1581 results about "Separation technology" patented technology

The invention provides an automatic early warning method for sudden weather in a target area, which belongs to the technical field of weather early warning, and comprises the following steps of: establishing a primary dense matrix by adopting adaptive filtering processing and a frequency domain signal separation technology, and generating a secondary dense matrix by applying a marine meteorological recognition model of a spiral progressive network structure; a dynamic statistical equation is used to calculate the physical coupling relationship of each parameter to establish a multi-scale weather process balance matrix, a maximum flow and minimum cut algorithm is used to optimize a weather system coupling relationship network to calculate a coupling degree matrix, and a dynamic threshold adjustment mechanism is established according to coupling strength parameters to adjust the early warning detection frequency. And based on a comparison result of the coupling degree moment order maximum characteristic value and a preset risk threshold value, establishing a grading early warning system and outputting a corresponding early warning signal to control an offshore oil and gas platform emergency response system. The technical problem that a multi-time scale weather process coupling relationship cannot be effectively processed is solved.

The invention discloses a BIM (Building Information Modeling)-based large-span post-tensioned bonded prestressed beam construction method. The BIM-based large-span post-tensioned bonded prestressed beam construction method comprises the following steps: collecting a vibration signal of a working rib and a matt rib reference signal of a matt rib; inputting the dummy rib reference signal into an adaptive filtering algorithm to which phase preserving constraint is applied, and performing noise cancellation processing on the working rib vibration signal to generate a purified pressure wave signal; performing multi-scale decomposition on the purified signal, extracting propagation time delay of the direct wave based on coherence analysis among components, and generating a phase-time delay characteristic matrix; and based on pre-configured geometric parameters of the BIM three-dimensional model, a real-time stress distribution field is calculated through inversion according to the phase-time delay characteristic matrix, and the real-time stress distribution field is synchronously updated to the BIM three-dimensional model. According to the method, the phase distortion problem under noise interference is solved through a physical reference channel and phase preserving filtering, the accuracy of time delay extraction is improved through a multi-path separation technology, and high-precision and high-robustness real-time monitoring of the prestress is achieved.

The invention belongs to the technical field of sewage treatment and membrane separation, and provides an in-situ nondestructive membrane pollution detection system and method based on an ultrasonic transmission signal, and the system comprises an ultrasonic excitation module which is used for generating a sine wave excitation signal which penetrates through a membrane body to excite the ultrasonic transmission signal for pollution detection; the signal processing module is used for continuously collecting and preprocessing ultrasonic transmission signals of the clean membrane body and the membrane bodies with different pollution degrees, extracting ultrasonic transmission signal characteristics under different pollution degrees, and establishing a pollution thickness-signal characteristic mapping model; wherein the ultrasonic transmission signal features comprise a time-frequency domain energy gravity center feature and a frequency attenuation spectrum slope feature; and the pollution detection module is used for judging the pollution stage of the membrane body to be detected based on the pollution thickness-signal feature mapping model, and completing in-situ nondestructive membrane pollution detection. According to the technical scheme, the sludge pollution state in the ceramic membrane and flat membrane filtering process can be monitored in real time, and early warning and pollution dynamic tracking are achieved.

The invention discloses a preparation method and application of organic peptide salt in the field of organic peptide salt, and the preparation method comprises the following steps: step 1) extraction of azolla filliculoidas active peptide: performing crushing, enzymolysis or ultrasonic-assisted extraction on azolla filliculoidas raw materials to obtain an azolla filliculoidas active peptide crude extract; and (2) purifying the rumex hanus active peptide. According to the method, the azolla filliculoidas active peptide is subjected to graded purification by adopting an ultrafiltration membrane separation technology, an active peptide component with uniform molecular weight distribution is obtained, and a high-quality raw material is provided for subsequent reaction; organic acid selection and reaction conditions are optimized, the yield and purity of the organic peptide salt are remarkably improved by selecting specific organic acid and optimizing the reaction conditions, ultrasonic-assisted reaction is introduced, the uniformity and efficiency of the reaction are improved through the ultrasonic-assisted reaction, and the stability and functionality of the organic peptide salt are further enhanced. The prepared organic peptide salt is not only suitable for the field of food, but also can be widely applied to health care products and cosmetics, and has remarkable market potential.

