1827 results about "Endcapping" patented technology

The invention discloses a scratch repair coating and a preparation method thereof, and relates to the technical field of high polymer materials. When the scratch repair coating is prepared, hydroxylated boron nitride reacts with 1-(3-triethoxysilylpropyl)-2-imidazoline to prepare pre-modified boron nitride, and then the pre-modified boron nitride and 4-chloro-1-butene are subjected to quaternization to prepare modified boron nitride; the preparation method comprises the following steps: reacting styryl phosphonic dichloride with 4, 4, 5, 5, 6, 6, 7, 7, 7-nonafluoro-1, 2-heptanediol to prepare a hydroxyl-terminated phosphorus-fluorine-containing polymer; the preparation method comprises the following steps: reacting isophorone diisocyanate with a hydroxyl-terminated phosphorus and fluorine-containing polymer to prepare a polyurethane prepolymer; reacting the polyurethane prepolymer with hydroxyl-terminated coumarin to generate modified polyurethane; and uniformly mixing the modified polyurethane, the modified boron nitride and a photoinitiator to prepare the scratch repair coating. The scratch repairing coating prepared by the invention has good self-repairing performance, flame retardant property, corrosion resistance and mechanical property.

Described herein are methods, compositions and articles of manufacture involving neutral conjugated polymers including methods for synthesis of neutral conjugated water-soluble polymers with linkers along the polymer main chain structure and terminal end capping units. Such polymers may serve in the fabrication of novel optoelectronic devices and in the development of highly efficient biosensors. The invention further relates to the application of these polymers in assay methods.

The invention discloses a high-cold-resistance environment-friendly PVC decorative material and application thereof, belongs to the technical field of PVC preparation, and is used for solving the technical problem that the low temperature resistance and the environmental protection property of a PVC material in the prior art need to be further improved. The high-cold-resistance environment-friendly PVC decorative material specifically comprises the following raw materials in parts by weight: 80-100 parts of composite PVC, 8-10 parts of a bio-based plasticizer and 6-10 parts of an auxiliary additive; the preparation method comprises the following steps: modifying montmorillonite by using a silane coupling agent, loading magnesium hydroxide to prepare a composite filler, carrying out ring-opening polymerization, amine end capping and oxidation on cyclotrisiloxane to generate a low-temperature-resistant agent containing an epoxy group, introducing trimethoxysilane into PVC through sulfydryl substitution, carrying out hydrolytic condensation to form a Si-O-Si cross-linked network, and covalently binding the Si-O-Si cross-linked network with the filler and the low-temperature-resistant agent to obtain the low-temperature-resistant PVC composite material. And reacting the epoxidized soybean oil with glycine, and carrying out calcium coordination to generate a bio-based plasticizer, thereby finally preparing the PVC decorative material.

The invention relates to the field of quantum dot ink, and discloses diffusion plate printing quantum dot ink and a preparation method thereof.The diffusion plate printing quantum dot ink comprises acrylic resin, hyperbranched polyester resin, a quantum dot material, modified boron nitride, a reactive diluent, a photoinitiator, a wetting agent and a defoaming agent; the hyperbranched polyester resin is prepared by reacting hyperbranched polyester acrylate and a sulfydryl-terminated silicon-containing reaction monomer, wherein the hyperbranched polyester acrylate is prepared by reacting pentaerythritol with 2, 2-dimethylolpropionic acid and then carrying out esterification reaction with acrylic acid; the sulfydryl-terminated silicon-containing reaction monomer is prepared by reacting eugenol with 1, 1, 3, 3-tetramethyldisiloxane and then carrying out esterification reaction with 3-mercaptopropionic acid; the modified boron nitride is prepared by modifying a cationic polymer which is prepared by carrying out a Mannich reaction on triethylene tetramine, formaldehyde and acetone and then carrying out a condensation polymerization reaction with formaldehyde. After the ink prepared by the invention is cured, a coating film is high in hardness, adhesive force and heat conductivity coefficient, and good in flexibility, heat resistance and migration barrier property.

