The invention discloses a preparation method of
carbon nanofiber loaded
platinum-based nanoparticles, which comprises the following steps: 1, heating N, N-
dimethylformamide, adding
polyacrylonitrile, and stirring to form a solution; 2, adding
chloroplatinic acid hexahydrate,
nickel nitrate hexahydrate and
triphenylphosphine into the solution, and stirring to obtain a precursor solution; 3, performing electrostatic
spinning on the precursor solution to obtain a fibrous precursor; 4, freeze-
drying the fibrous precursor; and 5, carrying out
pyrolysis reduction on the freeze-dried fibrous precursor. The
carbon nanofiber loaded
platinum-based nano-particles are prepared by adopting a method of combining electrostatic
spinning with high-temperature
pyrolysis, the carrier with high specific surface area and rich pore structures is obtained, the interaction between the carrier and the
platinum-based
alloy nano-particles is enhanced, rich catalytic active sites are generated, and the catalytic activity of the platinum-based
alloy nano-particles is improved. The
oxygen reduction reaction electrocatalytic activity and stability of the PtNi-coated PNCF are improved, and the PtNi-coated PNCF is suitable for being used as an
oxygen reduction reaction
electrocatalyst of a fuel
cell.