The invention relates to the technical field of membrane separation, in particular to a composite forward osmosis membrane based on mussel bionic interface enhancement and a preparation method thereof. The preparation method comprises the following steps: immersing a base material in a dopamine hydrochloride solution for oscillation reaction to obtain a modified base material; the surface of the modified base material is coated with a membrane casting solution in a blade coating mode, then phase inversion is carried out, the residual solvent is removed, then airing is carried out, and the composite forward osmosis membrane based on mussel bionic interface enhancement is obtained. By introducing the mussel bionic polydopamine intermediate layer, the long-standing technical contradictions of poor interfacial compatibility and weak binding force between the hydrophobic substrate and the hydrophilic separation layer are ingeniously solved, and the internal concentration polarization effect is remarkably inhibited. The prepared composite membrane has the advantages of high water flux, low salt reverse flux, stable structure and the like, and has wide application prospects in the fields of water treatment and substance separation.

The invention belongs to the technical field of membrane separation, and particularly relates to a recrystallized silicon carbide ceramic nanofiltration membrane as well as a preparation method and application thereof. The preparation method comprises the following steps: applying a polycarbosilane solution to a silicon carbide ceramic ultrafiltration body, and carrying out first pyrolysis to obtain a pyrolysis material; a polycarbosilane solution is applied to the pyrolysis material, and then second pyrolysis is carried out; the first pyrolysis process comprises the following steps: heating to 290-310 DEG C from room temperature, and preserving heat; raising the temperature from 290-310 DEG C to 790-810 DEG C, and keeping the temperature; raising the temperature from 790 to 810 DEG C to 1190 to 1210 DEG C, and keeping the temperature; the second pyrolysis comprises first pyrolysis and recrystallization which are carried out in sequence; the recrystallization process comprises the following steps: heating from 1190-1210 DEG C to 1590-1610 DEG C, and preserving heat; the temperature is increased to 2190-2210 DEG C from 1590-1610 DEG C, and heat preservation is conducted. The aperture of the recrystallized silicon carbide ceramic nanofiltration membrane is smaller than 10 nm, and nanofiltration can be achieved.

The invention discloses a self-cleaning composite piezoelectric ceramic membrane as well as a preparation method and application thereof, and belongs to the field of composite ceramic membranes. The technical problem that an existing ceramic membrane separation technology is poor in biomembrane pollution resisting effect is solved. According to the preparation method, the barium titanate ceramic membrane is firstly prepared to serve as the base membrane, then the copper oxide one-dimensional nanostructure is loaded on the piezoelectric ceramic substrate, and the base membrane has a large membrane surface area and can be combined with more catalysts, so that more active sites are provided for catalytic reaction; according to the composite membrane, the hydrophilicity, the anti-pollution performance and the piezoelectric catalysis self-cleaning performance of the membrane are remarkably improved, and pollutants in water can be quickly and effectively separated, so that the flux and the anti-pollution performance of the membrane are improved.

The invention belongs to the technical field of membrane separation, and particularly relates to a method for preparing a high-flux hollow fiber nanofiltration membrane based on interfacial polymerization, the obtained membrane and application. The method comprises the following steps: firstly, carrying out pre-adsorption treatment on a polyethersulfone hollow fiber ultrafiltration base membrane through a polyethyleneimine aqueous solution to form a reactive anchoring layer; then sequentially dipping in an aqueous phase solution containing piperazine, sodium phytate and nanoscale cellulose whiskers and an organic phase solution containing trimesoyl chloride and 5-isocyanate isopeptide acyl chloride for interfacial polymerization; and finally, carrying out heat treatment on the obtained primary composite membrane, and completing a gas-phase cross-linking reaction in a glutaraldehyde steam atmosphere. According to the method, the hollow fiber nanofiltration membrane with high flux, high selectivity, excellent chlorine resistance and pollution resistance is successfully prepared through a multi-stage strengthening process, and the hollow fiber nanofiltration membrane is suitable for the fields of drinking water purification, industrial wastewater reuse, material separation and the like.

