1011 results about "Endcapping" patented technology

The invention discloses an uvioresistant acrylic resin coating and a preparation method thereof, and belongs to the technical field of acrylic resin paints.The uvioresistant acrylic resin coating is characterized in that step-by-step functional design is adopted, a functional polyurethane prepolymer is constructed through prepolymerization reaction and double-bond end capping, fluorosilicone modified acrylate emulsion is prepared through a core-shell emulsion polymerization process, and the uvioresistant acrylic resin coating is obtained. Then carrying out surface silane modification on hexagonal boron nitride and carrying out composite coating to obtain a modified boron nitride auxiliary agent; and finally, carrying out composite emulsification and dispersion compounding on all the components to obtain the anti-ultraviolet acrylic resin coating. Through the synergistic enhancement effect of the fluorosilicone modified core-shell structure and the surface modified boron nitride, the ultraviolet aging resistance and the insulation reliability of the coating are remarkably improved on the basis of keeping high adhesive force, excellent flexibility and impact resistance of the coating; the problems that a traditional acrylic coating is prone to yellowing and pulverization under long-term ultraviolet radiation, and the mechanical property is reduced are effectively solved, and the acrylic coating is suitable for the field of electronic equipment protective coatings with high requirements for weather resistance, mechanical strength and electrical insulating property.

The invention relates to the technical field of preparation of building external wall thermal insulation materials, in particular to a building external wall thermal insulation board based on pearl wool and a preparation method of the building external wall thermal insulation board. The core layer is prepared from the following raw materials in parts by weight: 40 to 60 parts of pearl wool particles, 5 to 15 parts of graphene-loaded expanded graphite, 3 to 10 parts of nano silicon dioxide aerogel, 10 to 20 parts of ammonium polyphosphate, 5 to 12 parts of pentaerythritol, 3 to 8 parts of melamine, 15 to 25 parts of ethylene-vinyl acetate copolymer, 5 to 10 parts of maleic anhydride grafted polyethylene, 2 to 6 parts of nano montmorillonite and 1 to 5 parts of silicon carbide whisker; the composite material is prepared from the following components in parts by weight: 0.5-2 parts of a silane coupling agent KH560, 0.2-0.8 part of an antioxidant 1010, 3-8 parts of amino-terminated polyether and 0.3-1 part of a hindered amine light stabilizer 770. The thermal insulation board is excellent in thermal insulation, mechanical property and flame retardant property, good in weather resistance, stable in size and high in construction adaptability, pearl wool can be recycled, and the thermal insulation board has practical and environment-friendly values.

The invention relates to the technical field of drilling compositions, in particular to a composite plugging agent, a plugging composition and plugging cement paste for shale gas formation cracks. The composite plugging agent for shale gas stratum cracks is composed of a bridging material, a filling material and an end-capping material, the mass ratio of the bridging material to the filling material to the end-capping material is (1.2-1.4): 0.5: (0.1-0.3), the bridging material is organic fibers with the length of 3-5 mm, the filling material is composed of inert particles with the particle size of 35-280 [mu] m and micro-silicon with the particle size of 0.15-1 [mu] m, and the end-capping material is a mixture of silicon oxide and silicon oxide. The end-capping material is composed of organic fibers with the length of 8-9 mm and walnut shells with the particle size of 3-5 mm. Through compounding of different types of bridging materials, filling materials and end sealing materials and grading of fibers with different lengths and plugging particles with different particle sizes, the plugging agent can be matched with cement paste in complex cracks and large cracks (1-4 mm) of a stratum to form a stable and compact plugging layer, the compressive strength is high, effective retention is achieved, and the effect of plugging a complex leakage layer is achieved.

