2513 results about "Ammonium chloride mixture" patented technology

The invention relates to a ring structure betaine and double-tailed hydrophobic association polymer fracturing thickening agent and a preparation method thereof. The thickening agent is formed by copolymerization of four monomers, namely acrylamide, 2-allyl methylamino sodium ethanesulfonate, methyl diallyl sulfoethyl betaine and hydrophobic monomer double-tailed long-chain alkyl methyl allyl ammonium chloride. The preparation method comprises the following steps: firstly adding distilled water, then sequentially adding acrylamide, 2-allyl methylamino sodium ethanesulfonate, methyl diallyl sulfoethyl betaine and a hydrophobic monomer double-tailed long-chain alkyl methyl allyl ammonium chloride, adjusting the total concentration, introducing N2 to remove oxygen, adding an initiator, and reacting to prepare an AM / AMES / MDASBA / DCnMAAC quadripolymer, namely the polymer fracturing thickening agent. The thickening agent provided by the invention has good water solubility, and shows good salt resistance in mixed brine with the mineralization degree of greater than or equal to 30000 mg / L. The prepared linear solution and gel formed after crosslinking have high viscosity retention capacity at the temperature of 150 DEG C and the shearing rate of 170 s <-1 >, and the actual construction requirement for fracturing yield increase with the on-site mineralization degree larger than or equal to 30000 mg / L is met.

The invention relates to the field of membrane materials, and discloses an epoxy modified starch-based degradable membrane and a preparation method thereof, the epoxy modified starch-based degradable membrane comprises epoxidized starch, modified nanocellulose and a plasticizer; the modified nano cellulose is prepared by mixing a modified composite filler, a nano cellulose dispersion liquid and a zinc acetate dihydrate aqueous solution; the nano-cellulose dispersion liquid is prepared by adhering polytannic acid formed by oxidation and self-polymerization of tannic acid to the surface of nano-cellulose; the modified composite filler is prepared by performing carboxylation modification on nano titanium dioxide coated fumed silica nanoparticles by using succinic anhydride and gamma-aminopropyltriethoxysilane, then reacting with polyethyleneimine to obtain an aminated composite filler, and finally grafting glycidyl dodecyl dimethyl ammonium chloride to the surface of the aminated composite filler. The prepared film material is high in tensile strength, has certain hydrophobicity, and has good heat resistance, antibacterial property and flame retardant property.

The invention relates to the technical field of oilfield chemistry, and discloses a graft modified cellulose filtrate reducer and a preparation method thereof.The preparation method comprises the following steps that modified hydroxyethyl cellulose, 2-acrylamide-2-methyl propane sulfonic acid, dimethyl diallyl ammonium chloride, alkenylated cardanol and N, N '-methylene bisacrylamide are added into deionized water, stirring is conducted, and a mixture is obtained; the preparation method comprises the following steps: adding cellulose into a reaction kettle, stirring for 10-15 minutes at the temperature of 40-60 DEG C at the speed of 300-400 rpm, dropwise adding ammonium persulfate and sodium hydrogen sulfite into a system, and continuously reacting for 4-6 hours to obtain the grafted modified cellulose filtrate reducer. The filtrate reducer disclosed by the invention has good high temperature resistance and salt resistance.

The invention relates to a preparation method and application of an inner-rigid outer-soft core-shell structure silicon dioxide blocking agent for marine drilling fluid, and belongs to the field of deepwater oil and gas drilling. N-vinyl-2-pyrrolidone, dimethyl diallyl ammonium chloride, acrylamide and 2-acrylamide-2-methylpropanesulfonic acid are polymerized and grafted on the surface of nano silicon dioxide to form the silicon dioxide blocking agent with a core-shell structure and a rigid inside and a soft outside; by means of rigid plugging of a nano material and deformation filling flexible plugging of a high-molecular polymer, shale micro-nano pores are efficiently plugged with rigid inside and flexible outside, so that the stability of a well wall is maintained, meanwhile, secondary generation of hydrates is effectively inhibited, and the safety and efficiency of deepwater drilling are improved; the plugging agent provided by the invention reduces the demand on a large number of thermodynamic inhibitors, not only saves the cost, but also has the characteristic of environmental protection.

