1579 results about "Silicic acid" patented technology

The invention discloses a fluoride salt-free nitrate-free cast iron enamel semitransparent glaze as well as a preparation method and application thereof, and belongs to the technical field of enamel. The semitransparent glaze is prepared from quartz, anhydrous borax, sodium carbonate, potassium carbonate, calcium carbonate, potassium feldspar, zinc oxide, lithium carbonate, zirconium silicate, titanium dioxide, aluminum oxide, trisodium phosphate, antimony oxide, magnesium carbonate and barium carbonate according to a specific mass ratio. The preparation method comprises the steps of raw material mixing, high-temperature melting under a pure oxygen condition, wiredrawing detection, quenching and the like. The semitransparent glaze is completely free of fluoride salt and nitrate, the problems of fluoride emission and environmental protection equipment blockage are avoided from the source, the fluorine content of the product is not detected through detection, the product meets the requirements of European Union REACH regulations, meanwhile, the product has good porcelain surface, luster and low-temperature firing adaptability, and is suitable for cast iron matrixes, the firing temperature is 740-760 DEG C, and the firing time is 2-3 hours. The method can be used for producing green and environment-friendly enamel products.

The invention relates to a high-stability bronze powder pigment and a preparation method and application thereof.The preparation method comprises the following steps that copper-zinc alloy coarse powder, stearic acid and a dissolved compound passivator are taken and subjected to ball milling in the nitrogen atmosphere, and a ball milling product is screened, washed and subjected to suction filtration to obtain an amino-functionalized passivated base material; the preparation method comprises the following steps: dispersing SiO2 in anhydrous isopropanol to obtain a reaction system, adding deionized water and a catalyst, dissolving tetraethoxysilane and phenyltriethoxysilane in anhydrous isopropanol, slowly dropwise adding, carrying out a heat preservation reaction, and carrying out suction filtration and washing to obtain a phenyl modified SiO2 coated intermediate; the preparation method comprises the following steps: dispersing a compound stabilizer in anhydrous isopropanol to obtain a mixed system, heating and stirring, dissolving the compound stabilizer in anhydrous isopropanol, dropwise adding into the mixed system, reacting, centrifuging, washing, and drying in vacuum to obtain the bronze powder pigment. The bronze powder pigment disclosed by the invention has excellent oxidation resistance, chemical corrosion resistance and long-term storage stability, and can keep the natural color gloss of metal to the greatest extent.

The invention belongs to the technical field of nanocrystal nucleus early strength agents, and provides a damp and hot nanocrystal nucleus early strength agent, a tailing solidification filling material and a preparation method and application of the damp and hot nanocrystal nucleus early strength agent and the tailing solidification filling material. The invention discloses a molybdenum ore tailing slurry which is prepared from the following raw materials in parts by weight: 1 part of Portland cement, 4 to 6 parts of molybdenum ore tailings, 0.06 to 0.1 part of zeolite powder, 0.07 to 0.1 part of nanoscale attapulgite powder, 0.06 to 0.1 part of gamma-glycidyl ether oxypropyl trimethoxy silane, 0.03 to 0.1 part of potassium silicate, 0.04 to 0.1 part of sodium hydroxide, 0.06 to 0.1 part of calcium formate, 0.04 to 0.1 part of lithium metaaluminate and 1.25 to 1.75 parts of water. According to the technical scheme, the problem that a filling body prepared from an early strength agent in the prior art is low in early and later strength is solved, and meanwhile, the early strength agent is simple and convenient in preparation mode, low in cost and wide in application range.

