1467 results about "Ammonium chloride mixture" patented technology

The invention relates to the technical field of oilfield chemistry, and discloses a graft modified cellulose filtrate reducer and a preparation method thereof.The preparation method comprises the following steps that modified hydroxyethyl cellulose, 2-acrylamide-2-methyl propane sulfonic acid, dimethyl diallyl ammonium chloride, alkenylated cardanol and N, N '-methylene bisacrylamide are added into deionized water, stirring is conducted, and a mixture is obtained; the preparation method comprises the following steps: adding cellulose into a reaction kettle, stirring for 10-15 minutes at the temperature of 40-60 DEG C at the speed of 300-400 rpm, dropwise adding ammonium persulfate and sodium hydrogen sulfite into a system, and continuously reacting for 4-6 hours to obtain the grafted modified cellulose filtrate reducer. The filtrate reducer disclosed by the invention has good high temperature resistance and salt resistance.

The invention discloses a composite clarifying agent for alkali-free glass and a manufacturing method of an alkali-free glass substrate, and relates to the technical field of glass manufacturing, the composite clarifying agent for alkali-free glass comprises the following components by mass: 12-30% of ammonium chloride, 48-73% of sulfate, and 11-25% of calcium fluoride; the preparation method comprises the following steps: adding a composite clarifying agent accounting for 0.2-1.2% of the total weight of the glass raw material into the glass raw material, uniformly mixing to form a batch, and carrying out melting, molding, spraying, annealing, cutting, alkali cleaning and other processes on the batch to finally prepare the glass substrate. The prepared composite clarifying agent does not contain toxic substances such as arsenic oxide and antimony oxide, the glass substrate produced by using the clarifying agent not only has an excellent clarifying effect, but also can recycle SO2 and NH3 gas generated in the melting process, can effectively solve the quality problems such as micro-flaws on the surface of the glass substrate in the production process, and has a good application prospect. And the production cost can be reduced and the product quality can be improved.

The invention discloses a fermentation medium for regulating and controlling a clostridium aerovorans target product and a fermentation method of the clostridium aerovorans target product. The medium comprises a basic component and a regulating component, the basic components comprise ammonium chloride, potassium chloride, magnesium sulfate heptahydrate, sodium chloride, monopotassium phosphate, yeast powder, calcium chloride dihydrate, sodium selenite, nickel chloride hexahydrate, biotin, folic acid, pyridoxine hydrochloride, thiamine, riboflavin, nicotinic acid, D-calcium pantothenate, cobalamin, para aminobenzoic acid and lipoic acid; the adjusting component comprises sodium tungstate, ferrous sulfate and sodium molybdate, sodium tungstate and ferrous sulfate have a forward adjusting effect on increasing the yield of acetic acid, ethanol and butanol in the target product, and sodium molybdate has a reverse adjusting effect on the target product. By optimizing the proportion of trace elements in the culture medium, the clostridium metabolism efficiency is improved, synthesis of a target product is regulated and controlled, and the method is particularly suitable for industrial production of acetic acid, ethanol, butanol and the like.

The invention discloses a preparation method of a mesoporous Zn-ZSM-5 molecular sieve for preparing aromatic hydrocarbon from methanol, and belongs to the technical field of synthesis of inorganic materials. Aiming at the problems that a conventional mesoporous Zn / ZSM-5 molecular sieve catalyst Zn blocks orifices, the mesoporous structure is disordered, the molecular sieve solid yield is low, a molecular sieve framework is seriously damaged and the like, the preparation method comprises the following steps: uniformly mixing zinc gluconate with an aluminum source, a silicon source and a template agent, putting the mixture into a closed reaction container, carrying out hydrothermal crystallization, and sequentially washing, drying and roasting to obtain the mesoporous Zn / ZSM-5 molecular sieve catalyst. The sodium type molecular sieve is obtained; the preparation method comprises the following steps: carrying out multiple ion exchange on a sodium type molecular sieve by using an ammonium chloride solution, and sequentially carrying out suction filtration, washing, drying and roasting to obtain the mesoporous Zn-ZSM-5 molecular sieve. According to the preparation method of the methanol-to-aromatic hydrocarbon Zn / ZSM-5 molecular sieve provided by the invention, the obtained molecular sieve is used in the methanol-to-aromatic hydrocarbon process, and has the characteristics of high carbon deposition resistance, high aromatic hydrocarbon selectivity, low Zn wastage rate and the like.