The invention relates to the technical field of inorganic nonmetal ceramic materials, in particular to a ceramic tile and a preparation method thereof. The ceramic tile comprises the following raw materials: 40-50 parts of waste residues, 1-5 parts of barium carbonate, 5-8 parts of feldspar powder, 0.5-3 parts of zinc oxide, 2-7 parts of pigment, 15-20 parts of modified kaolin and 1-5 parts of water. The preparation process of the modified kaolin comprises the following steps: (1) adding kaolin into deionized water, then adding octadecyl bis (hydroxyethyl) methyl ammonium chloride, stirring, filtering and drying to obtain pretreated kaolin; and (2) adding the kaolin pretreated in the step (1) into deionized water, then adding cellulose and manganous nitrate, carrying out heating reaction, and then filtering, washing and drying to obtain the modified kaolin. Cellulose is carbonized on the surface of kaolin through a hydrothermal carbonization reaction, the heat conduction efficiency of the ceramic tile is reduced, the hybridization degree of the surface structure of kaolin is further improved by adding manganous nitrate, and the strength of the ceramic tile is improved.

The invention discloses a method for testing the content of platinum in a platinum compound solution, and belongs to the technical field of analytical testing. According to the test method, an ammonium chloride precipitation gravimetric method is replaced by a hydrogen reduction gravimetric method, platinum ions in a platinum compound solution are reduced into elemental platinum in a hydrogen reduction mode, and the content of platinum in the solution is calculated by weighing the weight of a reduced platinum sinter and subtracting the content of impurity elements in the platinum sinter at the same time. According to the method, the platinum content in the platinum compound solution can be accurately and quantitatively analyzed, the operation process is simple, good repeatability is achieved, the range of multiple analysis results of the same sample is smaller than or equal to 0.05% and is far lower than the repeatability limit 0.2% of a national standard method, the analysis accuracy is guaranteed, and meanwhile the analysis efficiency is greatly improved.

The invention relates to the technical field of cationic etherifying agents, and discloses a quaternary ammonium salt type cationic etherifying agent and a preparation method thereof.3-chloro-2-hydroxypropyl trimethyl ammonium chloride and sulfaguanidine modified quaternized chitosan are added into a reactor and stirred, and the quaternary ammonium salt type cationic etherifying agent is obtained. Quaternary ammonium salt, guanidyl and chitosan groups contained in the sulfaguanidine modified quaternized chitosan all have better antibacterial effects; wherein the quaternary ammonium salt is adsorbed to the surfaces of bacteria, and hydrophobic groups are inserted into lipoid layers, so that the permeability of cell membranes is changed, the membrane structure is destroyed, intracellular substances are leaked, and the bacteria are dead; guanidyl can be combined with protein and nucleic acid in bacterial cells to interfere the normal metabolic process of bacteria and further inhibit growth and reproduction of the bacteria, so that a natural antibacterial effect is achieved; and the chitosan group has a relatively good antibacterial effect.

The invention discloses a preparation method of an ultra-thin high-density fiberboard with ultra-low formaldehyde emission, which is characterized by comprising the following steps: peeling wood by using a peeling machine, chipping to obtain wood chips, washing the wood chips with water, cooking in a cooking cylinder, feeding into a defibrator, and adding molten paraffin for treatment to obtain fibers; meanwhile, formaldehyde is taken to be mixed with sodium bentonite, triethylene diamine and polyvinyl alcohol, then urea is added in five times, melamine is added in two times, a reaction is conducted, and melamine modified urea-formaldehyde resin is prepared; taking fibers, applying an adhesive formed by mixing melamine modified urea-formaldehyde resin, nano titanium dioxide and an ammonium chloride curing agent, drying and dehydrating the fibers uniformly mixed with the adhesive, sorting to remove micelles, fiber agglomerates and fiber bundles, and paving and forming to obtain a plate blank; and the plate blank is taken to be subjected to the hot pressing procedure to obtain a plate, and after the plate is cooled, the ultra-thin high-density fiberboard with the advantages of being high in strength, low in formaldehyde emission and the like is obtained after sanding.