The invention discloses two-component addition type low-density liquid foaming silicone rubber and a preparation method thereof, and belongs to the technical field of silicone rubber preparation. Comprising a component A and a component B, the component A is prepared from the following components in parts by weight: 50 to 70 parts of vinyl terminated polysiloxane, 10 to 20 parts of vinyl hydroxyl silicone oil, 0.5 to 2 parts of platinum catalyst, 15 to 25 parts of HGM (at) PN-rGO / APP and 3 to 8 parts of methyl vinyl MQ resin; the component B is prepared from the following components in parts by weight: 50 to 60 parts of vinyl-terminated polysiloxane, 8 to 15 parts of hydrogen-terminated hydrogen-containing silicone oil, 10 to 20 parts of methyl-terminated hydrogen-containing silicone oil, 5 to 10 parts of hydroxyl-terminated silicone oil, 0.002 to 0.01 part of an inhibitor, 10 to 20 parts of fumed silica and 1 to 3 parts of a tackifier. The synergistic components in the HGM-coated PN-rGO / APP can greatly improve the flame retardant property of the silicone rubber, improve the compression strength and reduce the heat release rate at the same time.

The invention provides a silicone rubber material for a composite insulator and a preparation method thereof.The silicone rubber material is prepared from, by mass, 100 parts of vinyl-terminated polydimethylsiloxane, 12-16 parts of hydrophobic modified white carbon black, 3-5 parts of borate modified white carbon black, 5-7 parts of hydroxyl-terminated polydimethylsiloxane, 8-12 parts of polymethylhydrosiloxane and 0.001-0.005 part of a platinum catalyst, and 0.1-1 part of a light stabilizer. Through the synergistic effect of boric acid ester modified white carbon black and hydroxyl-terminated polydimethylsiloxane introduced into a silicone rubber system, an organic-inorganic composite interface structure with a reversible bonding characteristic can be constructed in the material, so that a polydimethylsiloxane chain segment can realize slow-release migration and dynamic compensation in a complex service environment; therefore, the hydrophobicity retentivity and the surface self-recovery capability of the composite insulator silicone rubber are remarkably improved.

The invention belongs to the technical field of high-performance polymer materials, and relates to thermal-crosslinkable polyimide, polyimide foam and a preparation method and application thereof. Aiming at the problem that the foaming performance of the existing polyimide foaming material is poor due to the fact that the melt strength and the chain segment activity are difficult to balance, the invention provides a method for regulating and controlling the rheological property by controlling the number-average molecular weight (Mn = 15-45kDa) of a precursor and introducing a thermally-crosslinkable end-capping group. The precursor can form a parison with a specific elastic network structure through hot-pressing cross-linking, and then the polyimide foam which is high in foaming rate, uniform and fine in foam hole, low in density and excellent in heat resistance can be prepared through a two-step method of supercritical fluid saturation pressure relief and high-temperature secondary foaming. The method realizes predictable control from molecular parameters to foaming performance, is suitable for various thermoplastic polyimide systems, and has a wide application prospect in the fields of aerospace heat insulation and the like.

The invention relates to the technical field of composite materials, in particular to a polyaryletherketone-based shape memory composite material and a preparation method thereof. Comprising a terpolymer, shape memory polyurethane, a first heat-conducting filler and a second heat-conducting filler, 4, 4 '-difluorobenzophenone and hydroquinone are firstly pre-polymerized to obtain a PEEK prepolymer, the PEEK prepolymer is terminated by a hydroxyl olefine acid ester monomer to obtain a terminated copolymer, and then an acrylate monomer and the terminated copolymer are subjected to double-bond addition to obtain the terpolymer; the first heat-conducting filler is a one-dimensional nano heat-conducting filler; the second heat-conducting filler is a zero-dimensional and / or two-dimensional heat-conducting substance; the prepared composite material has the shape fixing rate of 85% or above and the shape recovery rate of 87% or above, the recovery time is shorter than 25 seconds, and the good shape memory performance is achieved.

