1618 results about "Iron powder" patented technology

The invention discloses a numerical calculation method for simulating combustion of iron powder group particles, belongs to the field of numerical simulation calculation of iron powder combustion, can perform numerical simulation on single-particle and iron powder group combustion under a microgravity condition, quantitatively analyzes the influence of differential diffusion on single-particle iron powder and iron powder group combustion flame temperature, and improves the calculation accuracy of the single-particle and iron powder group combustion flame temperature. And meanwhile, the influence of iron powder combustion characteristics and flame propagation speeds under different iron powder and oxygen concentration conditions is considered. The method has a certain guiding significance in research on low-propagation-speed lean-burn iron powder flames and subsequent application of iron powder fuel. The microgravity environment can eliminate the influence of convection and buoyancy, so that the combustion process is more stable and predictable, and the basic mechanisms of iron powder combustion, including combustion rate, oxidation process, phase change and the like, can be deeply researched.

The present invention discloses a sulfurized nano zero-valent iron material, its preparation method and application, including: a core-shell structure sulfurized nano zero-valent iron material and a preparation method, the inner core of the sulfurized nano zero-valent iron is zero-valent iron, and the outer shell is Fe9S 10 , calculated by the mass of the sulfurized nano zero-valent iron, the mass percentage of zero-valent iron is 70-80%, and the mass percentage of the iron sulfide is 20-30%; the preparation method includes: placing iron powder in an H2S gas atmosphere for calcination, after the calcination is completed, cooling to room temperature to obtain the sulfurized nano zero-valent iron material. This material can be used for in-situ remediation of chlorinated hydrocarbon organic pollutants in groundwater. Compared with the prior art, the prepared sulfurized nano zero-valent iron is less likely to be oxidized and can overcome the problem of rapid passivation of nano zero-valent iron during the remediation process.

The invention discloses a method for producing iron powder by solid reduction treatment of copper smelting slag in a rotary kiln. Copper slag powder is obtained by crushing the copper smelting slag; carrying out solid-state reduction on the pellets containing the copper slag powder in a rotary kiln; carrying out magnetic separation on the reduced material to obtain iron powder and tailings; the pellets are fed into the rotary kiln from the tail of the rotary kiln, air is blown into the rotary kiln from a kiln head, and the reduced materials are discharged from the kiln head; the raw materials of the pellets comprise copper slag powder, limestone powder and pulverized coal. According to the method, the copper smelting slag is subjected to solid-state reduction treatment through the rotary kiln to comprehensively recover and produce the iron powder, and treatment and resource recycling of the copper smelting slag are achieved; the reduction, harmlessness and recycling of the industrial waste residues are realized, the investment is saved, the energy is saved, the consumption is reduced, the operation cost is low, and the popularization is easy.

The present invention relates to the technical field of inorganic materials, and particularly to a method for clean smelting of beryllium oxide and beryllium oxide. The smelting method includes using iron powder to remove trivalent iron in the acid leaching solution of beryllium ore; using a non-saponified extraction system without sodium ions and ammonium cations, and the non-saponified extraction system exchanges hydrogen ions with itself when extracting beryllium ions. The present invention solves the problems existing in beryllium smelting preparation in the prior art, such as low beryllium recovery rate, easy interference by associated elements, large pollution, and difficult waste liquid treatment. An alkaline earth metal compound is used as a raffinate impurity removal reagent and a non-saponified extraction system, and the raffinate after impurity removal is recycled for beryllium ore leaching, improving the beryllium recovery rate and reducing the environmental pollution caused by waste liquid discharge.

The invention relates to the technical field of flux-cored wires. The preparation method comprises the following steps: weighing the following raw materials in parts by weight: 4-6 parts of chromium carbide powder, 7-9 parts of molybdenum powder, 6-8 parts of nickel powder, 10-15 parts of niobium powder, 15-18 parts of tungsten carbide powder, 7-11 parts of a modified titanium carbide agent, 5-8 parts of a blending agent added based on boron and 2-4 parts of 30-mesh natural graphite; 1-2 parts of sodium fluosilicate; 1-2 parts of aluminum powder; and 70-75 parts of iron powder. The flux-cored wire can adapt to complex service environments of parts such as rollers and continuous casting crystallizers in the metallurgical industry, the service life of the parts subjected to surfacing repair is prolonged, the production efficiency of the parts subjected to surfacing repair is improved, the obtained flux-cored wire achieves balance of high-temperature performance, mechanical performance and low-temperature stability, and the comprehensive applicability of products is improved.