The invention discloses an uvioresistant acrylic resin coating and a preparation method thereof, and belongs to the technical field of acrylic resin paints.The uvioresistant acrylic resin coating is characterized in that step-by-step functional design is adopted, a functional polyurethane prepolymer is constructed through prepolymerization reaction and double-bond end capping, fluorosilicone modified acrylate emulsion is prepared through a core-shell emulsion polymerization process, and the uvioresistant acrylic resin coating is obtained. Then carrying out surface silane modification on hexagonal boron nitride and carrying out composite coating to obtain a modified boron nitride auxiliary agent; and finally, carrying out composite emulsification and dispersion compounding on all the components to obtain the anti-ultraviolet acrylic resin coating. Through the synergistic enhancement effect of the fluorosilicone modified core-shell structure and the surface modified boron nitride, the ultraviolet aging resistance and the insulation reliability of the coating are remarkably improved on the basis of keeping high adhesive force, excellent flexibility and impact resistance of the coating; the problems that a traditional acrylic coating is prone to yellowing and pulverization under long-term ultraviolet radiation, and the mechanical property is reduced are effectively solved, and the acrylic coating is suitable for the field of electronic equipment protective coatings with high requirements for weather resistance, mechanical strength and electrical insulating property.

The invention belongs to the technical field of polymer insulating materials, and particularly discloses a high-toughness and high-insulating-strength epoxy insulating material and a preparation method thereof. Single-end amine-terminated straight-chain alkyl groups with different chain lengths in a specific molar ratio are grafted to fluorine-containing epoxy resin to construct a side chain structure, and then a step curing process is adopted to form a three-dimensional cross-linked network with a curing agent under the action of an accelerant. The fracture toughness is remarkably improved by utilizing an epoxy body chain extension effect in a side chain grafting process and a uniform microphase separation structure formed by self-assembly of a long alkyl side chain in a curing process; meanwhile, through the synergistic effect of steric hindrance of a short alkyl side chain and a fluorine atom charge trap, delocalized electron transmission of a benzene ring conjugated structure is inhibited, and the insulating property is synchronously enhanced. Compared with a traditional toughening technology, insulation deterioration caused by toughening modification is effectively avoided, and an epoxy resin material with mechanical reliability and insulation stability is provided for high-voltage electrical equipment.

The invention relates to the technical field of silicone rubber preparation, in particular to high-flame-retardant insulating liquid silicone rubber and a preparation method and application thereof. The high-flame-retardant insulating liquid silicone rubber is prepared from the following raw materials in parts by mass: 60 to 75 parts of vinyl-terminated polydimethylsiloxane, 5 to 8 parts of methylhydrosiloxane, 20 to 24 parts of a flame retardant, 0.1 to 0.2 part of a platinum catalyst, 25 to 30 parts of modified silicon dioxide and 2 to 3 parts of a silane coupling agent, and the flame retardant is prepared by mixing decabromodiphenyl ethane and modified magnesium hydroxide. The high-flame-retardant insulating liquid silicone rubber not only has excellent flame retardance, insulativity, high-temperature-resistant stability and the like, but also has remarkable advantages in mechanical properties and environmental adaptability, and provides safer and more reliable material choices for related fields.

The invention provides a wear-resistant, transparent, flexible and fluoride-free super-hydrophobic composite coating and a preparation method thereof. The preparation method comprises the following steps: mixing hydroxyl-terminated polydimethylsiloxane, gamma-aminopropyltriethoxysilane and dibutyltin dilaurate for reaction to obtain a modified precursor solution, adding swelled epoxy resin into the modified precursor solution, and heating for reaction to obtain siloxane modified epoxy resin; the preparation method comprises the following steps: dispersing nano silicon dioxide in an ethyl acetate solution to form a SiO2 suspension; and uniformly mixing the modified epoxy resin with a SiO2 suspension, adding polyether amine as a curing agent, stirring and mixing, and constructing the epoxy resin / hydroxyl-terminated polydimethylsiloxane / nano-silica super-hydrophobic coating on a substrate by adopting an air spraying mode. According to the preparation method disclosed by the invention, the super-hydrophobic coating with excellent transparency and flexibility and good adhesive force and wear resistance can be prepared, and the super-hydrophobic coating has a wide application prospect in the fields of wearable electronic equipment, photoelectric devices and the like.