The present disclosure relates to the technical field of drilling fluid, and discloses a high density environmentally friendly polymer water-based drilling fluid with resistance to 240° C. and saturated salts, a preparation method therefor and use thereof. The water-based drilling fluid comprises a micro-crosslinked heterocyclic polymer filtrate reducer, a hyper-branched strongly adsorbed filtrate reducer, a nanometer intercalated complex shearing potentiator, a flexible outer and rigid inner microsphere plugging agent, and water, wherein the micro-crosslinked heterocyclic polymer filtrate reducer is prepared by reacting sodium p-styrene sulfonate, N,N,N-trimethyl-3-(2-methylallylamino)-1-propyl ammonium chloride, N,N-diethyl acrylamide, N-vinyl caprolactam, tetramethyl ethylenediamine with phenyl triethoxy silane. The high density environmentally friendly polymer water-based drilling fluid with resistance to 240° C. and saturated salts of the present disclosure can exhibit good performance at high temperature and high salinity conditions, and has desirable weighting capability, it can meet the requirements of drilling well in the deep oil and gas formations.

The invention relates to the field of sponge materials, and provides an antibacterial degradable sponge material and a preparation method thereof. The material is prepared from protocatechuic acid modified quaternized chitosan, quaternary ammonium salt grafted gelatin, sodium alginate, polyhydroxybutyrate, polycaprolactone, a polylactic acid-glycolic acid copolymer, hexamethylene diisocyanate, a foaming agent, nano cellulose, vitamin E, polyethylene glycol, triethylamine and dimethylformamide. Protocatechuic acid and quaternized chitosan are subjected to amidation modification, and chitosan and gelatin are subjected to quaternization treatment by adopting 2, 3-epoxypropyl trimethyl ammonium chloride, so that the antibacterial property and biodegradability of the material are improved. In the material preparation process, through vacuum degassing, foaming vacuum degree and humidity control and a multi-step drying process, it is ensured that the average pore size of the material is uniform (50-200 microns) and the porosity is high (50%-90%), and the obtained material has excellent antibacterial property and degradability and has wide application value.

The invention relates to the technical field of plugging agents, and discloses a viscoelastic polymer type self-assembly plugging agent and a preparation method thereof. The preparation method comprises the following steps: adding acrylamide, butyl acrylate, 2-acrylamide-2-methylpropanesulfonic acid, quaternized cyclodextrin, gamma-glycidyl ether oxypropyl trimethoxy silane modified bentonite, Schiff base styrene, a sodium dodecyl benzene sulfonate emulsifier and octadecyl dimethyl allyl ammonium chloride into a reaction kettle; and adding an azodiisobutyronitrile initiator into the deionized water, uniformly mixing, and reacting for 4-5 hours at 50-65 DEG C to obtain the viscoelastic polymer type self-assembled plugging agent after the reaction is finished. The plugging agent disclosed by the invention has a relatively good plugging effect, and effectively solves the problem that the gel strength is weakened or the gelling is not thorough due to the formation shearing effect in a continuous gel migration process.

The invention discloses a composite clarifying agent for alkali-free glass and a manufacturing method of an alkali-free glass substrate, and relates to the technical field of glass manufacturing, the composite clarifying agent for alkali-free glass comprises the following components by mass: 12-30% of ammonium chloride, 48-73% of sulfate, and 11-25% of calcium fluoride; the preparation method comprises the following steps: adding a composite clarifying agent accounting for 0.2-1.2% of the total weight of the glass raw material into the glass raw material, uniformly mixing to form a batch, and carrying out melting, molding, spraying, annealing, cutting, alkali cleaning and other processes on the batch to finally prepare the glass substrate. The prepared composite clarifying agent does not contain toxic substances such as arsenic oxide and antimony oxide, the glass substrate produced by using the clarifying agent not only has an excellent clarifying effect, but also can recycle SO2 and NH3 gas generated in the melting process, can effectively solve the quality problems such as micro-flaws on the surface of the glass substrate in the production process, and has a good application prospect. And the production cost can be reduced and the product quality can be improved.

