2693 results about "Polystyrene" patented technology

The invention relates to a high-protection-performance metering box with polystyrene foam, and relates to the technical field of metering boxes, the metering box comprises a box body, two box doors are oppositely hinged to the box body, a plurality of heat dissipation holes are formed in two opposite side walls of the box body, and a protection plate for protecting the heat dissipation holes is installed outside the box body; two parallel fixing plates are vertically installed on the side face, away from the box door, of the box body, arc-shaped notches are formed in the side faces, away from the box body, of the fixing plates, flexible fixing ropes are detachably installed outside the fixing plates, and the flexible fixing ropes and the arc-shaped notches in the fixing plates jointly surround the periphery of a telegraph pole; according to the application, when the metering box is installed on the telegraph pole, the flexible fixing rope and the arc-shaped gap in the fixing plate jointly surround the periphery of the telegraph pole, so that the metering box can be pre-locked; and an acting point is provided for installation personnel, and the possibility of deviation or dislocation of the box body is greatly reduced.

The invention discloses a lithium battery diaphragm coating based on a nano material and application thereof, and relates to the technical field of lithium battery diaphragms. The coating comprises the following raw materials in parts by weight: 15-25 parts of polystyrene maleic anhydride copolymer modified polyvinylidene fluoride, 10-20 parts of polystyrene, 2-4 parts of nano silicon nitride, 3-6 parts of a boehmite / aluminum oxide and silicon dioxide composite material, 1-2 parts of a dispersing agent and 65-90 parts of a solvent, according to the lithium battery diaphragm coating provided by the invention, the wettability and absorptivity of a diaphragm to an electrolyte are remarkably improved, meanwhile, the lithium battery diaphragm coating also has excellent thermal stability, and the diaphragm can be effectively prevented from thermal shrinkage or melting under a high-temperature condition, so that the safety performance of a battery is remarkably enhanced.

The invention discloses a single-ion conductor polymer, a ternary composite binder solution, high-solid-content sulfide electrolyte slurry and a wet film forming method and application thereof, and belongs to the technical field of all-solid-state lithium batteries. The key technical problems in the wet membrane preparation of the sulfide electrolyte are solved through an innovative solvent-binder synergistic system, and the method specifically comprises the steps that 1, through the synergistic effect of a non-polar solvent and a weak-polar solvent, low-viscosity coating of high-solid-content slurry is achieved while the chemical stability of the sulfide electrolyte is guaranteed; 2, a poly (lithium styrenesulfonate-butyl acrylate), styrene butadiene rubber and polyisobutene ternary composite binder is designed, a lithium ion transmission channel is provided through a lithium sulfonate group, a benzene ring structure in the styrene butadiene rubber enhances the mechanical strength, long-chain alkane in the polyisobutene improves the interface adhesive force, and the mechanical strength is improved; the three components cooperate to realize balance of mechanical and electrochemical properties of the electrolyte membrane, so that the prepared electrolyte membrane has low porosity, high ionic conductivity and mechanical strength.

The invention provides syndiotactic polystyrene resin and a preparation method thereof, a resin composition and a product, the weight-average molecular weight of the syndiotactic polystyrene resin is 1.4 * 10 < 5 > g / mol to 2.2 * 10 < 5 > g / mol, the proportion of the syndiotactic polystyrene resin with the molecular weight larger than 3 times of the weight-average molecular weight is smaller than or equal to 10 wt%, and the proportion of the syndiotactic polystyrene resin with the molecular weight smaller than 0.2 times of the weight-average molecular weight is smaller than or equal to 6 wt%; the supercooling degree delta T of the syndiotactic polystyrene resin is 28 DEG C to 34 DEG C. According to the invention, the weight-average molecular weight of the syndiotactic polystyrene resin, the proportion of the high-molecular-weight syndiotactic polystyrene resin and the proportion of the low-molecular-weight syndiotactic polystyrene resin are controlled in a specific range, and the degree of supercooling is controlled in a specific range; the obtained syndiotactic polystyrene resin has excellent toughness and long-term dimensional stability after demolding.

