A new family of triblock (A-B-A type) thermoplastic, polyurethane, polyurethaneurea, polyurea and polyamide copolymers has been prepared. (A) blocks represent the hard segments, such as urethane, urea, urethaneurea or amide type segments. (B) blocks represent the soft segments, such as aliphatic polyethers, aliphatic polyesters, polydimethylsiloxanes, polyalkanes or their copolymers. These novel material display very interesting microphase morphologies, mechanical properties, solubility characteristics and melt behavior.