The invention provides a preparation method and application of boron isotope separation resin microspheres. The preparation method comprises the following steps: (1) adding dimethyl sulfoxide into polystyrene-divinylbenzene resin microspheres to swell for 3 hours, adding concentrated sulfuric acid to treat until the sulfonation rate is 0.3-0.4 meq / g, washing with water, treating with an ammonium chloride aqueous solution, washing with water, drying in vacuum, atomizing and spraying a ferric chloride-ferrous chloride aqueous solution, evaporating in vacuum to remove part of water, and introducing ammonia-containing nitrogen flow to treat to obtain polystyrene-divinylbenzene resin microspheres; and washing with water, grinding the surface, treating with a sodium hydroxide aqueous solution and washing with water. The boron isotope separation resin microspheres are suitable for chromatographic separation of 10B and 11B in a boric acid-sodium hydroxide aqueous solution with the pH of 6-7.5, a desorption solution is pure water, the feeding rate is 0.3-0.6 m / h, and a boric acid-containing aqueous solution enriched with 10B can be obtained; the service life of the chromatographic column is more than 6 months, the adsorption separation performance is reduced by not more than 20%, and the chromatographic column has a certain application prospect.

The invention discloses a method for preparing a catalytic material by synergistically utilizing red mud and electrolytic manganese residues as well as a product and application thereof. The method comprises the following steps: mixing electrolytic manganese residues and red mud, uniformly stirring, adding ammonium chloride, stirring, adding a hydrochloric acid solution, stirring, roasting and grinding. And adding an auxiliary agent, uniformly stirring, adding water, granulating, standing, carrying out hydrothermal reaction, and roasting to obtain the catalytic material. The preparation process is simple, the technological process is brief, the needed core raw materials are only the red mud and the electrolytic manganese residues, and resource utilization of the red mud and the electrolytic manganese residues is efficiently achieved. The prepared catalytic material can quickly adsorb pollutants in waste liquid under the condition of no photocatalysis, and the removal effect on COD (Chemical Oxygen Demand), ammonia nitrogen, total phosphorus and heavy metal mercury can be further remarkably improved under the photocatalysis condition.

The invention relates to the field of material science, and discloses a preparation process of a softwood rubber metal composite material, which comprises the following steps: S1, cleaning the surfaces of metal, softwood and rubber; s2, plasma treatment is conducted on the surfaces of the metal, the cork and the rubber; s3, preparing a modified chemical coupling agent, and coating the modified chemical coupling agent on the surfaces of metal, cork and rubber; s4, hot press molding is carried out, and metal, rubber and cork are stacked and subjected to hot press treatment; and S5, cooling treatment is conducted, and the cork rubber metal composite material is obtained. The modified chemical coupling agent is prepared from the following components in percentage by weight: 70 to 80 percent of 3-methyl propyl triethoxy silane; 10 to 20 weight percent of diisocyanate-based silicone oil; 5 to 10 wt% of polyethylene glycol; and 2-5 wt% of dimethyl diallyl ammonium chloride. The interface bonding strength of the softwood rubber metal composite material is remarkably improved, and the overall mechanical performance is enhanced.

The invention belongs to the field of flotation, and particularly relates to a method for flotation of copper cobalt oxide ore by using magnesium-containing tailing water, the magnesium-containing tailing water is used as flotation water to carry out five-stage roughing on the copper cobalt oxide ore, the first-stage roughing is carried out under a vulcanizing agent and a xanthate-thionocarbamate collecting agent, and the second-stage roughing is carried out under the action of a flotation agent; and the second-stage roughing is carried out under the condition of containing a compound additive, a vulcanizing agent and xanthate-hydroximic acid. The third-stage roughing is carried out under the action of a vulcanizing agent and xanthate-hydroximic acid; and the fourth-section roughing process and the fifth-section roughing process are carried out under the action of a hydroximic acid collecting agent. The compound additive comprises a component A and a component B with a structure shown in a formula 1 (# imgabs0 #); the component A comprises at least one of ammonium carbonate, ammonium bicarbonate, ammonium nitrate, ammonium acetate, ammonium sulfate and ammonium chloride; and the composite collecting agent comprises a xanthate collecting agent and a hydroximic acid collecting agent. By means of the method, the problem of flotation degradation caused by magnesium-containing tailing water recycling can be solved, and the excellent flotation effect can be achieved.