The invention discloses lactobacillus plantarum capable of relieving enteritis and toxicity of polystyrene nano-plastics, and the preservation number of the lactobacillus plantarum is CGMCC (China General Microbiological Culture Collection Center) NO.31420. The lactobacillus plantarum can be used for relieving enteritis and toxicity of polystyrene nano-plastics. The strain is obtained by separating and purifying baby feces, and can grow on an MRS culture medium, and the bacterial colony is round, off-white, smooth and opaque. Experiments show that the lactobacillus plantarum can effectively adsorb PS-NPs, promote the PS-NPs to be discharged along with excrement, reduce accumulation of the PS-NPs in organs, and significantly reduce toxicity and inflammatory response of organs such as liver and kidney of mice. In addition, the strain can repair the intestinal barrier function, regulate liver metabolism and relieve enteritis symptoms. The invention further provides a probiotic preparation containing the strain, and the probiotic preparation can be prepared into granules, capsules, tablets or oral liquid and the like and is used for preventing or treating intestinal injury and inflammatory diseases caused by PS-NPs. The strain is safe and efficient, and has a wide application prospect.

The invention belongs to the technical field of environmental protection, and provides a preparation method of an imine-modified functionalized mesoporous magnetic silicon dioxide nano material. The method comprises the following steps: synthesizing Fe3O4 magnetic nanoparticles in a Fe < 2 + > / Fe < 3 + > alkaline hydrolysis system through a coprecipitation method; then coating the magnetic nanoparticles with an amorphous silicon dioxide layer by taking TEOS (tetraethoxysilane) as a silicon source by adopting a sol-gel method, so as to prepare magnetic silicon coated nanoparticles; the prepared nano-particles are subjected to secondary silicon coating guided by a cetyl trimethyl ammonium bromide (CTAB) mesoporous template agent, and mesoporous magnetic silicon nano-particles are formed after calcination; and finally, carrying out surface amination modification on the mesoporous magnetic silicon nano-particles by utilizing an amino silane coupling agent, and then carrying out condensation reaction on the mesoporous magnetic silicon nano-particles and various aldehyde derivatives to construct imine bonds, so as to obtain the imine-modified functionalized mesoporous magnetic silicon dioxide nano-material. The imine-modified functionalized mesoporous magnetic silicon dioxide nano-material formed by the invention has the characteristics of efficient adsorption, rapid magnetic recovery and excellent environmental stability, and can effectively remove polystyrene micro-plastics and organic pollutants in a water body.

The invention provides a preparation method and application of a polystyrene resin-based spherical carbonaceous porous material, and belongs to the technical field of new energy materials. The method comprises the following steps: firstly, pre-mixing styrene with a cross-linking agent, a pore-forming agent, an initiator and a surfactant at a first preset temperature, then continuously stirring at a first preset stirring speed at a second preset temperature for a first preset time, and carrying out organic polymerization to prepare a polystyrene-based resin microsphere emulsion; then separating and drying the emulsion to obtain polystyrene-based resin microspheres; then oxidizing for a second preset time at a third preset temperature in an air atmosphere to prepare oxidized polystyrene-based resin microspheres; and finally, oxidizing at a fourth preset temperature for a third preset time to prepare the polystyrene resin-based spherical carbonaceous porous material. The method is simple in process and easy to implement, the preparation cost is effectively reduced while the yield is increased, and the method has wide application value and popularization prospects.

The invention discloses a thermal insulation material with enhanced thermal insulation performance and a processing method, and relates to the technical field of thermal insulation material processing. Comprising the following components in parts by weight: 100 to 200 parts of a nanopore matrix material, 20 to 120 parts of expanded perlite, 10 to 350 parts of polystyrene, 30 to 300 parts of polyurethane, 100 to 500 parts of nano titanium dioxide, 10 to 60 parts of graphene, 10 to 40 parts of silica sol and 1 to 55 parts of ferric oxide. A multi-stage pore structure is constructed through a nanopore matrix and expanded perlite, closed-cell foam of polystyrene and polyurethane is combined, and nano titanium dioxide and graphene functional filler are matched, so that the heat conductivity coefficient is reduced to 0.018 W / (mK) or below, the heat insulation efficiency is remarkably improved, nanoscale homogenization is ensured through high-shear dispersion in the process, the porosity is reserved through freeze drying, and the heat insulation performance is greatly improved. The microcapsule self-repairing layer can repair more than 85% of cracks, the service life is greatly prolonged, and in the aspect of function integration, the material has A-level fireproof, waterproof and weather-proof characteristics and heat preservation and heat insulation performance.

