888 results about "Polyurethane elastomer" patented technology

The invention belongs to the technical field of polyurethane elastomers, and particularly relates to a high-static-rigidity high-damping low-pressure-change polyurethane elastomer and a preparation method thereof. Comprising a polyol component and an isocyanate component, and the polyol component comprises polyol A, a chain extender, a stabilizer, a hydrolysis-resistant agent and a catalyst; the isocyanate component is prepared from isocyanate, polyhydric alcohol B and branched chain unit alcohol; the polyol A comprises amine ether polyol and polytetrahydrofuran ether polyol; the polyhydric alcohol B comprises bio-based hydrolysis-resistant polyhydric alcohol and polytetrahydrofuran ether polyhydric alcohol; the bio-based hydrolysis-resistant polyol is prepared by carrying out a reaction on sebacic acid, 1, 2-propylene glycol and 1, 4-butanediol; the branched-chain unit alcohol is prepared from tetrahydrofuran and isooctanol through a reaction. By introducing the bio-based hydrolysis-resistant polyhydric alcohol and branched chain monohydric alcohol, the damping effect is remarkably enhanced, and on this basis, through formula adjustment and raw material screening, the product toughness is greatly improved, the compression set is reduced, and the performance of the product in heavy haul railway application is effectively optimized.

The present invention relates to the technical field of regenerated plastics, and in particular relates to a flame-retardant regenerated plastic and a preparation method therefor. The regenerated plastic comprises the following specific components: 90-100 parts of regenerated high-density polyethylene, 5-10 parts of high-density polyethylene, 1-2 parts of calcium stearate, 1-2 parts of carbon black, 8-12 parts of maleic-anhydride-grafted polyethylene, 2-3 parts of an antioxidant, and 6-8 parts of a polyurethane elastomer. The regenerated high-density polyethylene is used as a main material, the high-density polyethylene is added thereto, the maleic-anhydride-grafted polyethylene is used as a compatibilizer, and then polyhydroxy polybutadiene, epoxidized hydroxyl-terminated polybutadiene and polypropylene oxide glycol are compounded and react with diphenylmethane diisocyanate to generate a polyurethane elastomer, thereby toughening the regenerated polyethylene; moreover, a flame-retardant effect is achieved by means of the synergy of phosphorus and nitrogen; therefore, a regenerated polyethylene plastic with high tensile strength and good flame-retardant performance is prepared. The regenerated plastic can be widely used in a plurality of fields, and has a relatively high level of practicability.

The invention relates to a modified polyurethane elastomer and application of the modified polyurethane elastomer in preparation of bimodal cellular structure foam, and belongs to the technical field of foam forming. The invention provides a modified polyurethane elastomer. The modified polyurethane elastomer comprises the following components: a thermoplastic polyurethane elastomer, a polyisocyanate-based chain extender and an antioxidant component, in the modified polyurethane elastomer, the mass ratio of the thermoplastic polyurethane elastomer to the polyisocyanate chain extender to the antioxidant component is 1: (0.01-3): (0.05-1). According to the modified polyurethane elastomer, non-uniform chain extension modification is carried out on the thermoplastic polyurethane elastomer by introducing an insufficient amount of a polyisocyanate group chain extender, and the thermoplastic polyurethane elastomer foam obtained by foaming the modified polyurethane elastomer has a bimodal (big and small holes) foam structure; and the material has various excellent performances of light weight, heat insulation, sound insulation, buffering, high resilience and the like.

The invention relates to the technical field of inorganic non-metallic materials, in particular to a quaternized cholic acid polyurethane modified polyvinyl chloride material, a preparation method and application. The quaternized cholic acid polyurethane polymer is based on a polyurethane elastomer developed by using cholic acid molecules with a rigid skeleton as a hard segment unit and flexible oligomeric ethylene glycol as a soft segment unit, hydroxyl on cholic acid polyurethane is quaternized to prepare cation modified cholic acid polyurethane, and the cation modified cholic acid polyurethane simulates amphiphilic characteristics of natural peptides. The quaternized cholic acid polyurethane is introduced into a polyvinyl chloride (PVC) matrix as an antibacterial agent, so that the growth of microorganisms such as bacteria and molds can be effectively inhibited, the antibacterial property is achieved, bacteria breeding on the inner surface of a pipeline is avoided, and the composite material is endowed with better biocompatibility and antibacterial property; meanwhile, the quaternized cholic acid polyurethane can effectively improve the strength and toughness of the PVC material; wide application prospects are realized.