The invention discloses a functional fracturing fluid directly prepared from flow-back fluid of complex water quality. The fracturing fluid is prepared by directly adding a salt-tolerant polymer and an ion trapping agent into the flow-back fluid. The addition amount of the salt-tolerant polymer accounts for 0.15-0.3% of the total mass of the fracturing fluid, and the addition amount of the ion trapping agent is 100-500ppm. The salt-tolerant polymer is prepared by copolymerization of acrylamide, a salt-tolerant monomer and an allyl quinoline monomer, and the molecular weight of the polymer is 4-15 million. The salt-tolerant monomer is acrylamide polyoxyethylene sodium benzenesulfonate or acrylamide sodium sulfonate. The ion trapping agent is prepared from amino trimethylene phosphonic acid, diethylene triamine penta (methylene phosphonic acid), ethylene glycol bis (2-aminoethyl ether) tetraacetic acid, p-methylphenyl diethanol amine, 2, 3-epoxypropyl trimethyl ammonium chloride, fatty alcohol-polyoxyethylene ether, citric acid and tetrahydrofurfuryl acrylate. The fracturing fluid can be directly prepared from the flow-back fluid, the flow-back fluid does not need to be pretreated, and repeated utilization of the fracturing flow-back fluid is achieved.

The invention discloses a fermentation medium for regulating and controlling a clostridium aerovorans target product and a fermentation method of the clostridium aerovorans target product. The medium comprises a basic component and a regulating component, the basic components comprise ammonium chloride, potassium chloride, magnesium sulfate heptahydrate, sodium chloride, monopotassium phosphate, yeast powder, calcium chloride dihydrate, sodium selenite, nickel chloride hexahydrate, biotin, folic acid, pyridoxine hydrochloride, thiamine, riboflavin, nicotinic acid, D-calcium pantothenate, cobalamin, para aminobenzoic acid and lipoic acid; the adjusting component comprises sodium tungstate, ferrous sulfate and sodium molybdate, sodium tungstate and ferrous sulfate have a forward adjusting effect on increasing the yield of acetic acid, ethanol and butanol in the target product, and sodium molybdate has a reverse adjusting effect on the target product. By optimizing the proportion of trace elements in the culture medium, the clostridium metabolism efficiency is improved, synthesis of a target product is regulated and controlled, and the method is particularly suitable for industrial production of acetic acid, ethanol, butanol and the like.

The invention belongs to the technical field of preparation of blocking removers, and particularly relates to a composite chelating blocking remover for an oil field and a preparation method of the composite chelating blocking remover. The composite chelating blocking remover for the oil field is prepared from the following raw materials in percentage by mass: 7 to 9 percent of 1-butyl-3-methylimidazole dodecyl sulfonate, 5 to 7 percent of erucamide propyl hydroxypropyl sulfobetaine, 3 to 4 percent of di-(2-ethylhexyl) sodium sulfosuccinate, 4 to 5 percent of ethylenediamine di-o-hydroxyphenylacetic acid, 5 to 7 percent of N, N '-di (2-hydroxybenzyl) ethylenediamine-N, N'-bis (2-hydroxybenzyl)-N, N '-bis (2-ethylhexyl)-N, N'-bis (2-hydroxybenzyl)-N, N '-bis (2-hydroxybenzyl)-N, N'-bis (2-hydroxyphenyl)-N, N '-bis (2-hydroxyphenyl)-N, N'-bis (2-hydroxyphenyl)-N The cleaning agent is prepared from the following components in percentage by weight: 3 to 4 percent of N, N '-diacetic acid, 2 to 3 percent of O-(3-(benzyloxy) propyl) hydroxylamine, 1 to 2 percent of heptadecenyl hydroxyethyl imidazoline quaternary ammonium salt, 1 to 1.5 percent of dimethyl diallyl ammonium chloride homopolymer and the balance of water. The composite chelating blocking remover for the oil field has excellent scale dissolution rate and paraffin inhibition rate when being applied to complex scale blocking removal of the oil field.

