The invention belongs to the technical field of LED luminescent materials, and relates to a preparation method of red fluorescent
powder, the general formula of the red fluorescent
powder is M2SiF6: Mn < 4 + >, M is K or Na, and the preparation method comprises the following steps: S1, reacting to generate
potassium fluoromanganate, washing and
drying; s2, crushing the dried
potassium fluoromanganate; s3, adding a
hydrofluoric acid solution into the
autoclave, then adding
potassium fluosilicate or
sodium fluosilicate, and fully stirring and dissolving; s4, adding the potassium fluoromanganate crushed in the step S2 into the solution obtained in the step S3 to serve as a
seed crystal; s5, adding a
crystal form control agent, heating, pressurizing, stirring and reacting, and then cooling, decompressing and recrystallizing; and S6, filtering the recrystallization liquid to obtain a pink product, cleaning,
drying and sieving to obtain the product. The red fluorescent
powder disclosed by the invention is large in
granularity, good in
dispersity, high in
crystallinity, high in brightness and good in
aging resistance; the absorption peak requirement of the light conversion material based on the LED is completely met, the cost is low, and the process is simple.