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433 results about "Amino functionalized" patented technology

Single-walled carbon nanotubes (SWCNT) functionalized with amino groups were prepared via chemical modification of carboxyl groups introduced on the carbon nanotube surface. Two different approaches (amide and amine-moieties) were used to produce the amino-functionalized nanotubes.

Amino-functional polysiloxanes and their use in coatings

InactiveUS20050148752A1Good gloss retentionImproved mechanical cohesive strengthEpoxy resin coatingsEpoxyPolymer science
The present invention relates to an amino-functional polysiloxane of formula (1) where each R1 is independently selected from alkyl or aryl radicals, each R2 is independently selected from hydrogen, alkyl or aryl radicals, n is selected so that the molecular weight for the functional polysiloxane is in the range of from 400 to 10,000 and R3 is a bivalent radical or —O—R3—NH—R5 is hydroxy or alkoxy, and R5 is selected from hydrogen, aminoalkyl, aminoalkenyl, aminoaryl, aminocycloalkyl radical, optionally substituted by alkyl, aryl, cycloalkyl, halogen, hydroxy, alkoxy, thioalkyl, amino, amino derivatives, amido, amidoxy, nitro, cyano, keto, acyl derivatives, acyloxy derivatives, carboxy, ester, ether, esteroxy, heterocycle, alkenyl or alkynyl and where 0 to 90% of —O—R3—NH—R5 is hydroxy or alkoxy. The present invention further relates to an epoxy-polysiloxane composition which includes an aminopolysiloxane hardener component or an amino-functional polysiloxane hardener component of formula (1), having active hydrogens able to react with epoxy groups in an epoxy resin to form epoxy polymers, and able to react with a polysiloxane to form polysiloxane polymers, wherein the epoxy chain polymers and polysiloxane polymers polymerize to form a cured epoxy-polysiloxane polymer composition.
Owner:SIGMAKALON SERVICES BV

Reverse osmosis composite membrane and preparation method thereof

The invention relates to spherical monodisperse amino functionalized mesoporous SiO2 nano particles and a reverse osmosis composite membrane prepared from the mesoporous SiO2 nano particles. An organic group functionalized mesoporous SiO2 material contained in the reverse osmosis composite membrane breakthroughs the limitation of a zeolite molecular sieve which has under-sized aperture, and the aperture is widened to the mesoporous field from the microporous field; and organic groups in the material can react with organic monomer molecules in the process of interfacial polymerization so that a molecular sieve can be firmly introduced into the membrane in a manner of chemical bonding. The invention provides a new design scheme for the development of the high-performance reverse osmosis composite membrane. The organic group functionalized mesoporous SiO2 material can be designed individually and the organic groups in the material can be selected according to the requirement of the organic monomer molecules in the polymerization process. On one hand, the molecular sieve can be firmly introduced into the membrane; and on the other hand, the molecular sieve is endowed with different properties by different organic groups and the application scope of the reverse osmosis composite membrane can be widened.
Owner:OCEAN UNIV OF CHINA

Mesoporous nano silicon ball compound targeting drug delivery system as well as preparation method and application thereof

The invention relates to a mesoporous nano silicon ball compound targeting drug delivery system as well as a preparation method and application thereof. The preparation method of the mesoporous nano silicon ball compound targeting drug delivery system comprises the following steps: 1) preparing amino-functionalized drug loading mesoporous silicon dioxide microspheres; 2) preparing hyaluronic acid-hydrosulphonyl polypeptide-adriamycin (HA-RGD-DOX); 3) preparing mesoporous microsphere-hyaluronic acid-hydrosulphonyl polypeptide-adriamycin--paclitaxel (MSNs-HA-RGD-DOX_PTX); and 4) preparing fluorescent marker modified mesoporous microsphere-hyaluronic acid-hydrosulphonyl polypeptide-adriamycin--paclitaxel compound (MSNs-HA-RGD-DOX-PTX). The mesoporous nano silicon ball compound targeting drug delivery system has the beneficial effects that firstly multi-targeting synergistic drug delivery is realized, multiple tumour cells and tissues can be killed, and reversal drug resistance is good; secondly, blood stability is excellent; thirdly, invisibility, drug release degree and controlled release properties are good; fourthly, in vivo tracing function is good; and fifthly, the mesoporous nano silicon ball compound targeting drug delivery system has good general applicability.
Owner:WUHAN UNIV OF TECH

Ionic liquid modified positively charged composite nanofiltration membrane and preparation method thereof

The invention discloses an ionic liquid modified positively charged composite nanofiltration membrane and a preparation method thereof. The preparation method comprises the following steps: on a supporting bottom film, firstly, carrying out interfacial polymerization on polyamine and polyacyl chloride to form a primary polyamide layer, and then carrying out an amidation reaction on acyl chloride groups remaining on the surface of the primary polyamide layer and amino functionalized ionic liquid to prepare the composite film. The preparation method comprises the following steps: (1) preparing apolyamine aqueous phase solution and a polyacyl chloride organic phase solution; (2) carrying out interfacial polymerization on the surface of the bottom film to prepare a primary polyamide nanofiltration membrane; and (3) reacting the amino-functionalized ionic liquid solution with acyl chloride groups on the surface of the primary polyamide layer, and carrying out heat treatment to obtain the positively charged composite nanofiltration membrane. By changing the charge property of the composite membrane, lithium resources in the salt lake brine with a high magnesium-lithium ratio can be effectively extracted, the magnesium-lithium separation factor of the composite membrane is lower than 0.15, and the flux is 40-50L/m<2>h. The method has the advantages that the preparation method is simple, and the method has a good industrial application prospect in the aspect of salt lake lithium extraction.
Owner:TSINGHUA UNIV

