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8908results about How to "Improve reaction efficiency" patented technology

Method for removing organic matters in water by utilizing three-dimensional electrode electro-fenton and device thereof

The invention relates to a method for carrying out oxidation treatment on organic waste water by utilizing a three-dimensional electrode electro-fenton and a device thereof. The device comprises a reactor shell, a carbon material cathode, an iron plate anode, a three-dimensional particle electrode of a fixed bed, a direct-current voltage-stabilizing power supply, a microporous aeration plate and an air pump, wherein a reactor consists of a reaction chamber and a gas chamber; the carbon material cathode, the iron plate anode and the particle electrode are positioned in the reaction chamber at the upper part of the reactor; and the gas chamber is formed between the bottom of the reactor and the microporous aeration plate. After direct current is introduced, the iron anode is oxidized to generate iron ions, oxygen in the gas chamber is reduced on the surface of the cathode to generate hydrogen peroxide, and the iron ions and the hydrogen peroxide form a fenton reagent to oxidize and remove organic matters in waste water; and simultaneously, due to the particle electrode, the contact area and the contact time of the waste water and the fenton reagent are increased, and the mass transfer effect of the waste water in the reactor is reduced. The invention is applicable to treatment of various types of organic waste water, the equipment is compact, the operation is easy, the whole reactor is easy to control, and the requirements of an actual water treatment unit are met.
Owner:HUAZHONG NORMAL UNIV

Method for undergoing chlorobenzene nitration reaction by using micro-channel reactor

The invention relates to a method for undergoing a chlorobenzene nitration reaction by using a micro-channel reactor, belonging to the technical field of application of organic synthesis. In the method, nitric acid, sulfuric acid, water and chlorobenzene are taken as initial reaction raw materials, and processes such as mixed acid preparation, mixed acid and chlorobenzene preheating, mixed acid and chlorobenzene reacting and the like are completed in a micro-channel reactor system. In the reaction, nitro-sulfuric mixed acid is taken as a nitrating agent, the effective concentration of sulfuric acid in the mixed acid is 50-90 percent, the molar ratio of the nitric acid to the sulfuric acid in the mixed acid is 1:1-1:10, the molar ratio of the chlorobenzene to the nitric acid is 1:1.0-1:2.0, the reaction temperature is 50-100 DEG C, and the reaction time is 30-120 seconds. The chlorobenzene transformation ratio is up to 97 percent, the selectivity of nitrochlorobenzene serving as a product is over 96.5 percent, and the ratio of ortho-para nitrochlorobenzene is over 0.6. A strengthened mixed micro-channel reactor adopted in the invention is particularly suitable for undergoing a continuous nitration reaction, and has the characteristics of stable temperature control and safe process.
Owner:CHANGZHOU UNIV

Multi-component oxidation micro-electrolytic filler and preparation method thereof

The invention belongs to the technical field of environmental engineering wastewater treatment, and particularly relates to multi-component oxidized micro-electrolysis filler and a preparation method thereof. The multi-component oxidized micro-electrolysis filler is mainly prepared from the following components in percentage by mass: 50-60% of iron, 20-30% of activated carbon, 12-15% of adhesive and 3-5% of catalyst through mixing, wherein iron is iron scrap or iron powder with particle size not more than 80 mesh; and activated carbon is in a powder and has particle size not more than 100 mesh. The preparation method of the multi-component oxidized micro-electrolysis filler comprises uniformly mixing iron, activated carbon, the adhesive and the catalyst according to the ratio, adding water, stirring and aging, then carrying out extrusion molding to obtain molded filler, demolding to obtain a filler blank, after naturally drying, drying, sintering in the absence of air, and cooling thefiller blank to obtain the multi-component oxidized electrolysis filler. According to the invention, the hardening, dead pool, stoppage and other practical problems existing in the use of the traditional micro-electrolysis fillers are solved.
Owner:CHINA COAL TECH & ENG GRP HANGZHOU ENVIRONMENTAL PROTECTION INST