The invention discloses an artificial SEI material and a preparation method thereof, an artificial SEI film and an artificial SEI film modified negative electrode. The artificial SEI material is an organic polymer brush (CNF-g-PSSX) prepared by grafting cellulose nanofibers with polystyrene sulfonate. The polymer brush is of a crystal structure and has a firm framework; and the side chain of polystyrene sulfonate has rich-SO3 functional groups which are matched with cations in sulfonate, so that a rapid ion transmission channel is provided, high-current-density circulation can be realized, and good interface contact is ensured. Due to a special molecular topological structure and a multi-component synergistic effect, when the organic polymer brush forms an artificial SEI film, high mechanical strength, high ionic conductivity and low interface impedance can be obtained at the same time, and through strong electrostatic repulsion between a negatively charged-SO3 group and the surface of a negatively charged lithium dendrite tip, the electrochemical performance of the artificial SEI film is improved. An obvious inhibition effect is shown on the continuous growth of dendritic crystals.

The invention provides a diaphragm and a preparation method thereof and a lithium ion battery, the diaphragm comprises a base membrane layer and a composite functional layer, the composite functional layer comprises hydrophobic SiO2 aerogel modified by a hydrophobic agent, a conductive ion polymer and a solid electrolyte, and the composite functional layer respectively accounts for 3-12wt%, 0.5-1.0 wt% and 0.5-1.5 wt% of the total mass of the diaphragm; the hydrophobic agent comprises trimethylchlorosilane, hexamethyldisilazane, perfluorooctyltriethoxysilane, polyvinylidene fluoride, polydimethylsiloxane and the like, the conductive ionic polymer comprises polyvinylpyrrolidone, lithium polymethacrylate, lithium polystyrene sulfonate, polyacrylamide and the like, and the solid electrolyte comprises lithium lanthanum titanium oxide, lithium lanthanum zirconium oxide, lithium lanthanum zirconium tantalum oxide and the like. The wettability is improved by the high porosity of the hydrophobic SiO2 aerogel, the stability and strong conductivity of a physical conductive network of the solid electrolyte and the ion affinity and amphoteric binding capacity of the conductive ion polymer are optimized, the electrochemical performance and thermal stability of the interface are optimized, and comprehensive optimization of the thermal-electric-interface performance of the diaphragm is realized through combination.

The invention relates to the field of foaming materials, in particular to a low-solvent-residue expandable polystyrene material and a preparation method thereof. The expandable polystyrene material with low solvent residue comprises the following raw materials in percentage by weight: 0.35-0.45% of a free radical initiation system, 0.35-0.45% of S, S, S, S, S, S, S, S, S, S, S, S, S, S, S According to the present invention, the material comprises, by weight, 0.1-0.15% of S, S '-bis (alpha, alpha'-dimethyl-alpha ''-acetoxy) trithiocarbonate, 0.15-0.2% of ascorbic acid, 0.1-0.2% of a nucleating agent, 0.2-0.3% of a suspending agent, 0.001-0.003% of an emulsifier, 5-6% of a foaming agent, 0.15-0.25% of a plasticizer, 0.001-0.002% of hydroxyethyl cellulose, 0.05% of sodium phosphate, 0.1-0.2% of zinc stearate, and 0.1-0.2% of glyceryl stearate, the obtained material has low solvent residue, meets food safety requirements, and is suitable for food packaging.

The invention provides an adsorbent capable of simultaneously adsorbing bilirubin and cytokines and a preparation method and application thereof, and the preparation method comprises the following steps: carrying out suspension polymerization reaction on a styrene monomer and a polyvinyl cross-linking agent in a dispersion medium under the action of a continuous multi-component pore-foaming agent and an initiator to prepare polystyrene-based macroporous resin; carrying out chloromethylation reaction on the polystyrene-based macroporous resin to prepare chlorine balls; carrying out post-crosslinking reaction on the chloromethylated beads to prepare the adsorbent capable of adsorbing bilirubin and cytokines at the same time; the continuous multi-component pore-foaming agent comprises a first pore-foaming agent, a second pore-foaming agent and a third pore-foaming agent of which the solubility parameters are gradually increased in sequence; the temperature of the suspension polymerization reaction is adjusted according to the mass fraction of the polyvinyl cross-linking agent in the monomer mixture and the solubility parameter of the continuous multi-component pore-foaming agent, and the monomer mixture is composed of styrene monomers and the polyvinyl cross-linking agent. The bilirubin and cell factors can be adsorbed at the same time, and the safety of blood purification is improved.