The invention relates to a water treatment and membrane separation technology, and provides an integrated catalytic separation membrane, a preparation method thereof, and a water treatment method and system. According to the membrane, polyvinylidene fluoride is used as a continuous phase to form a porous matrix, and cerium dioxide is embedded and fixed in a mode of uniform dispersion in a membrane body in a phase inversion membrane forming process; in the presence of illumination and peroxysulfate, active species are generated through in-situ activation on a membrane-water interface, and membrane separation is completed synchronously. The water treatment method comprises the following steps: adding peroxymonosulfate or peroxydisulfate into a water body to be treated, and filtering through the membrane under illumination; the photothermal effect generated by organic matter degradation intermediates in operation inhibits membrane pollution and maintains flux. According to the invention, short-range coupling of active sites and mass transfer channels is realized, the medicament and energy utilization rate is improved, the coating stripping and metal dissolution risk is reduced, and the method is suitable for drinking water pretreatment, reclaimed water deep treatment and treatment of water containing natural organic matters / humic acid.

The application relates to a modified separation membrane in the technical field of membrane materials, a preparation method and application thereof. The modified separation membrane comprises a base film and a nanostructure layer on the upper surface of the base film and the membrane hole surface close to one side of the upper surface of the base film; wherein the pore size of the base film is 120-400 mu m; the nanostructure layer is composed of microparticles with a size of 100-1000 nm; the preparation method comprises 3D printing of the separation membrane; and the upper surface of the separation membrane and the membrane hole surface close to one side of the upper surface of the separation membrane are subjected to plasma treatment. The modified separation membrane preparation method combines the 3D printing technology and the membrane separation technology, improves the traditional membrane preparation process, finds a more optimal membrane replacement process, and the modification method is free of chemical agents, has the advantages of being more convenient and fast to operate, high in separation efficiency, low in processing cost, green and pollution-free, and the like, and has important significance in the aspects of membrane separation technology improvement and application of oily wastewater treatment.

The invention belongs to the technical field of petroleum refining, and relates to a high-purity hydrogen recovery process for improving denitrification efficiency based on a PSA (Pressure Swing Adsorption) device, which comprises the following steps: carrying out primary adsorption impurity removal after pretreatment and pressure regulation on raw material gas, carrying out gas-liquid separation, pretreatment and pressure regulation on the obtained hydrogen-rich gas, and then carrying out membrane separation; the generated hydrogen-rich permeated gas is subjected to pressure regulation and then is sequentially input into a second-stage PSA device and a third-stage PSA device for further adsorption and purification, and finally finished hydrogen with the purity not lower than 99.9% is obtained. The membrane separation technology is adopted for selective separation of hydrogen and nitrogen, the membrane separation unit is arranged at the outlet of the first-stage PSA device, nitrogen is removed from the source, meanwhile, desorbed gas of the third-stage PSA device and retention gas of the membrane separation unit are combined for combustion, nitrogen accumulation in the system is avoided, the nitrogen circulation amount in the system is reduced, and the energy consumption of the system is reduced. The hydrogen recovery rate can be effectively improved while the adsorption efficiency is improved, the process is simple, the investment cost is low, the implementation period is short, and remarkable economic benefits and process advantages are achieved.

The invention belongs to the technical field of gas membrane separation technologies and catalytic materials, and particularly relates to a ZSM-12 molecular sieve-based separation membrane, a preparation method and application thereof, and a reaction separation device using the separation membrane. The preparation method comprises the following steps: mixing and stirring a PEI polymer solution and a ZSM-12 molecular sieve to obtain a ZSM-12PEI membrane casting solution, scraping the ZSM-12PEI membrane casting solution on a glass plate pasted with a base membrane at a constant speed by using a 200 [mu] m scraper, and then drying in a constant-temperature and constant-humidity chamber at the temperature of 30 DEG C and the humidity of 40RH for 24 hours. The reaction separation device disclosed by the invention is designed in a manner that four stages of chambers are connected in series, so that the CO purity can be purified to 99% through step-by-step enrichment. CO is timely separated to avoid secondary oxidation, and the utilization rate of the catalyst is greatly improved.