The invention provides an organic silicon pouring sealant for a new energy automobile heater and a preparation method thereof, the organic silicon pouring sealant comprises a component A and a component B, the mass ratio of the component A to the component B is 1: 0.9-1.1; the component A comprises the following components in percentage by mass: 35%-45% of double-end vinyl silicone oil; 3-5% of modified silicone oil; 10%-20% of spherical silica powder; 35-45% of aluminum hydroxide; 0.1%-0.3% of fumed silica; 1%-2% of a molecular sieve; 0.3%-0.5% of a platinum catalyst; 0.1%-0.3% of carbon black; wherein the modified silicone oil is vinyl alkoxy terminated silicone oil. According to the technical scheme provided by the invention, hydroxyl silicone oil is subjected to alkoxy and vinyl end-capping modification, so that the organic silicon pouring sealant can form good bonding sealing with an aluminum alloy matrix and an electronic component when being cured at normal temperature, does not have obvious smell, and is convenient to use.

The invention relates to the technical field of special cables, and discloses a high and low temperature resistant composite insulating layer cable and a preparation method thereof.The cable comprises a conductor core and a composite insulating layer wrapping the conductor core, and the composite insulating layer comprises a high temperature resistant heat conduction core layer and a low temperature resistant elastic layer; the high-temperature-resistant heat-conducting core layer is prepared from the following raw material: polyamide acid; hexagonal boron nitride; alpha-phase silicon carbide; the preparation method comprises the following steps: adding gamma-amino propyl triethoxy silane; nano barium titanate; the low-temperature-resistant elastic layer is prepared from the following raw materials: vinyl terminated polydimethylsiloxane; performing hydrophobic treatment on fumed silica; a Karstedt catalyst; a hydrogen-containing silicone oil crosslinking agent; the average particle size D50 of the 1-ethynyl-1-cyclohexanol and the alpha-phase silicon carbide is 0.5 to 2 mu m. According to the invention, by adopting a microwave selective heating and interlayer heat conduction mechanism, efficient and high-quality integrated curing of the composite insulating layer is realized.

The invention relates to the technical field of adhesives, and provides a high-thermal-conductivity modified silane polyether adhesive and a preparation method thereof.The silane-terminated polyether sealant is prepared from silane modified polyether resin, modified filler, a flame retardant, a silane coupling agent, a catalyst, an antioxidant and a water removal agent; the modified filler is obtained by grafting a hydroxylated AlN filler or a hydroxylated BN filler or a hydroxylated AlN and hydroxylated BN compound filler with silane under the catalysis of a weak acid to form a Si-O-Al or / and Si-O-B covalent bond network, and then mixing the Si-O-Al or / and Si-O-B covalent bond network with nano silicon dioxide particles of which the surfaces are coated with polydopamine. Through a multi-dimensional filler modification technology and reasonable matching of other auxiliaries, the problem of synergism of heat conduction, flame retardance and mechanical properties of the MS adhesive under a high filling system is solved, and the material is suitable for a new energy power battery module.

The invention provides an epoxy adhesive solution composition, a preparation method of an epoxy adhesive solution and a modified cellular board. The epoxy adhesive liquid composition comprises the following components in parts by weight: 53-58 parts of epoxy resin, 2-10 parts of a silane coupling agent, 1-10 parts of a curing agent, 1-5 parts of blocked isocyanate and 60-70 parts of water, wherein a blocking group of the blocked isocyanate is selected from hydroxyl, oximido, acylamino, amino, imidazolyl, pyrazolyl or piperazinyl. By introducing the blocked isocyanate with the specific structure, the epoxy adhesive liquid can be subjected to pre-crosslinking reaction in the early drying treatment process, the modulus and high temperature resistance of a formed dry film are improved, and the phenomenon of glue overflow in the subsequent curing stage is inhibited; therefore, the structural integrity and the bonding strength of the adhesive layer in the modified cellular board under the high-temperature condition are improved.