The invention discloses a method for synthesizing electronic-grade ethyl acetate through catalytic esterification of acidic ion exchange resin, and belongs to the technical field of ethyl acetate preparation. The method comprises the following steps: mixing crosslinked polystyrene white balls and a swelling agent, and dropwise adding concentrated sulfuric acid for reaction to obtain S-PS resin; mixing an EDTA disodium salt saturated solution and a polyacrylic acid solution, adding a cross-linking agent and an emulsifier, and carrying out a cross-linking curing reaction to obtain EDTA microcapsules; the preparation method comprises the following steps: dispersing S-PS resin in a solvent, adding EDTA microcapsules, a dehydration condensation agent and a catalyst, reacting under the protection of inert gas, and filtering and recovering after the reaction is finished to obtain S-PS-EDTA resin; mixing glacial acetic acid, absolute ethyl alcohol and S-PS (at) EDTA resin for reaction, and filtering and collecting liquid after the reaction is finished; and rectifying the collected liquid to obtain the product. According to the method provided by the invention, metal impurities can be chelated in the synthesis process, and the electronic-grade ethyl acetate with high purity and low impurity content is produced.

Methods for upgrading heavy aromatic waste streams, such as polystyrene, to chemical feedstocks are disclosed. The process involves feeding waste streams to a first pyrolysis zone followed by hydrogenation. The hydrogenation effluent is processed to recover ethylene, propylene, benzene, ethylbenzene, or their precursors. Optionally, the effluents are separated into light and heavy streams. The light stream from the first pyrolysis effluent is sent to hydrogenation, while the heavy stream is either removed, recycled to the first pyrolysis zone, or fed to a second pyrolysis zone. The light stream from the hydrogenation effluent is processed to recover the same chemicals, and the heavy stream is similarly managed. If present, the second pyrolysis effluent is separated into light and heavy streams, with the light stream processed to recover chemicals and the heavy stream managed as before.

The invention discloses a method for degrading polystyrene (PS) plastic and upgrading and recycling the PS plastic into benzoic acid based on nano MnO2 photocatalytic ozonation, and belongs to the technical field of solid waste recycling. The method comprises the following steps: firstly, mixing PS plastic fragments with nano MnO2 and an organic solvent, then simultaneously introducing ozone into a reaction system at normal temperature and normal pressure, and irradiating with light. Through synergistic catalysis of light and ozone, molecular chains of the PS plastic can be efficiently and selectively broken and oxidized, and finally the PS plastic is directionally converted into benzoic acid with high additional value. After the reaction is finished, a benzoic acid product can be obtained through simple separation, concentration and purification steps. The method provided by the invention realizes high-valued recycling of the waste PS plastic under mild conditions, solves the problems of high energy consumption, complex products, easy generation of secondary pollution and the like in a traditional treatment method, and has the outstanding advantages of green process, efficient reaction, high product value and the like.

The utility model relates to a lighting, heat-insulating and waterproof window well of a building and belongs to the technical field of window wells. Comprising a basement wall and a lighting assembly, window wells are arranged on the basement wall, the lighting assembly comprises lighting windows and suspended ceilings, the lighting windows and the suspended ceilings are located at the tops and the bottoms of the window wells respectively, the window wells comprise the upper window wells and the lower window wells, and the lower window wells are in a horn shape; a waterproof heat preservation assembly is arranged between the window well and the basement wall, a drainage pipe penetrating through the waterproof heat preservation assembly is arranged in the basement wall, the waterproof heat preservation assembly comprises a waterproof roll layer, a cement mortar smearing layer and a graphite polystyrene board, and the cement mortar smearing layer and the graphite polystyrene board conduct heat preservation on the window well. According to the building daylighting heat-preservation waterproof window well, the daylighting efficiency and uniformity are improved through the design of the outwards-convex-pyramid-shaped daylighting window and the horn-shaped lower window well, the waterproof heat-preservation assembly is combined with the graphite polystyrene board, heat transfer is effectively prevented, the heat-preservation performance is enhanced, and meanwhile the waterproof effect is improved through the waterproof roll layer and the cement mortar smearing layer.

