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645results about How to "Achieve self-healing" patented technology

Dihydric alcohol containing acylhydrazone bond, dihydric alcohol containing acylhydrazone bond and disulfide bond, self-repairing polyurethane elastomer and preparation method thereof

The invention provides dihydric alcohol containing an acylhydrazone bond, dihydric alcohol containing an acylhydrazone bond and a disulfide bond, a self-repairing polyurethane elastomer and a preparation method thereof. The polyurethane elastomer is prepared from the dihydric alcohol containing the acylhydrazone bond or the dihydric alcohol containing the acylhydrazone bond and the disulfide bond and a polyurethane prepolymer. The dihydric alcohol containing the acylhydrazone bond is prepared from a dihydrazide monomer and hydroxy aldehyde. The dihydric alcohol containing the acylhydrazone bond and the disulfide bond is prepared from a dithio lipid monomer, hydrazine hydrate and hydroxy aldehyde. The polyurethane prepolymer is prepared from a polyester or polyether polyol monomer and diisocyanate. After the self-repairing polyurethane elastomer is mechanically damaged, the acylhydrazone bond or the disulfide bond on a crosslinked polymer molecular chain achieves material self-repairing through dynamic exchange reaction. The self-repairing crosslinked polyurethane elastomer material is simple in preparation, can achieve self repairing at room temperature, is high in repairing capability, short in repairing time and capable achieving many times of self repairing and has better mechanical properties.
Owner:QINGDAO UNIV OF SCI & TECH +1

Mobile agent-based Internet of things middleware development method

The invention discloses a mobile agent-based Internet of things middleware development method, which is used for remarkably improving the application capability of Internet of things middleware and reducing the development cost of Internet of things middleware application for diversified quality of service (QoS) needs of the Internet of things and dynamic network states. To realize a mobile agent-based Internet of things application program, the method is required to be characterized in that: the functions of the whole application program are required to be realized by a mobile agent, and the functions of the mobile agent can be dynamically changed on a network, and can be dynamically inserted into or deleted from hardware equipment to change own functions of the hardware equipment so as to achieve the aim of reprogramming of the network; and the agents can cooperate and communicate with one another. In the method, powerful and flexible Internet of things middleware is constructed to maximally shield the low-level details of the network and completely develop the technical advantages in the aspects of multi-type data sensing, short-distance wireless communication, self-networking, multivariate data cooperative processing and the like.
Owner:NANJING UNIV OF POSTS & TELECOMM

Preparation method of cement-based material having deep self-repairing function

ActiveCN104261736AGood repairing effectAccelerated carbonate mineralization depositionC constantNondestructive testing
The invention provides a preparation method of a cement-based material having a deep self-repairing function. The preparation method disclosed by the invention comprises the following steps of: mixing concentrated solution of carbonic anhydrase generating bacteria with saccharomycete powder according to the mass ratio of (50-60) to 1, and immobilizing on a same carrier; mixing a substrate with a nutritional substance according to the mass ratio of (30-40) to 1, and fixing on another carrier; adding cement, sand and water by taking the carriers as lightweight aggregates, wherein the mass of the carriers is 17-23% of the total mass of mortar; uniformly stirring, and forming a test piece; and manufacturing a crack of the test piece after standard curing, and introducing air to maintain and repair under 25-30 DEG C constant-temperature water bath conditions. The repairing process of the test piece is monitored by utilizing a concrete nondestructive detection technology (ultrasonic sound); the repairing result is detected through a water permeability test; the result shows that the crack is completely repaired after repairing for 21 d; in addition, compared with other microbiological methods for repairing cracks of the cement-based material, the crack repairing speed and repairing depth are greatly improved.
Owner:SOUTHEAST UNIV

Self-repairing anti-glare waterborne polyurethane paint and preparation method thereof

The invention discloses anti-glare waterborne polyurethane paint with a self-repairing function and a preparation method thereof. The preparation method is characterized in that aliphatic polyether glycol subjected to dehydration treatment and diisocyanate are subjected to prepolymerization under the effect of organic tin catalyst; then, the aliphatic polyether glycol subjected to dehydration treatment is added to generate a segmented copolymer; primary chain extension is performed through dimethylolpropionic acid; neutralization is performed to form salt; deionized water and sodium sulfamate type chain extenders are subjected to emulsification and chain extension; sulfonic acid groups are introduced at a hard chain section; then, aliphatic diamine type or hydrazine chain extenders with higher reactivity is added, so that the rest isocyanate completely reacts; finally, the proper amount of auxiliary agents is mixed to obtain the waterborne polyurethane paint. The paint coating film has good diffusion performance and high transmissivity; the excellent anti-glare effect can be achieved without adding additional auxiliary agents or performing surface treatment; the coating film has the self repairing capability through a large number of reversible hydrogen bonds and sulfonic acid groups in polyurethane.
Owner:QINGYUAN YAKOO CHEM CO LTD

