1375 results about "Polymeric matrix" patented technology

The invention discloses a difunctional filler synergistically enhanced polymer solid electrolyte and a solid-state battery, and belongs to the field of solid-state batteries. The electrolyte adopts a polymer matrix, a lithium salt and two functional fillers: the first filler has a high dielectric constant, and can accelerate dissociation of the lithium salt, fix negative ions of the lithium salt and improve the transference number of lithium ions under the action of self polarization; and the second filler has high electrochemical window and ionic conductivity, can inhibit high-voltage decomposition, and is adaptive to a high-voltage positive electrode material. Through cooperation and balance design of the two kinds of filler, ion transmission, interface stability and high-pressure compatibility can be considered at the same time. In addition, the invention further designs a composite negative pole piece, the surface of the negative pole piece is coated with the solid electrolyte, and the ion transmission kinetics in the pole piece can be remarkably improved. On the basis, the invention develops a high-performance solid-state battery which is excellent in electrochemical performance and can play an important role in the fields of consumer electronics, electric automobiles, energy storage systems, low-altitude flight and the like.

The invention discloses a sulfuric acid erosion resistant self-repairing geopolymer system and a self-repairing method thereof, and relates to the technical field of composite materials and artificial intelligence. At least one self-repairing unit optimized for sulfuric acid erosion embedded within the geopolymer matrix; the in-situ multipoint pH sensing network is integrated in the geopolymer matrix and is used for monitoring spatio-temporal evolution data of a pH field in a sulfuric acid erosion process in real time; the edge calculation module is used for identifying a preliminary erosion indication according to the received spatio-temporal evolution data of the pH field; and the central AI decision module is used for evaluating an erosion state and predicting a development trend by utilizing an AI model optimized aiming at sulfuric acid erosion according to the identified preliminary erosion indication and the pH field spatio-temporal evolution data, and generating an optimal repair strategy to control the self-repair unit to perform self-repair. According to the invention, intelligent, active and refined protection and life management of the geopolymer in the sulfuric acid erosion process can be realized.

Various products, systems, and parts or components of such products and systems include a binder matrix (such as a polymer matrix) reinforced with carbon fibers and graphene particles. Inclusion of the carbon fibers and graphene particles substantially improves mechanical strength and utility of the resulting parts, components, and corresponding products and systems. The improvements facilitate substantial advances in various practices of fabrication using additive manufacturing techniques, which lend to applications in biomedical, industrial, agricultural, mechanical, energy generation, transmission, and storage, military, transportation, recreational, and other fields. The inventive materials are particularly well suited for manufacturing of parts for terrestrial vehicles, manned or unmanned aerial vehicles, and space-borne vehicles. Substantial improvements to mechanical strength are achieved even at very low levels of graphene loading (e.g., at about 0.1 wt %), such that the resulting products are substantially stronger than corresponding products lacking said graphene loading, while yet having substantially the same mass.

The invention provides a wear early-warning intelligent material based on conductive core-shell micro-nano particles and a preparation method of the wear early-warning intelligent material, and belongs to the technical field of sensing materials. Conductive core-shell micro-nano particles are used as basic sensing function units to be doped into a polymer matrix to form a sensing layer, a three-layer structure material of a bottom residual life layer, a middle sensing layer and a surface self-lubricating wear-resistant layer is designed, and the material is prepared on a metal auxiliary surface. The surface self-lubricating wear-resistant layer is consumed in the wear process, so that the wear reaches the middle sensing layer, and the resistance of the middle sensing layer is obviously changed due to the damage of the conductive micro-nano particles as an early warning signal, so that the early warning information that the surface self-lubricating wear-resistant layer is worn out and friction pair parts need to be replaced in time is realized.