The invention discloses a high-elasticity regenerated polyester material for chemical fibers and a preparation method thereof, and relates to the technical field of high polymer material regeneration. The invention discloses a high-elasticity regenerated polyester material for chemical fibers. The composite material is prepared from the following raw materials in parts by weight: 8 to 12 parts of glass fiber, 0.2 to 0.4 part of silane coupling agent KH-550, 4 to 6 parts of absolute ethyl alcohol, 4 to 6 parts of aluminum hypophosphite, 2 to 4 parts of melamine cyanurate, 0.05 to 0.15 part of aryl sodium phosphate, 65 to 75 parts of modified regenerated polyester, 20 to 30 parts of modified bio-based elastomer, 5 to 10 parts of maleic anhydride grafted polyolefin elastomer, 0.3 to 0.8 part of antioxidant and 1 to 2 parts of carbon black master batch. 0.1 to 0.3 part of a silicone lubricant; and 5 to 10 parts of didodecyl dimethyl ammonium chloride. Through supercritical chain extension, nano grafting and gradient crystallization technologies, the mechanical property and elasticity of the regenerated polyester are improved. The modified bio-based elastomer, the flame retardant and the antistatic agent have a synergistic effect, so that the material has high elasticity, flame retardance and antistatic functions. The method is suitable for high-end application in the field of chemical fibers, realizes high-value recycling of waste polyester, and has remarkable environmental protection benefits.

The invention relates to the technical field of wastewater treatment, and provides a treatment method of glycine production wastewater. The treatment method of glycine production wastewater comprises the following steps: (1) rectifying glycine wastewater to recover methanol, adding dilute sulphuric acid to adjust the pH value to 2.5-3.0, stirring, and standing; (2) transferring the supernate into another container, adding a ZIF-8 modified material, stirring, standing, filtering, collecting filter residues and filtrate, washing the filter residues with diethyl ether, and recovering urotropine; and (3) evaporating and concentrating the filtrate under the vacuum condition of-0.08 MPa and the temperature of 50-60 DEG C, and separating out high-purity ammonium chloride crystals. According to the treatment method for the glycine production wastewater, the problem that an existing treatment method is poor in removal effect on urotropin in the glycine production wastewater is solved; and the treated glycine production wastewater reaches the discharge standard.

The invention relates to a super-flexible supercapacitor with a multi-layer seamless interlocking interface and a preparation method of the super-flexible supercapacitor. The super-flexible supercapacitor takes a carbon nanotube or a composite film thereof as an electrode; and polyanion gel (polyacrylamide / polyacrylic acid / poly (3-sulfonic acid propyl methyl acrylic acid potassium salt) and polycation gel (polyacrylamide / polyacrylic acid / poly (methacryloyloxyethyl trimethyl ammonium chloride) are used as the double-layer heterogeneous electrolyte. A covalent connection electrode / electrolyte interface is constructed through anchoring interface polymerization, and double-layer gel electrolyte with electrostatic attraction and mutual entanglement is constructed through in-situ polymerization, so that the super-flexible supercapacitor with a multi-layer seamless interlocking interface is realized. Compared with the prior art, the super capacitor has super-strong interface toughness and interface adhesion, can resist mechanical deformation including bending, folding, twisting, winding, extruding, knotting and the like, the capacity retention ratio is greater than 95% after the super capacitor is folded for hundreds of thousands of times, and the capacity retention ratio is greater than 89% after the super capacitor is circularly charged and discharged for hundreds of thousands of times.