The invention discloses an aluminum substrate UV matt finish paint and a preparation process thereof, and relates to the technical field of paints.The aluminum substrate UV matt finish paint is prepared from, by mass, 10%-20% of modified polyurethane acrylate, 25%-32% of high-functionality aliphatic polyurethane acrylate, 18%-30% of special modified epoxy acrylate resin, 0.5%-2% of dispersing agent, 0.1%-0.5% of defoaming agent, 1%-3% of anti-settling powder and the balance water. The paint is prepared from the following components in percentage by weight: 10 to 15 percent of magnesium silicate mineral, 1 to 10 percent of matting powder, 0.2 to 1 percent of 1-hydroxycyclohexyl phenyl ketone, 0.5 to 3 percent of trimethylbenzoyl-diphenyl phosphine oxide, 1 to 3 percent of acrylate flatting agent, 0.2 to 1.2 percent of polyurea modified polyurethane rheological agent and 5 to 15 percent of trimethylolpropane triacrylate. According to the UV matte finishing paint disclosed by the invention, through compounding of ternary resin and enhancement of nano silicon dioxide, a rigid and tough cross-linked network is constructed, a paint film is free of cracks when being bent at 180 degrees, the adhesive force reaches grade 0, and a coating is resistant to acid and alkali etching liquid and free of corrosion by cooperating with a silane coupling agent and a light stabilization system, and the color difference is delta Elt after the UV matte finishing paint is subjected to high temperature of 260 DEG C; and 1.5, the anti-yellowing performance is excellent.

The invention discloses fluoride salt-free and nitrate-free low-temperature matte glaze for steel plate enamel as well as a preparation method and application of the low-temperature matte glaze, and belongs to the technical field of enamel. The matte glaze is prepared from quartz, borax pentahydrate, sodium carbonate, titanium dioxide, magnesium oxide, monopotassium phosphate, calcium carbonate, zinc oxide, magnesium carbonate, lithium carbonate, aluminum oxide and zirconium silicate according to a specific mass ratio. The preparation method comprises the following steps: mixing the raw materials, melting at 1300 + / -10 DEG C in a pure oxygen environment, and quenching after wiredrawing to detect a molten state. The matte glaze completely avoids the use of fluoride salt and nitrate, the problems of fluoride emission and environmental protection equipment blockage are eliminated from the source, the fluorine content of the product is not detected through detection, and the limit value requirements of European Union REACH regulations are met. Zinc oxide and ZnO / TiO2 are added, so that the liquid phase viscosity is reduced, ion diffusion is accelerated, and the opacity (opacification performance) and gloss of the porcelain glaze are enhanced.

The invention discloses a fluoride-salt-free and nitrate-free cast iron enamel zirconium white glaze as well as a preparation method and application thereof, and belongs to the technical field of enamel. The zirconium white glaze is prepared from quartz, borax pentahydrate, magnesium carbonate, potassium carbonate, potassium feldspar, zinc oxide, aluminum hydroxide, calcium carbonate, zirconium silicate, sodium tripolyphosphate and lithium carbonate according to a specific mass ratio. The preparation method comprises the steps of raw material mixing, high-temperature melting under a pure oxygen condition, wiredrawing detection, quenching and the like. The zirconium white glaze is completely free of fluoride salt and nitrate, the problems of fluoride emission and environmental protection equipment blockage are avoided from the source, the fluorine content of the product is not detected through detection, the product meets the requirements of European Union REACH regulations, and meanwhile, the zirconium white glaze has good porcelain surface, luster and firing adaptability, is suitable for cast iron matrixes, has the firing temperature of 740-760 DEG C and the firing time of 87-87 hours, and can be widely applied to cast iron substrates. The method can be used for producing green and environment-friendly enamel products.

The invention provides a multi-scale super-amphiphobic anti-wax coating and a preparation method thereof.The preparation method comprises the following steps that S1, cellulose nanofibers are added into an ethyl alcohol-water mixed solution, after ultrasonic treatment and uniform stirring are conducted, sodium methyl silicate is added for stirring reaction, then fluorosilane and tetraethoxysilane are added for hydrolytic condensation reaction, and a mixed solution is obtained; centrifuging and drying to obtain multi-scale fluorinated micro-nano particles; and S2, mixing the multi-scale fluorinated micro-nano particles, an adhesive and a diluent in proportion, performing ultrasonic stirring, spraying the mixture on a base material, and curing to obtain the multi-scale amphiphobic paraffin-proof coating. Hydrophobic modification is carried out on cellulose nanofibers by using fluorosilane, sodium methyl silicate and tetraethoxysilane to form a multi-scale micro-nano multilevel structure, and the structure can effectively capture air and is combined with ground surface energy, so that the coating has excellent super-amphiphobic performance.