The invention relates to the technical field of polymer room-temperature phosphorescent materials, in particular to a self-repairing room-temperature phosphorescent elastomer based on waterborne polyurethane and a preparation method and application thereof, and the specific preparation steps include: 1) synthesis of self-repairing waterborne polyurethane and 2) preparation of a self-repairing room-temperature phosphorescent waterborne polyurethane elastomer material. A self-repairing waterborne polyurethane elastomer material is taken as a polymer matrix for constructing a rigid network, and is combined with various micromolecular organic light-emitting units through physical doping, so that the self-repairing room-temperature phosphorescent waterborne polyurethane elastomer material with strong self-healing capability, excellent optical performance and good mechanical tensile property is obtained.

The invention discloses an anti-skid and noise-reduction multifunctional road hot melt coating and a gradient forming process thereof, and relates to the technical field of hot melt coatings. Comprising the following components in percentage by mass: 25-28wt% of bio-based resin, 8-12wt% of a noise reduction material, 15-20wt% of nano composite rubber particles and 5-8wt% of internally mixed reflective glass beads. The bio-based resin is used as a base material of the hot melt coating, the superfine bamboo fibers and the polyurethane elastomer are combined to serve as noise reduction materials, and honeycomb-shaped pores with the diameter of 0.1-1 micron exist in the superfine bamboo fibers, so that a coating produced by construction of the hot melt coating has good noise reduction performance; meanwhile, coarse-grade glass beads and fine-grade glass beads are introduced into the material, the coarse-grade glass beads provide basic light reflection, gaps are filled with the fine-grade glass beads to form a compact reflection layer, the coarse-grade glass beads and the fine-grade glass beads synergistically act to enable incident light to generate a composite effect of diffuse reflection and specular reflection, the retroreflection coefficient of the coating is increased by utilizing the effect, the light reflection performance in rainy days is further improved, and the safety is improved; and the hot-melt coating mostly adopts an environment-friendly material, is easy to degrade and is beneficial to environment protection.

The invention belongs to the technical field of polymer materials and electric wires and cables, and discloses a high-insulating-property composite cable and a preparation method thereof. The preparation method comprises the following steps: carrying out copolymerization reaction on hydroxyl-terminated hydrogen-containing polysiloxane, dihydric alcohol and diisocyanate to obtain an organic silicon modified polyurethane elastomer solution; then adding a vinyl cross-linking agent to carry out a cross-linking reaction, and after the reaction is completed, drying and granulating to obtain organic silicon modified polyurethane elastomer granules; uniformly mixing the elastomer granules with PE, EVA and reinforcing filler, extruding into a mold in which a metal wire is placed, coating, curing and forming to obtain an insulating layer; and finally, mixing nylon slices and color master batch, and coating the mixture on the surface of the insulating layer by injection molding for curing and forming to obtain the composite cable with high insulating property. The insulating layer adopts a specific TPE material to carry out blending modification on PE, so that the strength, the toughness and the thermal aging resistance of the insulating layer can be remarkably improved, and relatively high insulating performance can be maintained.

The invention discloses a preparation method of a photoresponsive self-cleaning optical coating with a dynamic self-repairing function. The preparation method comprises the following steps: adding a monomer containing a Diels-Alder reaction bond into a polyurethane prepolymer, and reacting to obtain the polyurethane elastomer with self-repairing capability. An azobenzene derivative is connected to a polyurethane elastomer through a covalent bond, and the photoresponsive self-repairing polymer is obtained. Hydrophobically modified TiO2 nanoparticles are prepared in situ through a sol-gel method. In order to further improve the dispersity of the TiO2 nanoparticles in the polymer, a silane coupling agent is adopted to carry out surface modification on the TiO2 nanoparticles. The preparation method comprises the following steps: mixing a photoresponsive self-repairing polymer and a TiO2 nanoparticle dispersion liquid in proportion, uniformly stirring, coating the mixed liquid on the surface of a base material, forming a uniform coating through a brush coating or spray coating method, and curing the coating at a proper temperature. Due to the excellent characteristics of light response self-repairing, ultraviolet resistance, wear resistance and the like, the coating can keep a long transparent period and good antifouling durability in an outdoor environment.