The invention relates to the technical field of wet metal separation, in particular to wet metal separation and wind drying equipment which comprises a first workbench, first supporting plates are fixedly connected to the four corners of the top of the first workbench, transmission parts are arranged on the inner sides of the first supporting plates, and an acid pickling part is arranged at the top of the first workbench. The front side of the first workbench is fixedly connected with a second workbench. According to the wet-process metal separation and wind-power drying equipment, efficient treatment of metal parts is achieved through cooperative work of the innovatively-designed transmission component and the acid pickling component, a cross beam structure driven by a reciprocating lead screw is adopted to be matched with a cam-rope linkage mechanism, and therefore lifting vibration precisely controlled by + / -5 degrees is achieved while a metal net cylinder horizontally moves; fitting of metal pieces is effectively prevented; a second toothed plate and gear meshing system designed in an involute tooth shape drives a rotary rubber rod array, acid liquor permeation is promoted through high-frequency random knocking, and the oxide stripping efficiency is improved by 40%.

The invention relates to the technical field of membrane separation, and discloses a polythiourea composite nanofiltration membrane as well as a preparation method and application thereof. The composite nanofiltration membrane comprises a bottom layer, a porous support layer and a polythiourea separation layer which are arranged in sequence, wherein the polythiourea separation layer comprises a structural unit A from polyamine and a structural unit B from a polyisothiocyano compound; wherein the structural unit A and the structural unit B are connected through a structure shown in a formula I, Ar1 is a residue obtained after a reaction of a compound containing polyisothiocyano groups, and Ar2 is a residue obtained after a reaction of polyamine. The separation layer structure of the polythiourea composite nanofiltration membrane contains C = S bonds, a large number of hydrogen bonds can be formed, the polythiourea composite nanofiltration membrane has excellent chemical stability, the structural stability of the composite nanofiltration membrane in a strong acid environment is remarkably improved on the premise that the separation performance of the composite nanofiltration membrane is guaranteed, and the acid resistance of the composite nanofiltration membrane is improved.

The invention belongs to the technical field of membrane separation, and particularly relates to a preparation method and application of a high-permeability polyamide reverse osmosis membrane. According to the invention, the problems of high energy consumption and poor water production quality caused by non-ideal flux and rejection rate of the current reverse osmosis membrane product are solved, tetrabutylammonium bromide and acyl chloride form ion pairs to reduce hydrophobicity, a hydrogen bond network of urea destroys a hydrophobic barrier of an organic phase, and migration of acyl chloride to a water phase interface is promoted; the eutectic solvent is adsorbed on a water phase interface to form a'catalytic microenvironment ', amido of an amine monomer is attracted to be close to the interface, and the concentration of a reaction area is increased. During reaction, tetrabutylammonium bromide enables an amine monomer to stably attack a transition state of acyl chloride through electrostatic interaction, and reaction activation energy is reduced; urea and sodium hydroxide in a water phase can be jointly used as an acid-binding agent to neutralize generated hydrochloric acid so as to prevent amido protonation inactivation. The method is simple to operate and suitable for large-scale production.

The invention relates to an acetylene purification system and method, in particular to a method for removing impurities in acetylene to an electronic-grade acetylene level through a membrane separation technology coupled rectification process, and belongs to the field of gas separation. Aiming at the characteristics of an industrial grade acetylene material, the invention provides a technology for preparing electronic grade acetylene based on membrane separation coupling rectification, the membrane separation technology and the rectification technology are organically coupled, and a safe solvent is introduced into a rectification tower, so that the thermal stability of liquid acetylene is effectively improved, and the explosion risk is remarkably reduced. According to the technology, efficient preparation of the electronic-grade acetylene (the purity is greater than or equal to 99.9999%) is realized, and the method has a good industrial application prospect and popularization value.

A sensor installation angle optimization system relates to the technical field of precision machinery detection. The invention aims to solve the problem of poor detection precision caused by harmonic suppression in a three-point method error separation technology. An angle result set is obtained by using a weight function optimization target equation; selecting a minimum value of an angle common factor; when the minimum value of the angle common factor is unique, taking an angle corresponding to the minimum value of the angle common factor as an optimal sensor mounting angle; and when the minimum value of the angle common factor is not unique, calculating Euclidean distances between all angles corresponding to the minimum value of the angle common factor and an expected optimal solution, and taking the angle corresponding to the minimum value of the Euclidean distances as an optimal sensor mounting angle. And the sensor is arranged on the angle dial according to the optimal sensor mounting angle so as to measure the detected rod on the machine tool.

