of measuring temperature of the alkali metal body.SELECTED DRAWING: Figure 1

The invention provides a method for eliminating residual alkali on the surface of a positive active material and generating a functional film-forming pre-metallization agent in situ and application thereof, and the method comprises the following steps: dissolving halogenated carboxylic acid in an organic solvent to obtain a mixed solution; mixing a positive electrode active material with the mixed solution, and reacting to obtain a positive electrode active material with a pre-metallization agent attached to the surface; wherein the pre-metallization agent is halogenated carboxylic acid metal salt, and the chemical general formula of the pre-metallization agent is Xm-R-(COOM) n; the chemical general formula of the active substance is LiNi < y > Co < z > Mn Q O < 2 > or M 'Li < x > Ni < y > Co < z > Mn Q O < 2 >; through treatment by the method, residual alkali on the surface of the positive electrode active material can be eliminated, and meanwhile, a pre-metallization agent is generated in situ on the surfaces of particles; the pre-metallization agent can be used as an alkali metal supplementing agent to improve the energy density of the electrochemical energy storage device, and MX generated by reaction with the electrolyte can be functionally formed into a film, so that the cycling stability of the electrochemical energy storage device is improved.