The invention discloses a high-toughness flame-retardant polyurethane cable insulation layer material and a preparation method and application thereof.According to the preparation method, firstly, a phosphorus-containing compound is grafted to polyhydric alcohol, molecular-level uniform dispersion of flame-retardant elements is achieved, and meanwhile the problems that a traditional additive type flame retardant is prone to migration and precipitation and deteriorates the mechanical property of polyurethane are solved; then polymerizing with a diisocyanate monomer and a chain extender, and then extruding and granulating with an antioxidant, a layered nano filler and a maleic anhydride grafted toughening agent through a double-screw extruder to obtain the polyurethane elastomer. The prepared polyurethane cable insulation layer material has the advantages of no halogen, environmental protection, high flexibility, excellent flame retardant property and the like. Besides, the strong polarity of the maleic anhydride grafted flexibilizer and the twin-screw extrusion process can promote the uniform dispersion of the layered nanofiller, so that not only are the flexibility and impact resistance of the material improved, but also the flame-retardant effect is further enhanced through the synergistic effect of the nanofiller, and the material has a wide application prospect in the field of wires and cables.

The invention discloses a vegetable oil-based room-temperature water-induced self-healing polyurethane elastomer and a preparation method thereof. The elastomer is prepared by taking polytetramethylene ether glycol and tung oil glycol as soft segments, isophorone diisocyanate as a hard segment, dimethylolpropionic acid as a hydrophilic chain extender and 3-aminophenylboronic acid as an end-capping reagent. Polytetramethylene ether glycol and tung oil glycol are used as soft segments, isophorone diisocyanate is used as a hard segment, dimethylolpropionic acid is used as a hydrophilic chain extender, 3-aminophenylboronic acid is used for blocking, then triethylamine is used for neutralization, and a waterborne polyurethane material with high-density crosslinking sites is synthesized. The material has good mechanical properties and fracture toughness, the tensile strength of the polyurethane film can reach 6.94 MPa, the elongation at break can reach 790.1%, and the film has good rebound resilience.

The invention discloses an epoxy resin tack coat oil material suitable for a steel bridge deck, which constructs a multi-scale toughening composite system through the synergistic effect of an epoxy-terminated polyurethane elastomer toughening agent (molecular-scale chemical grafting) and a nano-scale elastomer filler (nano dispersion toughening), and solves the problem of rigidity-flexibility imbalance of the traditional epoxy tack coat oil. The material has the advantages of fast curing (surface drying at 25 DEG C is less than or equal to 4 hours), high toughness (the elongation at break is greater than or equal to 250%) and excellent weather resistance (the performance retention rate is greater than or equal to 85% after ultraviolet aging for 500 hours), and is suitable for interlayer interface bonding of steel bridge deck pit slot and crack repair. According to the preparation method, uniform dispersion and interface chemical bonding of the nanofiller are achieved through a segmented stirring process, the comprehensive performance of the material is remarkably improved, and the important engineering application value is achieved.

The invention discloses a polyurethane elastomer for sealing and a preparation method thereof, and relates to the technical field of polymer materials, the polyurethane elastomer comprises polyether polyol, diisocyanate, a catalyst, a cross-linking agent, a stabilizer and a plasticizer; the polyurethane elastomer further comprises additives, the additives specifically comprise functionalized graphene oxide, an ionic liquid toughening agent, self-repairing microcapsules and a carbon quantum dot toughening agent, and the polyurethane elastomer is prepared based on the materials. According to the polyurethane elastomer for sealing and the preparation method thereof, the sealing property, the tensile property, the wear-resisting property and the self-repairing property of the material are remarkably improved. The functionalized graphene oxide, the ionic liquid toughening agent, the self-repairing microcapsule and the carbon quantum dot toughening agent are introduced into the polyurethane, so that the excellent performance of the polyurethane elastomer in high-stress, high-abrasion and damage environments is realized. The polyurethane elastomer not only has lower leakage rate and higher tensile strength, but also can be quickly self-repaired after being worn.

