The invention relates to the technical field of high-flux
photonics materials, in particular to a Sb < 3 + >-doped Cs3LnCl6 zero-dimensional
nanocrystal as well as a preparation method and application thereof. The
chemical formula of the Sb < 3 + >-doped Cs3LnCl6 zero-dimensional
nanocrystal is Cs3Ln1-xSbxCl6, x ranges from 0.005 to 0.1, Ln is selected from at least one of Y, Nd, Sm, Eu, Gd, Tb, Dy, Ho, Er, Tm, Yb and Lu, and the Sb < 3 + >-doped Cs3LnCl6 zero-dimensional
nanocrystal has the
chemical formula of Cs3Ln1-xSbxCl6. The material has a zero-dimensional structure of a C2 / c
space group, and is composed of an isolated [BCl6] 3-
octahedron and a gap Cs < + >, the zero-dimensional nanocrystal has a deep trap state of 0.6 eV to 1.2 eV. Through zero-dimensional [BCl6] 3-
octahedron lattice rigidity and deep trap
carrier recovery, high-temperature anti-
thermal quenching can be realized without external
coating, and the problem of external
passivation-performance side effects of the existing material is solved.