The invention relates to the technical field of waterproof agents for fabrics, and particularly discloses a fluoride-free waterproof agent for fabrics and a preparation method of the fluoride-free waterproof agent. The preparation method specifically comprises the following steps: dehydrating polyol / ester, adding isocyanate, heating to 80-90 DEG C, reacting for 2-3 hours, cooling, dropwise adding a chain extender, reacting for 0.5-1 hour at 45-48 DEG C, adding POSS, stirring for 1-2 hours at 45-48 DEG C, adding an acrylic monomer A for blocking, cooling, dropwise adding acid, stirring and neutralizing to obtain a prepolymer; pouring the prepolymer into water, stirring and emulsifying to obtain a POSS-PU emulsion; quickly stirring the POSS-PU emulsion, an acrylic monomer B, an emulsifier, water, a co-emulsifier, a pH regulator and the like to obtain a composite emulsion; homogenizing the composite emulsion until the composite emulsion has obvious blue light; and adding dodecanethiol and an azo amidine initiator, reacting at 68-70 DEG C for 3-7 hours, cooling, filtering and taking out to obtain the fluoride-free waterproof agent.

The invention discloses a copolyimide film with low dielectric constant and low thermal expansion coefficient and a preparation method thereof, and the preparation method comprises the following steps: reacting 0.019-0.021 mol of aromatic dianhydride and 0.017-0.023 mol of diamine unit in 0.45-0.48 mol of solvent, then adding 0.0004 mol of end-capping reagent dissolved in 0.13-0.15 mol of solvent, and reacting to prepare polyamide acid with a main chain containing o-hydroxyl; the diamine unit comprises 10-40 mol% of a monomer with a main chain containing o-hydroxyl and the balance of aromatic diamine; performing film coating and thermal imidization on polyamide acid to prepare a polyimide film; and heating to carry out thermal rearrangement reaction on the o-hydroxyl to obtain the copolyimide film with the main chain containing the oxazole ring. The dielectric constant of the prepared copolyimide film is 2.7-3.0, and the thermal expansion coefficient of the copolyimide film is 19.5-26.5 ppm / K.

The invention discloses a self-repairing nylon elastomer material as well as a preparation method and application thereof. The preparation method comprises the following steps: S1, polymerizing a nylon monomer in the presence of an amine end-capping reagent to prepare a double-amino-terminated nylon hard segment; s2, adding the double-amino-terminated nylon hard segment, the double-carboxyl-terminated polyether and / or polyester soft segment and a disulfide bond-containing chain extender into a reactor, adjusting the proportion of the raw materials, and polymerizing under an optional auxiliary A to obtain a double-amino-terminated pre-polymerized nylon elastomer; and S3, adding the double-amino-terminated pre-polymerized nylon elastomer and a dialdehyde chain extender into the reactor, and carrying out a reaction in the presence of an optional auxiliary agent B to obtain the self-repairing nylon elastomer material. According to the self-repairing nylon elastomer material provided by the invention, the nylon elastomer can be self-repaired in various environments through the synergistic effect of various dynamic covalent bonds, and the polymerization efficiency is remarkably improved.