The invention relates to the technical field of high polymer materials, and discloses a method for continuously producing brominated polystyrene, which comprises the following steps: I, preparing raw materials, ensuring the basic quality of the product by high-quality raw materials, and optimizing reaction conditions, improving the yield and reducing unnecessary byproducts by correct selection; step II, premixing and heating, full premixing ensures the consistency of the materials, and more uniform reaction can be realized. According to the method for continuously producing brominated polystyrene, continuous supply of materials is ensured by utilizing an automatic storage and conveying system, uniform dispersion and stable temperature rise of the materials are ensured by adopting a continuous feeding mixer and an indirect heating system, and efficient bromination reaction is performed by using a microchannel reactor; products are rapidly separated and purified by means of a continuous centrifugal separator and a membrane separation technology, and an automatic quality control system is combined with multiple analytical instruments to ensure that the quality of each batch of products is consistent, so that the effect of efficient, stable and continuous production can be achieved.

Mobile or stationary air filter (L) or room fan (RL) according to Figure 1, comprising an outer wall (5), a (2) for generating an airflow (3) which is guided through an air filter material (1.1), an air inlet (2.1) and an air outlet (2.2), wherein the air filter material (1.1) contains poly(styrenesulfonic acid) (sulfonic acid biocide) (1.3) cross-linked with divinylbenzene and / or an acidic salt (1.3.1) (sulfonic acid biocide salt) of the sulfonic acid biocide (1.3) with biocidal cations, wherein the sulfonic acid biocide (1.3) and / or sulfonic acid biocide salt (1.3.1)(i) are positively and / or materially bonded to and / or in inert carriers and, in the fixed state, are in direct contact with carrier materials (1.1.7) on and / or in which biocidal Metal microparticles of a mean particle size d50 of 0.1 µm to <1,000 µm are fixed, and / or (ii) with carrier materials (1.1.7) on and / or in which biocidal metal microparticles of a mean particle size d50 of 0.1 µm to <1.000 µm are fixed, are mixed; its use and methods for the production and environmentally friendly disposal of air filter materials (1.1).

The invention relates to the technical field of expanded polystyrene production, and discloses an expanded polystyrene automatic molding control system and method.The system comprises a detection module, a data analysis module and a central control module, and the detection module collects mold temperature distribution, molded blank local density and steam pressure data in real time; the data analysis module calculates a temperature fluctuation index according to the temperature data, obtains a dynamic density compensation coefficient by means of a density model, and determines a forming quality deviation level; and the central control module adjusts the steam heating power according to the deviation level, determines and corrects the mold opening and closing rate in combination with the pressure and density change rate, and generates a motion trail control parameter. The method comprises the steps of data acquisition, calculation and analysis, parameter adjustment and instruction output. Through multi-parameter cooperative control, forming automation and precision are achieved, the quality stability and the production efficiency are improved, and the method is suitable for production of related products.

The invention discloses a lithium iron manganese phosphate positive electrode material and a preparation method thereof, and belongs to the technical field of lithium ion batteries, the lithium iron manganese phosphate positive electrode material at least comprises lithium iron manganese phosphate particles and a coating layer coating the lithium iron manganese phosphate particles; the raw material of the coating layer comprises an aluminum fluoride embedded poly (ethylenedioxythiophene)-lithium polystyrene sulfonate compound. And the coating layer can be used as a physical barrier to form dynamic interface protection, so that dissolution of manganese and erosion of electrolyte are directly inhibited, and side reaction between the electrolyte and the positive electrode material is reduced. Meanwhile, a more flexible transmission channel is provided for lithium ions and electrons, the conductivity of the positive electrode material is enhanced while the transmission efficiency of the lithium ions is improved, and the lithium manganese iron phosphate positive electrode material with stable structure, high rate capability and cycling stability is obtained.

In one aspect, the disclosure relates to a flame retardant composition comprising a brominated polystyrene reacted with a first portion of a second polymer, and optionally at least a second portion of the second polymer that is not premixed with the brominated polystyrene alone. In some aspects, the first portion and the second portion of the second polymer can be selected from the group consisting of polyamides, polyolefins, polyesters, styrenic polymers or copolymers, or any combination thereof. In any of these aspects, the flame retardant compositions of the present disclosure are sufficiently mixed and have excellent properties, and can optionally include crosslinking to increase mechanical strength. Also disclosed herein are methods for preparing the compositions and articles of manufacture comprising the compositions.