The invention discloses preparation of DOPO-based hollow polymer microspheres and application of the DOPO-based hollow polymer microspheres in flame-retardant polymers, and belongs to the technical field of high polymer materials. The preparation method of the DOPO-based hollow polymer microspheres comprises the following steps: preparing a template core through self-stable precipitation polymerization, then polymerizing a DOPO-based flame-retardant monomer, an anhydride monomer and a cross-linking agent on the surface of the template core to construct a cross-linking shell layer in situ to obtain copolymer microspheres with a core-shell structure, and finally removing the template through solvent etching to obtain the DOPO-based hollow polymer microspheres. And the DOPO-based hollow polymer microspheres are prepared. The compatibility between the DOPO-based hollow polymer microspheres and a polymer matrix is greatly improved through rich anhydride groups on the surfaces of the DOPO-based hollow polymer microspheres, the flame retardant property of the polymer composite material is improved, the mechanical property of the polymer composite material is greatly improved, and due to the unique hollow structure of the polymer composite material, the flame retardant property of the polymer composite material is greatly improved. The polymer material is endowed with excellent transparency and low dielectric property.

The invention discloses a high-temperature-resistant composite insulated cable for an intelligent power grid, and belongs to the technical field of cables. The objective of the invention is to solve the problems of single function, poor high-temperature resistance and easy overload failure of the existing cable. The cable sequentially comprises a compressed circular tinned copper conductor, an inner shielding layer, an XLPE inner insulating layer, an outer shielding layer, a self-repairing composite insulating layer, a metal shielding layer and an outer sheath layer from inside to outside, the self-repairing composite insulating layer is prepared by blending a self-repairing polymer matrix and a microencapsulation phase change material, and the melting point of the microencapsulation phase change material is accurately matched with the double dynamic bond response temperature of the self-repairing matrix. Through cooperation of self-repairing and thermal buffering functions, integration of multiple functions of high temperature resistance, self-repairing and thermal buffering is achieved, the long-term working temperature reaches 105 DEG C or above, no breakdown occurs during thermal shock at 180 DEG C, the overload repairing rate exceeds 80%, the high-temperature and overload working conditions of an intelligent power grid can be effectively adapted, the preparation steps are clear and reproducible, and remarkable technical advantages and application value are achieved.

The invention relates to the technical field of antibacterial and antifouling fabrics, provides a preparation method of an antibacterial and antifouling fabric, and solves the problem of poor fabric durability caused by single functional component and lack of physical protection in the prior art. The preparation method comprises the following steps: S1, preparing MOFs loaded antibacterial fibers: blending a metal organic framework antibacterial composite nanomaterial and a polymer matrix material, and carrying out melt spinning to prepare the MOFs loaded antibacterial fibers; s2, constructing a self-cleaning functional coating: dispersing the fluorinated nanoparticles and a polymer adhesive in a solvent to prepare a self-cleaning coating solution; s2, performing surface activation treatment on the MOFs-loaded antibacterial fiber obtained in the step S1, soaking the MOFs-loaded antibacterial fiber in the self-cleaning coating liquid, and performing pulling and curing to form a bionic micro-nano structure coating on the surface of the MOFs-loaded antibacterial fiber so as to obtain a functional composite fiber; s3, spinning forming: taking the functional composite fibers obtained in the step S2 as warp yarns and / or weft yarns, and weaving to obtain the antibacterial and antifouling fabric.

The invention discloses a negative electrode interface modification material, a negative electrode plate, a positive electrode interface functional layer, a positive electrode plate, a solid-state battery and a power utilization device, and relates to the technical field of batteries, the negative electrode interface modification material comprises a first polymer matrix, a reinforcing filler, a conductive agent and a lithium salt, the modulus of the reinforcing filler is greater than 50 GPa. The tensile strength of the negative electrode interface modification material can be improved through the first polymer matrix, breakage of a negative electrode interface modification layer is reduced, interface impedance is reduced, meanwhile, the first polymer matrix can be matched with the expansion coefficient of a silicon-based material, and bulging of a negative electrode plate is reduced. The modulus of the reinforcing filler is greater than 50GPa, so that the modulus of the negative electrode interface modification layer can be improved, the expansion of the silicon-based active material is further inhibited, the conductive agent can relieve the problem that the flexible substrate interface of the copper foil and the negative electrode interface modification layer possibly causes unsmooth electron transmission, and the lithium salt can improve the ion conduction capability and reduce the interface impedance.