The invention discloses a composite fiber membrane for hydrogen production and oxygen production through light-driven full water decomposition and a preparation method of the composite fiber membrane, and belongs to the technical field of photocatalysis technology and nano material preparation, and the composite fiber membrane shows excellent photothermal conversion performance in the reaction of hydrogen production and oxygen production through light-catalyzed water decomposition and also has efficient water transmission capacity. The stability and the reusability are relatively high. According to the preparation method, a Ti source compound, a Sr source compound, tetraethyl orthosilicate and a spinning solution are used as raw materials for electrostatic spinning, and after pre-oxidation and carbonization treatment at a certain temperature, the SrTiO3 / SiO2 composite carbon fiber membrane is obtained, and Cr2O3 / Rh and CoOOH cocatalysts are supported. The fiber membrane prepared by the invention has the function of photocatalytic water decomposition to produce hydrogen under the irradiation of sunlight, can stably produce hydrogen and oxygen in various water resources, is simple in process and low in cost, and can be widely applied to the fields of energy sources, environmental protection and the like.

The invention provides an aluminum oxide aerogel composite material as well as a preparation method and application thereof, and belongs to the technical field of aluminum oxide aerogel preparation. The preparation method provided by the invention comprises the following steps: (1) preparing aluminum sol by taking coal gangue as an aluminum source; (2) mixing the aluminum sol obtained in the step (1) with aluminum silicate fibers, and performing gelation to obtain composite hydrogel; and (3) mixing the composite hydrogel obtained in the step (2) with ethanol, aging, mixing with a modifier, modifying, and carrying out graded normal-pressure drying to obtain the aluminum oxide aerogel composite material, the modifier in the step (3) is one or more of absolute ethyl alcohol, tetraethoxysilane and normal hexane. The alumina aerogel composite material prepared by the preparation method provided by the invention has the characteristics of low density, low heat conductivity coefficient and high strength, and is suitable for the high-temperature processing field of special materials and the aerospace field.

The invention provides a recycled aggregate product, a preparation method thereof and recycled concrete, and belongs to the technical field of recycling of building materials. The preparation method of the recycled aggregate product comprises the following steps: S1, crushing waste concrete to obtain crushed concrete; then carrying out sorting treatment and magnetic separation treatment on the crushed concrete to obtain concrete subjected to impurity removal; the concrete subjected to impurity removal is screened, and initial recycled aggregate is obtained; s2, performing soaking treatment on the initial recycled aggregate by adopting strengthening liquid, and then performing dehydration treatment to obtain strengthened recycled aggregate; wherein the strengthening liquid is prepared from potassium silicate, vinyl acetate-ethylene copolymer emulsion, nanometer aluminum oxide, a dispersing agent and water; s3, calcining the reinforced recycled aggregate to obtain a recycled aggregate product. According to the preparation method, high-value utilization of the waste concrete can be achieved, and the obtained recycled aggregate product is excellent in performance.

The invention belongs to the technical field of carbon-coated lithium ferrous silicate, and discloses a preparation method and application of carbon-coated lithium ferrous silicate, the preparation method of carbon-coated lithium ferrous silicate comprises the following steps: S1, adding a surfactant into a silicon source to obtain a solution A; s2, sequentially adding an iron source and a lithium source into the solution A, and uniformly mixing to obtain a carbon-coated lithium ferrous silicate precursor; s3, carrying out high-temperature sintering on the carbon-coated lithium ferrous silicate precursor to obtain carbon-coated lithium ferrous silicate; the surfactant in the step S1 is a block type polyurethane surfactant, and a hydrophilic part structure in the block type polyurethane surfactant comprises polyethylene glycol PEG and 2, 2-dimethylolbutyric acid DMBA. According to the preparation method of the carbon-coated lithium ferrous silicate, the block type polyurethane surfactant is adopted in the step S1 and is not only used as a surfactant, but also used as a reducing agent and a carbon source, and a carbon coating layer of the prepared carbon-coated lithium ferrous silicate is uniform in thickness and excellent in electrochemical performance.