The application provides a wear-resistant transparent flexible fluorine-free super-hydrophobic composite coating and a preparation method thereof. The preparation method comprises the following steps: mixing and reacting hydroxyl-terminated polydimethylsiloxane, gamma-aminopropyl triethoxysilane and dibutyl tin dilaurate to obtain a modified precursor solution, adding swelled epoxy resin into the modified precursor solution, and obtaining a siloxane modified epoxy resin after heating reaction; dispersing nano-silicon dioxide in an ethyl acetate solution to form a SiO2 suspension; uniformly mixing the modified epoxy resin and the SiO2 suspension, adding polyether amine as a curing agent, and stirring and mixing, and then adopting an air spraying mode to build an epoxy resin / hydroxyl-terminated polydimethylsiloxane / nano-silicon dioxide super-hydrophobic coating on a substrate. The preparation method can prepare a super-hydrophobic coating with excellent transparency and flexibility, good adhesion and wear resistance, and has a wide application prospect in the fields of wearable electronic devices and optoelectronic devices.

The invention discloses a hyperbranched polyether branching agent with an adjustable structure and a preparation method and application thereof.According to the branching agent, 3-butene-1-alcohol serves as an initiator, a hyperbranched skeleton is constructed through anion ring-opening polymerization reaction and diglycidyl ether, then esterification and end capping are conducted through anhydride, and the hyperbranched polyether branching agent with the adjustable structure is obtained. The tail end of the hyperbranched polyether contains vinyl double bonds, and the ester group structure of the hyperbranched polyether can be regulated and controlled. Different diepoxy compounds are selected to control a main chain structure, and different anhydrides are used for regulating and controlling the chemical composition of branched chains, so that accurate design of molecular weight, polarity and number of functional groups of the branching agent is realized. The branching agent has excellent dissolvability in common organic solvents, and solves the problem of poor dissolvability of the traditional polydiene branching agent. When the star-shaped branched butyl rubber is applied to the synthesis of star-shaped branched butyl rubber, the distribution and number of branched points can be accurately regulated and controlled, the weight-average molecular weight and molecular weight distribution index of the rubber are remarkably improved, and the side reaction of gel is avoided.

The invention discloses SIS (styrene-isoprene-styrene) containing dynamic reversible bonds and a preparation method thereof, and belongs to the technical field of high polymer materials. The copolymer is prepared through a Diels-Alder reaction with bismaleimide on the basis of a polystyrene construction unit with two tail ends capped with furan and a polyisoprene construction unit module with two tail ends capped with furan. Wherein the DA bond has a thermal reversible characteristic. The furan end-capped building unit module with controllable molecular weight and narrow distribution is prepared, and reversible connection and dissociation of blocks are realized through a modularization strategy. According to the invention, an inverse Diels-Alder reaction can be carried out at 120-140 DEG C, and is dissociated into an original construction unit module, so that the proportion of soft and hard segments of a copolymer is changed by supplementing a specific construction unit feeding amount and carrying out the Diels-Alder reaction again; the SIS has the advantages of being accurate in structure and designable in performance at the same time, flexible regulation and control over the block proportion are achieved through the SIS containing the dynamic reversible bonds, and meanwhile the SIS has wide application prospects in the fields of recyclable adhesives, intelligent packaging, flexible electronics and the like.

The invention relates to the field of polyimide films, and discloses a catalytic polyimide film with a low thermal expansion coefficient and a preparation method thereof, the catalytic polyimide film comprises 43-47% of a rigid polyimide material, 28-32% of a flexible polyimide material, 4-6% of a dynamic cross-linking agent, 7-9% of a component agent, and the balance of a solvent; the dynamic cross-linking agent comprises maleimide terminated polyamide and a difuran compound, and the ratio of the maleimide terminated polyamide to the difuran compound is 3: 2. Through the synergistic effect of constructing a stable framework by a rigid polyimide material, buffering stress by a flexible polyimide material and uniformly dissipating heat by flaky boron nitride, a chemical regulation and control system of'rigid constraint-flexible buffering-heat conduction balance 'is formed, thermal expansion is inhibited from the molecular level, and compared with a traditional physical method which purely depends on external force or a single component, the thermal expansion coefficient is greatly improved. According to the system, through complementation of chemical mechanisms of all components, the dimensional stability under temperature fluctuation is improved to a new height, and the problem that the thermal expansion coefficient in a wide temperature range is difficult to control is solved.