The invention provides a high-temperature-resistant desulfurization catalyst and a preparation method thereof, and relates to the technical field of catalysis, and the high-temperature-resistant desulfurization catalyst comprises the following components in percentage by weight: 30-35% of cobalt phthalocyanine, 10-15% of Fe-PBTCA-EDTMP, 10-15% of manganese sulfate monohydrate, 10-15% of 2, 3, 4-trimethyl-1, 3-pentanediol monoisobutyrate, 10-15% of 2, 3, 4-trimethyl-1, 3 The cleaning agent is prepared from 5-10% of 1, 4-dinitrophenol, 15-20% of tannin extract, 8-10% of sodium metavanadate, 8-10% of ammonium phosphate and 4-8% of ammonia-ammonium chloride solution. The high-temperature-resistant desulfurization catalyst disclosed by the invention has the advantages of being small in dosage, small in waste liquid discharge, good in regeneration effect, low in corrosion rate, low in operation cost, not easy to block a tower, capable of overcoming hydrogen cyanide poisoning, high-temperature-resistant and not easy to inactivate. In a wet oxidation desulfurization system, the high-temperature-resistant desulfurization catalyst provided by the invention overcomes the defects that a PDS desulfurization catalyst, an MSQ desulfurization catalyst, a vanadium pentoxide + tannin extract catalyst and an ADA catalyst are easy to inactivate and secondary salts in a desulfurization solution are increased quickly when the desulfurization solution is at a high temperature of 70 DEG C. In addition, the high-temperature-resistant desulfurization catalyst overcomes the defects that a complex iron catalyst is high in corrosivity, large in usage amount, prone to tower blockage and the like.

The invention discloses quick-dry water-based ink and a preparation method thereof, and relates to the technical field of ink. The preparation method comprises the following steps: firstly, enabling 4, 6-bis (allyloxy)-n-butyl-1, 3, 5-thiazine-2-amine and vinyl sulfonamide to participate in a polymerization reaction of acrylic acid and butyl acrylate, and preparing 4, 6-bis (allyloxy)-n-butyl-1, 3, 5-thiazine-2-amine and vinyl sulfonamide through a two-step emulsion polymerization method; the core-shell structure modified polyester emulsion with 2, 5-thiazine-2-amine and vinyl sulfonamide as soft shells and acrylic acid and butyl acrylate as hard cores improves the wear resistance and durability of the ink. Then allyl polyether reacts with 2-(p-chlorphenyl) ethylene oxide, so that the drying time is shortened, and the wear resistance of the ink is improved; then through addition reaction of reactants, bis (2-ethoxyl) dimethyl ammonium chloride and hydrogen-containing silicone oil, the epoxy-amino-polyether combined modified silicone oil flatting agent is formed, the flatting agent has hydrophilicity and hydrophobicity, the drying speed is increased, and the wear-resistant effect is improved.

The present invention provides an ammonia removal system for a urea granulation tower, which includes a hydrogen chloride gas spray head for spraying hydrogen chloride gas below the dust removal cloth bag of the urea granulation tower. During operation, on the one hand, the hydrogen chloride gas can act as a reactant to react with ammonia mixed in the air to form ammonium chloride, and the formed ammonium chloride is intercepted by the dust removal cloth bag, thereby achieving the purpose of ammonia removal; on the other hand, the hydrogen chloride gas can act as a catalyst to cause the tiny urea particles carried in the air to react with the moisture in the air under its catalytic action to form carbon dioxide and ammonia, thereby reducing the air humidity and solving the problem of the dust removal cloth bag being blocked. This ammonia removal system can not only achieve the purpose of ammonia removal, but also reduce the air humidity to solve the problem of the dust removal cloth bag being blocked, so it can be used in combination with the dust removal cloth bag.