The invention relates to chemical-corrosion-resistant full-polished glaze as well as a preparation method and application thereof, and belongs to the technical field of ceramic production and manufacturing. The chemical-corrosion-resistant fully-polished glaze comprises the following mineral components in percentage by mass: 5%-10% of quartz, 5%-10% of kaolin, 1%-10% of calcined talc, 20%-25% of wollastonite, 10%-20% of calcined kaolin, 1%-5% of calcined alumina, 1%-5% of calcined zinc oxide, 1%-5% of barium carbonate, 1%-3% of titanium oxide, 1%-5% of zirconium silicate and 10%-20% of boron frit. By specially designing a full-polishing glaze formula of the ceramic tile, adjusting the firing temperature and discharging or reducing defects such as air holes in a glaze layer as much as possible, the glaze layer forms a stable inert surface, and chemical substances cannot react with the glaze layer or only slightly react with the glaze layer, so that the transparency, integrity and glossiness of the surface are kept.

The invention discloses a method for recovering high-purity fluorine and silicon from fluorine-silicon slag and co-producing a low-alkali fluorine-free accelerator, which comprises the following steps: S1, dissolving the fluorine-silicon slag in a sodium hydroxide solution to obtain a solution A; s2, adding dilute sulphuric acid into the solution A, reacting until gel is obtained, and filtering to obtain filtrate A and high-purity silicon dioxide gel; s3, adding calcium sulfate and EDTA (Ethylene Diamine Tetraacetic Acid) into the filtrate A, stirring and reacting, and filtering after the reaction is finished to obtain calcium fluoride and filtrate B; and S4, taking clear water, heating, carrying out heat preservation, then adding aluminum sulfate, lithium sulfate, diethanol amine and the filtrate B obtained in S3, continuously stirring until the aluminum sulfate is completely dissolved, then adding hydrated magnesium silicate, continuously carrying out heat preservation stirring, and obtaining the low-alkali fluorine-free accelerator after stirring is finished. The method is simple in process and easy to implement industrially, and fluoride and silicon oxide obtained through separation are high in purity and beneficial to follow-up extension application; more importantly, high-value recycling of the fluorosilicon slag is achieved, and the problems of stockpiling waste and environmental pollution of the fluorosilicon slag are solved.

The invention relates to the technical field of metal materials, in particular to a ceramic reinforced aluminum alloy composite material and a preparation method thereof. The aluminum alloy composite material comprises the following raw materials in parts by weight: 75-85 parts of an aluminum alloy matrix and 10-20 parts of a ceramic reinforced phase, a preparation method of the ceramic reinforced phase comprises the following steps: step 1, adding silicon carbide and a silane coupling agent into absolute ethyl alcohol, and drying after ultrasonic dispersion; 2, dissolving tetraethoxysilane in an ethanol-water mixed solvent, adjusting the pH value to 3-4, adding the silicon carbide treated in the step 1, stirring to form sol, drying, converting into gel, and calcining to form a coating layer; step 3, dispersing the silicon carbide treated in the step 2 into water, adding nickel nitrate, uniformly stirring, adding a reducing agent, stirring for reaction, and collecting precipitate particles; and 4, adding an interface modifier, and uniformly mixing. The ceramic reinforced aluminum alloy composite material has high strength, high wear resistance and good mechanical property and thermal stability.