The invention relates to the technical field of sewage treatment, in particular to an MABR hollow fiber composite membrane and a preparation method and application thereof.The preparation method comprises the following steps that raw materials, a reinforcing agent and a dispersing agent are put into a kneading machine to be kneaded for 1-2 hours, a modifying agent is put into the kneading machine, the mixture is heated to 80-120 DEG C and kneaded for 4 hours, and a modified material is obtained; the preparation method comprises the following steps: uniformly mixing a modified material, a catalyst, a cross-linking agent and a solution to prepare mixed slurry with the solid content of 5-40%, coating the slurry on the surface of a hollow fiber tube, and curing to obtain the MABR hollow fiber membrane, so that the mechanical strength of a basic raw material is improved through a reinforcing agent, the membrane is not easy to damage, and the service life of the membrane is prolonged. According to the present invention, the reinforcing agent and other auxiliary agents are uniformly dispersed in the basic raw material through the dispersant so as to reduce defects, the raw material end-capping group is modified through the modifier so as to provide the product with characteristics of aging resistance and good biocompatibility, and the reaction speed is changed during the molding process through the catalyst so as to form the stable membrane structure through the molding cross-linking of the cross-linking agent and the raw material;

The invention discloses a vegetable oil-based room-temperature water-induced self-healing polyurethane elastomer and a preparation method thereof. The elastomer is prepared by taking polytetramethylene ether glycol and tung oil glycol as soft segments, isophorone diisocyanate as a hard segment, dimethylolpropionic acid as a hydrophilic chain extender and 3-aminophenylboronic acid as an end-capping reagent. Polytetramethylene ether glycol and tung oil glycol are used as soft segments, isophorone diisocyanate is used as a hard segment, dimethylolpropionic acid is used as a hydrophilic chain extender, 3-aminophenylboronic acid is used for blocking, then triethylamine is used for neutralization, and a waterborne polyurethane material with high-density crosslinking sites is synthesized. The material has good mechanical properties and fracture toughness, the tensile strength of the polyurethane film can reach 6.94 MPa, the elongation at break can reach 790.1%, and the film has good rebound resilience.

The invention discloses a quick-curing polyurethane seamless expansion joint material for roads and a preparation method, and belongs to the technical field of road engineering materials. The material is prepared from polyether polyol, polycaprolactone glycol, a bisphenol A epoxy-polyether block isocyanate terminated prepolymer, a methyl phenyl silicon-boron hybrid hydroxyl chain extender, diphenylmethane diisocyanate, calcium carbonate, wollastonite, a hindered amine anti-aging agent and dioctyl phthalate. Wherein the bisphenol A epoxy-polyether block isocyanate terminated prepolymer is prepared by the following steps: reacting bisphenol A with epoxy chloropropane to generate epoxy resin, reacting with polytetramethylene ether glycol, and introducing isophorone diisocyanate; the methyl phenyl silicon-boron hybrid hydroxyl chain extender is prepared by carrying out hydrosilylation and ethylene glycol reaction on methyl trimethoxy silane, 3-glycidyl ether oxypropyl trimethoxy silane and allylboronic acid pinacol ester; and the methyl phenyl silicon-boron hybrid hydroxyl chain extender is prepared by carrying out hydrosilylation on methyl trimethoxy silane, 3-glycidyl ether oxypropyl trimethoxy silane and allylboronic acid pinacol ester. The material has the advantages of quick curing property, weather resistance and high-temperature stability, and is suitable for road seamless expansion joint scenes.

The invention relates to the technical field of preparation of building external wall thermal insulation materials, in particular to a building external wall thermal insulation board based on pearl wool and a preparation method of the building external wall thermal insulation board. The core layer is prepared from the following raw materials in parts by weight: 40 to 60 parts of pearl wool particles, 5 to 15 parts of graphene-loaded expanded graphite, 3 to 10 parts of nano silicon dioxide aerogel, 10 to 20 parts of ammonium polyphosphate, 5 to 12 parts of pentaerythritol, 3 to 8 parts of melamine, 15 to 25 parts of ethylene-vinyl acetate copolymer, 5 to 10 parts of maleic anhydride grafted polyethylene, 2 to 6 parts of nano montmorillonite and 1 to 5 parts of silicon carbide whisker; the composite material is prepared from the following components in parts by weight: 0.5-2 parts of a silane coupling agent KH560, 0.2-0.8 part of an antioxidant 1010, 3-8 parts of amino-terminated polyether and 0.3-1 part of a hindered amine light stabilizer 770. The thermal insulation board is excellent in thermal insulation, mechanical property and flame retardant property, good in weather resistance, stable in size and high in construction adaptability, pearl wool can be recycled, and the thermal insulation board has practical and environment-friendly values.