The invention relates to a deep sewage defluorination method based on NH4F.LaF3 chemical precipitation, which comprises the following specific steps: adding a solution containing NH4 < + > and La < 3 + > into fluorine-containing water, adjusting the pH value of the sewage to 6-8, and carrying out NH4F.LaF3 chemical precipitation reaction; sediment is discharged, crystal particles in supernate are removed, deep defluorination of the sewage is achieved, and the concentration of fluorine ions in the water after defluorination can be stably lower than 1 mg / L. According to the method disclosed by the invention, by utilizing the characteristic that the solubility of double salt NH4F.LaF3 is very low, NH4 < + > ions (ammonium chloride or ammonia water and hydrochloric acid) and La < 3 + > ions (lanthanum chloride or lanthanum oxide and hydrochloric acid) are added into the fluorine-containing wastewater, so that equivalent reaction of fluorine, lanthanum ions, ammonium ions, fluorine ions and the like in the water is removed, and the addition of a medicament does not need to be excessive. The method has the characteristics of high efficiency and low cost, and has the advantages of small dosage of chemicals, high reaction speed, thorough reaction and low concentration of fluorine in effluent.

The invention discloses a preparation method of a mesoporous Zn-ZSM-5 molecular sieve for preparing aromatic hydrocarbon from methanol, and belongs to the technical field of synthesis of inorganic materials. Aiming at the problems that a conventional mesoporous Zn / ZSM-5 molecular sieve catalyst Zn blocks orifices, the mesoporous structure is disordered, the molecular sieve solid yield is low, a molecular sieve framework is seriously damaged and the like, the preparation method comprises the following steps: uniformly mixing zinc gluconate with an aluminum source, a silicon source and a template agent, putting the mixture into a closed reaction container, carrying out hydrothermal crystallization, and sequentially washing, drying and roasting to obtain the mesoporous Zn / ZSM-5 molecular sieve catalyst. The sodium type molecular sieve is obtained; the preparation method comprises the following steps: carrying out multiple ion exchange on a sodium type molecular sieve by using an ammonium chloride solution, and sequentially carrying out suction filtration, washing, drying and roasting to obtain the mesoporous Zn-ZSM-5 molecular sieve. According to the preparation method of the methanol-to-aromatic hydrocarbon Zn / ZSM-5 molecular sieve provided by the invention, the obtained molecular sieve is used in the methanol-to-aromatic hydrocarbon process, and has the characteristics of high carbon deposition resistance, high aromatic hydrocarbon selectivity, low Zn wastage rate and the like.

The invention provides a method for actively detecting the dosage of lime in lime stabilized soil for traffic infrastructure, and relates to the technical field of lime detection. The rapid detection method mainly comprises the following steps: preparing a plurality of test reagents, respectively adding a plurality of groups of lime stabilized soil containing different lime doses into an ammonium chloride solution to form a mixed solution, titrating the mixed solution by using a titrating solution, and detecting the conductivity of the solution, drawing a relation image of the solution conductivity and the dosage of the titrating solution, determining the dosage of the titrating solution when the conductivity is lowest, establishing a function relation between the lime dosage and the dosage of the titrating solution when the conductivity is lowest, repeating the steps and calculating the dosage of the lime in the to-be-detected lime stabilized soil in combination with the function relation. The invention overcomes the defects in the prior art, provides a new method for detecting the lime dosage of the lime-stabilized soil, and can quickly and accurately measure the lime dosage through the change of the conductivity in the solution and the characterization of the reaction process, thereby further improving the working efficiency.

The invention discloses a wet washing-high-temperature roasting combined treatment method for secondary aluminum ash, which comprises the following steps: firstly, carrying out wet washing treatment on the secondary aluminum ash to remove most of soluble salts and alkali metal elements in the secondary aluminum ash, reduce the flue gas amount in the roasting process and avoid the influence of the alkali metal elements on the performance of a refractory material; then, the washed secondary aluminum ash is subjected to high-temperature roasting, after the secondary aluminum ash is subjected to wet washing-high-temperature roasting treatment, a high-alumina refractory material with aluminum oxide and magnesium aluminate spinel as main components can be obtained, the high-alumina refractory material can be directly used as aggregate of the refractory material, and high-value resource utilization of the secondary aluminum ash is achieved; meanwhile, secondary aluminum ash wet washing and high-temperature roasting treatment process parameters are designed and optimized, so that the operation cost is reduced, and the treatment efficiency is improved; in addition, in the wet washing process, the ammonium chloride solution is used as washing liquid for the first time, and the content of aluminum oxide can be effectively increased on the premise that the removal rate of alkali metal elements is kept.