The application relates to the technical field of cosmetics, in particular to a high-concealment makeup-maintaining air cushion and a preparation method thereof. A film forming agent in the high-concealment makeup-maintaining air cushion comprises the following: trimethylsiloxy silicate 5-7 parts, isododecane 0.3-0.7 parts, and acrylic acid (ester) / polymethyltrimethicone methacrylate copolymer 2-3 parts. A colorant comprises the following raw materials in parts by weight: titanium dioxide 5-7 parts, silica 0.8-1.2 parts, mica powder 5-7 parts, CI 77492 0.4-0.8 parts, aluminum hydroxide 0.8-1.2 parts, CI 77491 0.4-0.6 parts, triethoxyl octyl silane 0.8-1.2 parts, and CI 77499 0.3-0.5 parts. The particle size of the titanium dioxide at least comprises any two of 4 nm, 30-50 nm and 200-260 nm. The air cushion has the advantages of prolonging the makeup-maintaining time of the air cushion and improving the concealment effect.

The application discloses a kind of nano magnetic flocculants and its preparation method and application, belong to drinking water processing technical field, including the following steps: step S1, modified ferroferric oxide nanosphere is ultrasonically dispersed in ammonia alcohol solution, while stirring, slowly drop adding tetraethyl orthosilicate, continue stirring after drop, after centrifugal separation, wash, obtain silica coated ferroferric oxide nanoparticles;Step S2, phenylalanine modified chitosan is added into glacial acetic acid solution, after completely swelling and dissolving, add silica coated ferroferric oxide nanoparticles and ultrasonic treatment, under low pressure ultraviolet lamp, then with anhydrous ethanol wash purification, vacuum drying to constant weight, obtain nano magnetic flocculants;The method of the application is simple and easy to operate, the nano magnetic flocculants prepared can be quickly adsorbed to the surface of sulfonamide antibiotics, produce flocculation and can be magnetically separated, very suitable for trace sulfonamide antibiotics in drinking water source efficient removal.

The invention provides a polysilicate aluminum zirconium coagulant as well as a preparation method and application thereof, and relates to the technical field of solid waste recycling. The preparation method of the polysilicate aluminum zirconium coagulant comprises the following steps: S1, activation preparation of a polysilicate solution; S2, introduction and pre-complexation of a metal salt solution; and S3, alkalization induced polymerization and curing. According to the invention, the efficient charge neutralization capability of zirconium and aluminum metal ions and the long-chain network structure characteristic of polysilicic acid are organically combined through a copolymerization reaction by molecular design, the developed polysilicate aluminum zirconium coagulant can maintain a good coagulation effect in a wide pH range, is suitable for treating residual sludge with different sources and properties, and has a good coagulation effect under the dosage of 7.5%. The CST value is reduced to 35.4 s from 190.7 s, the water content of a filter cake is reduced to 77.4%, and the Zeta potential is-8.2 mV, so that the polysilicate aluminum ferric coagulant is obviously superior to a traditional polysilicate aluminum ferric coagulant, and has the advantages of high operation flexibility, good process stability and good application prospect.

The application provides sodium zirconium cyclosilicate with controlled particle size distribution, which has less particles less than 3 microns, thereby improving drug safety, and has more than 95% ZS-9 crystal form, thereby having high KEC, and ensuring drug efficacy. The application further provides a preparation method and use of the sodium zirconium cyclosilicate.

The invention relates to a preparation method of silicon dioxide-boron nitride nanobelt aerogel, which comprises the following steps: dissolving melamine and boric acid in a co-solvent of tert-butyl alcohol and hot deionized water, stirring and mixing, carrying out ultrasonic treatment, freeze-drying and the like to obtain a melamine-boric acid aerogel precursor, placing the precursor in a tubular furnace, and carrying out vacuum drying to obtain the silicon dioxide-boron nitride nanobelt aerogel. Pyrolyzing in an ammonia gas atmosphere to obtain boron nitride nanobelt aerogel; and placing the boron nitride nanobelt aerogel in a xylene solution containing tetraethoxysilane and silicon tetrachloride, taking out the boron nitride nanobelt aerogel, and drying the boron nitride nanobelt aerogel. And hydrolyzing and pyrolyzing in an inert atmosphere to form a silicon dioxide layer on the surface, thereby obtaining the silicon dioxide-boron nitride nanobelt aerogel. The silicon dioxide and boron nitride nanobelt aerogel is low in density and excellent in mechanical property and oxidation resistance.

