The invention discloses a
perovskite thin film based on functionalized aromatic
amide micromolecules and a preparation method and application thereof, and the preparation method comprises the steps: introducing the micromolecules into a
perovskite precursor solution, replacing a traditional anti-
solvent process with a mild and controllable
gas quenching method, and achieving the preparation of a wide-
band gap perovskite thin film with highly uniform
initial distribution of a
halogen phase. According to the technology, the separation rate of the
bromine element is selectively delayed, the
crystallization process is optimized, the
crystallization quality of the thin film and the carrier transmission efficiency are remarkably improved, meanwhile, the problem of
halogen phase segregation caused by
ion migration can be inhibited through the continuous
passivation effect of small molecules, and the device has high efficiency and long-term working stability. According to the process, harmful substance
pollution and
raw material waste are reduced, the homogeneous film forming characteristic can be expanded to the field of preparation of perovskite / organic laminated cells and large-area assemblies, and a new path is provided for development of efficient and stable photoelectric devices.