The invention provides a separation and purification method of urokinase, and relates to the technical field of separation and extraction. The separation and purification method comprises the following steps: S1, regulating the pH value of male urine to 8.5, standing, and taking supernate; s2, mixing the supernate with an adsorption material, and eluting with an eluent to obtain a urokinase crude product solution; the adsorption material is a core-shell silica gel polymer, Fe3O4atSiO2-NH2 is taken as a core, and polystyrene is taken as a shell; the eluent is a sodium citrate buffer solution with the concentration of 0.5 to 0.15 M, acetonitrile with the concentration of 1 to 5 weight percent and EDTA (Ethylene Diamine Tetraacetic Acid) with the concentration of 0.5 to 1.5 mM; and S3, carrying out anion exchange column chromatography on the urokinase crude product solution, eluting with an eluent, and precipitating to obtain the urokinase. The urokinase prepared by the method has the advantages of high polymer urokinase content, high recovery rate and high activity yield.

The invention relates to polystyrene cation exchange resin as well as a preparation method and application thereof. The preparation method comprises the following steps: dissolving a dispersing agent in a solvent to obtain a dispersed phase for suspension polymerization reaction, uniformly mixing a reaction monomer, a cross-linking agent, a pore-foaming agent and an initiator, and carrying out suspension polymerization reaction under segmented stirring and segmented temperature change to prepare copolymer microspheres; and putting the dried microspheres into a reaction kettle, swelling, carrying out sulfonation reaction through a variable temperature program on the basis to obtain sulfonated microspheres, and carrying out alkali exchange reaction on the sulfonated microspheres to obtain the final product cation exchange resin. Compared with the prior art, the cation exchange resin preparation method provided by the invention has the characteristics of simple and feasible process, easiness in large-scale production, low cost, high specific surface area, high adsorption capacity and high separation efficiency, and is especially suitable for separating and purifying substances containing amino groups or aminoglycosidic bonds.

The invention belongs to the technical field of composite materials, and particularly relates to a composite material for a high-performance cone crusher lining plate and a preparation method of the composite material. The composite material is prepared from the following components in parts by weight: 70 to 90 parts of semi-aromatic polyamide, 20 to 30 parts of fiber reinforced filler, 10 to 20 parts of flexibilizer, 10 to 20 parts of brominated polystyrene, 10 to 15 parts of graphene, 1 to 5 parts of diatomite nanoparticles, 2 to 6 parts of metal compound flame-retardant aid, 0.5 to 3 parts of coupling agent, 0.5 to 3 parts of lubricant and 0.5 to 3 parts of antioxidant. The graphene and diatomite nanoparticles are added into the brominated polystyrene flame-retardant resin, so that the dispersity of brominated polystyrene and the compatibility of the brominated polystyrene and polyamide resin can be improved, the flame retardance and thermal stability of the composite material are improved, and the mechanical property of the composite material can be improved; and the use requirements of devices in equipment such as a cone crusher lining plate are met.

The invention discloses a roof waterproof and heat preservation integrated structure which comprises a roof base layer, a roof structural layer set, a parapet wall, a roof embedded sleeve, a rainwater pipe embedded assembly, a steam exhaust pipeline and a roof equipment platform which are sequentially arranged from bottom to top. The roof structure layer set comprises a first waterproof layer, a heat preservation layer, a slope making layer, a leveling layer, a second waterproof layer, an isolation layer and a waterproof protection layer which are sequentially arranged from bottom to top, an outer eave and an inner eave are arranged at the top end of the parapet wall, and the surface base layer exceeds the outer side of the parapet wall. The space between the outer eave of the parapet wall and the surface base layer is filled with a graphite polystyrene board and is used for building autoclaved aerated concrete blocks, and the second waterproof layer is upturned to an internal corner formed by the inner eave of the parapet wall and a vertical wall body of the parapet wall. The design of the outer eave and the inner eave at the top end of the parapet wall is matched with the filled graphite polystyrene boards and the built autoclaved aerated concrete blocks, so that the heat preservation and heat insulation performance of the parapet wall is effectively improved.