The invention relates to a double-tailed hydrophobic associated polymer oil-displacing agent with a benzene ring structure and a preparation method thereof. The oil-displacing agent is formed by copolymerizing three monomers, namely acrylamide, 2-allyl methylamino sodium ethanesulfonate and a hydrophobic monomer double-tailed long-chain alkyl methyl (p-3-carboxyl acrylamide benzyl) ammonium chloride with the benzene ring structure. The preparation method comprises the following steps: firstly adding distilled water, then adding acrylamide, 2-allyl methylamino sodium ethanesulfonate and a hydrophobic monomer double-tailed long-chain alkyl methyl (p-3-carboxyl acrylamide benzyl) ammonium chloride with a benzene ring structure, supplementing water, adjusting the total concentration, introducing N2 to remove oxygen, adding an initiator, and reacting at a certain temperature to prepare the terpolymer. The prepared polymer oil-displacing agent has good water solubility, temperature resistance and shearing resistance, shows good salt resistance in saline water with the mineralization degree larger than or equal to 30000 mg / L and shows a good oil-displacing effect in a heterogeneous core oil-displacing experiment, and the crude oil recovery rate can be increased by 10% or above.

The invention discloses a method for preparing nano vaterite calcium carbonate from carbonized carbide slag. The method comprises the following steps: 1) pretreatment of raw materials: drying the carbide slag, and grinding the carbide slag into powder for later use; 2) leaching: mixing the carbide slag, ammonium chloride and deionized water, stirring at normal temperature, reacting, and filtering to obtain filter residue and calcium-containing filtrate; and 3) carbonization reaction: introducing the calcium-containing filtrate obtained in the step 2) into an external circulation supergravity reactor, introducing CO2 gas at the same time, carbonizing at normal temperature, and filtering, washing and drying to obtain the nano vaterite type calcium carbonate. The method aims at the problems that in an existing process for preparing vaterite calcium carbonate from carbide slag, product particle size distribution is large, production efficiency is low, and additives are needed, and nano vaterite type calcium carbonate with the small particle size (50-80 nm) and uniform distribution can be efficiently prepared.

The invention relates to the technical field of emergency treatment of marine ecological disasters, and provides an algae remover for emergency treatment of red tide and a preparation method of the algae remover. The algae remover comprises the following raw materials in parts by weight: 70-90 parts of clay, 10-40 parts of an inorganic flocculant and 0.02-1 part of an organic flocculant. The organic flocculating agent comprises poly dimethyl diallyl ammonium chloride and polyvinyl alcohol; the mass ratio of the poly dimethyl diallyl ammonium chloride to the polyvinyl alcohol is 10: (1-8). According to the technical scheme, the problem of low red tide organism removal rate of an algae remover in related technologies is solved.

The invention discloses a process and equipment for recovering platinum and palladium from a petroleum catalyst, and relates to the field of metal material recovery, carbon-supported platinum group noble metals platinum and palladium are recovered by using the patent technology, firstly, fine grinding, hydrolysis and filtration are performed, then a reducing agent is adopted for reduction, then acidification and filtration are performed to remove base metals, and hydrochloric acid and nitric acid solutions are adopted for leaching and saltpeter removal, so that the platinum and palladium are recovered. The high-purity palladium powder is prepared from the solution subjected to platinum precipitation through ammonium chloride platinum precipitation, ammonium chloroplatinate hydrazine hydrate reduction, high-purity platinum powder and ammonia water palladium precipitation and hydrazine hydrate reduction, the purposes of saving energy and reducing the production cost are achieved, the ashing roasting furnace is adopted for static ashing, the technology process is simplified, the platinum group precious metal recovery rate is high, and the smelting cost is low. And the quality and purity of the platinum-palladium product are high, the metal recovery rate is high, and the smelting cost is low.