The invention relates to a low-loss multiphase inductance material which comprises a magnet and a winding, coils adjacent to the winding are wound in the reverse direction, meanwhile, the magnet extends out to form electrodes, and the magnet comprises Fe-based nanocrystalline and iron powder. The invention has the effect of reducing the loss of the inductance material.

The invention relates to the technical field of solid waste treatment and recycling, and discloses a waste incineration fly ash geopolymer composite material and a preparation method thereof, and the composite material is prepared from waste incineration fly ash, apatite minerals, zero-valent iron powder, persulfate and an alkali activator. The preparation method comprises the following steps: mixing the waste incineration fly ash, apatite minerals, zero-valent iron powder and persulfate to obtain composite powder; performing frequency conversion mechanochemical synergistic activation on the composite powder, wherein the activation process comprises a low-temperature activation stage and a high-energy pulse activation stage; and finally, mixing the activated powder with an alkali activator, pouring, molding and curing. According to the method, the reduction reaction and the oxidation reaction are driven step by step in the same system by regulating and controlling the mechanical energy input time sequence, the compatibility problem of a reducing agent and an oxidizing agent is solved, different types of persistent organic pollutants are synergistically degraded, meanwhile, heavy metal is stabilized, and the treatment effect is good. And the fly ash is recycled to prepare a geopolymer material with mechanical properties.

The invention relates to a waste ternary lithium ion battery black powder treatment method which comprises the following steps: in the presence of a reducing agent, carrying out acid leaching on waste ternary lithium ion battery black powder to be treated to obtain a leaching system; mixing the leaching system with iron powder, and reacting to obtain copper-removed ore pulp; and waste ternary lithium ion battery black powder is added into the copper removal ore pulp, the pH value of a reaction system is made to be 4-6, solid-liquid separation is carried out after reaction, and liquid with iron and aluminum removed and black powder filter residues are obtained. According to the treatment method, the technological process is short, production equipment can be simplified, the treatment cost is reduced, meanwhile, the recovery efficiency of valuable metal such as nickel, cobalt, manganese and lithium is effectively improved, the recycling value of black powder treatment is improved, and remarkable technical and economic advantages are achieved.

The invention relates to the technical field of non-oxide ceramic-based composite materials, in particular to Fe-N-based high-entropy nitride ceramic as well as a preparation method and application thereof. The method comprises the following steps: by taking iron powder as a sintering aid, mixing (Hf < 0.2 > Zr < 0.2 > Ti < 0.2 > Nb < 0.2 > Ta < 0.2 >) N high-entropy powder with the iron powder, and carrying out ball milling treatment to obtain ball-milled powder; and under the oxygen-free condition, the ball-milled powder is subjected to sintering treatment, transformation from the loose ball-milled powder to compact and uniform solid solution ceramic is achieved in the sintering treatment process, and the Fe-N-based high-entropy nitride ceramic is obtained. According to the method, a nitride thermal reduction method sintering process is adopted, energy is provided for densification of the Fe-N-based high-entropy nitride ceramic by utilizing reaction heat release of the (Hf0. 2Zr0. 2Ti0. 2Nb0. 2Ta0. 2) N high-entropy powder and the iron powder, the sintering temperature is reduced, energy is saved, and the defect that densification needs to be carried out under a high-temperature condition in the prior art is overcome.

The invention relates to the field of design and preparation of powder metallurgy friction materials, in particular to a copper-based powder metallurgy friction material and a preparation method thereof. Raw materials used in the method comprise, by mass, 45%-55% of copper powder, 8%-20% of iron powder, 6%-15% of ferrochromium, 16%-22% of graphite, 0.5%-4% of molybdenum disulfide, 0.5%-4% of tin sulfide and 0.5%-4% of nickel-coated tungsten disulfide, and the mass ratio of the tin sulfide to the nickel-coated tungsten disulfide is (1-2): (1-2). In the nickel-coated tungsten disulfide, the content of nickel is 5-40%; the sum of the total amount of molybdenum disulfide, nickel-coated tungsten disulfide and tin sulfide is less than or equal to 5%. The preparation method comprises the following steps: weighing raw material powder according to the designed components, mixing, pressing and sintering to obtain the product. The composition design has the characteristics of scientificity, simple and controllable process and the like, and the obtained product has excellent tribological performance and completely meets the friction braking requirement of high-speed heavy-load equipment of 400km / h and above.

