The invention discloses a method for synthesizing electronic-grade
ethyl acetate through catalytic esterification of acidic
ion exchange resin, and belongs to the technical field of
ethyl acetate preparation. The method comprises the following steps: mixing crosslinked
polystyrene white balls and a swelling agent, and dropwise adding concentrated
sulfuric acid for reaction to obtain S-PS resin; mixing an EDTA disodium salt saturated solution and a
polyacrylic acid solution, adding a cross-linking agent and an emulsifier, and carrying out a cross-linking curing reaction to obtain EDTA microcapsules; the preparation method comprises the following steps: dispersing S-PS resin in a
solvent, adding EDTA microcapsules, a
dehydration condensation agent and a catalyst, reacting under the protection of
inert gas, and filtering and recovering after the reaction is finished to obtain S-PS-EDTA resin; mixing glacial
acetic acid, absolute ethyl
alcohol and S-PS (at) EDTA resin for reaction, and filtering and collecting liquid after the reaction is finished; and rectifying the collected liquid to obtain the product. According to the method provided by the invention,
metal impurities can be chelated in the synthesis process, and the electronic-grade
ethyl acetate with high purity and low
impurity content is produced.