The application relates to the technical field of
quantum materials, in particular to a van der Waals
heterojunction type high-efficiency superconducting
diode and a preparation method and application thereof. The superconducting
diode comprises a substrate layer, an
electrode layer, an Ising superconducting layer, a magnetic material layer and a packaging layer which are sequentially stacked from bottom to top; or, the superconducting
diode comprises a substrate layer, a magnetic material layer, an Ising superconducting layer, an
electrode layer and a packaging layer which are sequentially stacked from bottom to top. A
heterojunction is formed by the Ising superconducting layer and the magnetic material layer to realize double symmetry cooperative breaking, and a
system capable of realizing high-efficiency superconducting diode effect (SDE) is constructed by combining a vertical
magnetic field training technology; wherein, the magnetic material layer breaks time reversal symmetry, and the Ising superconducting layer and the magnetic material layer form a
heterojunction to break spatial inversion symmetry. The superconducting diode can maintain super-high SDE efficiency under
zero field and has strong zero-field stability.