The invention belongs to the technical field of functional nano materials, and particularly relates to a preparation method of a detachable engine type braking nano motor, a nano drug carrier is jointly composed of HMSN and CAT modified PNA, tetraethyl orthosilicate serves as a silicon source, and solid silicon dioxide balls are synthesized; on the basis, tetraethyl orthosilicate is used as a silicon source, CTAB is used as a pore-forming agent to synthesize mesoporous silica coated solid silica spheres; etching the core silicon dioxide ball through sodium carbonate to obtain a hollow mesoporous silicon dioxide ball; then, amino modification is carried out on the CAT modified PNA2 through 3-aminopropyltrimethoxysilane, PNA1 is connected with HMSN through an amido bond, and a double-chain structure is formed by the CAT modified PNA2 and PNA1 through complementary base pairing. According to the nano motor provided by the invention, the engine CAT of the nano motor can be detached by adding the unwinding chain PNA3, so that in-vivo deceleration and braking are realized.

This invention relates to a detoxification method for simultaneously removing dioxins and heavy metals from waste incineration fly ash. The method includes fly ash pretreatment and simultaneous removal of dioxins and heavy metals. First, sodium and potassium salts are removed from the fly ash by immersion washing to avoid reducing the ability of the sintered products formed during high-temperature sintering to solidify heavy metals. Then, the pretreated fly ash is separated to obtain a solid phase, which is mixed with magnesium and / or calcium salts and subjected to high-temperature roasting. This allows the chlorine from the decomposition of dioxins in the fly ash to react with the heavy metals to form gaseous heavy metal chlorides, thus removing the heavy metals from the fly ash. During the high-temperature roasting process, the magnesium and / or calcium salts react with the ash in the fly ash to form calcium silicate and / or magnesium silicate, enhancing the solidification ability of the internal lattice of the fly ash sintered products. After detoxification treatment of waste incineration fly ash using this method, no heavy metals Hg, Pb, Cd, Cu, and Ni were detected in the fly ash leachate, significantly reducing the leaching risk of residual heavy metals in the fly ash.

The invention provides a dark metal modified lithium orthosilicate-based thermochemical heat storage material as well as a preparation method and application thereof, and belongs to the technical field of energy and material science. The components of the heat storage material comprise lithium orthosilicate and dark metal, the proportion of the dark metal in the heat storage material is 2-10 mol%, and the source of the dark metal comprises one or more of manganese dioxide, ferric oxide, nickel oxide and copper oxide. Metal ions introduced into the obtained dark metal modified lithium orthosilicate-based thermochemical heat storage material have the effects of promoting the ion migration rate and resisting material sintering, and specifically, the heat storage density and the cycling stability of the material are remarkably enhanced. In addition, due to the introduction of the dark metal oxide, the color of the heat storage material is remarkably deepened, the solar spectrum absorptivity is greatly improved, the light absorption performance of the material is greatly enhanced, and the heat storage material has higher photo-thermal conversion efficiency and is more suitable for a concentrating solar energy storage system.