The invention belongs to the technical field of chemical engineering and medicines, and particularly relates to polyether polyol of high-molecular-weight sucrose and a synthesis method of the polyether polyol. The average molecular weight of the sucrose polyether polyol is 5000-10000, adding an initiator, namely a mixture consisting of sucrose, small molecular alcohol and water, and an alkali metal catalyst into a reactor, heating, and introducing epoxide to carry out polymerization reaction; preserving heat, curing, heating and dehydrating; introducing epoxide for polymerization reaction, and adding water and an adsorbent for refining to obtain a refined polyether polyol stub bar; the preparation method comprises the following steps: adding a refined polyether polyol material head, DMC and an acidic material into a container, heating for dehydration, introducing epoxide for polymerization reaction, and adding water and an adsorbent for refining to obtain the polyether polyol of high molecular weight cane sugar. The sucrose polyether with the ultra-high molecular weight can be synthesized, is narrow in molecular weight distribution, high in functionality and stable in storage, and is applied to the fields of semi-rigid foam polyurethane, polyurethane elastomers and the like, or applied to micromolecule inclusion, recognition and slow release in the fields of medicines and foods.

The invention relates to the field of polyurethane film materials for batteries, and discloses a TPU composite material for a new energy battery and a preparation method of the TPU composite material. A TPU composite material for a new energy battery is composed of a cloth film layer, an adhesive film layer and a TPU film layer, the TPU film layer is prepared by melting and casting TPU hot melt adhesive, and the TPU hot melt adhesive is prepared from the following raw materials in parts by weight: 60-80 parts of polyurethane elastomer, 20-30 parts of a toughening aid, 15-25 parts of a flame retardant, 8-15 parts of a heat conducting agent, 2-4 parts of a lubricant and 1-3 parts of an antioxidant; the toughening auxiliary agent is prepared from a POE (Polyolefin Elastomer), long carbon chain alkyl glycidyl ether, dibutyl itaconate and a vinyl dimethyl terminated dimethyl-methyl trifluoropropyl polysiloxane copolymer. The TPU composite material disclosed by the invention is applied to a new energy battery, has relatively good buffering and damping effects and puncture resistance, and is good in flame retardance and thermal conductivity.

The invention relates to the technical field of photoelectric composite cables, in particular to a cold-resistant tensile photoelectric composite cable and a rapid laying method thereof, and the cable comprises a conductor part, an insulating layer, an optical fiber unit, a filling layer and an outer sheath which are coaxially arranged from inside to outside and are sequentially wrapped. The conductor part is formed by twisting a plurality of strands of copper wires, a carbon fiber reinforced core is arranged in the conductor part, and the insulating layer is made of EAA and PEBA blending modified materials and contains nano boron nitride particles; the optical fiber unit is of a PBT loose tube structure, a plurality of single-mode optical fibers and special ointment are arranged in the PBT loose tube structure, micro-nano protrusions are arranged on the inner wall of a loose tube, and the surface of each micro-nano protrusion is covered with a silicon dioxide antireflection film. The cable integrates the functions of cold resistance, stretch resistance, electric conduction, insulation, communication, heat dissipation and protection. The insulating layer adopts EAA and PEBA blending modified materials to be combined with nano boron nitride particles, so that the cold resistance and the insulativity are improved; and the polyurethane elastomer of the filling layer is compounded with the glass beads, so that the structural stability and the comprehensive performance are enhanced.

The present invention relates to the field of polyurethane materials and particularly to a temperature-induced color-changing vehicle film and a preparation method therefor. The method of the present invention comprises: firstly, using polyurethane to wrap vanadium dioxide powder to obtain color-changing microcapsules; then using 1,1,1,3,5,5,5-heptamethyltrisiloxane and 3-allyloxy-1,2-propanediol as raw materials to synthesize an organosilicon-modified diol, and enabling trimellitic anhydride to react with toluene diisocyanate to synthesize a dicarboximide compound; enabling the organosilicon-modified diol and the dicarboximide compound to undergo an esterification reaction and a polymerization reaction to obtain an organosilicon-modified imide polyester diol; then mixing the organosilicon-modified imide polyester diol with polytetrahydrofuran ether glycol 2000, and then enabling the mixture to react with toluene diisocyanate to obtain a polyurethane elastomer; and mixing the polyurethane elastomer, the color-changing microcapsules, a silane coupling agent, a plasticizer, an antioxidant, and an ultraviolet light absorber, followed by melt extrusion and blow molding into a film, so as to obtain the temperature-induced color-changing vehicle film.