The invention relates to the technical field of environmental chemistry, in particular to a double-vacancy Fe0. 96S (at) MoS2 nano composite material as well as a wet-type mechanochemical synthesis method and application thereof. The preparation method comprises the following steps: firstly carrying out co-ball milling by utilizing a wet mechanical chemical synthesis method to obtain a low-crystallinity Fe0. 96S (at) MoS2 precursor, and then carrying out further calcination treatment to accelerate the thermal reaction of the precursor, improve the crystallinity and remove redundant sulfur powder impurities, thereby obtaining the high-crystallinity Fe0. 96S (at) MoS2 nano composite material. Iron powder is introduced in the process of preparing MoS2 nanosheets from molybdenum powder and sulfur powder, the reaction activity of the molybdenum powder and the sulfur powder is improved and the formation energy of MoS2 is reduced by utilizing the characteristic of ball-milling heat release of the iron powder and the sulfur powder, the reaction barrier that MoS2 is difficult to prepare between Mo and S through a mechanical ball-milling process originally is broken, and the generation of the MoS2 nanosheets is promoted.

The invention relates to the technical field of cement-based material preparation, and particularly discloses a preparation method of an anti-carbonization all-solid waste slag-sulphoaluminate cementing material, which comprises the following steps: (1) putting a wet material formed by lead-zinc tailing powder and water into a reaction container, sealing, and heating; and mixing the obtained product with iron powder and / or iron oxide powder and water, stirring, separating out a solid product, and heating and drying in an air atmosphere to obtain the anti-carbonization tailing powder. And (2) mixing the anti-carbonization tailing powder with sulphoaluminate cement powder, and carrying out mechanical grinding treatment to obtain the modified sulphoaluminate cement. And (3) uniformly mixing blast furnace slag powder, the modified sulphoaluminate cement, fly ash, waste gypsum powder, an alkali activator, gypsum and a water reducing agent serving as raw materials to obtain the cementing material. According to the invention, the resource utilization of industrial solid waste is realized, the carbonization resistance of the cementing material is effectively improved, and the service durability of the cementing material is improved.

The invention discloses an injection molding high-density alloy steel sintering integrated preparation process, which comprises the steps of alloy raw material proportioning, feed preparation, injection molding, continuous thermal desorption sintering treatment and enhanced heat treatment, and comprises the following steps: selecting gas atomization pure iron powder subjected to vacuum reduction treatment, and matching with chromium, nickel, molybdenum, vanadium, carbon, silicon, manganese and iron powder multi-component alloy proportioning; a phenolic resin-polyformaldehyde composite binder is adopted, 0.5-1.5% of a lubricating additive is added, internal mixing parameters are controlled under the protection of inert gas according to the powder-to-rubber ratio of 72-77%: 23-28%, and the problem that the compatibility of a single binder and alloy powder is poor is solved; three-section gradient temperature control injection molding and a continuous atmosphere furnace sectional degreasing-sintering integrated process are combined, and strengthening heat treatment is matched, so that sufficient diffusion of elements and densification of a green body are realized, and defects are avoided. The technology effectively solves the technical problems that traditional raw materials are high in impurity content and insufficient in element diffusion, and therefore the alloy steel sintering preparation efficiency can be improved.