Method for producing MnO2 supported catalyst as well as method of using the same and apparatus for treating waste water

The invention discloses a method for preparing MnO2 supported catalysts, an application method thereof and a wastewater treatment device. The preparation method comprises the following steps: manganese acetate is prepared into a solution; one of activated carbon, active aluminium sesquioxide, white silica gel, a molecular sieve, zeolite or diatomite is taken as a carrier and dipped in the solution; and supported solid catalysts are prepared through dipping, evaporation, concentration, drying and roasting. A reactor of the wastewater treatment device is divided into a plurality of reaction spaces by baffles, and the catalysts exist as fluidized beds on every baffle. When the MnO2 supported catalysts prepared by the method are used in the reaction of degrading refractory organic matter through ozone catalytic oxidation, the contact time among the MnO2 supported catalysts, wastewater and ozone is between10 and 120 minutes, and the mass ratio of the adding amount of the catalysts to the wastewater in the reaction is between 1 to 200 and 1 to 20. The MnO2 supported catalysts prepared by the method have the characteristics of easy recovery, high repeat utilization property and high efficiency of catalyzing and degrading refractory organic matters.
Owner:GUANGDONG UNIV OF TECH

Surface modification method for carbon nano tube

The invention provides a surface modification method for a carbon nano tube and belongs to the field of nanotechnology. The method includes step one, uniformly mixing a carbon nano tube which is subjected to acidification by a strong oxidizing acid with a silane coupling agent and deionized water, reacting under a certain condition, filtering, washing, and drying to obtain a primary modified carbon nano tube; step two, uniformly mixing the primary modified carbon nano tube with polyhydric alcohols and a concentrated sulfuric acid, reacting under a certain condition, filtering, washing to neutral, and drying to obtain a secondary modified carbon nano tube; uniformly mixing the secondary modified carbon nano tube with an organic carboxylic acid, an esterification reaction catalyst and N,N-dimethylformamide, reacting under a certain condition by the aid of the protection of inert gases, cooling to the room temperature, filtering, washing, and drying to obtain the surface modification carbon nano tube. When the prepared modified carbon nano tube which is provided with ester groups on the surface is mixed with a polyester resin, the interface-free mixing is achieved, and the heat stability and the mechanical property of the modified polyester resin can be improved.
Owner:TAIYUAN UNIV OF TECH

Organic wastewater treatment film reactor utilizing sunlight-assisted electro-catalysis

InactiveCN102603037AAccelerated adsorption/desorption rateThe actual user interface increasesWater/sewage treatment by irradiationEnergy based wastewater treatmentPhoto assistedPorous channel
The invention relates to an organic wastewater treatment film reactor utilizing solar energy photo-assisted electro-catalysis, which comprises a storage tank of water to be processed, a flow controllable constant flow pump, a photoelectric chemical reactor, a clear water storage tank and a solar battery component, wherein a photo anode and a cathode are correspondingly arranged in the reactor; the photo anode takes a porous metal membrane as a base body, and a TiO2 nano tube or a TiO2 mesoporous membrane is formed on the surface of a porous titanium membrane (net) by an electrochemical anisotropic etching technology; a porous channel film is used as the base body; a metal oxide coating electrode with high electrochemical catalytic activity and high electrical conductivity is prepared by a dipping film-forming method, simultaneously, by doping and modifying operations, the electrode material has photo catalytic activity and the reaction efficiency is improved. The reactor integrates electrochemistry, photocatalysis and film separation technologies; the three technologies are coupled to enhance a synergistic effect; the wastewater treatment efficiency can be improved; a solar component is adopted as a power supply; the clean solar energy is utilized to the maximal degree, and the organic wastewater treatment film reactor has social benefits of reducing environment load and economic benefits of reducing cost.
Owner:NANJING UNIV OF TECH

Method for preparing catalyst for treating high-concentration organic wastewater through catalytic oxidation