The invention relates to the field of drag chain cables, in particular to a high-flexibility shielding type drag chain cable and a preparation method thereof. The drag chain cable sequentially comprises a conductor layer, a shielding layer and a sheath layer from inside to outside. The conductor layer is formed by compositely twisting silver-plated copper wires and carbon fibers; the shielding layer comprises an inner shielding layer and an outer shielding layer, the inner shielding layer is wrapped by an aluminum-plastic composite belt, and the outer shielding layer is a tinned copper wire woven mesh. The sheath layer comprises the following components: a modified polyurethane elastomer, an ethylene-vinyl acetate copolymer, nitrile rubber, a composite flame retardant, a plasticizer, an antioxidant, a light stabilizer and a lubricant. Through the structural design of the conductor layer, the shielding layer and the sheath layer and the optimization of the material formula of the sheath layer, the problems that an existing drag chain cable is insufficient in strength and flexibility, limited in shielding effectiveness, poor in wear resistance and weather resistance and difficult to consider both flame retardance and mechanical property are solved.

The invention relates to a silicon-containing polycarbonate diol, a polyurethane elastomer material and a preparation method thereof, and belongs to the technical field of organic materials. The glass transition temperature (Tg) of the silicon-containing polycarbonate diol ranges from 40 DEG C to 60 DEG C below zero, the hydroxyl value ranges from 60.4 mgKOH / g to 67.9 mgKOH / g, the product purity is high, the product purity is 98 or above, and the number-average molecular weight of the polycarbonate diol ranges from 1900 Da to 2200 Da. The low-temperature flexibility of the polycarbonate diol is effectively improved, and the use temperature range of the polycarbonate diol is widened. The polycarbonate diol disclosed by the invention is stable in hydroxyl value and narrow in molecular weight distribution; the product quality is good, and subsequent application is facilitated. The polycarbonate diol is short in preparation time, high in efficiency, simple in technological process, mild in technological condition and suitable for large-scale industrial production. The raw materials are low in cost.

The invention provides a carbon dioxide based polycarbonate-polyester-polyether block copolymerized diol, a star-shaped carbon dioxide based polycarbonate-polyester-polyether copolymerized polyol, and a star-shaped carbon dioxide based polycarbonate-polyester-polyether copolymerized polyol with a low molecular weight. By adjusting the specific polyether content, chain segment distribution and molecular weight, the three polyols can be used for preparing polyurethane elastomers, soft foam and hard foam respectively. The low-temperature brittleness of the polyurethane material is improved while the elasticity of the polyurethane material is improved.

The invention discloses a preparation method and application of a reproducible self-healing polyurethane elastomer with synergism of dynamic silicon oxygen bonds and multiple hydrogen bonds. The method comprises the following steps: (1) carrying out a pre-polymerization chain extension reaction on polytetrahydrofuran, isophorone diisocyanate and a catalyst; (2) adding a 3, 13-dihydroxy propyl octaphenyl double-layer silsesquioxane monomer to carry out a chain extension reaction, and then adding carbohydrazide to carry out a reaction; and (3) adding glycerol and camphorsulfonic acid, uniformly stirring, pouring into a mold, curing and drying, thereby obtaining the reproducible self-healing polyurethane elastomer with synergistic dynamic silicon-oxygen bonds and multiple hydrogen bonds. According to the invention, a common fabric is soaked in a dispersion liquid formed by uniformly mixing diluted polyurethane and hydrophobically modified MXene to obtain the multifunctional composite material with the functions of self-cleaning, self-repairing, photo-thermal conversion and human body sensing.

The invention belongs to the technical field of polyurethane composite materials, and particularly discloses a preparation method of an aramid nanofiber / polyurethane composite material. The method comprises the following steps: (1) preparing an organic silicon modified polyurethane prepolymer; (2) preparing a fluorinated modified aramid nanofiber (FANF); and (3) uniformly dispersing FANF in a solvent to form a dispersion liquid, adding a chain extender into the organosilicon modified polyurethane prepolymer according to a preset chain extension coefficient, then doping the FANF dispersion liquid, and mixing, curing and molding to obtain the high-performance polyurethane elastomer (PUE). Through the synergistic effect of the rigidity enhancement effect of the aramid nanofibers and the interface lubrication characteristic of the polydimethylsiloxane, the wear resistance and mechanical strength of the material are remarkably improved, and the obtained PUE has excellent tensile strength (gt; 35 MPa) and an elongation at break (gt; 400%), and can be widely applied to the fields of industrial sealing, flexible electronics and high-load transmission parts.