The invention provides bio-based MS base resin, bio-based MS glue and a preparation method of the bio-based MS base resin and the bio-based MS glue, and belongs to the technical field of high polymer materials. The MS base resin is isocyanate group silane terminated bio-based polyether polyol or polyether polyol subjected to chain extension. The polyether polyol is selected from one or more of bio-based polyethylene glycol, bio-based polypropylene glycol, bio-based poly (trimethylene ether glycol) and bio-based polytetrahydrofuran ether glycol. And mixing the bio-based MS base resin, the plasticizer, the filler, the catalyst III, the coupling agent and the auxiliary agent, and stirring under a vacuum condition to obtain the bio-based MS adhesive. The bio-based MS adhesive prepared by the invention is high in bio-based material content, uncomplicated in preparation process and low in energy consumption, and meanwhile, an adhesive body is good in mechanical property, high in stability and good in high temperature resistance and humidity and heat resistance.

The invention relates to the technical field of fibers, in particular to a controlled-release anti-aging polypropylene fiber and a preparation method thereof. The fiber is prepared from polypropylene homopolymer resin, a reaction type interface layer master batch and a controlled release anti-aging master batch, the reactive interface layer master batch is formed by reacting and extruding maleic anhydride modified polypropylene and 3-aminopropyl terminated polydimethylsiloxane, so that the interface compatibility is enhanced; the controlled-release anti-aging master batch contains hydroxyl and peracetylated cyclodextrin grafted siloxane carriers, and an ultraviolet absorbent, a light stabilizer and an antioxidant are included, so that the controlled release of an anti-aging agent is realized. The preparation method comprises the steps of master batch preparation, final mixing granulation, melt spinning and drafting setting. The fiber strength is remarkably improved, the boiling water shrinkage rate is reduced, the strength retention rate after ultraviolet aging reaches 93% or above, the yellow index change is small, and the outdoor service life is prolonged.

The invention belongs to the field of polyester resins, and provides a weather-resistant polyester resin for low-temperature curing and a preparation method thereof. A three-step progressive design that a polyester prepolymer is terminated by silane and then is subjected to hydrolytic polycondensation with tetraethyl orthosilicate to construct an organic-inorganic covalent hybrid network is adopted; through cooperation of the condensation catalyst, the hindered amine light stabilizer and the ultraviolet absorbent, the mechanical properties that the pencil hardness reaches the HB level or above and the cross-cut test level is not higher than the first level under the low-temperature curing condition of not higher than 100 DEG C are achieved, and the long-term weather resistance that the color difference is not larger than 2.0 and the gloss retention rate is not lower than 80% after 500-hour artificial accelerated aging is achieved. The technical problems of poor storage stability and difficulty in consideration of high solid content and low viscosity caused by insufficient low-temperature curing capacity and non-uniform organic-inorganic hybridization of the traditional polyester resin are solved, and the polyester resin has wide application value in the fields of building coatings, automobile refinishing paints, wood coatings and the like with strict requirements on low-temperature curing and weather resistance.

The invention discloses a modified waterborne polyurethane adhesive and a preparation method thereof, and relates to the technical field of adhesives. The carbon dioxide-based polycarbonate polyol is prepared from the following raw materials in parts by mass: 70 to 84 parts of carbon dioxide-based polycarbonate polyol, 8 to 9.6 parts of hexamethylene diisocyanate, 3 to 3.6 parts of isophorone diisocyanate, 0.01 to 0.012 part of dibutyltin dilaurate, 10 to 12 parts of N-methyl pyrrolidone, 3.5 to 4.2 parts of dimethylolpropionic acid, 0.1 to 0.5 part of 1, 3-butanediol, 0.1 to 0.5 part of a catalyst and 0.1 to 0.5 part of a catalyst. The adhesive is prepared from the following components in parts by weight: 1 to 1.2 parts of 1, 4-butanediol, 21 to 25.2 parts of modified polyurethane dispersion, 2 to 2.5 parts of silane-terminated dynamic cross-linking agent, 2.8 to 3.4 parts of triethylamine, 40 to 60 parts of acetone, 200 to 220 parts of deionized water and 10 to 12 parts of ethylenediamine aqueous solution. By introducing the modified polyurethane dispersion and the silane-terminated dynamic cross-linking agent, the base material universality, water resistance and temperature resistance of the adhesive are effectively improved.

