The invention relates to an SCWO (supercritical water oxidation) reaction control system. The SCWO reaction control system comprises an oxidizing agent conveying pipeline, a fuel conveying pipeline, a material conveying pipeline, a reactor, a gaseous product discharge unit, a liquid product discharge unit and a control unit, wherein the control unit comprises sensors, field execution components, controllers and an upper computer, the field execution components are connected with the controllers through input and output modules, and the sensors, the controllers and the upper computer are in signal connection through a communication protocol; the sensors and the field execution components are arranged on the oxidizing agent conveying pipeline, the fuel conveying pipeline, the material conveying pipeline, the reactor, the gaseous product discharge unit and the liquid product discharge unit. The control unit is used for realizing the control processes such as starting, stopping, emergency stop, temperature adjustment, pressure adjustment and the like of the system, system operation data can be effectively acquired, stored and analyzed, reliable basis is provided for process adjustment and optimization, and necessary conditions are provided for stable, safe and reliable operation of the system.