The invention discloses a high-CTI (comparative tracking index) flame-retardant polycarbonate composite material which comprises the following components in parts by weight: 70-80 parts of polycarbonate; 8-12 parts of a phosphate flame retardant; 3-7 parts of low-melting-point glass powder; 7-15 parts of titanium dioxide; and more than or equal to 80 mol% of end groups in the polycarbonate are terminated. Through cooperation of the phosphate flame retardant, the low-melting-point glass powder and the titanium dioxide, 1.5 mm V-0 flame retardance and even 1.0 mm flame retardance can be achieved on the premise that fluorine-containing anti-dripping agents such as PFAS are not contained and low filler filling is achieved, and meanwhile the CTI larger than or equal to 600 V is achieved.

The invention discloses a super-strong mute building drainage pipe and a preparation method thereof, and relates to the technical field of high polymer materials. Comprising the following raw materials in parts by mass: 100 parts of high-density polyethylene, 5-7 parts of a cold-resistant toughening agent, 8-12 parts of a synergist, 8-10 parts of a sound insulation filler and 0.3-0.5 part of an antioxidant. By introducing the synergist prepared from the components such as polyamine polyether methylene phosphonic acid, zinc nitrate hexahydrate, magnesium nitrate hexahydrate and the like, the sound insulation, flame retardance and smoke suppression capabilities of the drainage pipe can be effectively improved; by introducing the sound insulation filler prepared from the modified halloysite nanotubes, hydroxyl-terminated polydimethylsiloxane, aziridine cross-linking agent and the like, the sound insulation, flame retardance and smoke suppression capabilities of the drain pipe are further improved. Therefore, the drainage pipe prepared by the invention has a wider application prospect.

The invention discloses a low-temperature-resistant organic silicon elastic damping body and a preparation method thereof, and belongs to the field of synthesis of organic polymer materials. The invention relates to a high-efficiency photoinitiator, which is prepared from the following ingredients in parts by weight: 95 to 110 parts of fluorosiloxane-phenylsiloxane segmented copolymers, 25 to 35 parts of boric acid ester end-capped polyurethane prepolymers, 10 to 15 parts of neodymium-containing metal organic frameworks, 20 to 40 parts of azobenzene modified CNT / TiO2, 2 to 4 parts of photoinitiators 1173 and 2 to 3 parts of neodymium acetylacetonate. Ultralow-temperature adaptability, self-repairing and high-modulus coexistence and wide-temperature-range damping stability are achieved through fluorosilicone / phenyl block copolymer molecular design, a borate-neodymium coordination double-dynamic network, stress response filler and a light-heat gradient curing process. The low-temperature-resistant organic silicon elastic damping body prepared by the invention provides a new solution idea for an extreme environment damping material, and has a wide application prospect.

The invention discloses a high-strength moisture-proof gypsum board and a preparation method thereof, and relates to the technical field of gypsum board preparation. The high-strength moisture-proof gypsum board is prepared by dipping the surface paper in the composite dipping liquid and then pouring the surface paper and the gypsum core with the waterproof agent, the composite dipping liquid comprises the methoxy vinyl ether copolymer and the epoxy polyoxymethylene dimethyl ether, and the methoxy vinyl ether copolymer is 2, 3, 5-trimethyl-1, 3-pentanediol monoisobutyrate. According to the present invention, epoxy polyoxymethylene dimethyl ether is prepared by reacting 2, 4-dimethoxymethoxyphenylacetic acid with 2-hydroxyethyl vinyl ether, and the epoxy polyoxymethylene dimethyl ether is prepared by terminating polyoxymethylene dimethyl ether with allyl and then reacting with phthalimide hexperoxy acid, such that the waterproofness and the mechanical property of the gypsum board are improved; the waterproof agent is prepared by reacting hydrogen-containing silicone oil and fluorine-containing hyperbranched amide polyurea urethane, so that the moisture resistance and bonding strength of the gypsum board surface paper are enhanced, and additional mechanical support is provided for the gypsum board.