The application belongs to the technical field of oil and gas field development, and provides a phase permeability improver, a fracturing fluid system containing the same, and respective preparation methods and applications. The phase permeability improver is obtained by copolymerization and hydrolysis of acrylamide AM, a functional monomer 2-acrylamido-2-methylpropanesulfonic acid AMPS, and cationic hydrophobic monomers A and B; the cationic hydrophobic monomer A is at least one of tetradecyl dimethyl allyl ammonium chloride, hexadecyl dimethyl allyl ammonium chloride, and octadecyl dimethyl allyl ammonium chloride; the cationic hydrophobic monomer B is at least one of methacryloyloxyethyl trimethyl ammonium chloride, acryloyloxyethyl trimethyl ammonium chloride, and acryloyloxyethyldimethyl benzyl ammonium chloride; the phase permeability improver and the fracturing fluid system containing the same can significantly reduce the water phase permeability after fracturing operation, while having a smaller influence on the oil phase permeability, and have a significant effect of stabilizing oil and controlling water, and can significantly improve the stable production effect of fracturing operation in a low-permeability oil reservoir.

The invention relates to the technical field of precious metal recovery, in particular to a process for separating precious metal from copper-nickel smelting waste, which comprises the following steps: crushing and grading the waste, adding a sulfuric acid solution containing etidronic acid, leaching, and washing, drying and crushing filter residues to obtain a pretreated material; mixing the pretreated material with a sodium peroxide-sodium carbonate composite flux, roasting, leaching with water, and filtering to obtain a filter residue B; adding a leaching agent containing hydrochloric acid, sodium chlorate and 1, 2-cyclohexanediamine tetraacetic acid into the filter residue B according to the ratio of 1: 3-1: 5, and filtering to obtain filtrate C and filter residue C; adjusting the pH value of the filtrate C to 1.5-2.5, adding an ethanol solution of sodium N, N-diethyldithiocarbamate, precipitating, washing and calcining to obtain sponge palladium; adding ammonium chloride into the filtrate D, precipitating and calcining to obtain sponge platinum; and leaching the filter residue C by using a hydrochloric acid-chloroauric acid mixed solution containing diphenylthiourea, and replacing and calcining zinc powder to obtain crude gold. According to the process, the leaching rates of platinum, palladium and gold and the product purity are greatly improved; flux and reagent systems are optimized, consumption and energy consumption are reduced, waste liquid treatment is matched for up-to-standard discharge, and efficient resource recovery and environment-friendly cooperation are achieved.

The invention discloses an alkaline medium-coarsening micro-etching solution as well as a preparation method and a micro-etching method thereof, and relates to the technical field of printed circuit board production. The alkaline medium-coarsening micro-etching liquid is prepared from the following components in mass concentration: 5-30 g / L of ammonium chloride, 0.5-2 g / L of tetramethylammonium hydroxide, 5-15 g / L of ammonia water, 2-10% of a catalyst, 0.1-1% of a wetting agent, 0.2-2% of an accelerator, 0.3-1.5% of a stabilizer, 0.5-5% of a color difference regulator and the balance of deionized water. The invention provides an alkaline medium-coarsening micro-etching solution and a preparation method and a micro-etching method thereof, which can solve the problem of color change of a board surface after micro-etching of a circuit board and overcome the defect that a sulfuric acid hydrogen peroxide micro-etching system is easily polluted by chloride ions, and can effectively improve the problem that hydrogen peroxide is easily decomposed by replacing sulfuric acid hydrogen peroxide with an alkaline substance. And the micro-etching rate is stable.

The invention discloses a method for preventing ammonium chloride from sublimating and escaping in the roasting process, and belongs to the field of chemical metallurgy. The method comprises the following steps: uniformly mixing the alkaline chemical metallurgical material and ammonium chloride, grinding, and carrying out compression molding to obtain compact ore balls or ore grains, and roasting the compact ore balls or ore grains. In the heating and roasting process of the dense ore balls or the ore grains, HCl generated by thermal decomposition of ammonium chloride cannot escape, so that the HCl reacts with alkaline substances in the alkaline chemical metallurgical materials to be converted into chloride, the chloride absorbs ammonia and is converted into ammonochloride, and the ammonochloride on the surface layer of the dense ore balls or the ore grains is thermally decomposed to release NH3; the method has the advantages of being economical, efficient, clean, environmentally friendly and the like, and is suitable for large-scale industrial production of roasting of the alkaline chemical metallurgical material ammonium chloride.