The invention discloses yellowing-resistant light-cured organic silicon resin and a preparation method thereof, and belongs to the technical field of light-cured resin. The resin is prepared from the following raw materials in parts by weight: 80 to 100 parts of vinyl-terminated polysiloxane, 15 to 25 parts of trimethylolpropane tri (3-mercaptopropionate), 1 to 3 parts of yellowing-resistant aid, 2 to 4 parts of photoinitiator and 0.5 to 1 part of flatting agent. When the resin is prepared, the raw materials are uniformly mixed under a dark condition, and the resin is obtained after vacuum defoaming. Wherein the yellowing-resistant auxiliary agent is a benzotriazole ultraviolet light absorber and is synthesized through a multi-step reaction, the structure simultaneously contains a benzotriazole ring and anthryl, and the benzotriazole ring and the anthryl have a synergistic effect so that ultraviolet rays can be efficiently absorbed and yellowing can be inhibited. The obtained resin has excellent yellowing resistance and high curing speed, and is suitable for the fields of coatings, printing ink, adhesives, electronic packaging and the like.

The invention provides polyether base oil and a preparation method and application thereof.According to the polyether base oil, a melt polycondensation method is adopted, a diester group-COO-R-COO-is introduced into a molecular structure through hydroxyl groups at the two ends of polyalkylene oxide, a polyether ester molecular chain with ether bonds and diester bonds distributed alternately is formed, and the polyether base oil is prepared. Then, carboxyl at the end group of a molecular chain is further subjected to an end-capping reaction with an amine compound, a unique amine double-end-capped polyether ester structure is obtained, and the polyether base oil has excellent viscosity-temperature performance, oxidation resistance, anti-rust performance and anti-wear and anti-friction performance.

The invention relates to a heat-resistant dealcoholized heat-conducting organic silicon adhesive and a preparation method thereof, and belongs to the technical field of high polymer materials. The adhesive is prepared from the following raw materials in parts by weight: 100 parts of trimethoxysilyl terminated polydimethylsiloxane, 1 to 20 parts of a heat-resistant plasticizer, 100 to 800 parts of heat-conducting powder, 3 to 10 parts of heat-resistant filler, 1 to 15 parts of a silane crosslinking agent and 0.5 to 5 parts of a titanate catalyst. The heat-resistant filler is selected from one or more of ferric oxide, cerium oxide, titanium dioxide, zirconium dioxide, carbon black and phthalocyanine blue. Through reasonable proportioning of the raw materials and addition of the heat-resistant filler, the adhesive forms a compact siloxane network after being cured, has excellent heat conductivity, heat resistance and adhesive performance, and is suitable for heat dissipation and adhesive application in the fields of high-power electronic equipment, new energy automobiles, aerospace and the like. The preparation method is simple and easy for industrial production.

The invention discloses a high-elasticity anti-aging foamed silica gel sealing element, and belongs to the technical field of sealing materials. The silicone rubber is prepared from raw materials including methyl vinyl silicone rubber, fumed silica, hydroxyl-terminated polydimethylsiloxane and the like according to specific parts by weight through the processes of mixing, foaming vulcanization and the like. The apparent density of the sealing element is 0.3-0.6 g / cm < 3 >, the Shore A hardness is 25-45 degrees, the tensile strength is larger than or equal to 2.5 MPa, the elongation at break is larger than or equal to 350%, the performance retention rate is high after the sealing element is aged for 1000 h at the temperature of 150 DEG C, and the sealing element has excellent elasticity and aging resistance. The surface of the anti-slip sealing gasket can be provided with anti-slip textures to meet sealing requirements in the fields of automobiles, electronics and the like, and is long in service life and high in practicability.