The invention relates to the technical field of drilling compositions, in particular to a composite plugging agent, a plugging composition and plugging cement paste for shale gas formation cracks. The composite plugging agent for shale gas stratum cracks is composed of a bridging material, a filling material and an end-capping material, the mass ratio of the bridging material to the filling material to the end-capping material is (1.2-1.4): 0.5: (0.1-0.3), the bridging material is organic fibers with the length of 3-5 mm, the filling material is composed of inert particles with the particle size of 35-280 [mu] m and micro-silicon with the particle size of 0.15-1 [mu] m, and the end-capping material is a mixture of silicon oxide and silicon oxide. The end-capping material is composed of organic fibers with the length of 8-9 mm and walnut shells with the particle size of 3-5 mm. Through compounding of different types of bridging materials, filling materials and end sealing materials and grading of fibers with different lengths and plugging particles with different particle sizes, the plugging agent can be matched with cement paste in complex cracks and large cracks (1-4 mm) of a stratum to form a stable and compact plugging layer, the compressive strength is high, effective retention is achieved, and the effect of plugging a complex leakage layer is achieved.

The invention relates to a high-temperature-resistant UV viscosity-reducing adhesive tape and a preparation method thereof, and belongs to the technical field of UV viscosity-reducing adhesive tapes. The high-temperature-resistant UV viscosity-reducing adhesive tape comprises a base material layer, an adhesive layer and a release layer which are sequentially arranged, wherein the adhesive layer is prepared from an adhesive; the adhesive is prepared from the following components in parts by weight: 100 parts of an acrylate polymer, 0.1 to 2 parts of a cross-linking agent, 1 to 3 parts of a photoinitiator, 0.2 to 0.8 part of an antioxidant and 35 to 100 parts of a first solvent; the acrylate polymer comprises the following components in parts by weight: 70-80 parts of a soft monomer, 20-30 parts of a hard monomer, 5-10 parts of a polyfunctional monomer, 0.1-1 part of an initiator, 0.05-0.2 part of a polymerization inhibitor, 1-7 parts of an end-capping reagent and 100-200 parts of a second solvent. The UV viscosity-reducing adhesive tape can still keep excellent viscosity-reducing performance after being subjected to high-temperature treatment, and the effect that the viscosity is not reduced or even improved after being subjected to high-temperature treatment can be achieved.

The invention discloses two-component addition type low-density liquid foaming silicone rubber and a preparation method thereof, and belongs to the technical field of silicone rubber preparation. Comprising a component A and a component B, the component A is prepared from the following components in parts by weight: 50 to 70 parts of vinyl terminated polysiloxane, 10 to 20 parts of vinyl hydroxyl silicone oil, 0.5 to 2 parts of platinum catalyst, 15 to 25 parts of HGM (at) PN-rGO / APP and 3 to 8 parts of methyl vinyl MQ resin; the component B is prepared from the following components in parts by weight: 50 to 60 parts of vinyl-terminated polysiloxane, 8 to 15 parts of hydrogen-terminated hydrogen-containing silicone oil, 10 to 20 parts of methyl-terminated hydrogen-containing silicone oil, 5 to 10 parts of hydroxyl-terminated silicone oil, 0.002 to 0.01 part of an inhibitor, 10 to 20 parts of fumed silica and 1 to 3 parts of a tackifier. The synergistic components in the HGM-coated PN-rGO / APP can greatly improve the flame retardant property of the silicone rubber, improve the compression strength and reduce the heat release rate at the same time.