The invention discloses a polyolefin composite material as well as a preparation method and application thereof, and belongs to the technical field of high polymer materials, the polyolefin composite material comprises the following components in parts by weight: 18-32 parts of polyolefin resin, 19-31 parts of vinyl coupling agent modified metal powder, 19-31 parts of a nitrogen-phosphorus flame retardant, 4.5-11 parts of graphite and 0.9-5.2 parts of an interface improver; the vinyl coupling agent modified metal powder comprises a vinyl coupling agent and metal powder, and the metal powder comprises at least one of carbonyl iron powder, reduced iron powder, electrolytic iron powder and iron-based alloy powder. Under the combined action of the polyolefin resin, the vinyl coupling agent modified metal powder, the nitrogen-phosphorus flame retardant, the graphite and the interface improving agent, excellent electromagnetic shielding performance and flame retardant performance are obtained, and the polyolefin material is suitable for preparing electronic components, especially suitable for preparing electric control boxes, such as high-temperature-resistant materials, high-temperature-resistant materials, high-temperature-resistant materials, high-temperature-resistant materials, high-temperature-resistant materials, high-temperature-resistant materials, high-temperature-resistant materials and the like. The invention discloses a lithium battery pack and an electronic appliance protection shell.

The invention relates to the technical field of diamond saw blades, in particular to a laser welding diamond saw blade for ultra-narrow slit cutting and a preparation method of the laser welding diamond saw blade. The copper-cobalt-tin alloy material comprises the following raw materials: copper-cobalt-tin alloy powder, tungsten carbide powder, titanium-aluminum nitride, spherical cobalt powder, rare earth yttrium powder, ferrophosphorus powder and diamond abrasive particles. According to the preparation method, the core of the preparation method lies in the combination of powder metallurgy prefabrication of the tool bit and the precise laser welding process, especially the innovative laser welding process, and the prepared diamond saw blade is high in welding seam strength, narrow in heat affected zone and extremely small in matrix deformation; the problems of base body deformation, insufficient welding seam strength, short service life and the like of a traditional saw blade in the ultra-narrow seam cutting process are solved, and the saw blade is perfectly suitable for ultra-narrow seam cutting scenes with extremely high requirements for precision and stability.

The invention belongs to the field of material surface treatment, and relates to a glass explosion-proof rubber coating process. According to the process, alpha-Al2O3 nanoparticles and fatty acid grafted modified nano SiO2 are prepared, a nano composite adhesive containing aramid fibers and nickel hydroxyl iron powder is prepared in combination with a three-stage dispersion process (mechanical shearing, ultrasonic cavitation and rolling grinding), and a glass surface nano rough interface is constructed in combination with plasma treatment and a PECVD (Plasma Enhanced Chemical Vapor Deposition) technology. A magnetoelectric synergistic coating (magnetic field orientation + vacuum infiltration + gradient pressure + electrostatic overlock) and electromagnetic curing-gradient cooling process is adopted to realize uniform coating and rapid crosslinking of an adhesive layer. Through cooperation of material modification and a multi-field coupling process, the impact energy absorption of an adhesive layer is greater than or equal to 80%, the interface bonding strength reaches 22MPa, the curing time is shortened by 50%, degumming is avoided in an extreme environment, and the thickness deviation of the adhesive layer is + / -5 [mu] m. By adopting natural raw materials and a low-VOC formula, the anti-explosion glass is suitable for scenes such as building curtain walls and automobile glass, the anti-explosion performance is improved, and the service life is prolonged.

The invention relates to the technical field of welding materials, and particularly discloses a high-temperature-resistant flux-cored wire containing rare earth elements and a preparation method of the high-temperature-resistant flux-cored wire. The high-temperature-resistant flux-cored wire containing the rare earth elements comprises a welding wire skin and a flux core. The flux core comprises the following raw materials of dehydrated rutile, dehydrated potassium feldspar, zircon sand, metal chromium powder, metal nickel powder, electrolytic manganese, ferrotitanium, ferro-aluminum, potassium cryolite, potassium titanate, sodium titanate, fine iron powder, yttrium-based iron alloy powder, atomized ferrosilicon, nitrided ferrochrome, bismuth oxide, auxiliaries and the balance reduced iron powder. The auxiliary agent is a mixture of a zirconium-iron alloy, a titanium-iron alloy and an aluminum-magnesium alloy. A specific alloy auxiliary is introduced into the flux core to protect stable transition of rare earth yttrium, yttrium and multiple components synergistically optimize the weld joint performance, 253MA heat-resistant steel is matched, slag and electric arc regulation and control components and a reasonable process are matched, and the welding quality of the welding wire is improved.