The invention belongs to the technical field of membrane separation, and particularly relates to a monovalent selective cation exchange membrane and a preparation method thereof, the preparation method comprises the following steps: (1) mixing a first exchange monomer, a first cross-linking agent, a first solvent and a first initiator to obtain a first prepolymer solution; (2) mixing a second exchange monomer, a second cross-linking agent, a second solvent and a second initiator to obtain a second prepolymer solution; (3) coating the first prepolymer solution on a first substrate film to obtain a first composition; (4) coating a second substrate film with the second prepolymer solution to obtain a second composition; and (5) oppositely laminating the coating surfaces of the first composition and the second composition, and stripping the first substrate membrane and the second substrate membrane after initiation polymerization is completed, so as to obtain the monovalent selective cation exchange membrane.

The invention discloses a protein / polyphenol composite nanofiltration membrane and application thereof, and belongs to the technical field of protein membrane separation. The nano-filtration membrane is formed by modifying an amyloid-like protein film with the thickness of 50-300 nm and the average pore size of 0.4-1 nm by polyphenol and then adhering the amyloid-like protein film to a porous base material, wherein the amyloid-like protein film is formed by unfolding and self-assembling protein under the action of a modifier. The nanofiltration membrane disclosed by the invention can realize efficient selective separation of Mg < 2 + > / Li < + > in salt lake brine with a high magnesium-lithium ratio, has selective separation capacity on mixed anions Cl <-> / SO4 < 2->, can effectively remove heavy metal ions and perfluoro / polyfluoroalkyl compounds in water, and provides an important basis for developing a sustainable and high-performance next-generation membrane separation technology.

The invention relates to the technical field of industrial wastewater treatment and resource recovery, discloses a printing and dyeing wastewater desizing water alkali recovery method, and solves the problem of low recovery treatment efficiency caused by serious membrane pollution when printing and dyeing desizing wastewater is treated by an existing membrane separation technology. The method comprises the following steps: carrying out homogenization and dissolved air flotation pretreatment on high-temperature desizing water to remove most of grease and suspended solids; then, clear liquid is filtered through an ultrafiltration membrane, a negative pressure environment is constructed on the membrane shell side to extract penetrating fluid in real time, meanwhile, fine bubbles are injected into feeding liquid to form gas-liquid two-phase flow, and the net pushing force of the membrane surface is controlled to be maintained in a 0.02-0.04 MPa micro-positive pressure interval so as to reduce membrane pollution; and carrying out nanofiltration purification on the primarily filtered water to finally obtain high-purity recovered alkali liquor. According to the invention, the problems of serious membrane pollution and fast flux attenuation in the traditional membrane treatment process are effectively solved, and efficient recovery of alkali and long-term stable operation of the system are realized.

The invention belongs to the technical field of advanced oxidation and membrane separation, and particularly relates to a PES / CP / CoCo-PBA composite catalytic membrane and a preparation method and application thereof.The PES / CP / CoCo-PBA composite catalytic membrane comprises a PES basement membrane and a catalytic activity layer combined on the PES basement membrane in situ through a phase inversion method, the catalytic activity layer is made of a CP / CoCo-PBA composite material, and the preparation method of the composite catalytic membrane comprises the steps that the PES basement membrane and the catalytic activity layer are combined in situ through a phase inversion method; the CP / CoCo-PBA composite material is formed by enabling catalytic particles CoCo-PBA to grow on a carbon material in situ through a hydrothermal method. The PES / CP / CoCo-PBA composite catalytic membrane provided by the invention has excellent catalytic degradation performance and good stability, not only has conductivity to realize the effect of electrochemically activating PMS, but also can keep higher mechanical strength and pollution resistance to meet the requirements of long-term operation and large-scale industrial application.