The invention discloses a preparation process of polyether-ether-ketone, and relates to the technical field of preparation of inorganic compounds. The preparation process comprises the following steps: reacting 4, 4 '-difluorobenzophenone, sodium carbonate and hydroquinone to generate polyether-ether-ketone, taking a polyaryletherketone block oligomer as an end-capping reagent, reacting 4, 4'-difluorobenzophenone with 4, 4 '-dimercaptodiphenyl sulfone, and then reacting with pentaerythritol phosphate to obtain the polyaryletherketone block oligomer. The thioester bond reversibly breaks at the polymerization temperature, exposed active sulfenyl reacts with hydroxyl at the tail end of the polyether-ether-ketone to form a more stable covalent bond, volatilization of the end-capping reagent is avoided, meanwhile, the initial decomposition temperature of the end-capped polyether-ether-ketone is increased, and the stability of the end-capping reagent is improved. The polyether-ether-ketone generated in the polyether-ether-ketone resin product is subjected to treatment procedures of crushing, organic solvent extraction, water washing, filtering, drying and the like, so that the product polyether-ether-ketone is obtained, less three wastes are generated, the solvent can be recycled, the atom economy is relatively high, and the preparation process of comprehensive utilization of resources is realized.

The invention discloses a hydrophobic anti-icing material based on silver ions and application in a power transmission line, and belongs to the technical field of hydrophobic anti-icing materials, the hydrophobic anti-icing material is prepared from the following raw materials in parts by weight: 80-120 parts of hydroxyl-terminated polydimethylsiloxane, 5-15 parts of tetraethoxysilane, 0.5-3 parts of silver nitrate, 3-10 parts of hydrophobic nano silicon dioxide and 1-5 parts of nano titanium dioxide. The invention discloses an anti-icing and deicing composite material, which is prepared from the following components in parts by weight: 80 to 120 parts of butyl acetate, 0.1 to 0.5 part of dibutyltin dilaurate, 0.5 to 2 parts of sodium citrate and 2 to 5 parts of modified fluorinated phosphotungstic acid imidazole compound, and solves the problems that the existing material is insufficient in photo-thermal utilization rate, poor in stability in a severe environment, insufficient in hydrophobic capacity and difficult to give consideration to anti-icing and deicing effects. According to the scheme, the modified fluorinated phosphotungstic acid imidazole compound and silver ions are introduced to form a synergistic effect, formation of an ice layer is inhibited, melting of the ice layer is promoted, meanwhile, lasting super-hydrophobicity is provided, a durable hydrophobic anti-icing coating based on the silver ions is formed, and the safety of a power grid is guaranteed.

The invention relates to a novel quaternary ammonium salt modified positively charged nanofiltration membrane and a preparation method thereof, and belongs to the technical field of membrane separation. Adding the prepared novel quaternary ammonium salt monomer QAC serving as an additive into a water-phase solution containing an amine monomer and lauryl sodium sulfate (SDS) to form a mixed water-phase solution; and carrying out polymerization reaction with acyl chloride monomers in an oil phase on a water-oil interface by an interfacial polymerization method to realize preparation of the novel quaternary ammonium salt modified positively charged nanofiltration membrane. The QAC monomer serving as a novel end-capping reagent can react with acyl chloride groups in acyl chloride monomers in the interfacial polymerization process, so that further reaction between the QAC monomer and amine monomers in a water phase is prevented, the crosslinking degree of a macromolecular network structure in the polymerization process is reduced, and the permeation flux of the composite membrane is favorably improved. Meanwhile, the quaternary ammonium salt structure also effectively enhances the positive charge density of the surface of the nanofiltration membrane, so that the interception performance of the nanofiltration membrane on divalent magnesium ions in the magnesium-lithium separation process is enhanced, and efficient separation of magnesium and lithium is realized.