The invention relates to blended modified asphalt and a preparation method thereof, and belongs to the technical field of asphalt material compositions. The blended modified asphalt is prepared from 90 # heavy traffic road petroleum asphalt, 70 # road petroleum asphalt, natural rock asphalt, an emulsifier op-10, an HDI-trihydroxymethyl hexyl lactone cross-linked polymer, phenylpropyl dimethyl siloxy silicate ester, vinyl-terminated polydimethylsiloxane, thermoplastic styrene-butadiene rubber, nanoscale calcium carbonate, organobentonite and diatomite according to a specific proportion. Polyethylene wax, an anti-rut agent, an antioxidant and the like. Wherein the natural rock asphalt is pre-modified by the HDI-trihydroxymethyl hexyl lactone cross-linked polymer, the 70 # road petroleum asphalt is pre-modified by the phenylpropyl dimethyl siloxy silicate ester, and the thermoplastic styrene-butadiene rubber is pre-modified by the vinyl terminated polydimethylsiloxane. The modified components are better in compatibility and good in blending homogeneity, the components are not easy to reject, and the blended modified asphalt is excellent in use performance.

The invention belongs to the technical field of memristors, and particularly relates to a preparation method of a high-stability heterojunction material memristor, and the method comprises the following steps: S1, making a sample, and employing a conductive material as a substrate and a bottom electrode; s2, preparing a Cs3Bi2Br9 solution, and preparing the Cs3Bi2Br9 solution by mixing CsBr powder, BiBr3 powder, DMSO (Dimethylsulfoxide) and DMF (Dimethyl Formamide); s3, mixing and stirring the Cs3Bi2Br9 solution in the S2, adding HBr after 1 hour, and then continuously stirring and mixing; s4, performing plasma treatment on the sample in the S1, and spin-coating the sample with a Cs3Bi2Br9 solution; s5, sputtering a ZnO thin film on the sample subjected to spin coating in the step S4 for end sealing; s6, plating a top electrode on the sample subjected to ZnO film end sealing; by using the ZnO thin film to seal the end, the challenge brought by the traditional solution method for constructing the active layer of the perovskite memristor at present can be overcome, the preparation repetition rate of the memristor is effectively improved, the stability of the perovskite and the reliability of the device are effectively improved, and the problem that the stability of the existing preparation method of the perovskite thin film memristor is relatively poor is solved.

The invention provides a methacrylate-terminated polyurethane prepolymer, a preparation method and two-component dual-curing photosensitive resin, and relates to the technical field of 3D printing new materials. The structure of the methacrylate-terminated polyurethane prepolymer is shown as a formula IV, and the invention also provides a two-component dual-curing photosensitive resin which comprises the methacrylate-terminated polyurethane prepolymer shown as the formula IV, the bi-component dual-curing photosensitive resin is prepared by the following steps: firstly, fully mixing a methacrylate-terminated polyurethane prepolymer as shown in a formula IV, a reactive diluent and a photoinitiator as a component A and diamine as a component B at room temperature to form the bi-component dual-curing photosensitive resin. According to the invention, the methacrylate-terminated polyurethane prepolymer generates a mismatched supramolecular effect through the molecular structure design of'rigid main chain-flexible side chain ', so that the strength and toughness of the material are synergistically improved, and a 3D printed product shows ultrahigh mechanical properties.

The invention discloses resin composite liquid with dual self-repairing and high ethanol solvent wiping resistance as well as a preparation method and application of the resin composite liquid, and belongs to the technical field of polyurethane emulsion coatings. Aiming at the problems that an existing waterborne polyurethane coating is poor in ethanol resistance due to residual carboxyl / hydroxyl of a hydrophilic chain extender and the self-repairing efficiency of a single dynamic bond is low, a metal ion buffer solution is added into a hydroxyl-terminated polyurethane emulsion to coordinate with the carboxyl of the hydrophilic chain extender, so that a hydrophilic group is closed, and the crosslinking density is increased; meanwhile, a boric acid compound is introduced to form dynamic boric acid ester bonds with residual hydroxyl groups of the system, and hydrophilic groups in the system are consumed while a dual self-repairing network is constructed. The coating prepared by the invention has good self-repairing and ethanol wiping resistance.