The application provides an octadecane-loaded cellulose-based composite phase change material evaporator and a preparation method and application thereof in seawater desalination, and belongs to the fields of photo-thermal conversion materials and separation technologies. Nanocellulose and polyvinyl alcohol are mixed to prepare an aerogel, octadecane is encapsulated in the pores of the aerogel by a vacuum impregnation method to obtain a composite phase change material aerogel, and the composite phase change material aerogel is coated with a non-woven fabric loaded with polypyrrole to obtain the octadecane-loaded cellulose-based composite phase change material evaporator. The evaporator is a composite phase change material evaporator based on the coupling of interfacial evaporation and phase change energy storage, solves the problems of discontinuous evaporation and low solar energy utilization rate caused by day and night alternation, has excellent light absorption performance, good heat insulation performance and sufficient water supply and the like, can be used for seawater desalination, and has the advantages of high evaporation rate, high energy conversion efficiency, salt precipitation prevention and the like.

The invention provides an aerogel film with a continuous gradient pore structure and a preparation method and application thereof.The preparation method comprises the steps that a pre-crosslinking solution containing a polymer nanofiber suspension, a sodium alginate solution, a polyethyleneimine aqueous solution and a crosslinking agent is sprayed to a temperature-conducting substrate with the initial temperature ranging from-20 DEG C to-15 DEG C at high pressure; and freeze-drying to obtain the aerogel film with the continuous gradient pore structure. The aperture of the aerogel film is gradually increased from bottom to top, and the range of the aperture is mainly 1-110 [mu] m. The aerogel film is placed in a filter membrane clamp, so that a solution to be filtered passes through the aerogel film according to the sequence of'macropore-mesopore-micropore ', the aerogel film is used for intercepting and recycling particles with different sizes, such as micro-plastics, and high water flux and high rejection rate are both considered. The pore size of the aerogel film can be changed by adjusting the temperature of the temperature-conducting substrate; the prepared aerogel film improves the trade-off effect in the existing filtration separation technology, and has a wide market prospect.

The invention relates to the technical field of synthesis of organic compounds, and discloses a dibenzoylmethane preparation method, which comprises the following steps: preparation of a functionalized ionic liquid, preparation of a deep eutectic solvent, construction of a composite system, implementation of a condensation reaction, regeneration of catalytic active sites, pH adjustment, crystal separation and the like. According to the method, a temperature-responsive two-phase system formed by the functionalized ionic liquid and the deep eutectic solvent is combined with a catalyst regeneration process and a pH regulation crystallization separation technology, so that the greenization, high efficiency and integration of the dibenzoylmethane synthesis process are realized, the product purity and yield are remarkably improved, and the environmental pollution and the production cost are reduced.

The utility model provides a BOG (Boil Off Gas) dehydrogenation system, which belongs to the technical field of gas separation and comprises a dehydrogenation device, the dehydrogenation device is connected with a mixed gas source unit and a circulating heat exchange medium unit, and one end, far away from the mixed gas source unit, of the dehydrogenation device is connected with a dehydrogenation mixed gas unit; the dehydrogenation device comprises a heat exchange box body, a plurality of hydrogen storage alloy tank bodies are arranged in the heat exchange box body, each hydrogen storage alloy tank body is connected with a mixed gas inlet and a mixed gas outlet, the mixed gas inlet is connected with a mixed gas source unit, and the mixed gas outlet is connected with a dehydrogenation mixed gas unit; the BOG gas dehydrogenation system further comprises a control system, and the control system is connected with the dehydrogenation device. According to the BOG dehydrogenation system disclosed by the utility model, the purpose of hydrogen separation is achieved by adopting reversible reaction of hydrogen storage alloy and hydrogen adsorption, the process is carried out under the conditions of normal temperature and low pressure, and compared with the existing methods of low-temperature separation, high-pressure adsorption and the like, the energy consumption is greatly reduced, and energy conservation and emission reduction are facilitated.