The invention relates to the technical field of lithium ion batteries, in particular to a silicon-based negative electrode material and a preparation method and application thereof. The silicon-based negative electrode material comprises slurry and a copper sheet, and the mass ratio of the slurry to the copper sheet is (0.5-1): 8.4; the slurry is prepared from silicon powder, sodium alginate, a conductive agent, poly (3, 4-ethylenedioxythiophene) / polystyrolsulfon acid, an initiator and a solvent; the initiator is a polar solvent. The structural stability of the silicon-based negative electrode material in the lithiation / delithiation process is realized by constructing a three-dimensional (3D) cross-linked network structure on the surface of the silicon particles and optimizing a self-repairing SEI layer interface. And the network structure can effectively inhibit volume expansion of the silicon negative electrode material and maintain the integrity of the silicon negative electrode morphology, so that the specific capacity and the cycle performance of the lithium ion battery are remarkably improved.

The invention relates to the technical field of lithium ion batteries, in particular to a silicon-based negative electrode binder as well as a preparation method and application thereof. The silicon-based negative electrode binder comprises sodium alginate, poly (3, 4-ethylenedioxythiophene) / polystyrolsulfon acid, an initiator and a solvent. On the basis of double design of a 3D cross-linked network formed by sodium alginate, poly (3, 4-ethylenedioxythiophene) / polystyrolsulfon acid and a silicon material and a self-healing SEI layer interface, volume expansion of a silicon-based negative electrode in a lithiation / lithium removal process is inhibited, so that the capacity of the silicon-based negative electrode material is improved, and the cycle performance of a lithium ion battery is improved.

The invention belongs to the technical field of high polymer materials, and particularly relates to a lightweight high-strength expandable polystyrene material and a preparation method thereof. The high-temperature-resistant foaming material is prepared from the following components in parts by weight: 90 to 100 parts of styrene, 200 to 250 parts of deionized water, 0.3 to 0.6 part of a dispersing agent, 1.5 to 2.5 parts of a nucleating agent, 0.2 to 0.6 part of an initiator, 0.2 to 0.5 part of a particle size regulator, 4 to 7 parts of a foaming agent and 3 to 6 parts of composite filler, the composite filler is prepared by mixing modified graphene and modified silicon dioxide; the modified graphene is maleic anhydride copolymer sulfonate modified graphene, and the modified silicon dioxide is polydopamine / carboxymethyl cellulose modified silicon dioxide; the water dispersibility and interfacial compatibility of the composite filler are remarkably improved in a physical and chemical grafting manner, and the mechanical property, thermal stability and flame retardance of the polystyrene material are synchronously optimized by utilizing a multi-component synergistic effect.

The invention discloses polyurethane polystyrene foam as well as a preparation method and application thereof, and belongs to the field of polyurethane materials. The polyurethane polystyrene foam comprises a component A and a component B, and the weight ratio of the component A to the component B is 1: (1.3-1.5); the component A is prepared from the following components in parts by weight: 5 to 14 parts of melamine polyol, 32 to 37 parts of high-functionality polyether polyol, 30 to 35 parts of low-viscosity polyether polyol, 15 to 20 parts of a liquid flame retardant, 1.0 to 1.5 parts of a foam stabilizer, 1.5 to 2.0 parts of a catalyst, 0.1 to 0.2 part of a retarder and 1.0 to 1.5 parts of deionized water; and the component B is polymethyl polyphenyl polyisocyanate. The polyurethane polystyrene foam provided by the invention can achieve the effects of low density, excellent heat insulation property and high dimensional stability.

The invention belongs to the field of biomedical materials, and discloses a hydrogel patch with piezoelectricity, conductivity and high adhesion and a preparation method and application of the hydrogel patch. Polyvinyl alcohol (PVA) and acrylic acid (AA) serve as polymer frameworks of the hydrogel patch; the invention relates to a nano-zinc oxide / poly (3, 4-ethylenedioxythiophene) / poly (styrenesulfonic acid) (PEDOT: PSS) composite conductive adhesive, which comprises nano-zinc oxide (ZnO) as a piezoelectric material, poly (3, 4-ethylenedioxythiophene)-poly (styrenesulfonic acid) (PEDOT: PSS) as a conductive material, and N-hydroxysuccinimide acrylate (NHS-AA) as an adhesive functional monomer. According to the invention, active ester groups in the N-hydroxysuccinimide acrylate are utilized, so that the patch can quickly form covalent amido bonds with amino groups on the surface of a tissue in a dry state, firm adhesion is realized, local nerve repair can be effectively promoted through a piezoelectric effect, a novel ideal material is provided for disease treatment, and the patch has wide application prospects. Wide clinical application prospects are realized in the field of biological medicines.