A method for recycling various metals from sintering machine head ash comprises the steps that S1, the sintering machine head ash is subjected to pulping and magnetic separation, and tailing pulp and iron-containing concentrate are separated; s2, settling the tailing pulp to obtain bottom mud and supernate, carrying out filter pressing on the bottom mud to obtain silver-containing tailings and beneficiation water, and mixing the supernate and the beneficiation water to obtain mixed waste liquid; s3, treating the mixed waste liquid to obtain a heavy filter cake and high-salt waste water, and concentrating and separating out salt to obtain potassium sodium salt, condensed water and high-chlorine waste liquid; and S4, leaching the silver-containing tailings by using the high-chlorine waste liquid to obtain a silver-rich liquid, and carrying out an iron powder replacement reaction to obtain crude silver. Through the steps of magnetic separation, sedimentation, leaching and replacement, iron, silver, potassium, sodium and other metals are efficiently recycled, the process is simplified, and the efficiency is improved.

The invention provides a method for preparing high-purity titanium from ferrotitanium complex ore, and relates to the technical field of nonferrous metallurgy. The method comprises the following preparation steps: calculating and adding a carbonaceous reducing agent according to the components of the ferrotitanium complex ore and a specific principle, mixing and pelletizing, and reducing to generate a Fe (alloy)-TiC-MOx mixture; according to the content of TiC and Fe in the mixture, adding metal iron powder and Fe2O3 or iron ore concentrate according to a certain stoichiometric ratio, mixing, pelletizing, and reducing to obtain a titanium-iron alloy; and the obtained ferrotitanium alloy serves as a soluble anode, and high-purity titanium is prepared through electrolysis in halide molten salt containing low-valence titanium salt. According to the method, the reaction characteristic of iron and iron oxide with TiC at high temperature is utilized, the ferrotitanium alloy is generated from the ferrotitanium complex ore to serve as the soluble anode, then the high-purity titanium is prepared through molten salt electrolysis, the adverse effects of component deviation and anode precipitates existing in the soluble anode containing the titanium compound are avoided, and meanwhile casting forming is easy, and the method is more suitable for industrialization.

The invention relates to low-cost high-strength low-copper high-manganese non-magnetic steel and a preparation method thereof, and the low-cost high-strength low-copper high-manganese non-magnetic steel is prepared from the following raw material powder: high-manganese high-carbon pre-alloyed powder is used as a matrix, graphite powder accounting for 0.5-1% of the weight of the matrix, copper powder accounting for 0.3-0.5% of the weight of the matrix, Fe3P powder accounting for 2-2.5% of the weight of the matrix and iron powder accounting for 1-2% of the weight of the matrix are used as composite activators, and a reinforced phase formed by mixing SiC powder and Y2O3 powder accounting for 1-1.5% of the weight of the matrix is used; and the high-strength low-copper high-manganese non-magnetic steel is obtained from the raw material powder through a powder metallurgy method. Through one-time sintering, the sintering density can be 6.3-7.0 g / cm < 3 >, the tensile strength can be 630 MPa or above, the percentage elongation after fracture can be 10.1% or above, the mechanical property is excellent, and the cost is greatly reduced by integrally using the lower-content Cu element.

The invention discloses a copper-based friction plate of a wind power high-speed shaft brake and a manufacturing method, the friction plate comprises a friction material, the friction material comprises a friction layer and a friction layer, the friction layer comprises the following raw materials in percentage by weight: 65-72% of copper powder, 1-6% of iron powder, 3-10% of high-carbon ferrochrome powder, 8-15% of copper-tin-titanium powder and 15-20% of graphite powder; 1 to 5% of TiB2; and the transition layer comprises the following raw materials in percentage by weight: 70-75.4% of iron powder, 23-28% of copper powder, 1-3% of graphite powder and 0.6-1.2% of copper welding powder. The friction plate in the technical scheme is low in cost, does not contain harmful elements such as lead, meets the environmental protection requirement, integrates the advantages of a copper-based friction plate and an iron-based friction plate, has a stable friction factor and good wear resistance, and has the friction performance superior to that of an imported friction plate.