The invention provides a method for synthesizing high-valued amorphous calcium carbonate through carbon sequestration of carbide slag, and belongs to the technical field of carbon sequestration and high-valued utilization of industrial solid waste resources. The method comprises the following steps: carrying out active calcium extraction reaction on a dried and ball-milled carbide slag aqueous solution through ammonium chloride, stirring and filtering to obtain a calcium-containing solution; the method comprises the following steps: adding a certain amount of absolute ethyl alcohol and magnesium chloride into a calcium-containing solution, fully stirring, adjusting the pH value to a certain value, and introducing CO2 gas for mineralization reaction to obtain a turbid liquid containing calcium carbonate precipitate; and carrying out centrifugal separation, alcohol washing and drying on the turbid liquid to obtain powder calcium carbonate. According to the method disclosed by the invention, the calcium carbide slag active calcium liquid is extracted by adopting ammonium chloride, and absolute ethyl alcohol-magnesium chloride is added to precisely regulate and control the reaction steps of CO2 and the extracted calcium liquid, so that the CO2 is efficiently fixed, and meanwhile, mineralization is performed to obtain a mixed crystal type amorphous nano calcium carbonate product. According to the technology, double targets of synthesizing high-valued calcium carbonate through carbide slag carbon sequestration are achieved, and an innovative technical path is invented for current solid waste resource utilization.

The invention relates to the technical field of chemical fiber manufacturing, in particular to a preparation process of graphene reinforced porous hollow polyester fibers. The problems that existing polyester fibers are insufficient in mechanical property and poor in moisture absorption and air permeability are solved. The preparation method comprises the following steps: modifying a PET sheet by using 2, 2-dimethylolpropionic acid and hydroxyl-terminated polydimethylsiloxane to obtain modified PET; the preparation method comprises the following steps: taking chitosan modified graphene as a carrier, and loading metal ions to obtain loaded graphene; polyethylene glycol and sodium bicarbonate are used as pore-foaming agents; modifying octadecyl dimethyl allyl ammonium chloride to obtain an antibacterial toughening agent; all the components are mixed, and the polyester fiber is prepared through melt spinning, stretching, heat treatment and alkali treatment. The mechanical property of the fiber is improved through the introduction of graphene and the modification treatment of the PET sheet; by utilizing the composite pore-foaming agent and adjusting the process, the moisture absorption and air permeability of the fiber are improved, and the service life of the fiber is prolonged.

The invention discloses a mildew-proof cosmetic alcohol-permeable adhesive and a preparation process thereof, and relates to the technical field of dealcoholized silicone adhesives, the mildew-proof cosmetic alcohol-permeable adhesive comprises the following components: 80-100 parts of alkoxy-terminated polydimethylsiloxane, 7-20 parts of a plasticizer, 6-18 parts of a filler, 0.6-3.5 parts of fumed silica, 5-15 parts of a cross-linking agent, 1.2-2.0 parts of a mildew-proof agent, and 0.2-2.5 parts of a catalyst. According to the invention, alkoxy-terminated polydimethylsiloxane is used as a main component, siloxane is used as a cross-linking agent, and a plasticizer and a filler are added to prepare the alcohol-permeable adhesive. Morpholinyl siloxane and ammonium chloride siloxane can be selectively added into the cross-linking agent, quaternized modified silicone oil and a synergistic mildew inhibitor are added into the plasticizer, so that the alcohol-permeable adhesive can play antibacterial and mildew-proof effects, has relatively good broad-spectrum and rapid bactericidal activity and thermal stability, and also has a lasting mildew-proof effect in a humid environment.

The invention discloses a cationic polymer acid-resistant thickening agent as well as a preparation method and application thereof, and belongs to the technical field of oil-gas field development. The polymer thickening agent is prepared from the following components in percentage by mass: 65 to 85 weight percent of acrylamide, 15 to 35 weight percent of methacryloyloxyethyl trimethyl ammonium chloride, 0.01 to 0.05 weight percent of dicationic functional monomer and 1 to 8 weight percent of cosolvent, the acid liquor system comprises the following components in percentage by mass: 5wt%-30wt% of solid acid, 0.01 wt%-0.6 wt% of a cationic polymer acid-resistant thickener, 0.5 wt%-5.0 wt% of a corrosion inhibitor, 0.3 wt%-1.0 wt% of an iron ion stabilizer and the balance of water; wherein the solid acid consists of 5wt%-15wt% of a solid metal catalyst and 85wt%-95wt% of solid particle acid; the acid liquid system has excellent slow release performance, is simple in formula, convenient to transport, low in cost and suitable for site construction, and has wide market prospects.