The invention relates to the technical field of cables, and provides a high-temperature-resistant flame-retardant power cable and a preparation method thereof. A high-temperature-resistant flame-retardant power cable comprises a conductor and a high-temperature-resistant flame-retardant outer layer wrapping the conductor. The high-temperature-resistant flame-retardant outer layer is prepared from the following raw materials in parts by weight: linear low-density polyethylene, an ethylene-vinyl acetate copolymer, ethylene propylene diene monomer, chopped polyimide fibers, nano-coated magnesium hydroxide, zinc borate, zinc stannate, polyethylene grafted maleic anhydride, an anti-aging agent, dicumyl peroxide, an antioxidant, polyethylene wax, calcium stearate and cerium dioxide. According to the cable prepared in the invention, the reliability of an existing high-temperature-resistant flame-retardant power cable under thermal cycle is improved, and the problem of local temperature resistance difference caused by agglomeration and high-temperature migration of nanoparticles in a polymer matrix is improved.

The invention discloses an electrolytic adhesive, an electrolytic cotton adhesive tape and a preparation method of the electrolytic adhesive. The electrolytic cotton adhesive tape comprises the following components in parts by weight: 5-10 parts of 1, 1 '-ferrocene diformyl chloride, 10-15 parts of acrylic acid beta-cyclodextrin ester, 3-8 parts of polyethylene glycol diglycidyl ether, 10-20 parts of ionic liquid, 1.5-3 parts of a cross-linking agent, 10-15 parts of tackifying resin and 0.5-1.5 parts of an initiator, and a polymer matrix comprises an acrylic acid-hydroxypropyl acrylate copolymer and acrylic acid-2-ethylhexyl ester. Comprising an adhesive layer and an adhesive tape base layer, the adhesive layer is prepared from the electrolytic adhesive, and the adhesive tape base layer is prepared from acrylic foam; the obtained electrolytic cotton adhesive tape has high initial adhesion and viscosity strength after power-on and power-off re-adhesion.

The present application provides an entropy-regulated composite dielectric film, which comprises a polymer matrix; and fillers dispersed in the polymer matrix, wherein the fillers comprise Bi 4‑a M 1a Ti (3‑3b) M 2b O 12 , wherein M1 comprises at least one of lanthanum, neodymium, samarium and praseodymium, M2 comprises at least one of zirconium, hafnium and tin, 0 The entropy-regulated composite dielectric film has high temperature resistance, high breakdown strength, high polarization strength, high energy storage density and good stability.

The invention relates to the field of oil storage microcapsules, and discloses a porous covalent organic framework oil storage microcapsule as well as a preparation method and application thereof. Under the catalysis of p-toluenesulfonic acid, 4, 4 ', 4' '-(1, 3, 5,-triazine-2, 4, 6-triyl) triphenylamine and trialdehyde phloroglucinol monomers are promoted to be subjected to condensation reaction in the repeated oscillation process, a product is purified to prepare a 4, 4', 4 ''-(1, 3, 5,-triazine-2, 4, 6-triyl) triphenylamine covalent organic framework, and by means of a periodic pore structure of the covalent organic framework, the covalent organic framework can be used for preparing the covalent organic framework. And the lubricating oil is adsorbed and stored and can be controllably separated out to provide lubrication during working, so that a high-performance self-lubricating effect can be realized. In addition, covalent organic frameworks are used as hard particles to be doped into a polymer matrix to modify the polymer matrix, so that the wear resistance of the polymer matrix can be greatly enhanced, and the performance of the self-lubricating bearing material is improved.

The invention relates to an adsorbent and a preparation method and application thereof, the adsorbent comprises a polymer matrix and a nanofiller uniformly embedded in the polymer matrix, the polymer matrix comprises a calcium / boron cross-linked polyvinyl alcohol-sodium alginate blend, and the nanofiller is sulfonic acid / carboxylic acid functionalized graphene oxide; the mass fraction of the nano filler in the adsorbent is 0.05%-0.60%; wrinkles and irregular hole structures are distributed on the surface of the adsorbent. The adsorbent is used for removing tritium in water and is high in adsorption capacity, stable in structure and good in recycling performance. The removal rate of tritium in the single-stage adsorption process is greater than 8.5%, and the removal rate of tritium in the third-stage adsorption process is 19.4-57.7%.