The invention discloses a nano-diamond reinforced powder metallurgy brake pad friction body material and a preparation method thereof, and relates to a brake pad friction body material and a preparation method thereof. The problem that in the prior art, the stability of a braking system of a train at a high running speed cannot be achieved is solved. The friction body material comprises a matrix component, a lubricating component, a friction component and a basic reinforcing component, wherein the sum of the mass percentages of the matrix component, the lubricating component, the friction component and the basic reinforcing component is 100%; wherein the mass percent of the copper powder in the matrix component is 50%-70%, and the mass percent of the iron powder in the matrix component is 10%-30%; the mass percent of the lubricating component is 10%-20%; the mass percent of the friction component is 1%-5%; the mass percent of the nano-diamond in the enhanced component is 0.1%-1%; the friction component is composed of one or more of silicon dioxide, aluminum oxide, titanium carbide, tungsten carbide, silicon carbide powder and zirconium oxide powder; the lubricating component is composed of one or more of graphite, carbon nanotubes and molybdenum disulfide. Belongs to the technical field of powder metallurgy.

The invention provides a foundation pit water gushing iron ore grading thixotropic blockage reduction method which comprises the steps that iron ore tailings are crushed and screened into multi-stage particle size particles, and a customized mold is subjected to 3D printing based on foundation pit scanning data; paving particles in a mold layer by layer, doping iron powder, and cementing and curing cement paste to form a prefabricated body; the prefabricated body is installed to a water gushing area, the slurry viscosity is increased through a grading contact network, a weak gravitational flow state is triggered to be transiently changed to an anti-scouring state, and water flow speed reduction is achieved; alternating field induction micro-vibration is synchronously started during lateral grouting, and grout permeation and bubble discharge are driven; after solidification, the guide core body is pulled away, and remaining pore channels are self-compacted by a grading system to form an anti-seepage structure. The method has the advantages that the anti-scouring performance is enhanced; particle-slurry-foundation pit curved surface triple self-adaptive combination is carried out; the engineering cost is reduced.

The invention discloses a tungsten-zirconium active material and a preparation method thereof. The method comprises the following steps: 1, mixing tungsten powder, nickel powder, iron powder and zirconium hydride powder to prepare mixed powder; 2, carrying out one-time compression molding on the mixed powder by adopting a cold isostatic press to obtain a pressed blank; 3, performing vacuum dehydrogenation treatment on the pressed blank by adopting a vacuum degumming furnace to obtain a pre-sintered blank; and 4, carrying out vacuum sintering on the pre-sintered blank by adopting a vacuum sintering furnace to prepare the tungsten-zirconium active material. The powder metallurgy method is adopted, densified sintering is achieved at the low sintering temperature, the problems of tungsten component sedimentation and zirconium powder oxidation are avoided, the tungsten content and the structure uniformity in the tungsten-zirconium active material are improved, the tungsten-zirconium active material with the tungsten mass content as high as 80% is obtained, the material has the remarkable damage effect, armor piercing after-effect is provided for damaged bullet seeds, and the application range of the tungsten-zirconium active material is widened. The method is suitable for the weapon manufacturing field.

The invention discloses an insulation coating method for a magnetically soft alloy powder material, and belongs to the field of inductance material preparation. Insulation coating of the magnetically soft alloy powder material is inorganic coating. The method comprises the following steps: 1) mixing magnetically soft alloy powder with a nitrogen-rich compound; 2) putting the mixed powder into a heat treatment furnace protected by an inert gas atmosphere, and carrying out passivating treatment; 3) sieving and collecting the coated alloyed powder.The magnetically soft alloy powder can be FeSiCr alloy powder, FeSiAl alloy powder or carbonyl powder.According to the magnetically soft alloy powder insulation coating material, under the condition that the effective magnetic conductivity is kept, the loss performance of a magnetic powder core composite material is remarkably reduced, and the magnetically soft alloy powder insulation coating material is suitable for large-scale production and preparation.

An objective of the present invention is to provide a conductive fiber which not only has excellent tensile strength, bending durability and corrosion resistance, but also in which the conductive fiber does not become magnetized and create a magnetic field disturbance, generate heat due to the magnetic field, attract iron powder, and the like. Another objective is to provide a fiber structure that includes the conductive fiber of the present invention and that has excellent flexibility.　The present invention relates to: a conductive fiber (1) including a liquid crystal polyester fiber (10) having a tensile strength of 18 cN / dtex or greater and a metallic foil (20) with a relative permeability of less than 3 spirally wound around the liquid crystal polyester fiber (10); and a fiber structure including the conductive fiber (1).