The invention discloses a method for producing p-coumaric acid through double-enzyme cascade catalysis, which comprises the following steps: taking phenol, pyruvic acid and ammonium chloride as substrates, and carrying out cascade enzyme catalytic reaction on a tyrosine phenol lyase product and a tyrosine ammonia lyase product to synthesize p-coumaric acid. According to the method, phenol, pyruvic acid and ammonium chloride are used as substrates, a tyrosine phenol lyase product and a tyrosine ammonia lyase product are used as catalysts, the tyrosine phenol lyase product can convert the substrates into L-tyrosine, and the tyrosine ammonia lyase product can directly use the L-tyrosine as the substrate to convert the L-tyrosine into p-coumaric acid. Therefore, the tyrosine phenol lyase product and the tyrosine ammonia lyase product can realize cascade enzyme catalytic reaction in the same reactor, phenol with lower cost can be adopted as a conversion substrate, separation and purification of an intermediate product L-tyrosine are avoided, and the whole process flow is simple and efficient.

The invention relates to a method for prolonging the fresh-keeping storage period of garlic, belongs to the technical field of food fresh keeping, and provides a collaborative fresh-keeping method based on double-layer coating and low-temperature regulation aiming at the problems of short fresh-keeping period, quality reduction and the like caused by improper humidity control, microorganism breeding and germination in traditional garlic storage. The method is characterized by comprising the following steps: selecting damage-free garlic, pre-cooling and drying in the shade, and sequentially immersing the garlic into an inner-layer film coating liquid and an outer-layer film coating liquid, the inner-layer film coating liquid is prepared by compounding 8-12 mmol / L glycine betaine and 400-600 [mu] mol / L melatonin according to a ratio of (0.8-1.2): 1, the outer-layer film coating liquid is prepared from 1.5-2.5 wt% of sodium alginate, 1-1.5 wt% of hydroxypropyl trimethyl ammonium chloride chitosan, 0.2-0.5 wt% of nano zinc oxide and 0.1-0.3 wt% of calcium chloride, and the outer-layer film coating liquid is prepared from 1-1.5 wt% of sodium alginate, 1-1.5 wt% of hydroxypropyl trimethyl ammonium chloride chitosan, 0.2-0.5 wt% of nano zinc oxide and 0.1-0.3 wt% of calcium chloride. And filling the coated garlic into a mesh bag with the aperture of 0.08-0.12 cm, and storing in a refrigeration house with the temperature of 0-1 DEG C and the humidity of 65-75%. According to the method, water loss and microorganism breeding are inhibited through the composite coating, the storage period of garlic can be remarkably prolonged, the plumpness and flavor of garlic cloves are kept, and the method is suitable for large-scale storage and cold-chain transportation scenes.

The invention relates to the technical field of synthesis of chemical products, in particular to a synthesis method of acryloyloxyethyl trimethyl ammonium chloride. According to the method, a one-pot reaction system is adopted, ethyl acrylate and N, N-dimethylaminoethanol are taken as raw materials and are subjected to quaternization reaction with chloromethane under an alkaline condition, and efficient conversion is realized through the synergistic effect of a composite catalytic system and a polymerization inhibitor. The composite catalyst is constructed by compounding magnetic nanoparticles and a metal organic framework material, forms a multilevel structure through titanate crosslinking, and has high catalytic activity and magnetic separation and recovery characteristics. The method simplifies the traditional step-by-step process, has the advantages of simple and convenient one-pot operation, recyclable catalyst, high raw material utilization rate, environmental friendliness and the like, and is suitable for large-scale preparation of acryloyloxyethyl trimethyl ammonium chloride.