The invention belongs to the field of polyester resins, and provides a weather-resistant polyester resin for low-temperature curing and a preparation method thereof. A three-step progressive design that a polyester prepolymer is terminated by silane and then is subjected to hydrolytic polycondensation with tetraethyl orthosilicate to construct an organic-inorganic covalent hybrid network is adopted; through cooperation of the condensation catalyst, the hindered amine light stabilizer and the ultraviolet absorbent, the mechanical properties that the pencil hardness reaches the HB level or above and the cross-cut test level is not higher than the first level under the low-temperature curing condition of not higher than 100 DEG C are achieved, and the long-term weather resistance that the color difference is not larger than 2.0 and the gloss retention rate is not lower than 80% after 500-hour artificial accelerated aging is achieved. The technical problems of poor storage stability and difficulty in consideration of high solid content and low viscosity caused by insufficient low-temperature curing capacity and non-uniform organic-inorganic hybridization of the traditional polyester resin are solved, and the polyester resin has wide application value in the fields of building coatings, automobile refinishing paints, wood coatings and the like with strict requirements on low-temperature curing and weather resistance.

The present application relates to a kind of foam type organic chlorine disinfectant and its preparation method and application, belong to disinfectant technical field.Utilize the modification treatment of magnesium sulfate with polysilicic acid, make and form stable package system between modified magnesium sulfate and organic chlorine, greatly improve the stability and long-acting of effective chlorine component in the process of use;While introducing the synergism between surfactant and sodium dimethyl benzene sulfonate, an additional protective layer is constructed, further strengthens the overall stability of organic chlorine disinfectant, blocks the harmful contact that organic chlorine disinfectant can encounter under complex or adverse environmental conditions, effectively prevents the performance decline or potential harm caused by environmental factors, ensures the safe and efficient use of disinfectant.The foam type organic chlorine disinfectant of the present application utilizes double package system, not only improves the long-acting and stability of disinfection effect, but also significantly enhances the environmental adaptability and use safety of product.

The invention relates to the technical field of dechlorinating agents, in particular to a dechlorinating agent and a preparation method thereof. The preparation method of the dechlorinating agent comprises the following steps: 1) uniformly mixing quaternary ammonium salt and organic amine, then adding silicate ester, uniformly mixing, reacting for 2-6 hours, carrying out solid-liquid separation, washing a solid, and drying; 2) roasting the solid dried in the step 1) at 550-650 DEG C for 5-10 hours, and cooling to obtain a carrier; 3) uniformly mixing the carrier prepared in the step 2) with a calcium source and a zinc source in water, adjusting the pH value to 10-12, reacting, standing, carrying out solid-liquid separation, and drying the solid, and 4) calcining the dried solid in the step 3) at 800-1000 DEG C for 10-24 hours, and cooling to obtain the dechlorinating agent. The prepared dechlorinating agent is uniform in pore diameter and high in penetrating chlorine capacity, and can effectively reduce the loss of active ingredients.

The invention relates to the technical field of building glazed tiles, in particular to an antibacterial glazed tile and a preparation method thereof.The antibacterial glazed tile comprises a green body layer and an antibacterial glaze layer which are sequentially arranged from bottom to top; wherein the antibacterial glaze layer is obtained by calcining antibacterial glaze; the antibacterial glaze is prepared from the following raw materials: high-temperature antibacterial frit, calcined kaolin, corundum, quartz, dolomite, calcined talc, strontium carbonate, wollastonite, potassium feldspar and albite; the high-temperature antibacterial frit is prepared from the following raw materials: zirconium silicate, a silver antibacterial agent, calcined aluminum oxide, calcined talc, quartz, wollastonite, kaolin, calcium phosphate, potassium feldspar, albite, boric acid and lithium carbonate. According to the antibacterial glazed tile and the preparation method thereof provided by the invention, the formula of the antibacterial glaze is optimized, so that the antistatic property and the corrosion resistance can be improved on the premise of ensuring the antibacterial property of the antibacterial glazed tile.