The invention discloses a method for preparing a catalyst for treating high-concentration organic wastewater through catalytic oxidation, which comprises the following steps: 1) drying a cocoanut active charcoal at a temperature of between 100 and 120 DEG C for 8 to 15 hours, taking out and adding the cocoanut active charcoal into 2 to 10 percent sulfuric acid solution to perform soakage for 12 to 36 hours, adding the cocoanut active charcoal into a 1 to 10 percent oxydol solution to perform soakage for 12 to 36 hours, taking the cocoanut active charcoal out, and draying the cocoanut active charcoal in shade to obtain an activated charcoal for standby; and 2) soaking constant volume of the activated charcoal into transition metal salt solution for 12 to 36 hours, drying the activated charcoal at a temperature of between 100 and 120 DEG C for 8 to 15 hours, and calcining the activated charcoal at a temperature of between 300 and 650 DEG C for 3 to 8 hours to obtain the catalyst for treating the high-concentration organic wastewater through the catalytic oxidation. The service life of an active charcoal catalyst bed prepared by the method can reach over 0.5 to 1 year. After the treatment of the wastewater, compared with a Fenton reagent, the treatment efficiency of the catalyst is improved obviously, and the treatment cost is reduced by about 20 percent.
Owner:ENVIRONMENTAL SCI RES & DESIGN INST OF ZHEJIANG PROVINCE

Method and device for removing organic matters from water by using double-pool double-effect visible light in response to photo-electro-Fenton reaction

The invention discloses a method and a device for removing organic matters from water by using double-pool double-effect visible light in response to a photo-electro-Fenton reaction. The device comprises a cathode pool, an anode pool, a saturated potassium chloride (KCl) salt bridge, a visible light response semiconductor membrane material anode, a carbon-iron composite material oxygen negative electrode, an air pump, a magnetic stirrer, a direct current stabilized voltage power supply and a visible light source, wherein an anode performs photoelectrocatalysis under the actions of visible light and anode bias voltage to remove organic pollutants from water; the carbon-iron composite material oxygen negative electrode performs cathode potential reduction on O2 under the conditions of external voltage and introduced air to produce hydrogen peroxide which is subjected to an electric Fenton reaction to generate active substances such as hydroxyl radicals and the like capable of effectively removing the organic matters from the water; electrons produced by a photoanode migrate towards an oxygen cathode under the action of anode bias voltage; the O2 is reduced by the electrons on the cathode to generate more H2O2; and the H2O2 produced on the cathode cannot migrate to the anode pool for consumption, so that higher H2O2 concentration is ensured, and the oxidation reaction of the organic matters by electric Fenton is ensured. The method and the device are suitable for treating various types of organic waste water.
Owner:HUAZHONG NORMAL UNIV

High-efficiency intelligent aerobic fermentation reaction system and method

The invention discloses an aerobic fermentation reaction system and method. The high-efficiency intelligent aerobic fermentation reaction system comprises an aerobic fermentation reactor, a circular water system, a gas intake and exhaust system, a detection system and a control system, wherein a water jacket is arranged outside a horizontal roller of the aerobic fermentation reactor; a material feeding and discharging hole and a gas intake and exhaust hole are respectively formed in sealing covers at two sides of the horizontal roller; the circular water system is connected and communicated with the water jacket on the horizontal roller; the gas intake and exhaust system is connected and communicated with the gas intake and exhaust hole in the sealing cover of the horizontal roller; a sensor of the detection system is arranged in the aerobic fermentation reactor and on a water passing pipe of the aerobic fermentation reactor; a signal output by the sensor is respectively connected with the control system; and the control system is used for controlling the circular water system, the gas intake and exhaust system, the aerobic fermentation reactor and external feeding and discharging conveying equipment. According to the high-efficiency intelligent aerobic fermentation reaction system and method disclosed by the invention, the occupied area is smaller and the fermentation efficiency is higher; no secondary pollution occurs; and the reduction, harmlessness and resourceful treatment of organic wastes can be quickly realized.
Owner:HUNAN SAKAL ENVIRONMENTAL SCI & TECH CO LTD +1
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