The invention discloses a preparation method of a coal slime water treatment flocculant, and relates to the technical field of wastewater treatment.The preparation method comprises the following steps that modified polyacrylamide, modified chitosan, polymeric chloride and water are mixed and stirred by weight, and the coal slime water treatment flocculant is obtained; the modified polyacrylamide is obtained by physically blending a nano cellulose based TiO2 nano composite material and polyacrylamide; the modified chitosan is obtained by grafting N-benzyl-2-(methylacryloyloxy)-N, N-dimethylethane-1-ammonium chloride after SiO2 and chitosan are hybridized through a silane coupling agent, and the modified chitosan is obtained by grafting N-benzyl-2-(methylacryloyloxy)-N, N-dimethylethane-1-ammonium chloride; through the synergistic interaction of the inorganic coagulant, the natural modified polymer and the nano composite material, multiple targets of efficient flocculation, broad-spectrum purification, environment friendliness and cost optimization in slime water treatment are achieved, and the composite material is particularly suitable for high-turbidity and high-organic-matter-load complex slime water quality or heavy metal-containing complex slime water quality and has remarkable industrial application potential.

The invention belongs to the field of luminescent materials, and relates to stimuli-responsive self-repairing fluorescent hydrogel. In particular to stimuli-responsive self-repairing fluorescent hydrogel as well as a preparation method and anti-counterfeiting application thereof. According to the method, firstly, hydrophobic anthryl fluorophore 9-anthracene methyl methacrylate is wrapped by an aggregate formed by a surfactant hexadecyl trimethyl ammonium chloride to form micelles, and then, a micelle solution and polymer monomers acrylic acid and zirconium chloride are subjected to free radical-initiated copolymerization to obtain the stimuli-responsive fluorescent hydrogel. The hydrogel has self-repairing capability and fluorescence stimulation response capability, and is expected to be applied to the fields of bionic intelligent materials and information.

The application relates to the technical field of adhesives, and discloses a low-VOC flame-retardant double-faced adhesive for automobile interiors and a preparation method thereof. In the application, tetramethyl ethylene (epoxy propyl ammonium chloride) and bis (4-aminophenyl) -phenyl phosphate are reacted to obtain a cationic flame retardant, which is then added into a water-based acrylic resin emulsion to obtain a flame-retardant water-based acrylic resin adhesive and a flame-retardant double-faced adhesive. The cationic groups in the cationic flame retardant and the sodium carboxylate anions in the water-based acrylic resin form electrostatic force, the crosslinking degree between acrylic resin molecular chains is improved, the cohesion is increased, and the bonding performance and tensile shear strength of the adhesive are improved. The cationic flame retardant contains a triphenyl phosphate flame-retardant structure, has condensed-phase flame-retardant effect, improves the limiting oxygen index and the flame-retardant performance of the adhesive, and has good practical application in adhesives for new energy vehicles, double-faced adhesives and the like.

The invention belongs to the technical field of petroleum drilling engineering, and discloses a chitosan-quaternary ammonium salt modified composite shale inhibitor and a preparation method thereof. According to the inhibitor, natural chitosan is used as a main chain, dimethyl diallyl ammonium chloride (DMDAAC) is adopted for free radical grafting modification, glycine is combined as a synergistic auxiliary agent, and a composite structure with high cation density is constructed. The preparation method comprises the following steps: dissolving 15-25 parts of chitosan in 1000 parts of 1% glacial acetic acid, and stirring at room temperature; dropwise adding 2 to 4 parts of DMDAAC, reacting at 65 to 75 DEG C, and then adding 0.1 to 1 part of ammonium persulfate for grafting for 3.5 to 4.5 hours; and cooling, filtering and drying to obtain powder. And dissolving 10-20 parts of the solution in deionized water, adding 1.5-2.5 parts of glycine, and uniformly mixing to obtain the composite inhibition liquid. The inhibitor has good water solubility and thermal stability, can significantly inhibit shale hydration expansion and particle dispersion, and experiments show that the inhibitor can be suitable for well wall stability control of complex stratums such as high-temperature deep wells and the like, and has good field adaptability and industrial popularization value.

The present invention relates to a cationic carrier and application thereof of a loadable cosmetic lipophilic active substance. The raw material of the cationic carrier includes an aqueous solution of a nonionic emulsifier, silk fibroin nanofiber and cocamidopropyl PG-dimethyl ammonium chloride phosphate, wherein the mass ratio of the nonionic emulsifier, the aqueous solution and the cocamidopropyl PG-dimethyl ammonium chloride phosphate is 1:(1.5~5):(0.7~2), and the content of β-folding in the silk fibroin nanofiber is 25%~45%. The cationic carrier provided by the present invention has a stronger lipophilic active substance loading capacity, and the cationic inclusion containing the cationic carrier has better permeability, stability and mildness simultaneously, and has broad application prospects.