The invention discloses a preparation method and application of a tobacco source aroma raw material rich in micromolecular aroma components, and the preparation method comprises the following steps: crushing and sieving tobacco leaves, adopting a 40% ethanol solution as a solvent, and carrying out long-time extraction and vacuum concentration under proper conditions to prepare a tobacco extract with set baume degree; the method comprises the following steps: unfreezing, activating and culturing a Wickerham LY13 strain to obtain a high-activity bacterial solution; inoculating the bacterial liquid into the tobacco extract, fermenting under a controlled condition, and enhancing the aroma components in a biotransformation manner; after fermentation is completed, fragrance components in different molecular weight ranges are finely separated out through a high-temperature sterilization and multi-stage membrane separation technology; the four groups of separated permeate liquid are used as the tobacco source flavor raw materials to be added into cigarettes, sensory evaluation is carried out, and the result shows that after the tobacco source flavor raw materials prepared through the method are applied to the cigarettes, the sensory quality of the cigarettes can be remarkably improved, and the effects of coordinating the tobacco flavor, increasing the smoke concentration, improving the aftertaste and the like are achieved.

The invention relates to the technical field of separation, and discloses a molecular sieve separation system for medical oxygen production, which comprises an adsorption separation group, a fluid control valve group, a pressure monitoring unit and a self-adaptive control center, the self-adaptive control center executes capacity locking logic and regeneration clamping logic based on fluid impedance fingerprint characteristics, monitoring the actual pressurizing duration of the adsorption pressurizing stage in real time, calculating a deviation value between the actual pressurizing duration and the reference adsorption duration, and generating a primary switching instruction; meanwhile, the real-time residual desorption pressure of the other adsorption bed layer is obtained and compared with a regeneration end point pressure threshold value, a final step sequence switching instruction is output when the conditions are met, and self-adaptive locking of the real adsorption capacity of the molecular sieve is achieved by recognizing the adsorption capacity saturation characteristics and decoupling gas source fluctuation.

The invention relates to the technical field of fine separation in fluorine chemical industry, in particular to a method and a system for purifying thionyl fluoride by combining multi-stage rectification and adsorption. The method comprises the following steps: carrying out heat exchange on raw material gas, feeding the raw material gas into a first-stage rectifying tower, carrying out primary separation, removing low-boiling impurities, feeding the raw material gas into a second-stage rectifying tower, carrying out further purification, condensing the rectified high-purity gas into a liquid crude product, and carrying out deep impurity removal through a mixed adsorbent fixed bed to finally obtain a thionyl fluoride product with the purity higher than 99.999%. The system comprises a raw material gas feeding unit, a two-stage rectifying tower, a condenser, an adsorption device and a product storage tank, modules are sequentially connected, and the system is provided with a temperature and pressure control and anti-corrosion structure and is suitable for industrial purification production of continuous high-purity thionyl fluoride.

The invention discloses an acid-resistant nanofiltration membrane and a preparation method thereof, and belongs to the technical field of membrane separation. The gradient heterojunction active layer is formed on the base film through sequential interfacial polymerization and comprises a polysulfonamide bottom layer adjacent to the base film and a polyamine-metal organic framework composite layer located on the polysulfonamide bottom layer; the gradient heterojunction active layer is coated with the pH response self-repairing layer, and the self-repairing layer comprises pH response type microcapsules dispersed in cross-linked polyvinyl alcohol hydrogel; the membrane has excellent self-repairing capability and maintenance convenience, the repairing efficiency of artificial microcosmic damage in an acid environment within 24 hours can reach 85% or above, tiny scratches and defects generated in the operation or installation process of the membrane can be automatically repaired, the failure of the whole membrane element caused by tiny damage expansion is avoided, and the service life of the membrane element is prolonged. And the unplanned shutdown risk and the special repair and maintenance cost are reduced.

The application provides a preparation method of a functionalized phage probe and application of the functionalized phage probe in detection of escherichia coli. The functionalized phage is a recombinant phage (M13KO7@SaBP) in which streptavidin binding peptide (SaBP) is fused and expressed at the N terminal of the main capsid protein P8 protein of M13K07 phage. In the application, the gene encoding SaBP (MDVEAWLGAR) is inserted into the N terminal of the P8 protein gene of M13K07 phage by site-directed mutagenesis to prepare M13K07@SaBP. The stable signal amplification is realized by using the abundant P8 protein (about 2700) of M13 phage and the super strong binding force of biotin-streptavidin, the interference of food sample matrix is reduced by combining the magnetic separation technology, and a detection method of escherichia coli with high sensitivity and small sample matrix interference is constructed.