The invention relates to a mesoporous LLZO / PVDF-HFP composite solid electrolyte membrane as well as a preparation method and application thereof. The electrolyte membrane comprises a polymer matrix PVDF-HFP and a disordered mesoporous LLZO filler dispersed in the polymer matrix PVDF-HFP, and the mass ratio of LLZO to PVDF-HFP is (1: 7)-(7: 1). The composite membrane is prepared through a solvent exchange-freeze drying method, and the process comprises the following steps: dissolving PVDF-HFP in an organic solvent, adding mesoporous LLZO, stirring to form uniform slurry, coating the slurry, and carrying out solvent exchange and freeze drying treatment to obtain the membrane. The obtained electrolyte membrane is stable in structure and excellent in ionic conductivity, can be applied to a lithium metal battery as a solid electrolyte membrane material, and remarkably improves the cycling stability and rate capability of the battery.

The invention discloses an industrial high-temperature-resistant cable, and belongs to the technical field of cables. The cable comprises a cable core and a sheath layer wrapping the cable core. The sheath layer comprises the following components in parts by weight: 32-38 parts of alkenyl polyvinyl chloride, 38-42 parts of methyl vinyl silicone rubber, 15-20 parts of modified basalt fibers, 1-2 parts of a vulcanizing agent, 6-10 parts of a plasticizer, 1-2 parts of a lubricant, 1-2 parts of a stabilizer and 0.3-0.8 part of an antioxidant. Functional modification is performed on the surface of the basalt fiber, so that the basalt fiber and a polymer matrix of the cable sheath can form a multi-layer and firm chemical structure, and the comprehensive performance of the sheath material is effectively improved.

The invention discloses a composite solid electrolyte and a preparation method and application thereof, and belongs to the technical field of solid lithium batteries. The composite solid electrolyte comprises a polymer matrix, a lithium salt and a lithium ion modified ionic metal organic framework (MOF) material. The metal center of the ion-conducting MOF material can be selected from Zr, Ti, Hf and the like, and the organic ligand can be selected from organic acids containing sulfydryl, sulfo groups and the like. The MOF material can effectively inhibit crystallization of a polymer matrix and increase the proportion of an amorphous region, Lewis acid sites on the surface of the MOF material can promote dissociation of lithium salt, and a lithium ion coordination channel formed in the MOF material can provide an extra rapid transmission path for lithium ions. When the electrolyte is applied to the solid-state lithium battery, the growth of lithium dendrites can be effectively inhibited, and the rate capability, the cycling stability and the safety of the battery can be remarkably improved.

The invention discloses a flexible piezoresistive sensor and a preparation method and application thereof, the flexible piezoresistive sensor comprises an upper layer flexible conductive member, the upper layer flexible conductive member comprises an upper layer flexible substrate and an upper layer conductive layer, one surface of the upper layer flexible substrate is provided with a microstructure formed by sand paper reverse molding, and the upper layer conductive layer is embedded in the surface of the microstructure; the lower-layer flexible conductive member comprises a lower-layer flexible substrate, a lower-layer conductive layer and an elastic conductive layer; the lower-layer flexible substrate is provided with an arc-shaped stripe array microstructure; the elastic conductive layer includes a polymer matrix and a conductive filler dispersed therein. Through the double-gradient design of the gradient conductivity and the gradient structure, the core contradiction that a traditional flexible piezoresistive sensor is difficult to consider high sensitivity and wide linear range at the same time is successfully solved by utilizing the deep coupling and synergistic effect of the conductivity gradient and the structure gradient, and synchronous improvement of the sensitivity and the linear range is realized.