The present invention discloses a waterborne polyurethane and silica gel composite biomimetic material, its preparation method and application, belonging to the technical field of biomimetic skin. The biomimetic material includes a silica gel layer and a polyurethane layer. The material of the silica gel layer includes two-component silica gel, and the material of the polyurethane layer includes double-bond terminated waterborne polyurethane. The preparation method of the biomimetic material is as follows: Spray the double-bond terminated waterborne polyurethane into a mold, heat and dry it to obtain a polyurethane layer; Spray a platinum catalyst on the surface of the polyurethane layer, then mix the A component and B component of the two-component silica gel evenly and pour them into the mold, oscillate and level them, and cure and form to obtain the waterborne polyurethane and silica gel composite biomimetic material; The biomimetic material has the characteristics of high peel strength, good environmental performance, good folding resistance, high wear resistance, good heat resistance, etc., and especially has a baby-like skin-friendly touch, and has broad application prospects in artificial skin, soft robots, wearable devices, prosthetic epidermis, etc.

The invention provides a porous bio-based polymer microsphere as well as a preparation method and application thereof. The porous bio-based polymer microsphere provided by the invention comprises a mixture of a bio-based high-molecular polymer P1 and a bio-based block copolymer P2, wherein the bio-based block copolymer P2 is a bio-based block copolymer of which the end-capped group at one end is a hydrophilic group and the end-capped group at the other end is a hydrophobic group. The porous microspheres are prepared by adopting a method of combining condensation phase separation, solvent replacement and solvent volatilization, the obtained microspheres are uniform and stable, the pelletizing rate of the microspheres is nearly high, the yield is high, and subsequent screening is not needed; the process is simple, and the difficulty in operation and control of the process caused by introduction of multiple water phases / oil phases is reduced.

The invention relates to the technical field of high polymer materials, and discloses a wear-resistant and anti-slip plastic tray and a manufacturing method thereof. Comprising the following steps: S1, adding polytetrahydrofuran glycol and dihydroxyl-terminated polysiloxane into acetone, uniformly stirring, heating to 65-70 DEG C, adding isophorone diisocyanate and a tin catalyst, and stirring for 2-3 hours to obtain an isocyanato-terminated polyurethane prepolymer; adding a branching agent, reacting for 2-3 hours at the temperature of 60-70 DEG C, adding hydroxyethyl methylacrylate, stirring and reacting until the content of isocyanate groups in the system is not changed any more, and carrying out rotary evaporation to remove the solvent, so as to obtain modified polyurethane acrylate; s2, taking urethane acrylate, a photoinitiator, modified urethane acrylate, modified silicon dioxide and a diluent, and uniformly stirring to obtain a wear-resistant antiskid coating; and S3, the outer surface of the tray base body is coated with the wear-resistant and anti-skid coating, curing is conducted, and the wear-resistant and anti-skid plastic tray is obtained.

The invention belongs to the technical field of composite pipes, and relates to a polytetrafluoroethylene and soluble polytetrafluoroethylene composite pipe as well as a processing method and application thereof. The preparation method comprises the following steps: firstly, carrying out ring opening polymerization on D3F and blocking by using an amino-containing silane coupling agent to prepare amino-terminated fluorosilicone oil, and taking the amino-terminated fluorosilicone oil as a lubricating agent for compounding and processing PTFE and PFA. The amino-terminated fluorosilicone oil contains a CF3 chain segment which has excellent compatibility with PTFE or PFA, and meanwhile, the cross-linking agent is added to form a chemical bond and a cross-linked structure with amino at the tail end of the lubricant, so that the wear resistance, tensile strength, permeability resistance and high-temperature creep resistance of the PTFE and PFA composite pipe can be improved, and the PTFE and PFA composite pipe can adapt to a long-term high-temperature working environment.