Aromatic terminal hydroxyl chain extender containing acylhydrazone bond, self-repairing polyurethane and preparation method thereof

ActiveCN107236106AEasy to prepareStrong performance controllabilityHydrazone preparationAlcoholRoom temperature
On the basis of the current situation of self-repairing polyurethane materials, the invention provides an aromatic terminal hydroxyl chain extender containing an acylhydrazone bond, self-repairing polyurethane prepared by using the aromatic terminal hydroxyl chain extender and a preparation method of the self-repairing polyurethane. Compared with dihydric alcohol containing an acylhydrazone bond, the aromatic terminal hydroxyl chain extender containing the acylhydrazone bond has the advantages that the molecular structure of the aromatic terminal hydroxyl chain extender has the large pi bond of a hydrazide benzene ring and the pi-pi conjugative effect of the pi bond of carbon-oxygen double bonds, and accordingly the chain extender is stable in structure. The prepared self-repairing polyurethane has the advantages that the molecular chain of the polyurethane contains the reversible acylhydrazone bond, can achieve self-repairing under room temperature, and is high in repairing efficiency and good in mechanical performance. The preparation of the self-repairing polyurethane has the advantages that the method is simple, raw materials are products which are commercially produced, and the prepared polyurethane is high in performance controllability and promising in application prospect.
Owner:QINGDAO UNIV OF SCI & TECH +1

Stimulus-responsive self-repair anticorrosive coating material and preparation method

The invention discloses a stimulus-responsive self-repair anticorrosive coating material and a preparation method. The coating material comprises a CuO microcapsule and a coating matrix. The CuO microcapsule comprises a capsule core and a capsule core carrier, the capsule core is a corrosion inhibitor, and the capsule core carrier is porous CuO; and the surface of the CuO microcapsule is coated byan anionic polyelectrolyte layer and a cationic polyelectrolyte layer alternately. The invention successfully constructs the anticorrosive coating material with ph responsiveness and self-repair dualefficacy. The porous CuO can improve the loading rate and encapsulation rate of the capsule core substance; at the same time, the anionic polyelectrolyte can be adsorbed on the surface by means of layer-by-layer self-assembly, under the action of Coulomb force, then cationic polyelectrolyte can be adsorbed on the surface, thus improving the dispersibility of the microcapsule in the coating, solving the agglomeration problem of the porous substance CuO, and at the same time improving the bonding performance of the capsule core carrier and the coating matrix, and the anticorrosion performance of the coating material can be further improved.
Owner:SUN YAT SEN UNIV

Method for preparing visible light self-repairing waterborne polyurethane coating material with double selenium bonds on main chain

The invention discloses a method for preparing a visible light self-repairing waterborne polyurethane coating material with double selenium bonds on a main chain. The method comprises the following steps: firstly, preparing an isocyanate end capped polyurethane prepolymer with double selenium bonds on a main chain from raw materials of diisocyanate, dihydroxyethyl diselenide, macromolecule dihydric alcohol and dimethylolpropionic acid; secondly, adding triethylamine for neutralization, further adding a proper amount of deionized water for rapid emulsification, slowly adding a diamine chain extender which is diluted with water, and performing emulsification chain expansion under a condition that the rotation speed is greater than 1200r/min, thereby obtaining the visible light self-repairing waterborne polyurethane coating material with the double selenium bonds on the main chain. On the basis of the visible light reversibility characteristic of double-selenium dynamic covalent bonds, the waterborne polyurethane coating material with the double selenium bonds on the main chain is capable of achieving self-repairing of cracks and broken parts under radiation of gentle visible illumination, so that the service life of the material can be greatly prolonged, the potential safety hazard in use can be reduced, and a relatively long service life can be achieved for the waterborne polyurethane coating material. The waterborne polyurethane coating material with double selenium bonds on the main chain is applicable to coating of leather, textiles, paper, furniture, wall surfaces and the like, and has wide application prospects.
Owner:SICHUAN UNIV

Multistage electrical-network self-healing control device and control method thereof