Tea solid phase extraction column and sample pretreatment method for testing pesticide residues in tea leaves

The invention relates to a tea solid phase extraction column and a sample pretreatment method for testing pesticide residues in tea leaves. The tea solid phase extraction column comprises a column pipe and filler in the column pipe, wherein, the filler comprises the following components: 2 to 10 parts of carbon material, 2 to 10 parts of amino-group functionalized adsorbent material and 1 part of polar functional group modified high-polymer materials; the carbon filler is filled in the bottom layer of the column pipe; the amino-group functionalized adsorbent material and the polar functional group modified polymer materials are mixedly filled in the upper layer of the column pipe and a polypropylene sieve plate is provided between the two layers for separation. The invention also discloses a sample pretreatment method for testing pesticide residues in tea leaves. By utilizing the tea solid phase extraction column in sample pretreatment, the pesticide and the metabolite in hundreds of kinds of tea such as black tea, green tea, scented tea, puerh tea can be analyzed and detected, and 653 kinds of pesticide residues can be extracted and purified through sample treatment for once. Therefore, the tea solid phase extraction column and the sample pretreatment method for testing pesticide residues in tea leaves is speedy, economical and is high in universality.
Owner:天津博纳艾杰尔科技有限公司

Protein molecular imprinting polyion liquid membrane electrochemical transducer

The invention relates to the technical field of electro-analytical chemistry and protein identification transducers, and discloses a synthesizing method of functionalized ionic liquid and a preparation method and application of a molecular imprinting electrochemical transducer composed of the functionalized ionic liquid, carboxylation multiwalled carbon nanotubes and glassy carbon electrodes. The preparation method of the molecular imprinting electrochemical transducer comprises the steps that the polymerizable amino-functionalized ionic liquid is used as a functional monomer, BSA is used as template protein, N, N'-methylene bisacrylamide is used as a cross-linking agent, an oxidation-reduction system composed of ammonium persulfate and TEMED is used as an initiator, after polymerization, a molecularly imprinted polymer film is formed on the surfaces of the glassy carbon electrodes decorating the carboxylation multiwalled carbon nanotubes, and then the template protein is eluted to obtain the molecular imprinting electrochemical transducer which can identify template protein in a specific mode. The molecular imprinting electrochemical transducer has the advantages of being simple in preparation, low in material cost, high in selectivity, good in biocompatibility, and capable of being used for identifying and detecting protein in aqueous solution.
Owner:SOUTH CENTRAL UNIVERSITY FOR NATIONALITIES

Preparation method and adsorption method of Ni<2+> adsorbent

The invention discloses a preparation method and an adsorption method of a Ni<2+> adsorbent. The method comprises the following steps: (1) with tetraethoxysilane as a silicon source and triblock copolymer (P123, EO20PO70EO20) as a template agent, synthesizing a silica-based mesoporous material SBA-15, and modifying the inner surface of the silica-based mesoporous material SBA-15 with 3-aminopropyl triethoxy silane (APTES) through an alkyl coupling method to obtain an amino functionalized silica-based mesoporous material NH2-SBA-15; (2) grafting amino acid onto NH2-SBA-15 by a post-transplantation method to obtain the amino acid modified silica-based mesoporous material, namely, the adsorbent; (3) regulating the pH value of the adsorbent to 3-5 by virtue of a water solution containing Ni<2+>, and feeding the adsorbent to adsorb Ni<2+> in a water body, wherein the mass ratio of the adsorbent to Ni<2+> in the water body is 5:1 to 8:1, the adsorption temperature is 20-30 DEG.C, and the adsorption time is 10-30 minutes. The adsorbent preparation method is high in operability and good in reproducibility, the obtained amino acid modified silica-based mesoporous material has a good removal effect for heavy metal ions, Ni<2+>, in a water body, the equilibrium adsorption capacity of the adsorbent reaches up to 60mg.g<-1> above, and thus the actual application value of the adsorbent is good.
Owner:常熟紫金知识产权服务有限公司

A green synthesis method for carbon quantum dot bonded silica gel chromatography filler

This invention has discloses a green synthesis method for carbon quantum dot bonded silica gel chromatography filler, which comprises the concrete steps of: mixing the solid powder of aconitic acid and tryptophan to be ground evenly, letting the mixture react under the temperature of 180oC- 200oC for 3 - 6 hours. Through dissolution, centrifugation and freeze drying of the generated solid, the amino-functionalized carbon quantum dots (NCDs) are obtained; After that, NCDs are dispersed in DES and added with gamma-glycidoxypropyl trimethoxy siloxane(GPTMS). Under the protection of N2 and the temperature of 55oC- 65oC, the mixture is stirred to react for 22 - 25 hours, then the silica gel (SiO2) is added to react for another 12 - 48 hours. Water and absolute ethyl alcohol are alternatively used to wash the raw product generated from the reaction. Silica gel chromatography filler modified by carbon quantum dots will be generated after drying. This green synthesis method realizes the surface bond of carbon quantum dots and silica gel through epoxy group and amino. DES used in the process of reaction is reaction solvent, which serves as an excellent dispersing agent for carbon quantum dots and silica gel, ensures higher bonded amount, and at the same time, meets the requirements of green chemistry.
Owner:LANZHOU INST OF CHEM PHYSICS CHINESE ACAD OF SCI
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