The invention provides a heat dissipation composite material and a preparation method and application thereof. The heat dissipation composite material comprises a bonding layer, an insulating breathable layer, a heat conduction layer and a heat conduction diffusion layer which are sequentially arranged from bottom to top. Wherein the bonding layer is obtained by mixing and reacting a polymer matrix material, a composite filler and a molecular bridging agent, the insulating breathable layer is a porous insulating material, the heat conduction layer is a graphene film, and the heat conduction diffusion layer is prepared from porous matrix composite heat conduction nanoparticles. According to the invention, through combination and structural design of each layer of material, a synergistic effect of a multi-layer structure is realized, firm and stable bonding of the heat dissipation composite material and a heating electronic device is realized, the heat dissipation efficiency and insulation air permeability of the heat dissipation composite material are remarkably improved, and the heat dissipation requirement of high-power-density electronic equipment can be met.

The invention belongs to the field of moisture absorption materials, and discloses a temperature-sensitive hydrophilic-hydrophobic reversible conversion low-temperature regenerated moisture absorption material and a preparation method and application thereof. The temperature-sensitive hydrophilic-hydrophobic reversible conversion low-temperature regenerated moisture absorption material comprises a polymer matrix and inorganic salt, the polymer matrix is a copolymer of a temperature-sensitive monomer and a hydrophilic monomer, and the inorganic salt is loaded inside and on the surface of the polymer matrix. The hygroscopic material prepared by the method has reversible transition from a hydrophilic state to a hydrophobic state near the lowest phase transition critical temperature; the material is in a hydrophilic state during moisture absorption and is in a hydrophobic state during desorption, and the material has excellent moisture absorption performance and low-temperature desorption regeneration performance; the lowest phase transition critical temperature can be adjusted according to actual requirements to adapt to different moisture absorption application scenes, the polymer gel moisture absorption material is a ternary system, the three components achieve breakthrough improvement of the moisture absorption-desorption performance through the multi-stage synergistic effect, and a new normal form is provided for environment self-adaptive material design.

The invention discloses a high-solid-content MIL-101 (Fe) / PIM-1 mixed matrix membrane and a preparation method thereof, and belongs to the technical field of gas separation membranes. The preparation method comprises the following steps: firstly, dissolving an iron source in a PIM-1 polymer solution to form a homogeneous membrane casting solution; forming the obtained membrane casting solution, and removing the solvent to obtain a PIM-1 / Fe (II) composite substrate containing Fe (III); then, the substrate is alternately immersed in a terephthalic acid methanol solution and a ferric salt methanol solution, and MIL-101 (Fe) is generated in the polymer matrix through in-situ limited crystallization by layer-by-layer limited crystallization. According to the method, the problem of interfacial compatibility between the MOF filler and the polymer matrix is effectively solved, and high loading capacity (up to 52.9 wt.%) of MIL-101 (Fe) is realized without agglomeration. Meanwhile, the membrane has excellent COplasticizing resistance and long-term operation stability, and has a wide application prospect in the fields of carbon capture and the like.

The invention discloses a composite solid electrolyte layer, a preparation method and application, the composite solid electrolyte layer comprises a porous membrane laminated on a negative pole piece, and pores in the porous membrane and gaps between the porous membrane and the negative pole piece are filled with in-situ generated polymers. Inorganic solid electrolyte is also dispersed in the porous membrane, and lithium salt is dispersed in the polymer and the porous membrane. The composite solid electrolyte layer is obtained through in-situ polymerization of a polymer in pores in the porous membrane and gaps between the porous membrane and the negative electrode plate, and a novel interface structure with the electrode-electrolyte integration characteristic is constructed. By adopting a collaborative optimization strategy of a polymer matrix and inorganic filler double-crosslinking network system and an interface stable layer, the volume effect problem of a silicon-based negative electrode, the electrolyte interface impedance problem and the battery safety problem can be solved at the same time, so that the cycling stability and the rate capability of the lithium ion battery are remarkably improved.