The invention belongs to the technical field of microbial culture, and particularly relates to a culture medium composition and application thereof in PDRN recombinant escherichia coli fermentation. The culture medium composition comprises a fermentation culture medium and a fed-batch culture medium, the fermentation culture medium consists of disodium hydrogen phosphate, monopotassium phosphate, ammonium sulfate, magnesium chloride, calcium nitrate tetrahydrate, glycerol and water; the supplemented culture medium is composed of dipotassium phosphate, sodium dihydrogen phosphate, sodium sulfate, ammonium sulfate, ammonium chloride, diammonium hydrogen citrate, glycerin and water, and the metabolic requirements of PDRN recombinant escherichia coli are accurately matched. Meanwhile, the invention provides a fermentation method using the composition, and the problems of unbalanced nutrition, low fermentation efficiency and the like of an existing culture medium are solved. Stable proliferation of thalli can be remarkably promoted, the yield of PDRN products is increased, the culture medium is easy and convenient to prepare, fermentation conditions are easy to control, and the culture medium is suitable for industrial large-scale production and has important application value.

The invention relates to the field of textiles, and particularly discloses a preparation process of antibacterial fibers, which comprises the following steps: S1, respectively drying and preparing polymer slices and an antibacterial agent; s2, performing melt spinning on the polymer slices and an antibacterial agent, performing air cooling, and then performing traction and winding to obtain antibacterial fibers; wherein the antibacterial agent is prepared by mixing dodecyl trimethyl ammonium chloride, polyvinylpyrrolidone and core-shell type antibacterial particles according to the mass ratio of (0.4-0.5): (0.1-0.2): 1, the core-shell type antibacterial particles are prepared by loading nano-zinc oxide and nano-silver particles on intercalation modified montmorillonite and then forming a silicon dioxide coating layer through a sol-gel method, and the core-shell type antibacterial particles are prepared from the silicon dioxide coating layer through a sol-gel method. And carrying out spray drying to obtain the core-shell antibacterial particles. The preparation method has the characteristic of improving the antibacterial durability and uniformity of the antibacterial fiber.

The invention discloses application of a carbon steel corrosion inhibitor based on combination of physical adsorption, chemical adsorption and hydrophobic barrier, and relates to the technical field of metal corrosion inhibition. The technical problem that a corrosion inhibitor in the prior art is low in corrosion inhibition efficiency in a high-temperature strong-acid environment is solved. The preparation method of the carbon steel corrosion inhibitor comprises the following steps: firstly, ultrasonically dissolving 4-aminopyridine to obtain a solution I; then, dropwise adding an isopropanol solution of 2, 3-epoxypropyltrimethylammonium chloride into the solution I according to a molar ratio of 1: 1, removing a solvent through a rotary evaporation method, washing with ethanol, centrifuging to obtain quaternized 4-aminopyridine, and drying the quaternized 4-aminopyridine; and finally, the dried quaternized 4-aminopyridine and bromododecane are added into acetonitrile for a reaction, diethyl ether is dropwise added into obtained reaction liquid for precipitation, and the quaternized 4-aminopyridine-bromododecane carbon steel corrosion inhibitor is obtained after drying. The prepared carbon steel corrosion inhibitor is high in corrosion inhibition efficiency in a high-temperature and strong-acid environment.