The invention provides a multistage electrical-network self-healing control device and a control method thereof. The invention aims at satisfying the following demands: realizing interactive balance between a power supply and a load; controlling coordination cooperation of various kinds of distributed power supplies, different levels of micro-grids and main networks; automatically identifying networking or island state of the network; maximumly guaranteeing an energy supply. The multistage electrical-network self-healing control device is connected in one stage or multiple stages of the multistage electrical network and comprises a parameter acquisition monitoring unit, a central processing unit, a man-machine interface and configuration parameter setting input unit and a regulation and control unit. A frequency is served as an information carrier used to characterize an electrical network connection state and an area coverage stage so that the load and the power supply in the electrical network can self-identify the network state and automatically switch according to a preset strategy. The frequency is taken as an information link. Through self-adjustment of the power supply and the load in the system, supply and demand matching of the electric power can be realized, and automatic balance and stabilization of the electrical network under the states of the networking and the island can be guaranteed.
Owner:ZHUHAI UNITECH POWER TECH CO LTD

Crosslinked polyurea elastomer with self-repairing property and preparation method thereof

The invention discloses a crosslinked polyurea elastomer with a self-repairing property and a preparation method thereof. The preparation method comprises the following step of copolymerizing a diisocyanate group-containing monomer, an amino-terminated vinyl ether monomer, trifunctional or higher functional isocyanate and a disulfide bond-containing monomer to obtain the crosslinked polyurea elastomer with the self-healing property. According to the preparation method, the trifunctional or higher functional isocyanate is used as a crosslinking agent, and the disulfide bond-containing monomer is attached to the polyfunctional isocyanate to form a dynamic crosslinking point of a polyurea system; a rapid dynamic exchange reaction can be performed on a disulfide bond in the obtained polyurea elastomer at a certain temperature, so that destruction and recombination of the dynamic crosslinking point are achieved; moreover, dissociation and reconstruction of a hydrogen bond in the system areachieved under the action of the temperature, so that reconstruction of a whole novel polyurea network structure is promoted and repairing and reworking of damages such as cracks are achieved; therefore, the polyurea elastomer has the excellent self-healing property and repeated processing performance and good mechanical properties.
Owner:TSINGHUA UNIV

Self-repairing microcapsule used for metal anticorrosion coating and preparation method thereof

The invention discloses a self-repairing microcapsule used for a metal anticorrosion coating and a preparation method thereof, which belong to the technical field of self-repairing materials. The wall material of the self-repairing microcapsule is urea resin, the core material of the self-repairing microcapsule is natural plant oil, and the self-repairing microcapsule is prepared with a one-step in-situ polymerization method. The natural plant oil has the advantages of wide source and low cost and is easy to obtain. The metal anticorrosion coating is coated on the surface of metal to form an anticorrosion coating. Microcracks appear in the long-term use process, the self-repairing microcapsule embedded in the coating is broken by external force, and released natural plant oil and oxygen in the air can directly generate crosslinking polymerization reaction without catalysts to repair the microcracks to prevent the surface of the metal from being further corroded. The self-repairing microcapsule synthetized by the core material substance has the advantages of good mechanical performance, simple preparation technology and low cost and can be widely applied to the self repairing of metal anticorrosion coatings, such as automobile industry, ship industry and the like.
Owner:SOUTH CHINA UNIV OF TECH

Intelligent firefighting rescue command and dispatch system

The invention discloses an intelligent firefighting rescue command and dispatch system. The intelligent firefighting rescue command and dispatch system comprises a main individual transmitter, a positive pressure air breathing apparatus, an intelligent firefighting bracelet, an audio and video helmet, a Mesh network repeater, an interphone, an emergency command box, a positioning module and a main positioning IPC (Industrial Personal Computer), wherein the main individual transmitter performs information exchange with each of the positive pressure air breathing apparatus, the intelligent firefighting bracelet, the audio and video helmet and the Mesh network repeater through the wireless network, the Bluetooth, signal lines and the Mesh network, so as to monitor the on-site rescue situation in real time; the emergency command box performs information exchange with the 119 command center through 4G; and the positioning module is connected with the main positioning IPC through a wireless serial port to realize the positioning of rescue workers. According to the intelligent firefighting rescue command and dispatch system, the seamless information integration of a plurality of departments is realized through the effective network convergence, and meanwhile the vital signs of rescue workers and the air pressure values in air bottles can be monitored in real time, an early warning is given to the rescue workers, and the expansibility is good due to reserved interfaces.
Owner:恒德科技有限公司
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