The invention relates to the technical field of inorganic material preparation and new energy materials, and particularly discloses a lithium metal battery composite solid electrolyte as well as a preparation method and application thereof. Lithium niobate with high lithium ion conductivity and high dielectric constant is used as an inorganic filler, polyvinylidene fluoride-co-hexafluoropropylene is used as a polymer matrix, and the lithium metal battery composite solid electrolyte is prepared. The lithium metal battery solid electrolyte with a continuous lithium ion transport path is constructed through a freeze casting technology, the dielectric constant of the solid electrolyte is effectively improved by adding the dielectric inorganic filler lithium niobate, lithium salt dissociation is promoted, preparation of the modified electrolyte can be simply completed on a large scale, industrial expansion is facilitated, coulombic efficiency is improved, and the lithium metal battery solid electrolyte is suitable for industrial production. According to the present invention, the lithium metal battery electrolyte meets the industrial requirement on the high lithium utilization rate, the lithium negative electrode can be well protected, the cycle life of the lithium electrode can be improved, the battery electrolyte and the lithium electrode show the good interface compatibility and the good cycle stability, and the new feasible way is provided for the application of the lithium metal battery.

The invention discloses an ultra-flexible stretchable dimming film and a preparation method thereof, and relates to the technical field of dimming films, and the ultra-flexible stretchable dimming film comprises an upper transparent electrode layer, a dimming function layer and a lower transparent electrode layer which are sequentially stacked from top to bottom; the preparation method comprises the following steps: 1) preparing a main matrix material / ultraviolet curing resin mixture; 2) assembling the dimming film; and 3) ultraviolet light curing. According to the invention, through surface phosphonic acid functionalization treatment, covalent bond anchoring of cerium oxide nanoparticles is realized on a thermoplastic polyurethane fiber network; by constructing a full-thermoplastic polyurethane material system, the breakthrough of interfacial compatibility between a fiber reinforced phase and a polymer matrix is realized, so that the film has high tensile strain capacity and excellent fatigue resistance on the premise of keeping high transparency.

The invention relates to the technical field of flexible electronics and sensing, in particular to a capacitive flexible pressure sensor based on a barium titanate composite dielectric layer, which sequentially comprises a lower electrode layer, an upper electrode layer, a lower electrode layer and an upper electrode layer from bottom to top, the composite dielectric layer is arranged on the lower electrode layer and is formed by compounding an elastic polymer matrix and a high-dielectric-constant barium titanate (BaTiO3) filler; the upper electrode layer is made of a flexible conductive material and is arranged on the composite dielectric layer; the lower electrode layer and the upper electrode layer are connected with an external capacitance measuring circuit through wires. According to the sensor disclosed by the invention, the comprehensive performance of high sensitivity, wide detection range, low hysteresis and excellent cycle stability is realized by optimizing the shape of the barium titanate filler, surface modification and composite structure design.

The invention provides a solid electrolyte membrane, a preparation method thereof and a solid-state battery. The solid electrolyte membrane comprises an inorganic filler, a polymer matrix and a lithium salt, wherein the inorganic filler comprises a dielectric conductive ion material and oxide particles; wherein the dielectric conductive ion material comprises a dielectric filler and a silane coupling agent which is coated on the outer surface of the dielectric filler and contains cyano groups, the dielectric filler contains transition metal elements, and the transition metal elements are Nb elements and / or Ta elements; the oxide particles comprise lanthanum oxide particles; the mass ratio of the dielectric conductive ion material to the oxide particles is (1-5): 1, and the ratio of the total mass of the inorganic filler to the mass of the polymer matrix is (10-50): 100. The solid electrolyte membrane provided by the invention has relatively high ionic conductivity, mechanical strength and structural stability, and can effectively improve the comprehensive performance of the solid lithium metal battery.

The invention provides a preparation method of a high-temperature-resistant and anti-aging cable sheath material, which comprises the following steps: acquiring molecular chain distribution data of a polymer matrix and an inorganic filler, and establishing a bonding strength distribution diagram; obtaining regional non-uniform points, and optimizing filler distribution parameters; calculating a crosslinking temperature gradient model based on the compatibility improvement coefficient; predicting crosslinking density according to the model and correcting reaction parameters; evaluating the aging rate distribution and optimizing the dosage of the modifier. According to the method, filler dispersion is regulated and controlled through molecular-level bonding strength, a crosslinking temperature field is made to adapt to filler distribution, a formula is predicted and optimized in combination with aging behaviors, therefore, the structural uniformity and heat resistance of the material are remarkably improved, the service life of the material is remarkably prolonged, and the method solves the problems that in a traditional process, filler dispersion is not uniform, a crosslinking thermal field is mismatched, and aging evaluation is not accurate.