The invention discloses a submerged nozzle lining material for rare earth steel continuous casting and a preparation method thereof, and relates to the field of refractory materials. The high-strength wear-resistant ceramic material comprises the following components in percentage by weight: 40-65 wt% of fused white corundum, 8-20 wt% of quartz, 15-25 wt% of crystalline flake graphite, 1-2 wt% of metal silicon powder, 2-4 wt% of ferro-silicon nitride powder, 0.5-1 wt% of boron carbide powder and 8-12 wt% of thermosetting phenolic resin. The method has the beneficial effects that the raw materials are processed through the processes of mixing, drying and the like to prepare the pug, the pug is used for manufacturing the submersed nozzle lining, the submersed nozzle using the lining is used for rare earth steel pouring, the nodulation problem of an inner hole of the nozzle is remarkably relieved, the content of inclusions in molten steel is reduced, the quality of steel billets is improved, and meanwhile the production cost is reduced. And the service life of the submersed nozzle is prolonged, so that the submersed nozzle is more suitable for production of rare earth steel protective pouring.

The invention relates to a tungsten-based heavy alloy and a preparation method thereof. The tungsten-based heavy alloy comprises the following components in percentage by mass: (100-x)% of W-Ni-Fe-Co; m: x%; wherein x is more than 0 and less than or equal to 0.5, and m is high-hardness nano-particle carbide or high-hardness nano-particle oxide. Spherical tungsten powder, national standard fine tungsten powder, spherical nickel powder, spherical iron powder, spherical cobalt powder and m particles are taken to be evenly mixed and dried, mixed powder is obtained, in 93% by mass of W powder, the content of the spherical tungsten powder is 73%-83%, and the content of the national standard fine tungsten powder is 10%-20%; secondly, efficient forming and printing are conducted, specifically, the mixed powder in the first step is subjected to binder jet printing forming, and a blank is obtained; 3, degreasing process; 4, sintering process; and 5, a vacuum heat treatment process. The freely-formed tungsten-based heavy alloy with excellent mechanical properties can be obtained.

The invention discloses a powder metallurgy brake shoe for a locomotive and a preparation method, and relates to the technical field of metallurgy brake shoes, the powder metallurgy brake shoe comprises the following raw materials by mass percentage: 50%-70% of a matrix component, 10%-18% of a reinforcing component, 10%-16% of a lubricating component and 10%-16% of a friction component; the matrix component comprises electrolytic copper powder; the reinforcing components comprise reduced iron powder, superfine iron powder, atomized nickel powder, molybdenum powder and zinc powder; the lubricating component comprises artificial graphite and sulfide. According to the invention, the performance reduction of the brake shoe and the decline of a matrix at high temperature are effectively inhibited, the stability of a friction coefficient is kept, the abrasion is reduced, and the service life is prolonged.

According to the method, sodium carbonate, limestone and coke are used as sintering aids and are uniformly mixed with the high-iron Bayer process red mud, the mixed material is sintered by adopting a one-step low-calcium reduction sintering process, and the sintered clinker is subjected to water leaching and dissolution to obtain a sodium aluminate crude solution and filter residues. And returning the sodium aluminate crude liquid to an aluminum oxide industrial production line to prepare aluminum oxide, and carrying out a hydrolysis alkali recovery process on filter residues to obtain industrial sodium carbonate. The hydrolysis residues are subjected to magnetic separation and recovery to obtain fine iron powder, and the remaining tailings are completely harmless and can be used as raw materials of building materials or used for soil backfilling. The process is characterized in that the one-step low-calcium reduction sintering temperature is 200-300 DEG C lower than the sintering temperature of a sintering method, and the energy consumption is low; na2CaSiO4 is a sintering target product, Ca2SiO4 generally generated by a traditional sintering method is not generated, the situation that Ca2SiO4 is hydrolyzed in the water leaching process to inhibit dissolution of aluminum oxide is avoided, and the recycling rate of aluminum oxide is increased while the using amount of limestone is greatly reduced. The technological process is simple, efficient, energy-saving and free of three-waste emission, and the method is a novel method capable of treating the high-iron red mud in a large-scale and reduction mode.