The invention relates to an epoxy hardener and a preparation method thereof and a preparation method of a visbreaking uncovering protective film, and the preparation method of the epoxy hardener comprises the following steps: adding 2, 2 '-(1, 3-phenylene)-dioxazoline and a phenolic hydroxyl group or carboxyl group-containing bifunctional monomer into a first solvent, stirring at normal temperature to obtain a first solution, heating to a first temperature, and stirring at normal temperature to obtain a second solution; the first temperature is 155 DEG C to 165 DEG C, and refluxing for 3.5 hours to 4.5 hours; adding a terminated monomer containing carboxyl or phenolic hydroxyl into a reaction system of the first solution, and continuing to carry out reflux reaction for 2.5-3.5 hours at the first temperature; and after the reaction is finished, purifying and drying to obtain the epoxy curing agent. The epoxy curing agent disclosed by the invention has compatibility with low-polarity glue and has a relatively high curing degree in a high-temperature environment; the viscosity-reducing uncovering protective film has the advantages that the viscosity is reduced at high temperature, and the uncovering design efficiency of different types of PCBs is improved.

The invention relates to the technical field of coatings, discloses a multifunctional fireproof and waterproof polysiloxane coating and a preparation method thereof, and aims at solving the problems that the hydrophobic function of an existing fireproof and waterproof polysiloxane coating is irreversibly lost after a fire disaster, and the fireproof and waterproof synergistic performance is remarkably attenuated in a medium-high-temperature environment. Hydroxyl-terminated methyl phenyl siloxane is used as matrix resin, and is matched with a flame-retardant system composed of melamine modified ammonium polyphosphate, pentaerythritol and amino modified nano-montmorillonite, a hydrophobic repair system composed of polysiloxane capsule wall fluorosilane microcapsules, an interface modifier compounded by an epoxy group and an amino silane coupling agent, and a special auxiliary agent. A three-dimensional covalent network is constructed to anchor all the components, efficient charring and temperature response type hydrophobic repair are achieved, the finished product is prepared through microcapsule preparation, modified flame retardant compounding and coating main body blending, and the finished product has excellent fireproof and waterproof performance, a renewable hydrophobic function after a fire disaster and stable performance at medium and high temperatures and is suitable for industrial long-term protection scenes.

The invention provides an acrylic polyurethane coating and a preparation method thereof, and belongs to the technical field of coating compositions.The preparation method comprises the following steps that hexylpolyurethane based on non-isocyanate sorbitol, methacrylic anhydride, p-toluenesulfonic acid and hydroquinone monomethyl ether are mixed and heated for a reaction, ethyl acetate is added for mixing, washing, drying, filtering and vacuum concentration are performed, and the acrylic polyurethane coating is obtained. The bio-based polyurethane acrylate is obtained; the preparation method comprises the following steps: mixing ZG nanoparticles, methylbenzene, 3-(methacryloyloxy) propyltrimethoxysilane and hydroquinone monomethyl ether, heating, stirring, centrifuging and washing to obtain functionalized ZG; and fully mixing the bio-based polyurethane acrylate, the photoinitiator, the acrylate-based single-terminated reactive polysiloxane, the reactive diluent and the functionalized ZG to obtain the acrylic polyurethane coating. The coating can improve the curing speed, and has hydrophobic and oleophobic properties and corrosion resistance at the same time.

The invention provides a low-viscosity and high-strength modified epoxy resin grouting material which is mainly prepared from a component A and a component B in a mass ratio of (2: 1)-(3: 1) during use, carboxyl-terminated modified epoxy resin is adopted, and a carboxyl group with strong hydrophilicity and a hydroxyl group generated in the modification process are introduced into an epoxy resin molecular chain, so that the high-strength modified epoxy resin grouting material is obtained. According to the epoxy resin grouting material and the preparation method thereof, the affinity of the epoxy resin grouting material to water molecules is greatly enhanced, hydrophilic groups of modified epoxy molecules extend into a water covering layer in a crack of a building body, the defect that an existing grouting material is incompatible with the water covering layer is overcome, the surfactant contains a defoaming polysiloxane component, particles can be uniformly dispersed in a mixture, and the grouting effect is improved. A good dispersion effect is achieved; the silane coupling agent is added, so that the performance and the bonding strength of the epoxy resin grouting material are also improved.