The invention relates to a process for recovering
sulfuric acid and
sulfate from waste acid generated in the preparation of
titanium dioxide by using a
sulfuric acid method, belonging to the technical field of waste
acid treatment in the industrial production. The invention recovers
sulfuric acid and
sulfate products from waste acid generated in the production process for preparing the
titanium dioxide by using the sulfuric acid method through the
sedimentation pretreatment and the simple process including the first segment of
flash evaporation-
crystallization, concentration and separation, the second segment of
vacuum evaporation, concentration and separation and the third segment of
vacuum evaporation, concentration and separation. The invention has simple process, convenience of operation, simple equipment, high performance
price ratio and high yield,
high concentration and less impurities of the product acid, can recycle resources without waste liquid or waste residue emission and can be favorable to
environmental protection and energy saving, and emitted exhaust mainly contains air and less vapor, is non-toxic to the environment and can effectively overcome the difficulties of
fouling and clogging of the equipment. The invention can be widely applied to the
recovery of waste acid in the industrial production and be particularly suitable for recovering the waste acid generated in the preparation of
titanium dioxide by using the sulfuric acid method.