The embodiment of the invention provides an electrolyte, a battery and electric equipment, the electrolyte comprises a lithium salt, an organic solvent and a polymer matrix, and monomers of the polymer matrix comprise vinylene carbonate and isocyanate ethyl acrylate. In the electrolyte provided by the embodiment of the invention, the monomers of the polymer matrix comprise vinylene carbonate and isocyanate ethyl acrylate, and the low HOMO energy level of isocyanate ethyl acrylate can weaken the electron loss ability of the polymer matrix and improve the oxidation stability of the electrolyte, so that the relatively poor electrochemical stability is improved; and a copolymerization structure of vinylene carbonate and isocyanate ethyl acrylate reduces the crystallinity of a polymer matrix and provides a smoother path for Li < + > transmission, so that the ionic conductivity of the electrolyte is improved. Therefore, the electrolyte provided by the invention can effectively improve the problems of low room-temperature ionic conductivity and relatively poor electrochemical stability of the existing gel electrolyte, and has a good application prospect.

The invention belongs to the technical field of solid-state batteries, and provides a lithium-ion solid-state electrolyte and a preparation method and application thereof. The lithium ion solid electrolyte comprises a polymer matrix, a lithium salt, a polar organic compound, a polymer monomer (comprising a first monomer and a second monomer) and an anion acceptor. The preparation method comprises the following steps: mixing a lithium salt and a polar organic compound to obtain a eutectic mixture; mixing a polymer matrix, a first monomer, a second monomer and an anion acceptor with the eutectic mixture to obtain a precursor solution; and coating a substrate with the precursor solution, curing and drying. The invention also discloses a solid-state lithium ion battery comprising the lithium-ion solid-state electrolyte and a manufacturing device of the solid-state lithium ion battery. The lithium ion solid electrolyte disclosed by the invention is high in room-temperature ionic conductivity, excellent in tensile strength, tensile elongation and high in breaking strength and incombustibility, and the lithium ion transference number is increased; therefore, the battery has long-term cycle stability, and the problem of electrode stress failure under low stacking pressure is solved.

Inventive techniques for forming unique compositions of matter are disclosed, as well as various advantageous physical characteristics, and associated properties of the resultant materials. In particular, particles comprising polymer matrices are characterized by having carbon disposed within the polymer matrix structure thereof. The carbon is primarily, or entirely, present at interstitial sites of the polymer matrix, and may be present in amounts ranging from about 15 wt % to about 90 wt %. The carbon, moreover, forms covalent bonds with both atoms of the polymer matrix and other carbon atoms present in, but not part of, the matrix. This facilitates substantially homogeneous dispersal of the carbon throughout the resultant material, conveying unique and advantageous properties such as strength-to-weight ratio, density, mechanical toughness, sheer strength, flex strength, hardness, anti-corrosiveness, electrical and / or thermal conductivity, etc. as described herein. In some approaches, the resultant materials may be powderized or pelletized.

The invention relates to the technical field of oil and gas gathering and transportation pipelines, and particularly discloses a lining pipe material for an oil and gas gathering and transportation pipeline, a preparation method of the lining pipe material and the oil and gas gathering and transportation pipeline. The lining pipe material for the oil and gas gathering and transportation pipeline comprises 78-90 parts of polyolefin resin and 10-22 parts of polyolefin resin grafted inorganic heat-conducting filler, the polyolefin resin grafted inorganic heat-conducting filler is prepared from polyolefin resin and inorganic heat-conducting filler by adopting an irradiation crosslinking technology. By adopting a physical irradiation grafting modification method, grafting of the polyolefin and the inorganic heat-conducting filler is realized, the dispersion uniformity of the inorganic heat-conducting filler in a polymer matrix is improved, and the high temperature resistance of the prepared polyolefin pipe is improved.