The invention discloses a bio-based nylon 12 elastomer prepared by a one-step method and a preparation method and application thereof, and belongs to the technical field of polyamide materials, the method comprises the following steps: (1) material preparation: mixing, heating and uniformly stirring bio-based 12-amino dodecanoic acid, polyether amine, a reaction aid and water in a material preparation tank to form a mixture; (2) feeding: pressing the mixture into a polymerization kettle through nitrogen pressurization; and (3) polymerizing. By optimizing the raw material combination and the polymerization process path, the one-step method (namely, in the same polymerization kettle) is realized to complete the polymerization reaction taking the bio-based 12-amino dodecanoic acid monomer as the main component, and the polyether block amide type nylon 12 elastomer is constructed, so that the elongation at break and the rebound resilience are improved, the stable polymerization process and the controllable product quality are realized, and the production cost is reduced. And the polyurethane elastomer has good elasticity and machinability, and is suitable for the fields of soles, sealing strips, soft devices and the like.

The utility model discloses a steel core copper conductor stainless steel wire armored combination cable for a buggy ladle, which comprises three power wire cores and a control wire core, the three power wire cores and the control wire core are uniformly distributed at intervals of 90 degrees in the circumferential direction through an X-shaped polyurethane elastomer isolation core, a central hole is formed in the central part of the X-shaped polyurethane elastomer isolation core, and a galvanized steel wire reinforced core is sleeved in the central hole; and a polyether polyurethane inner sheath layer, a Kevlar fiber inner braid layer, a stainless steel wire armor layer, a Kevlar fiber outer braid layer and a polyether polyurethane outer sheath layer are sequentially coated outside the X-shaped polyurethane elastomer isolation core. The cable is better in flexibility and structural stability, the sheath is prevented from wrinkling, the cable is prevented from being twisted and deformed, the durability and the applicability are improved, and potential safety hazards are reduced.

The present invention relates to a method for preparing a thermosetting polyurethane elastomer for 3D printing, belonging to the field of rapid prototyping and manufacturing technology. This method utilizes a blocked isocyanate process to quantitatively control the reaction rate of a highly reactive polyurethane system, thereby obtaining a single-component thermosetting polyurethane elastomer stock solution. A polyurethane prepolymer is prepared using diisocyanate and oligomer polyol as raw materials. A blocked prepolymer is then prepared using an active hydrogen-containing blocking agent and a blocked prepolymer. A metered diamine chain extender and catalyst are then added to obtain a single-component thermosetting polyurethane elastomer stock solution. This method quantitatively controls the reaction rate of the highly reactive polyurethane system. The polyurethane elastomer stock solution is stable and low-toxic upon storage at room temperature. The raw material viscosity is adjusted by heating to meet the viscosity requirements for 3D printing, thereby achieving the green production of high-performance polyurethane elastomers.

The invention relates to the technical field of medical instruments, and discloses a high-pressure-resistant injection type central venous catheter and a preparation method thereof.The high-pressure-resistant injection type central venous catheter is characterized in that a polyurethane elastomer is used as a main body material, and the polyurethane elastomer has high tearing strength and flexibility; the aramid fiber and carbon nanotube composite material is used as a reinforcing layer and is used for improving the pressure resistance and fatigue resistance of the catheter; according to the catheter, polyether block amide is used as an inner layer material, the polyether block amide has excellent elastic restoring force and biocompatibility, and the outer layer material of the catheter is polyether-ether-ketone, so that the temperature resistance and chemical resistance of the catheter are enhanced. By adopting the design of the multi-layer composite material, the high-pressure resistance and the tear resistance of the conduit are remarkably improved, the rigidity problem caused by increase of the wall thickness of a traditional conduit is solved, the sealing performance and the pressure resistance are improved through the design of the conical sealing structure and the metal reinforcing ring of the connector part, and the leakage risk is avoided.

The invention discloses a supramolecular polyurethane prepolymer, supramolecular polyurethane prepolymer ink, a supramolecular polyurethane elastomer as well as a preparation method and application of the supramolecular polyurethane prepolymer. The structural formula of the supramolecular polyurethane prepolymer is as follows: # imgabs0 #; wherein m is 5-35, n is 6-28, and R is 2-acetyl benzene, phenyl or biphenyl. The supramolecular polyurethane prepolymer has multiple strong hydrogen bonds formed by allophanate bonds and carbamate bonds, microphase separation of soft and hard segments of polyurethane is promoted, the tightness of chain segment spatial conformation is increased by utilizing a planar structure of boron atoms, hydrogen bonds between the carbamate bonds are enhanced, and the microphase separation of soft and hard segments of polyurethane is promoted. The tensile strength, the thermal stability and the toughness of a 3D printed product are improved by virtue of multi-reinforcement coupling due to the dynamic characteristics of the boric acid ester bond, and the 3D printed product has excellent bearing capacity.