The invention discloses a battery thermal runaway self-inhibition coating based on a heat absorption type reverse thermit reaction as well as a preparation method and application thereof. The battery thermal runaway self-inhibition coating comprises the following raw materials in percentage by weight: 40-60% of Fe2O3, 15-25% of Al powder, 20-35% of a heat absorption additive, 5-10% of a binder and 0-5% of a trigger regulator, the heat absorption additive is Bi2O3 or SrCO3; the binder is a potassium silicate aqueous solution or high-temperature-resistant polysiloxane resin; the trigger regulator is copper oxide or manganese dioxide. The coating is not a single functional material, but is a'reaction system ', an thermit reaction is converted into an endothermic reaction by introducing an endothermic additive, and a product of the coating can be fused and sintered in situ to generate a compact porous ceramic-metal composite heat insulation layer during the endothermic reaction, so that a battery cell can be isolated in space, and the performance of the battery cell is improved. And heat radiation can be effectively blocked due to low heat conductivity, so that double insurance of heat absorption and isolation is realized.

The invention discloses a hydrophobic anti-icing material based on silver ions and application in a power transmission line, and belongs to the technical field of hydrophobic anti-icing materials, the hydrophobic anti-icing material is prepared from the following raw materials in parts by weight: 80-120 parts of hydroxyl-terminated polydimethylsiloxane, 5-15 parts of tetraethoxysilane, 0.5-3 parts of silver nitrate, 3-10 parts of hydrophobic nano silicon dioxide and 1-5 parts of nano titanium dioxide. The invention discloses an anti-icing and deicing composite material, which is prepared from the following components in parts by weight: 80 to 120 parts of butyl acetate, 0.1 to 0.5 part of dibutyltin dilaurate, 0.5 to 2 parts of sodium citrate and 2 to 5 parts of modified fluorinated phosphotungstic acid imidazole compound, and solves the problems that the existing material is insufficient in photo-thermal utilization rate, poor in stability in a severe environment, insufficient in hydrophobic capacity and difficult to give consideration to anti-icing and deicing effects. According to the scheme, the modified fluorinated phosphotungstic acid imidazole compound and silver ions are introduced to form a synergistic effect, formation of an ice layer is inhibited, melting of the ice layer is promoted, meanwhile, lasting super-hydrophobicity is provided, a durable hydrophobic anti-icing coating based on the silver ions is formed, and the safety of a power grid is guaranteed.

The invention discloses an anti-aging bronze powder pigment and a preparation method and application thereof in the technical field of bronze powder pigments, and the anti-aging bronze powder pigment takes copper-zinc alloy as a base material, and is sequentially connected with a composite chemical passivation layer, a functionalized organic-inorganic hybrid compact barrier layer and a surface super-hydrophobic layer through chemical bonding from inside to outside; wherein the composite chemical passivation layer is formed by treating a passivation solution containing phytic acid, ammonium metavanadate and sodium tungstate; the functionalized organic-inorganic hybrid compact barrier layer is constructed by a silane mixed solution containing 3-mercaptopropyltriethoxysilane, a reaction type ultraviolet light absorber Si-BP, a reaction type hindered amine light stabilizer Si-HALS and tetraethyl orthosilicate through a sol-gel process. Through the design of a multi-layer composite system, the aging resistance of the bronze powder is improved, and meanwhile, the optical decoration performance can be reserved to the maximum extent, so that the dual strict requirements of high-end outdoor applications such as automobile coatings on durability and visual texture can be met.

The invention discloses a preparation method of a low-magnetic-conductivity high-strength iron-silicon magnetic powder core, which comprises the following steps of: 1, phosphating iron-silicon alloy magnetic powder, and physically coating the phosphated magnetic powder by using magnesium aluminum silicate gel with a layered structure; 2, preheating the magnetic powder obtained in the step 1 in an inert atmosphere; 3, sufficiently and uniformly mixing magnesium aluminum silicate gel, a binder and the magnetic powder obtained in the step 2, heating a mixed system, and mechanically stirring until the powder is dried; 4, the magnetic powder obtained in the step 3 and a lubricant are mechanically stirred to be evenly mixed and then pressed into a magnetic powder core blank; and 5, the blank obtained in the step 4 is subjected to heat treatment under the inert protective atmosphere. The magnetic powder core prepared by the method has the characteristics of low magnetic conductivity and high strength.