The invention relates to the field of dry strength agents, and discloses a nano-cellulose modified novel reinforced dry strength agent, which is prepared from the following raw materials in parts by weight: 10 to 20 parts of nano-cellulose, 30 to 50 parts of acrylamide, 10 to 20 parts of methacryloyloxyethyl trimethyl ammonium chloride, 5 to 15 parts of dimethylaminoethyl methacrylate, 3 to 8 parts of itaconic acid, 3 to 8 parts of sodium methallyl sulfonate, 3 to 8 parts of N, N-dimethylformamide, 3 to 8 parts of sodium dodecyl benzene sulfonate, 3 to 8 parts of sodium dodecyl benzene sulfonate, 3 to 8 parts of sodium dodecyl benzene sulfonate, 3 to 8 parts of sodium dodecyl benzene sulfonate, 3 to 8 parts of sodium dodecyl benzene sulfonate and 5 to 10 parts of sodium dodecyl benzene sulfonate. 5 to 15 parts of N, N-dimethylacrylamide, and 5 to 15 parts of 2-acrylamido-2-methylpropanesulfonic acid. Nano cellulose is used as a core reinforcing component, by means of the nanoscale size and high reaction activity, a surface group and fibers form a hydrogen bond and are chemically bonded with a polymeric monomer, a three-dimensional network structure is constructed among the fibers, and electrostatic adsorption of a cationic monomer and the crosslinking effect of a polar group are cooperated, so that the binding force among the fibers of the paper is improved; and the tensile property is obviously enhanced.

The invention discloses a functional and recoverable vegetable protein adhesive with high strength and toughness and a preparation method of the functional and recoverable vegetable protein adhesive. The adhesive is prepared from the following components in parts by mass: 30 parts of soybean protein, 4 to 7.5 parts of acrylamide, 0.5 to 4 parts of methacryloyloxyethyl trimethyl ammonium chloride, 1 to 3 parts of a peptide self-assembly cross-linking agent, 1.6 parts of ammonium persulfate, 5 parts of a metal-polyphenol catalyst and 65 parts of a dispersion medium. The preparation method comprises the following steps: weighing the components in proportion, dispersing the acrylamide, the methacryloyloxyethyl trimethyl ammonium chloride, the peptide self-assembly cross-linking agent and the ammonium persulfate in a medium, uniformly stirring, adding the soybean protein, finally adding the metal-polyphenol catalyst, and uniformly dispersing. The self-assembled amphiphilic peptide fiber is introduced as a dynamic cross-linking agent, and a multi-stage energy dissipation structure is constructed in the adhesive, so that the mechanical strength, the toughness and the function customizability of the adhesive are remarkably improved, and meanwhile, room-temperature polymerizability, recoverability and reprocessing are realized.

The invention provides a high-barrier nanocellulose-based composite liquid mulching film and a preparation method thereof.The preparation method comprises the steps that sodium periodate is added into a sodium alginate solution for an oxidation reaction, an oxidized sodium alginate solution is obtained, a chitosan solution is added into the oxidized sodium alginate solution, and a composite solution is obtained after uniform mixing; mixing the nanocellulose solution with the composite solution, dropwise adding an ammonia water solution to adjust the pH value, and carrying out a cross-linking reaction to obtain a matrix solution; the preparation method comprises the following steps: dissolving 2-acrylamido-2-methylpropanesulfonic acid and methacryloyloxyethyl trimethyl ammonium chloride in deionized water to obtain a precursor solution, and adding an initiator into the precursor solution for copolymerization to obtain a zwitterionic polymer; adding a zwitterionic polymer into the Na-montmorillonite dispersion liquid for intercalation reaction to obtain modified montmorillonite; and uniformly mixing the matrix solution, the modified montmorillonite, the plasticizer, the rheology modifier and the surfactant, and then carrying out standing curing and vacuum defoaming.

The invention relates to the technical field of polyester degradable plastics, and discloses a biodegradable shrink film as well as a preparation method and application thereof. The preparation method of the biodegradable shrink film comprises the following steps: reacting (R)-3-hydroxybutyric acid with 1, 4-dibromobutane to obtain a dihydric alcohol monomer; the preparation method comprises the following steps: copolymerizing a dihydric alcohol monomer and L-lactide to obtain modified polylactic acid; carrying out copolymerization on the geraniol-based compound and L-lactide to obtain a bio-based plasticizer; modifying the bio-based plasticizer with allyl trimethyl ammonium chloride to obtain a modified bio-based plasticizer; the biodegradable shrink film is prepared by taking modified polylactic acid, poly (butylene adipate-co-terephthalate), a modified bio-based plasticizer, a functional filler and palm wax as raw materials. The biodegradable shrink film has the advantages of flexibility, shrinkage performance, lasting antibacterial performance and good barrier performance, and can be used in food packaging materials.