The invention discloses a transparent polyurethane elastomer and a preparation method thereof, and relates to the technical field of polyurethane elastomers, the preparation method comprises the following steps: carrying out vacuum dehydration on polytetrahydrofuran ether glycol-2000 and polytetrahydrofuran ether glycol-1000 for later use; the preparation method comprises the following steps: preheating a reaction container, adding isophorone diisocyanate and benzoyl chloride, uniformly stirring, adding polytetrahydrofuran ether glycol-2000 and polytetrahydrofuran ether glycol-1000, and carrying out heat preservation reaction to obtain a polyurethane prepolymer; uniformly stirring polyether polyol N330, a chain extender, dibutyltin dilaurate, silicone oil, a defoaming agent, an antioxidant and an ultraviolet light absorber, carrying out vacuum degassing, adding into the polyurethane prepolymer, uniformly stirring, pouring into a mold, curing, molding and demolding to obtain the transparent polyurethane elastomer.

The invention relates to the technical field of epoxy resin coatings, and particularly discloses a low-corrosion snow-melting and deicing coating and a preparation method thereof. The low-corrosion snow-melting and deicing coating comprises a component A, a component B and a component C in a mass ratio of 100: (40-50): (90-100), and the component A comprises the following raw materials: 100 parts of epoxy resin, 15-25 parts of a polyurethane elastomer, 2-5 parts of an epoxy reactive diluent, 0.5-1 part of a defoaming agent, 2-5 parts of a silane coupling agent and 30-50 parts of a microcapsule snow-melting agent; the component B comprises the following raw materials in parts by weight: 40-60 parts of a polyamide curing agent and 5-10 parts of phytic acid; the component C comprises a reinforcing filler; the microcapsule snow-melting agent comprises a core material and a polyurethane wall material wrapping the core material, wherein the core material comprises potassium acetate and sodium molybdate in a mass ratio of 100: (2-4). According to the invention, the slow release effect of the snow-melting agent in the snow-melting and deicing coating can be improved, and the coating has excellent low corrosion and cracking resistance.

The invention relates to the field of high polymer material processing, in particular to an in-situ elastomer fiber toughened polylactic acid composite material and a preparation method thereof. The in-situ elastomer fiber toughened polylactic acid composite material provided by the invention comprises a polylactic acid matrix and elastomer fibers dispersed in the polylactic acid matrix, and the elastomer fibers are formed in the polylactic acid matrix in situ by a fiber forming phase; the fiber forming phase is a polyolefin elastomer, a polyurethane elastomer or a styrene elastomer; the polylactic acid matrix is formed by polylactic acid, and the mass ratio of the polylactic acid to the fiber forming phase is (80-100): (1-20). The elastomer added in the in-situ elastomer fiber toughened polylactic acid composite material prepared by the invention forms fibers in situ, so that the stress of a crack propagation tip is effectively absorbed, and the toughness of polylactic acid can be effectively improved under the condition of maintaining the strength and modulus of polylactic acid.

The invention discloses a high-temperature-resistant polyurethane elastomer and a preparation method thereof, and relates to the technical field of polymer materials, the high-temperature-resistant polyurethane elastomer comprises the following specific components: polyether polyol, poly (toluene diisocynate) pMD I, a chain extender and a cross-linking agent; the high-temperature-resistant polyurethane elastomer further comprises additives, wherein the additives specifically comprise nano aluminum silicate fibers, a titanium phosphate-based temperature-resistant synergist, a multi-walled carbon nanotube grafted amide group and a metal organic framework composite material. According to the high-temperature-resistant polyurethane elastomer and the preparation method thereof, multiple additives and nano aluminum silicate fibers are introduced into the polyurethane elastomer, so that the thermal isolation property of the material is effectively improved; the multi-walled carbon nanotube grafted amide group improves the thermal conductivity, and solves the problem of poor dispersibility of the carbon nanotube in a polyurethane matrix; the thermal stability of the material is further improved by the titanium phosphate-based temperature-resistant synergist; the introduction of the metal organic framework composite material significantly improves the gas isolation and thermal stability of the material.